CN109231839A - Porcelain production method - Google Patents
Porcelain production method Download PDFInfo
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- CN109231839A CN109231839A CN201811252763.XA CN201811252763A CN109231839A CN 109231839 A CN109231839 A CN 109231839A CN 201811252763 A CN201811252763 A CN 201811252763A CN 109231839 A CN109231839 A CN 109231839A
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- kiln
- glaze
- porcelain
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of porcelain production methods, comprising the following steps: (1) takes china clay production moulded pottery not yet put in a kiln to bake and dry moulded pottery not yet put in a kiln to bake；(2) with the mass ratio of water and ceramic glaze for 0.57~0.65:1, water intaking and ceramic glaze are mixed, and grinding obtains glaze slip；(3) glaze slip is filtered, screens out particulate matter therein；(4) filtered glaze slip is sprayed on the moulded pottery not yet put in a kiln to bake of drying, obtains porcelain billet；(5) porcelain billet is put into kiln, point six stages are roasted；(6) porcelain of firing is polished, selects colour sorting.The porcelain made of the method for the present invention and specific formula are fired, glaze paint is smooth, surface texture is naturally beautiful, in 200 times of microscopically observation glaze paint, glaze paint crystalline substance is used up, almost without micro-crack, Mohs' hardness is 5-7, for the modulus of rupture up to 85.3MPa, glaze paint is not easy to crack, has longer service life and higher economic value.
Description
Technical field
The present invention relates to ceramic technology fields, and in particular to a kind of porcelain production method.
Background technique
An important class of the ceramic material as inorganic non-metallic material, achieves very big development.Structural ceramics with
The advantages that its high mechanical strength, high hardness and corrosion resistance, is widely used in the fields such as metallurgy, mine factory and space flight.At present on the market
In the ceramic product of appearance, much all there are problems that glaze paint is easy cracking, the main reason is that glaze paint is not smooth enough, although respectively
Product is very perfect in terms of macro surface, but observation can find there is more tiny micro-crack and pit under the microscope, due to this
Crackle and pit slightly can gradually develop in the use process of porcelain as bigger crackle, lead to the service life of these porcelain
It is shorter, economic value is lower.
Summary of the invention
In view of this, it is necessary to provide the ceramic glazes that one kind can prepare the porcelain that surface is smooth, micro-crack is less by the present invention
Material.
Specific technical solution is as follows:
A kind of porcelain production method, comprising the following steps:
(1) it takes china clay production moulded pottery not yet put in a kiln to bake and dries moulded pottery not yet put in a kiln to bake；
(2) with the mass ratio of water and ceramic glaze for 0.57~0.65:1, water intaking and ceramic glaze are mixed, and are ground
To glaze slip, the ceramic glaze includes the raw material of following mass percent: glass powder 31%~43%, zinc oxide 16%~
26%, quartzy 10%~18%, titanium dioxide 7%~14%, talcum powder 3%~6%, frit 0.2%~0.5%, copper oxide
1.5%~3%, iron oxide 0.6%~1.5%, manganese oxide 2.5~4%, methylcellulose 0.02%~0.04%, potassium feldspar
2%~4%, glaze mud 5%~7%, the glaze are black mud or bentonite or black mud and bentonitic mixture with mud；
(3) glaze slip is filtered, screens out particulate matter therein；
(4) filtered glaze slip is sprayed on the moulded pottery not yet put in a kiln to bake of drying, obtains porcelain billet；
(5) porcelain billet is put into kiln and is roasted stage by stage, the first stage: the kiln lid of kiln stays 3~5 centimetres of seam
Gap opens the chimney of kiln top, burns 1.2~1.5h using oxidation, gradually rises kiln in-furnace temperature to 550 DEG C by room temperature；
Second stage: closing kiln lid, burns 2.5~3h using oxidation, gradually rises kiln in-furnace temperature to 950 DEG C by 550 DEG C；Third rank
Section burns 3.2~3.7h using reduction, gradually rises kiln in-furnace temperature to 1230 DEG C by 950 DEG C；Fourth stage: using oxidation
1.2~1.5h is burnt, gradually rises kiln in-furnace temperature to 1280 DEG C by 1230 DEG C；5th stage: it is burnt, is made in kiln using oxidation
Temperature 0.5~0.8h is kept between 1270~1290 DEG C；6th stage: closing kiln power supply, and kiln in-furnace temperature is cooled to
Wicket is opened at 150 DEG C, the porcelain being burnt by porcelain billet can be taken out when being cooled to 50 DEG C or less；
(6) porcelain of firing is polished, selects colour sorting.
Preferably, the method that glaze slip is made in step (2) is: water and ceramic glaze being put into ball mill, ground
17~21h.
Preferably, in step (3), the method for filtering glaze slip is: glaze slip is crossed 180 meshes.
Further, in step (4), before spraying glaze slip on moulded pottery not yet put in a kiln to bake, the concentration of glaze slip is adjusted to 52 Baume degrees.
Preferably, in step (4), the glaze pulp layer that is sprayed on moulded pottery not yet put in a kiln to bake with a thickness of 0.8~1.3mm.
Further, the 6th stage of step (5) opens the chimney of kiln while closing kiln power supply.
Further, the ceramic glaze further includes the raw material of following mass percent: ox bone ash 0.5%~0.8%,
Lion mountain ash 0.25%~0.4%, vanadic anhydride 0.02%~0.05%, barium carbonate 0.02%~0.05%, zirconium silicate
0.05%~0.1%, star Zhu 0.5%~1%, rice-straw ash 0.5%~1%.
Preferably, the zinc oxide is calcining zinc oxide.
Preferably, the frit is 8# frit.
Compared with prior art, the invention has the following beneficial effects:
The porcelain made of the method for the present invention and specific formula are fired, glaze paint is smooth, surface texture natural beauty
It sees, in 200 times of microscopically observation glaze paint, glaze paint crystalline substance is used up, and almost without micro-crack, Mohs' hardness 5-7 is broken mould
For number up to 85.3MPa, glaze paint is not easy to crack, has longer service life and higher economic value.
Specific embodiment
To facilitate the understanding of the present invention, below will be to invention is more fully described, there is shown of the invention
Preferred embodiment.But the invention can be realized in many different forms, however it is not limited to embodiment described herein.
It is made the disclosure of the present invention more thorough and comprehensive on the contrary, purpose of providing these embodiments is.
The invention proposes a kind of porcelain production methods, comprising the following steps:
(1) it takes china clay production moulded pottery not yet put in a kiln to bake and dries moulded pottery not yet put in a kiln to bake；
(2) with the mass ratio of water and ceramic glaze for 0.57~0.65:1, water intaking and ceramic glaze are mixed, and are ground
To glaze slip, the ceramic glaze includes the raw material of following mass percent: glass powder 31%~43%, zinc oxide 16%~
26%, quartzy 10%~18%, titanium dioxide 7%~14%, talcum powder 3%~6%, frit 0.2%~0.5%, copper oxide
1.5%~3%, iron oxide 0.6%~1.5%, manganese oxide 2.5~4%, methylcellulose 0.02%~0.04%, potassium feldspar
2%~4%, glaze mud 5%~7%, the glaze are black mud or bentonite or black mud and bentonitic mixture with mud；
(3) glaze slip is filtered, screens out particulate matter therein；
(4) filtered glaze slip is sprayed on the moulded pottery not yet put in a kiln to bake of drying, obtains porcelain billet；
(5) porcelain billet is put into kiln and is roasted stage by stage, the first stage: the kiln lid of kiln stays 3~5 centimetres of seam
Gap opens the chimney of kiln top, burns 1.2~1.5h using oxidation, gradually rises kiln in-furnace temperature to 550 DEG C by room temperature；
Second stage: closing kiln lid, burns 2.5~3h using oxidation, gradually rises kiln in-furnace temperature to 950 DEG C by 550 DEG C；Third rank
Section burns 3.2~3.7h using reduction, gradually rises kiln in-furnace temperature to 1230 DEG C by 950 DEG C；Fourth stage: using oxidation
1.2~1.5h is burnt, gradually rises kiln in-furnace temperature to 1280 DEG C by 1230 DEG C；5th stage: it is burnt, is made in kiln using oxidation
Temperature 0.5~0.8h is kept between 1270~1290 DEG C；6th stage: closing kiln power supply, and kiln in-furnace temperature is cooled to
Wicket is opened at 150 DEG C, the porcelain being burnt by porcelain billet can be taken out when being cooled to 50 DEG C or less；
(6) porcelain of firing is polished, selects colour sorting.
Above-mentioned zinc oxide use calcining zinc oxide, above-mentioned frit be it is a kind of through high temperature melting quenching made of glass,
It is polished to impose on various vessel with speciality such as insolubility, stability, at the nature of glass of a thin layer after firing.We
The frit that method uses is 8# frit (i.e. No. 8 frit).China clay for making moulded pottery not yet put in a kiln to bake is common china clay, and pure china clay is also known as height
Ridge soil.The method that glaze slip is made in step (2) is: water and ceramic glaze being put into ball mill, 17~21h is ground.Step (3)
In, the method for filtering glaze slip is: glaze slip is crossed 180 meshes.In step (4), before spraying glaze slip on moulded pottery not yet put in a kiln to bake, by the dense of glaze slip
Degree be adjusted to 52 Baume degrees, the glaze pulp layer sprayed on moulded pottery not yet put in a kiln to bake with a thickness of 0.8.1~1.3mm.In general, with water and ceramic glaze
The mass ratio of material is glaze slip made from 0.57~0.65:1, and concentration is slightly higher, needs plus the dilution of a small amount of water can just obtain 52 Baumes
The glaze slip of degree；When concentration of glaze slip is lower, the partial moisture in slurry can be absorbed using the material of the good water absorptions such as gypsum, or
The higher glaze slip of some concentration is added so that the concentration of glaze slip is adjusted to 52 Baume degrees in person.In step (5), oxidation, which is burnt, to be referred in kiln
Fire porcelain under oxygen abundance state in furnace can realize by opening the chimney of kiln top, can be with if chimney is too small
One blower is set in the pipeline of chimney, using the outside air draft of blower, makes to keep oxygen sufficient in kiln；Reduction, which is burnt, then to be referred to
Fire porcelain in the state of anoxic in kiln, the chimney by closing kiln top can be realized.6th rank of step (5)
Section opens the chimney of kiln, makes the temperature natural cooling in kiln while closing kiln power supply.
The effect that furnace/kiln reserves 3~5 centimetres of gaps is to promote the stream of kiln furnace air by the first stage of step (5)
It is logical, the moisture on porcelain is discharged all evaporation and from chimney, avoid these vapor at high temperature with the ingredient shape in porcelain
At hydrate, these hydrates can reduce the modulus of rupture of porcelain, reduce the gloss of glaze, lead to that the glaze of porcelain is easy to crack, light
Damp degree is poor.It in step (5) in five stages of fire porcelain, is successively burnt using oxidation, oxidation is burnt, reduction is burnt, oxidation is burnt, oxygen
Change and burn, the purpose is to promote the chemical reaction in glaze between each constituent, first stage and second stage to burn using oxidation
It can make glaze paint that gorgeous brilliant color be presented, the reduction burning of phase III can then restore fractions, enhance the matter of glaze
Sense and smoothness, fourth stage and the 5th stage reuse oxidation and burn, and the component portion restored can be aoxidized, make glaze
The natural texture of gradual change is presented in face, and glossiness further gets a promotion.
Embodiment 1:
The raw material proportioning of ceramic glaze is by mass are as follows: glass powder 43%, calcining zinc oxide 16%, quartzy 11%, titanium white
Powder 8%, talcum powder 3.7%, 8# frit 0.28%, copper oxide 3%, iron oxide 1%, manganese oxide 4%, methylcellulose
0.02%, potassium feldspar 4%, glaze mud 6%, the glaze is black mud with mud.Specific porcelain production method is same as above.
After porcelain in the present embodiment forms by a firing, glaze paint is smooth, and surface texture is naturally beautiful, in 200 times show
Micro- microscopic observation glaze paint, glaze paint crystalline substance are used up, and almost without micro-crack, the Mohs' hardness of the glaze paint measured with scarification is 5, are adopted
Reach 82.8MPa with the modulus of rupture that Ceramic Tiles modulus of rupture analyzer measures.Glaze paint is not easy to crack, uses the longevity with longer
Life and higher economic value.
Embodiment 2:
The raw material proportioning of ceramic glaze is by mass are as follows: glass powder 32%, calcining zinc oxide 26%, quartzy 10%, titanium white
Powder 14%, talcum powder 4%, 8# frit 0.37%, copper oxide 2%, iron oxide 0.6%, manganese oxide 2.5%, methylcellulose
0.03%, potassium feldspar 3%, glaze mud 5.5%, the glaze are black mud and bentonitic mixture with mud, black mud and bentonite
Mass ratio be 1:1.Specific porcelain production method is same as above.
After porcelain in the present embodiment forms by a firing, the Mohs' hardness of glaze paint is 5, and the modulus of rupture reaches 85.3MPa,
200 times of microscopically observation glaze paint, glaze paint crystalline substance is used up, almost without micro-crack.
Embodiment 3
The raw material proportioning of ceramic glaze is by mass are as follows: glass powder 31%, calcining zinc oxide 21%, quartzy 18%, titanium white
Powder 10%, talcum powder 3%, 8# frit 0.2%, copper oxide 2.4%, iron oxide 0.7%, manganese oxide 3%, methylcellulose
0.03%, potassium feldspar 3.3%, glaze mud 5%, ox bone ash 0.8%, lion mountain ash 0.25%, vanadic anhydride 0.05%, barium carbonate
0.02%, zirconium silicate 0.05%, star Zhu 0.7%, rice-straw ash 0.5%, the glaze are black mud with mud.Specific porcelain producer
Method is same as above.
After porcelain in the present embodiment forms by a firing, in 200 times of microscopically observation glaze paint, glaze paint crystalline substance is used up, several
There is no micro-crack；The Mohs' hardness of glaze paint reaches 7, and modulus of rupture 71.9MPa is compared with embodiment 1, embodiment 2, hardness
It is significantly improved.
Embodiment 4
The raw material proportioning of ceramic glaze is by mass are as follows: glass powder 37%, calcining zinc oxide 19%, quartzy 12%, titanium white
Powder 7%, talcum powder 6%, 8# frit 0.5%, copper oxide 1.5%, iron oxide 1.5%, manganese oxide 3.5%, methylcellulose
0.04%, potassium feldspar 2%, glaze mud 7%, ox bone ash 0.6%, lion mountain ash 0.4%, vanadic anhydride 0.03%, barium carbonate
0.03%, zirconium silicate 0.1%, star Zhu 1%, rice-straw ash 0.8%, the glaze is black mud and bentonitic mixture with mud, black
Mud and bentonitic mass ratio are 1:1.Specific porcelain production method is same as above.
After porcelain in the present embodiment forms by a firing, in 200 times of microscopically observation glaze paint, glaze paint crystalline substance is used up, several
There is no micro-crack；The Mohs' hardness of glaze paint reaches 6, modulus of rupture 74.6MPa, compares embodiment 1 and embodiment 2, hardness
It is highly improved.
Embodiment 5
The raw material proportioning of ceramic glaze is by mass are as follows: glass powder 34%, calcining zinc oxide 22%, quartzy 13%, titanium white
Powder 9%, talcum powder 5%, 8# frit 0.4%, copper oxide 1.7%, iron oxide 0.9%, manganese oxide 3%, methylcellulose
0.04%, potassium feldspar 3.5%, glaze mud 5%, ox bone ash 0.5%, lion mountain ash 0.32%, vanadic anhydride 0.02%, barium carbonate
0.05%, zirconium silicate 0.07%, star Zhu 0.5%, rice-straw ash 1%, the glaze are bentonite with mud.The present embodiment makes porcelain
Processing step it is same as Example 1.
After porcelain in the present embodiment forms by a firing, in 200 times of microscopically observation glaze paint, glaze paint crystalline substance is used up, several
There is no micro-crack；The Mohs' hardness of glaze paint reaches 6, modulus of rupture 73.8MPa, compares embodiment 1 and embodiment 2, hardness
It is highly improved.
Claims (9)
1. a kind of porcelain production method, which comprises the following steps:
(1) it takes china clay production moulded pottery not yet put in a kiln to bake and dries moulded pottery not yet put in a kiln to bake；
(2) with the mass ratio of water and ceramic glaze for 0.57~0.65:1, water intaking and ceramic glaze are mixed, and grinding obtains glaze
Slurry, the ceramic glaze includes the raw material of following mass percent: glass powder 31%~43%, zinc oxide 16%~26%,
Quartz 10%~18%, titanium dioxide 7%~14%, talcum powder 3%~6%, frit 0.2%~0.5%, copper oxide 1.5%~
3%, iron oxide 0.6%~1.5%, manganese oxide 2.5~4%, methylcellulose 0.02%~0.04%, potassium feldspar 2%~
4%, glaze mud 5%~7%, the glaze are black mud or bentonite or black mud and bentonitic mixture with mud；
(3) glaze slip is filtered, screens out particulate matter therein；
(4) filtered glaze slip is sprayed on the moulded pottery not yet put in a kiln to bake of drying, obtains porcelain billet；
(5) porcelain billet is put into kiln and is roasted stage by stage, the first stage: the kiln lid of kiln stays 3~5 centimetres of gap, beats
The chimney for opening kiln top burns 1.2~1.5h using oxidation, gradually rises kiln in-furnace temperature to 550 DEG C by room temperature；Second-order
Section: closing kiln lid, burns 2.5~3h using oxidation, gradually rises kiln in-furnace temperature to 950 DEG C by 550 DEG C；Phase III adopts
3.2~3.7h is burnt with reduction, gradually rises kiln in-furnace temperature to 1230 DEG C by 950 DEG C；Fourth stage: 1.2 are burnt using oxidation
~1.5h gradually rises kiln in-furnace temperature to 1280 DEG C by 1230 DEG C；5th stage: it is burnt using oxidation, makes the temperature in kiln
Degree keeps 0.5~0.8h between 1270~1290 DEG C；6th stage: closing kiln power supply, and kiln in-furnace temperature is cooled to 150 DEG C
When open wicket, the porcelain being burnt by porcelain billet can be taken out when being cooled to 50 DEG C or less；
(6) porcelain of firing is polished, selects colour sorting.
2. porcelain production method according to claim 1, which is characterized in that the method that glaze slip is made in step (2) is: will
Water and ceramic glaze are put into ball mill, grind 17~21h.
3. porcelain production method according to claim 1, which is characterized in that in step (3), the method for filtering glaze slip is:
Glaze slip is crossed into 180 meshes.
4. porcelain production method according to claim 1, which is characterized in that in step (4), on moulded pottery not yet put in a kiln to bake spray glaze slip it
Before, the concentration of glaze slip is adjusted to 52 Baume degrees.
5. porcelain production method according to claim 1, which is characterized in that in step (4), the glaze pulp layer that is sprayed on moulded pottery not yet put in a kiln to bake
With a thickness of 0.8~1.3mm.
6. porcelain production method according to claim 1, which is characterized in that the 6th stage of step (5) closes kiln electricity
The chimney of kiln is opened while source.
7. porcelain production method according to claim 1, which is characterized in that the ceramic glaze further includes following quality
The raw material of percentage: ox bone ash 0.5%~0.8%, lion mountain ash 0.25%~0.4%, vanadic anhydride 0.02%~0.05%,
Barium carbonate 0.02%~0.05%, zirconium silicate 0.05%~0.1%, star Zhu 0.5%~1%, rice-straw ash 0.5%~1%.
8. porcelain production method according to claim 1, which is characterized in that the zinc oxide is calcining zinc oxide.
9. porcelain production method according to claim 1, which is characterized in that the frit is 8# frit.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811252763.XA CN109231839A (en) | 2018-10-25 | 2018-10-25 | Porcelain production method |
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| CN201811252763.XA CN109231839A (en) | 2018-10-25 | 2018-10-25 | Porcelain production method |
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ID=65082231
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115650584A (en) * | 2022-11-18 | 2023-01-31 | 齐鲁工业大学 | Ceramic glaze suitable for high-yellow-river-mud-content porcelain body and preparation method thereof |
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|---|---|---|---|---|
| JPS5361607A (en) * | 1976-11-15 | 1978-06-02 | Matsushita Electric Works Ltd | Process for making inorganic sintered object |
| CN102060572A (en) * | 2010-11-18 | 2011-05-18 | 梅州市林海陶瓷有限公司 | Method for manufacturing ceramic weathered glaze |
| CN103964900A (en) * | 2014-05-12 | 2014-08-06 | 成都朋和科技有限公司 | formula and preparation method of Sky blue transmutation glaze |
| CN107586021A (en) * | 2017-09-27 | 2018-01-16 | 禹州市正玉钧窑有限公司 | A kind of glaze of pottery disk and preparation method thereof |
| CN107602068A (en) * | 2017-09-28 | 2018-01-19 | 禹州市正玉钧窑有限公司 | A kind of crack resistence pottery and its preparation technology |
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2018
- 2018-10-25 CN CN201811252763.XA patent/CN109231839A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5361607A (en) * | 1976-11-15 | 1978-06-02 | Matsushita Electric Works Ltd | Process for making inorganic sintered object |
| CN102060572A (en) * | 2010-11-18 | 2011-05-18 | 梅州市林海陶瓷有限公司 | Method for manufacturing ceramic weathered glaze |
| CN103964900A (en) * | 2014-05-12 | 2014-08-06 | 成都朋和科技有限公司 | formula and preparation method of Sky blue transmutation glaze |
| CN107586021A (en) * | 2017-09-27 | 2018-01-16 | 禹州市正玉钧窑有限公司 | A kind of glaze of pottery disk and preparation method thereof |
| CN107602068A (en) * | 2017-09-28 | 2018-01-19 | 禹州市正玉钧窑有限公司 | A kind of crack resistence pottery and its preparation technology |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115650584A (en) * | 2022-11-18 | 2023-01-31 | 齐鲁工业大学 | Ceramic glaze suitable for high-yellow-river-mud-content porcelain body and preparation method thereof |
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