CN109239145A - 一种金纳米粒子/三维氧化锰/聚吡咯修饰玻碳电极的制备方法及应用 - Google Patents
一种金纳米粒子/三维氧化锰/聚吡咯修饰玻碳电极的制备方法及应用 Download PDFInfo
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- CN109239145A CN109239145A CN201810886020.1A CN201810886020A CN109239145A CN 109239145 A CN109239145 A CN 109239145A CN 201810886020 A CN201810886020 A CN 201810886020A CN 109239145 A CN109239145 A CN 109239145A
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- manganese oxide
- electrode
- carbon electrode
- gold nanoparticle
- moral
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- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 title claims abstract description 118
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims abstract description 56
- 229910052737 gold Inorganic materials 0.000 title claims abstract description 56
- 239000010931 gold Substances 0.000 title claims abstract description 56
- 239000002105 nanoparticle Substances 0.000 title claims abstract description 56
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 39
- 229920000128 polypyrrole Polymers 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims abstract description 88
- -1 benzene alkene Chemical class 0.000 claims abstract description 41
- 229910021397 glassy carbon Inorganic materials 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 21
- 238000002484 cyclic voltammetry Methods 0.000 claims abstract description 12
- 238000001903 differential pulse voltammetry Methods 0.000 claims abstract description 10
- 238000000835 electrochemical detection Methods 0.000 claims abstract description 10
- 238000004070 electrodeposition Methods 0.000 claims abstract description 9
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 9
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 8
- SJUCACGNNJFHLB-UHFFFAOYSA-N O=C1N[ClH](=O)NC2=C1NC(=O)N2 Chemical compound O=C1N[ClH](=O)NC2=C1NC(=O)N2 SJUCACGNNJFHLB-UHFFFAOYSA-N 0.000 claims abstract description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 30
- 239000008367 deionised water Substances 0.000 claims description 29
- 229910021641 deionized water Inorganic materials 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 239000000243 solution Substances 0.000 claims description 18
- 239000007864 aqueous solution Substances 0.000 claims description 16
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 16
- 235000019441 ethanol Nutrition 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 13
- 238000001514 detection method Methods 0.000 claims description 12
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 10
- 229910021607 Silver chloride Inorganic materials 0.000 claims description 8
- 229910052697 platinum Inorganic materials 0.000 claims description 8
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 8
- 229920000557 Nafion® Polymers 0.000 claims description 7
- 230000004048 modification Effects 0.000 claims description 7
- 238000012986 modification Methods 0.000 claims description 7
- 239000012286 potassium permanganate Substances 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 229910004042 HAuCl4 Inorganic materials 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 238000001548 drop coating Methods 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 235000007164 Oryza sativa Nutrition 0.000 claims description 3
- 238000011095 buffer preparation Methods 0.000 claims description 3
- 235000013339 cereals Nutrition 0.000 claims description 3
- 235000009566 rice Nutrition 0.000 claims description 3
- 238000000151 deposition Methods 0.000 claims description 2
- 230000008021 deposition Effects 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 230000005518 electrochemistry Effects 0.000 claims 1
- 230000035945 sensitivity Effects 0.000 abstract description 5
- 241000245665 Taraxacum Species 0.000 description 5
- 235000005187 Taraxacum officinale ssp. officinale Nutrition 0.000 description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000001294 liquid chromatography-tandem mass spectrometry Methods 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 239000002086 nanomaterial Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 241000209094 Oryza Species 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000000840 electrochemical analysis Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- ZISJNXNHJRQYJO-CMDGGOBGSA-N 5-[(e)-2-phenylethenyl]-2-propan-2-ylbenzene-1,3-diol Chemical compound C1=C(O)C(C(C)C)=C(O)C=C1\C=C\C1=CC=CC=C1 ZISJNXNHJRQYJO-CMDGGOBGSA-N 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 201000004681 Psoriasis Diseases 0.000 description 1
- 206010061926 Purulence Diseases 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- VVAUMULFPDPRCF-UHFFFAOYSA-N azanium;acetonitrile;formate Chemical compound [NH4+].CC#N.[O-]C=O VVAUMULFPDPRCF-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 206010009887 colitis Diseases 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000000132 electrospray ionisation Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 208000026278 immune system disease Diseases 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000002547 new drug Substances 0.000 description 1
- 238000005220 pharmaceutical analysis Methods 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/308—Electrodes, e.g. test electrodes; Half-cells at least partially made of carbon
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/416—Systems
- G01N27/48—Systems using polarography, i.e. measuring changes in current under a slowly-varying voltage
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Carbon And Carbon Compounds (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
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CN201810886020.1A CN109239145B (zh) | 2018-08-06 | 2018-08-06 | 一种金纳米粒子/三维氧化锰/聚吡咯修饰玻碳电极的制备方法及应用 |
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CN201810886020.1A CN109239145B (zh) | 2018-08-06 | 2018-08-06 | 一种金纳米粒子/三维氧化锰/聚吡咯修饰玻碳电极的制备方法及应用 |
Publications (2)
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CN109239145A true CN109239145A (zh) | 2019-01-18 |
CN109239145B CN109239145B (zh) | 2021-02-19 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110658244A (zh) * | 2019-09-25 | 2020-01-07 | 北京工业大学 | 一种车间无组织排放烟尘中铅的电化学检测方法 |
CN111809207A (zh) * | 2020-07-30 | 2020-10-23 | 济南大学 | 一种采用电沉积法制备三维花状碲化锌纳米材料的方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100094041A1 (en) * | 1999-12-06 | 2010-04-15 | Welichem Biotech Inc. | Anti-inflammatory and psoriasis treatment and protein kinase inhibition by hydroxy stilbenes and novel stilbene derivatives and analogues |
CN105158303A (zh) * | 2015-09-09 | 2015-12-16 | 安徽工程大学 | 贵金属/贱金属氧化物/石墨烯三元复合气敏材料及制备 |
-
2018
- 2018-08-06 CN CN201810886020.1A patent/CN109239145B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100094041A1 (en) * | 1999-12-06 | 2010-04-15 | Welichem Biotech Inc. | Anti-inflammatory and psoriasis treatment and protein kinase inhibition by hydroxy stilbenes and novel stilbene derivatives and analogues |
CN105158303A (zh) * | 2015-09-09 | 2015-12-16 | 安徽工程大学 | 贵金属/贱金属氧化物/石墨烯三元复合气敏材料及制备 |
Non-Patent Citations (2)
Title |
---|
SOUNDAPPAN THIAGARAJAN ET.AL: "Electrochemical Fabrication of Nano Manganese Oxide Modified Electrode for the Detection of H<sub>2</sub>O<sub>2</sub>", 《INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE》 * |
郝世阳: "聚吡咯-钴氧化物的制备及其催化H<sub>2</sub>O<sub>2</sub>电还原性能研究", 《中国优秀硕士学位论文全文数据库(电子期刊)工程科技I辑》 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110658244A (zh) * | 2019-09-25 | 2020-01-07 | 北京工业大学 | 一种车间无组织排放烟尘中铅的电化学检测方法 |
CN110658244B (zh) * | 2019-09-25 | 2021-09-14 | 北京工业大学 | 一种车间无组织排放烟尘中铅的电化学检测方法 |
CN111809207A (zh) * | 2020-07-30 | 2020-10-23 | 济南大学 | 一种采用电沉积法制备三维花状碲化锌纳米材料的方法 |
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Effective date of registration: 20240320 Address after: 5th Floor, Office Building of Boyun Lugu Industrialization Base Testing Center, No. 500 Lusong Road, Lugu Street, Xiangjiang New District, Changsha City, Hunan Province, 410000 Patentee after: Changsha pocheng Technology Co.,Ltd. Country or region after: Zhong Guo Address before: 511340 13, Qu Dong three lane, dun village, Xintang Town, Zengcheng District, Guangzhou, Guangdong. Patentee before: GUANGZHOU BAIXING NETWORK TECHNOLOGY Co.,Ltd. Country or region before: Zhong Guo |