CN109266264A - A kind of low-temperature setting fabric flocking stick - Google Patents
A kind of low-temperature setting fabric flocking stick Download PDFInfo
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- CN109266264A CN109266264A CN201810977412.9A CN201810977412A CN109266264A CN 109266264 A CN109266264 A CN 109266264A CN 201810977412 A CN201810977412 A CN 201810977412A CN 109266264 A CN109266264 A CN 109266264A
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- mass parts
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- emulsifying agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/02—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to polysaccharides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/08—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of low-temperature setting fabric flocking sticks, including following raw material and its weight fraction: methacrylic acid is 20-25 mass parts；Methyl methacrylate is 5-8 mass parts；Butyl acrylate is 10-15 mass parts；Phthalazinone polyarylether is 5-10 mass parts；Acryloyl-beta-cyclodextrin ester is 6-11 mass parts；Multiple crosslinking agent is 2-4 mass parts；Ammonium nitrate is 2-4 mass parts；Crossing sodium hydrogensulfite is 6-8 mass parts；Compound emulsifying agent is 6-12 mass parts and appropriate amount of deionized water.The compound emulsifying agent that the present invention uses is good to the emulsifying effectiveness of raw material, the stability in stick preparation process can effectively be enhanced, extend the storage time of stick, reduce the processing step in stick preparation process and the cost of preparation, and the present invention has preferable chemical stability, there is the effect for the ehter bond for improving macromolecular chain toughness again, improves the heat resistance of stick.
Description
Technical field
The present invention relates to flocking stick technical field, specially a kind of low-temperature setting fabric flocking stick.
Background technique
Fabric flocking is adhesive in textile industry and is also referred to as electrospinning, is former using the electrostatic induction of high-pressure electrostatic electric field
Villus is planted a kind of technology to various body surfaces, is important application one of of the electrostatic technique in textile industry by reason.Electrostatic is planted
Suede is will to be placed in negatively charged container to flocking hair with the physical characteristic for denounceing different suction using charge, it is made to take negative electrical charge,
The object for needing flocking is put in zero potential or ground connection, mobile container makes negatively charged container and planted close to by flocking object
A high voltage electric field is formed between suede object, villus band is negative electrical charge, by different current potential by the attraction of flocking object, at vertical
State acceleration is flown on the surface for the object for needing flocking, and due to being coated with adhesive by flocking object, villus is just by vertical viscous plant
To on by plant.
Currently, there is also the places of some shortcomings for existing low-temperature setting fabric flocking stick, such as；Existing low temperature
Solidify in fabric flocking stick preparation process that compound emulsifying agent is poor to the emulsifying effectiveness of raw material, reduces stick preparation process
In stability, shorten the storage time of stick, improve the processing step in stick preparation process and the cost of preparation, and
And existing low-temperature setting fabric flocking stick chemical stability is poor, cannot improve the effect of the ehter bond of macromolecular chain toughness
Fruit reduces the heat resistance of stick.
Summary of the invention
The purpose of the present invention is to provide a kind of low-temperature setting fabric flocking sticks, solve proposed in background technique
Problem.
To achieve the above object, the invention provides the following technical scheme: a kind of low-temperature setting fabric flocking stick, including with
Lower raw material and its weight fraction: methacrylic acid is 20-25 mass parts；Methyl methacrylate is 5-8 mass parts；Acrylic acid
Butyl ester is 10-15 mass parts；Phthalazinone polyarylether is 5-10 mass parts；Acryloyl-beta-cyclodextrin ester is 6-11 quality
Part；Multiple crosslinking agent is 2-4 mass parts；Ammonium nitrate is 2-4 mass parts；Crossing sodium hydrogensulfite is 6-8 mass parts；Composite Milk
Agent is 6-12 mass parts and appropriate amount of deionized water.
As a kind of preferred embodiment of the invention, the low-temperature setting fabric flocking stick, including following raw material
And its weight fraction: methacrylic acid is 20 mass parts；Methyl methacrylate is 5 mass parts；Butyl acrylate is 10 mass
Part；Phthalazinone polyarylether is 6 mass parts；Acryloyl-beta-cyclodextrin ester is 8 mass parts；Multiple crosslinking agent is 3 mass parts and fits
Measure deionized water.
As a kind of preferred embodiment of the invention, the low-temperature setting fabric flocking stick, including following raw material
And its weight fraction: methacrylic acid is 20 mass parts；Methyl methacrylate is 5 mass parts；Butyl acrylate is 10 mass
Part；Phthalazinone polyarylether is 6 mass parts；Acryloyl-beta-cyclodextrin ester is 8 mass parts；Multiple crosslinking agent is 3 mass parts；Nitre
Sour ammonium is 2 mass parts；Crossing sodium hydrogensulfite is 8 mass parts；Compound emulsifying agent is 9 mass parts and appropriate amount of deionized water.
As a kind of preferred embodiment of the invention, the compound emulsifying agent includes following raw material and its weight fraction:
Isopropanol is 20-30 mass parts；Tetrasodium pyrophosphate is 1-3 mass parts；Methacrylic acid is 4-8 mass parts；Acrylic acid -2-
Ethylpropyl is 10-20 mass parts；Diethyl phthalate is 3-5 mass parts；Ammonium hydroxide is 1-3 mass parts and suitable
Water.
As a kind of preferred embodiment of the invention, steps are as follows for the compound emulsifying agent preparation method:
S1. first by isopropanol, tetrasodium pyrophosphate, methacrylic acid, acrylic acid-2-ethyl propyl ester, phthalic acid two
Ethyl ester and ammonium hydroxide weigh according to parts by weight；
S2. and then again by isopropanol, tetrasodium pyrophosphate, methacrylic acid, acrylic acid-2-ethyl propyl ester and phthalic acid
Diethylester is put into mixer, and suitable water is added and is mixed, and temperature when mixing is 34~45 DEG C, and the mixed time is
20-30min, be made mixed solution Q, then again by ammonium hydroxide along the inner wall of mixer be added slowly to mixer with mix
Solution Q is mixed, and compound emulsifying agent is made；
S3. finally compound emulsifying agent is put into container again and is cooled down.
As a kind of preferred embodiment of the invention, the low-temperature setting fabric flocking stick, preparation method step
It is as follows:
A. above-mentioned raw materials are weighed according to parts by weight first；
B. after the completion of step a, then methacrylic acid, methyl methacrylate and butyl acrylate is put into mixing and held
Suitable deionized water is added in device to be stirred, temperature when stirring is 20~30 DEG C, and the time of stirring is 10-15min,
Obtain mixed liquor A；
C. it after the completion of step b, then by ammonium nitrate and crosses sodium hydrogensulfite and is put into mixing vessel, be subsequently added into appropriate
Deionized water be stirred, obtain mixed liquid B；
D. after the completion of step c, then the mixed liquor A prepared and mixed liquid B is added to mixer and mixed, mixed
When temperature be 50~65 DEG C, the mixed time is 5-10min, then again pastes Phthalazinone polyarylether, acryloyl-β-ring
Smart ester, multiple crosslinking agent and compound emulsifying agent are added sequentially to mixer, then add suitable deionized water and are mixed,
Temperature when mixing is 70~85 DEG C, and the mixed time is 30-45min, and stick is made；
E. after the completion of step d, then stick is put into filter and is filtered, finally again by filtered stick into
Row cooling.
As a kind of preferred embodiment of the invention, ammonium nitrate and sodium hydrogensulfite proportion excessively are 3 in the step c:
7, speed when stirring is 350-500r/min.
Compared with prior art, beneficial effects of the present invention are as follows:
The compound emulsifying agent that the present invention uses is good to the emulsifying effectiveness of raw material, can effectively enhance in stick preparation process
Stability, extend the storage time of stick, reduce the processing step in stick preparation process and the cost of preparation, and
The present invention has preferable chemical stability, and has the effect for the ehter bond for improving macromolecular chain toughness, improves the heat-resisting of stick
Property.
Detailed description of the invention
Upon reading the detailed description of non-limiting embodiments with reference to the following drawings, other feature of the invention,
Objects and advantages will become more apparent upon:
Fig. 1 is a kind of flow chart of low-temperature setting fabric flocking stick of the present invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.
Referring to Fig. 1, the present invention provides a kind of technical solution: a kind of low-temperature setting fabric flocking stick, including following original
Material and its weight fraction: methacrylic acid is 20-25 mass parts；Methyl methacrylate is 5-8 mass parts；Acrylic acid fourth
Ester is 10-15 mass parts；Phthalazinone polyarylether is 5-10 mass parts；Acryloyl-beta-cyclodextrin ester is 6-11 mass parts；
Multiple crosslinking agent is 2-4 mass parts；Ammonium nitrate is 2-4 mass parts；Crossing sodium hydrogensulfite is 6-8 mass parts；Composite emulsifying
Agent is 6-12 mass parts and appropriate amount of deionized water.
Further, the low-temperature setting fabric flocking stick, including following raw material and its weight fraction: methacrylic acid
For 20 mass parts；Methyl methacrylate is 5 mass parts；Butyl acrylate is 10 mass parts；Phthalazinone polyarylether is 6 mass
Part；Acryloyl-beta-cyclodextrin ester is 8 mass parts；Multiple crosslinking agent is 3 mass parts and appropriate amount of deionized water.
Further, the low-temperature setting fabric flocking stick, including following raw material and its weight fraction: methacrylic acid
For 20 mass parts；Methyl methacrylate is 5 mass parts；Butyl acrylate is 10 mass parts；Phthalazinone polyarylether is 6 mass
Part；Acryloyl-beta-cyclodextrin ester is 8 mass parts；Multiple crosslinking agent is 3 mass parts；Ammonium nitrate is 2 mass parts；Cross bisulfite
Sodium is 8 mass parts；Compound emulsifying agent is 9 mass parts and appropriate amount of deionized water.
Further, the compound emulsifying agent includes following raw material and its weight fraction: isopropanol is 20-30 mass parts；
Tetrasodium pyrophosphate is 1-3 mass parts；Methacrylic acid is 4-8 mass parts；Acrylic acid-2- ethylpropyl is 10-20 quality
Part；Diethyl phthalate is 3-5 mass parts；Ammonium hydroxide is 1-3 mass parts and suitable water.
Further, steps are as follows for the compound emulsifying agent preparation method:
S1. first by isopropanol, tetrasodium pyrophosphate, methacrylic acid, acrylic acid-2-ethyl propyl ester, phthalic acid two
Ethyl ester and ammonium hydroxide weigh according to parts by weight；
S2. and then again by isopropanol, tetrasodium pyrophosphate, methacrylic acid, acrylic acid-2-ethyl propyl ester and phthalic acid
Diethylester is put into mixer, and suitable water is added and is mixed, and temperature when mixing is 34~45 DEG C, and the mixed time is
20-30min, be made mixed solution Q, then again by ammonium hydroxide along the inner wall of mixer be added slowly to mixer with mix
Solution Q is mixed, and compound emulsifying agent is made；
S3. finally compound emulsifying agent is put into container again and is cooled down.
Further, the low-temperature setting fabric flocking stick, steps are as follows for preparation method:
A. above-mentioned raw materials are weighed according to parts by weight first；
B. after the completion of step a, then methacrylic acid, methyl methacrylate and butyl acrylate is put into mixing and held
Suitable deionized water is added in device to be stirred, temperature when stirring is 20~30 DEG C, and the time of stirring is 10-15min,
Obtain mixed liquor A；
C. it after the completion of step b, then by ammonium nitrate and crosses sodium hydrogensulfite and is put into mixing vessel, be subsequently added into appropriate
Deionized water be stirred, obtain mixed liquid B；
D. after the completion of step c, then the mixed liquor A prepared and mixed liquid B is added to mixer and mixed, mixed
When temperature be 50~65 DEG C, the mixed time is 5-10min, then again pastes Phthalazinone polyarylether, acryloyl-β-ring
Smart ester, multiple crosslinking agent and compound emulsifying agent are added sequentially to mixer, then add suitable deionized water and are mixed,
Temperature when mixing is 70~85 DEG C, and the mixed time is 30-45min, and stick is made；
E. after the completion of step d, then stick is put into filter and is filtered, finally again by filtered stick into
Row cooling.
Further, ammonium nitrate and to cross sodium hydrogensulfite proportion be 3:7 in the step c, speed when stirring is 350-
500r/min。
Embodiment one
The low-temperature setting fabric flocking stick, including following raw material and its weight fraction: methacrylic acid is 20 matter
Measure part；Methyl methacrylate is 5 mass parts；Butyl acrylate is 10 mass parts；Phthalazinone polyarylether is 6 mass parts；Third
Alkene acyl-beta-cyclodextrin ester is 8 mass parts；Multiple crosslinking agent is 3 mass parts and appropriate amount of deionized water.
Steps are as follows for preparation method:
A. above-mentioned raw materials are weighed according to parts by weight first；
B. after the completion of step a, then methacrylic acid, methyl methacrylate and butyl acrylate is put into mixing and held
Suitable deionized water is added in device to be stirred, temperature when stirring is 20~30 DEG C, and the time of stirring is 10-15min,
Obtain mixed liquor A；
C. it after the completion of step b, then by ammonium nitrate and crosses sodium hydrogensulfite and is put into mixing vessel, be subsequently added into appropriate
Deionized water be stirred, obtain mixed liquid B；
D. after the completion of step c, then the mixed liquor A prepared and mixed liquid B is added to mixer and mixed, mixed
When temperature be 50~65 DEG C, the mixed time is 5-10min, then again pastes Phthalazinone polyarylether, acryloyl-β-ring
Smart ester, multiple crosslinking agent and compound emulsifying agent are added sequentially to mixer, then add suitable deionized water and are mixed,
Temperature when mixing is 70~85 DEG C, and the mixed time is 30-45min, and stick is made；
E. after the completion of step d, then stick is put into filter and is filtered, finally again by filtered stick into
Row cooling.
Embodiment two
The low-temperature setting fabric flocking stick, including following raw material and its weight fraction: methacrylic acid is 20 matter
Measure part；Methyl methacrylate is 5 mass parts；Butyl acrylate is 10 mass parts；Phthalazinone polyarylether is 6 mass parts；Third
Alkene acyl-beta-cyclodextrin ester is 8 mass parts；Multiple crosslinking agent is 3 mass parts；Ammonium nitrate is 2 mass parts；Crossing sodium hydrogensulfite is 8
Mass parts；Compound emulsifying agent is 9 mass parts and appropriate amount of deionized water.
Steps are as follows for preparation method:
A. above-mentioned raw materials are weighed according to parts by weight first；
B. after the completion of step a, then methacrylic acid, methyl methacrylate and butyl acrylate is put into mixing and held
Suitable deionized water is added in device to be stirred, temperature when stirring is 20~30 DEG C, and the time of stirring is 10-15min,
Obtain mixed liquor A；
C. it after the completion of step b, then by ammonium nitrate and crosses sodium hydrogensulfite and is put into mixing vessel, be subsequently added into appropriate
Deionized water be stirred, obtain mixed liquid B；
D. after the completion of step c, then the mixed liquor A prepared and mixed liquid B is added to mixer and mixed, mixed
When temperature be 50~65 DEG C, the mixed time is 5-10min, then again pastes Phthalazinone polyarylether, acryloyl-β-ring
Smart ester, multiple crosslinking agent and compound emulsifying agent are added sequentially to mixer, then add suitable deionized water and are mixed,
Temperature when mixing is 70~85 DEG C, and the mixed time is 30-45min, and stick is made；
E. after the completion of step d, then stick is put into filter and is filtered, finally again by filtered stick into
Row cooling.
Conventional fabrics flocking stick data parameters table 1 is as follows:
| Test item | Stability when preparation | Storage time | Preparation cost | Heat resistance |
| Parameter index | It is poor | It is short | It is high | It is poor |
One fabric flocking stick data parameters table 1 of embodiment is as follows:
| Test item | Stability when preparation | Storage time | Preparation cost | Heat resistance |
| Parameter index | Generally | Generally | Generally | Generally |
Two fabric flocking stick data parameters table 2 of embodiment is as follows:
| Test item | Stability when preparation | Storage time | Preparation cost | Heat resistance |
| Parameter index | Well | It is long | It is low | Well |
It to sum up states, is obtained referring to the data comparison of table 1, table 2 and table 3, can effectively be enhanced in stick preparation process
Stability extends the storage time of stick, reduces the processing step in stick preparation process and the cost of preparation, Er Qieben
Invention has preferable chemical stability, and has the effect for the ehter bond for improving macromolecular chain toughness, improves the heat resistance of stick.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention, for this field skill
For art personnel, it is clear that invention is not limited to the details of the above exemplary embodiments, and without departing substantially from spirit of the invention or
In the case where essential characteristic, the present invention can be realized in other specific forms.Therefore, in all respects, should all incite somebody to action
Embodiment regards exemplary as, and is non-limiting, the scope of the present invention by appended claims rather than on state
Bright restriction, it is intended that including all changes that fall within the meaning and scope of the equivalent elements of the claims in the present invention
It is interior.Any reference signs in the claims should not be construed as limiting the involved claims.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (7)
1. a kind of low-temperature setting fabric flocking stick, it is characterised in that: including following raw material and its weight fraction: methacrylic acid
For 20-25 mass parts；Methyl methacrylate is 5-8 mass parts；Butyl acrylate is 10-15 mass parts；Phthalazinone is poly-
Aryl oxide is 5-10 mass parts；Acryloyl-beta-cyclodextrin ester is 6-11 mass parts；Multiple crosslinking agent is 2-4 mass parts；Nitric acid
Ammonium is 2-4 mass parts；Crossing sodium hydrogensulfite is 6-8 mass parts；Compound emulsifying agent is 6-12 mass parts and appropriate deionization
Water.
2. a kind of low-temperature setting fabric flocking stick according to claim 1, it is characterised in that: including following raw material and its
Weight fraction: methacrylic acid is 20 mass parts；Methyl methacrylate is 5 mass parts；Butyl acrylate is 10 mass parts；It is miscellaneous
Naphthalene biphenyl polyarylether is 6 mass parts；Acryloyl-beta-cyclodextrin ester is 8 mass parts；Multiple crosslinking agent is 3 mass parts and goes in right amount
Ionized water.
3. a kind of low-temperature setting fabric flocking stick according to claim 1, it is characterised in that: including following raw material and its
Weight fraction: methacrylic acid is 20 mass parts；Methyl methacrylate is 5 mass parts；Butyl acrylate is 10 mass parts；It is miscellaneous
Naphthalene biphenyl polyarylether is 6 mass parts；Acryloyl-beta-cyclodextrin ester is 8 mass parts；Multiple crosslinking agent is 3 mass parts；Ammonium nitrate is
2 mass parts；Crossing sodium hydrogensulfite is 8 mass parts；Compound emulsifying agent is 9 mass parts and appropriate amount of deionized water.
4. a kind of low-temperature setting fabric flocking stick according to claim 1, it is characterised in that: the compound emulsifying agent packet
Include following raw material and its weight fraction: isopropanol is 20-30 mass parts；Tetrasodium pyrophosphate is 1-3 mass parts；Methacrylic acid
For 4-8 mass parts；Acrylic acid-2-ethyl propyl ester is 10-20 mass parts；Diethyl phthalate is 3-5 mass parts；Ammonia
Water is 1-3 mass parts and suitable water.
5. a kind of low-temperature setting fabric flocking stick according to claim 4, it is characterised in that: the compound emulsifying agent system
Steps are as follows for Preparation Method:
S1. first by isopropanol, tetrasodium pyrophosphate, methacrylic acid, acrylic acid-2-ethyl propyl ester, diethyl phthalate
It is weighed according to parts by weight with ammonium hydroxide；
S2. and then again by isopropanol, tetrasodium pyrophosphate, methacrylic acid, acrylic acid-2-ethyl propyl ester and phthalic acid diethyl
Ester is put into mixer, and suitable water is added and is mixed, and temperature when mixing is 34~45 DEG C, and the mixed time is 20-
30min is made mixed solution Q, ammonium hydroxide is then added slowly to mixer and mixed solution Q along the inner wall of mixer again
It is mixed, compound emulsifying agent is made；
S3. finally compound emulsifying agent is put into container again and is cooled down.
6. a kind of low-temperature setting fabric flocking stick according to claim 1, it is characterised in that: preparation method step is such as
Under:
A. above-mentioned raw materials are weighed according to parts by weight first；
B. after the completion of step a, then methacrylic acid, methyl methacrylate and butyl acrylate be put into mixing vessel
Suitable deionized water is added to be stirred, temperature when stirring is 20~30 DEG C, and the time of stirring is 10-15min, is obtained
Mixed liquor A；
C. after the completion of step b, then by ammonium nitrate and cross sodium hydrogensulfite be put into mixing vessel, be subsequently added into suitable go
Ionized water is stirred, and obtains mixed liquid B；
D. after the completion of step c, then the mixed liquor A prepared and mixed liquid B is added to mixer and mixed, when mixing
Temperature be 50~65 DEG C, the mixed time be 5-10min, then again by Phthalazinone polyarylether, acryloyl-beta-cyclodextrin ester,
Multiple crosslinking agent and compound emulsifying agent are added sequentially to mixer, then add suitable deionized water and are mixed, mixing
When temperature be 70~85 DEG C, the mixed time be 30-45min, be made stick；
E. after the completion of step d, then stick is put into filter and is filtered, finally again carried out filtered stick cold
But.
7. a kind of low-temperature setting fabric flocking stick according to claim 6, it is characterised in that: nitric acid in the step c
Ammonium and to cross sodium hydrogensulfite proportion be 3:7, speed when stirring is 350-500r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810977412.9A CN109266264A (en) | 2018-08-27 | 2018-08-27 | A kind of low-temperature setting fabric flocking stick |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810977412.9A CN109266264A (en) | 2018-08-27 | 2018-08-27 | A kind of low-temperature setting fabric flocking stick |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109266264A true CN109266264A (en) | 2019-01-25 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810977412.9A Pending CN109266264A (en) | 2018-08-27 | 2018-08-27 | A kind of low-temperature setting fabric flocking stick |
Country Status (1)
| Country | Link |
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| CN (1) | CN109266264A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100159185A1 (en) * | 2008-12-22 | 2010-06-24 | Illinois Tool Works Inc. | Applying a design on a textile |
| CN103290675A (en) * | 2013-05-16 | 2013-09-11 | 任芳芳 | Textile composite emulsifier |
| CN105542689A (en) * | 2016-02-29 | 2016-05-04 | 苏州纺友新材料有限公司 | Fabric flocking adhesive with low-temperature cured capacity |
-
2018
- 2018-08-27 CN CN201810977412.9A patent/CN109266264A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100159185A1 (en) * | 2008-12-22 | 2010-06-24 | Illinois Tool Works Inc. | Applying a design on a textile |
| CN103290675A (en) * | 2013-05-16 | 2013-09-11 | 任芳芳 | Textile composite emulsifier |
| CN105542689A (en) * | 2016-02-29 | 2016-05-04 | 苏州纺友新材料有限公司 | Fabric flocking adhesive with low-temperature cured capacity |
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Application publication date: 20190125 |