CN110028244B - Red glaze and the Ceramic Tiles and preparation method thereof for using the red glaze - Google Patents
Red glaze and the Ceramic Tiles and preparation method thereof for using the red glaze Download PDFInfo
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- CN110028244B CN110028244B CN201910511281.XA CN201910511281A CN110028244B CN 110028244 B CN110028244 B CN 110028244B CN 201910511281 A CN201910511281 A CN 201910511281A CN 110028244 B CN110028244 B CN 110028244B
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- glaze
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- red pigment
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- 239000000919 ceramic Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000001054 red pigment Substances 0.000 claims abstract description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 26
- AYJRCSIUFZENHW-UHFFFAOYSA-L Barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims abstract description 20
- 239000011787 zinc oxide Substances 0.000 claims abstract description 16
- YIXQSYHBXUBLPM-UHFFFAOYSA-N dioxido(oxo)silane;zirconium(4+) Chemical compound [Zr+4].[O-][Si]([O-])=O.[O-][Si]([O-])=O YIXQSYHBXUBLPM-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 11
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 11
- 239000000454 talc Substances 0.000 claims abstract description 11
- 235000012222 talc Nutrition 0.000 claims abstract description 11
- 229910052623 talc Inorganic materials 0.000 claims abstract description 11
- 239000006004 Quartz sand Substances 0.000 claims abstract description 10
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 10
- 230000000694 effects Effects 0.000 claims description 23
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 16
- 238000010304 firing Methods 0.000 claims description 16
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 16
- 238000005507 spraying Methods 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- 238000005245 sintering Methods 0.000 claims description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 10
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 8
- 229910052681 coesite Inorganic materials 0.000 claims description 8
- 229910052593 corundum Inorganic materials 0.000 claims description 8
- 229910052906 cristobalite Inorganic materials 0.000 claims description 8
- NTGONJLAOZZDJO-UHFFFAOYSA-M disodium;hydroxide Chemical compound [OH-].[Na+].[Na+] NTGONJLAOZZDJO-UHFFFAOYSA-M 0.000 claims description 8
- 230000005484 gravity Effects 0.000 claims description 8
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 8
- 229910052904 quartz Inorganic materials 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 229910052682 stishovite Inorganic materials 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 229910052905 tridymite Inorganic materials 0.000 claims description 8
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 8
- 238000002386 leaching Methods 0.000 claims description 7
- 239000000725 suspension Substances 0.000 claims description 7
- 239000007921 spray Substances 0.000 claims description 2
- 239000003086 colorant Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000004220 aggregation Methods 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
- 238000000498 ball milling Methods 0.000 description 4
- 239000011449 brick Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000004576 sand Substances 0.000 description 3
- PGWFQHBXMJMAPN-UHFFFAOYSA-N CTK4B5078 Chemical compound [Cd].OS(=O)(=O)[Se]S(O)(=O)=O PGWFQHBXMJMAPN-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000010427 ball clay Substances 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- VCYBIENCKPXWDZ-SGWCAAJKSA-N (4E)-4-[(2,5-dichlorophenyl)hydrazinylidene]-3-oxo-N-phenylnaphthalene-2-carboxamide Chemical compound ClC1=CC=C(Cl)C(N\N=C\2C3=CC=CC=C3C=C(C/2=O)C(=O)NC=2C=CC=CC=2)=C1 VCYBIENCKPXWDZ-SGWCAAJKSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- OFJATJUUUCAKMK-UHFFFAOYSA-N Cerium(IV) oxide Chemical compound [O-2]=[Ce+4]=[O-2] OFJATJUUUCAKMK-UHFFFAOYSA-N 0.000 description 1
- 229910018162 SeO2 Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- HWKQNAWCHQMZHK-UHFFFAOYSA-N Trolnitrate Chemical compound [O-][N+](=O)OCCN(CCO[N+]([O-])=O)CCO[N+]([O-])=O HWKQNAWCHQMZHK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- CXKCTMHTOKXKQT-UHFFFAOYSA-N cadmium oxide Inorganic materials [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 230000004301 light adaptation Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000001062 red colorant Substances 0.000 description 1
- 230000003014 reinforcing Effects 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3232—Titanium oxides or titanates, e.g. rutile or anatase
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3272—Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
Abstract
The present invention provides red glaze and the Ceramic Tiles and preparation method thereof using the red glaze.Red glaze includes base glaze and Red pigment, and the base glaze includes: potassium feldspar 22~26% by mass, and kaolin 8~12% burns talcum 5~8%, calcite 13~18%, quartz sand 25~35%, zinc oxide 2~5%, zirconium silicate 3~8%, barium carbonate 4~7%；The Red pigment is the 8~15% of the quality of the base glaze.
Description
Technical field
The present invention relates to red glaze and using the Ceramic Tiles and preparation method thereof of the red glaze, belong to ceramic tile production system
Make technical field.
Background technique
Red glaze firmly gets liking for compatriots due to its celebrating color.But used on building ceramic decoration also not
It is very extensively, especially the Ceramic Tiles of high temperature firing, red color development are not bright-coloured enough.Patent document 1(CN104860720A) it is open
A kind of ceramic decoration high temperature scarlet color ink-jet ink is prepared by following parts by weight of component: 15~25 parts of basic powdered frit,
15~25 parts of Red pigment, 50~70 parts of solvent；Basis powdered frit therein: it is prepared by following parts by weight of component: frit 86~
90 parts, 2~4 parts of kaolin, 4~6 parts of titanium dioxide, 4~6 parts of cerium oxide, 0.02~0.04 part of additional carboxymethyl cellulose,
0.2~0.4 part of sodium tripolyphosphate, 37~40 parts of water.But the high temperature scarlet color ink-jet ink deposit at high temperature it is red not enough
Gorgeous disadvantage.
Summary of the invention
For red colorant, the weaker problem of color development, the present invention develop at high temperature by adjusting the formula of parent glaze
A kind of red glaze, and there are using large red made from the red glaze and colorant the Ceramic Tiles of aggregation, suspension effect, have
Good artistic effect and chromatic colour.
In a first aspect, the present invention provides a kind of red glaze comprising base glaze and Red pigment, the base glaze packet
Include: by mass percentage, potassium feldspar 22~26%, kaolin 8~12% burns talcum 5~8%, calcite 13~18%, quartz sand
25~35%, zinc oxide 2~5%, zirconium silicate 3~8%, barium carbonate 4~7%；The Red pigment is the quality of the base glaze
8~15%.
According to the present invention, the effect of suspension is independently assembled in sintering process and presented to the Red pigment in red glaze, hair
Color is bright-coloured, has preferable artistic decorative effect.
Preferably, the base glaze includes: potassium feldspar 25% by mass percentage, kaolin 10% burns talcum 6%,
Calcite 15%, quartz sand 30%, zinc oxide 4%, zirconium silicate 5%, barium carbonate 5%；The Red pigment is the matter of the base glaze
The 10% of amount.
Second aspect, the present invention provide a kind of preparation method of Ceramic Tiles, comprising: it is big that any one of the above is applied on green body
Red glaze applies clear frit, is then burnt into.
Preferably, the red glaze is using glaze spraying or leaching glaze mode glazing, it is preferable that glaze spraying technological parameter are as follows: specific gravity
1.40~1.50, weight is 450~650g/m2。
Preferably, the chemical component of the clear frit includes are as follows: SiO2: 55~60%, Al2O3: 11~15%, Fe2O3: 0.1
~0.3%, TiO2: 0.1~0.3%, CaO:9~13%, MgO:2~4%, K2O:2.5~4.0%, Na2O:3.0~5.0%, ZnO:2
~4%, it burns and loses: 5~7%.
Preferably, clear frit is using glaze spraying or leaching glaze mode glazing, it is preferable that glaze spraying technological parameter are as follows: specific gravity 1.40~
1.55, weight is 450~650 g/m2。
Preferably, the chemical component of the green body includes: SiO2: 64.5~66%, Al2O3: 22~25%, Fe2O3: 0.4~
0.7%、TiO2: 0.25~0.35%, CaO:0.25~0.35%, MgO:0.5~0.80%, K2O:2.0~2.4%, Na2O:2.6~
3.0%, it burns and loses: 4.5~5.5%.
Preferably, maximum sintering temperature is 1200~1220 DEG C, firing period is 40~60 minutes.
The third aspect, the present invention provide a kind of Ceramic Tiles as made from any of the above-described preparation method.
The utility model has the advantages that the Red pigment in red glaze of the invention is independently assembled in sintering process and the effect of suspension is presented
Fruit, has preferable artistic decorative effect, and red glaze of the invention can be used as ornament materials applied to house ornamentation field.
Detailed description of the invention
Fig. 1 is the process flow chart of an embodiment of the present invention.
Fig. 2 is the ceramic tile face effect picture of the embodiment of the present invention 1.
Fig. 3 is the ceramic tile face effect picture of the embodiment of the present invention 2.
Fig. 4 is the ceramic tile face effect picture of the embodiment of the present invention 3.
Specific embodiment
The present invention is further illustrated below in conjunction with attached drawing and following embodiments, it should be appreciated that attached drawing and following embodiments
It is merely to illustrate the present invention, is not intended to limit the present invention.Following percentage composition refers both to mass percentage unless otherwise instructed.
It is disclosed a kind of red glaze comprising base glaze and Red pigment.
The base glaze can include: by mass percentage, potassium feldspar 22~26%, kaolin 8~12% burns talcum 5
~8%, calcite 13~18%, quartz sand 25~35%, zinc oxide 2~5%, zirconium silicate 3~8%, barium carbonate 4~7%.
The Red pigment can be the 8~15% of the quality of the base glaze.If the content of Red pigment is too low,
Red congregational rate is unobvious, if the too high levels of Red pigment, glaze are uneven.
In the red glaze, Red pigment is independently assembled in sintering process and the effect of suspension is presented, and color development is bright-coloured.
Calcite can substantially reduce the firing temperature of glaze, and zinc oxide can reduce the firing temperature of glaze and can help colorant
Color development, zirconium silicate, which is added, prevents Red pigment during high temperature firing from dissolving to which color development weakens.
Red pigment can be Red pigment well known in the art, preferably the cadmium sulfoselenide crimson pigment of zirconium silicate package,
Color development is gorgeous at high temperature and will not decompose for the Red pigment.
In one embodiment, the chemical component of red glaze can include: SiO2: 57~61%, Al2O3: 9~12%, Fe2O3: 0.1
~0.3%, TiO2: 0.1~0.2%, CaO:7~10%, MgO:1~3%, K2O:1~4%, Na2O:0.5~0.8%, ZnO:3.0~
4.0%、ZrO2: 7~8.5%, BaO:3.5~4%, CdO:0.5~0.6%, SeO2: 0.4~0.5%, SO3: 0.1~0.2%, it burns and loses:
2~4%.
In one preferred embodiment, red glaze includes: potassium feldspar 25% by mass percentage, and kaolin 10% burns talcum
6%, calcite 15%, quartz sand 30%, zinc oxide 4%, zirconium silicate 5%, barium carbonate 5%；Additional Red pigment 10%.
A kind of bright red glaze slip is also disclosed herein comprising above-mentioned red glaze and water.
In bright red glaze slip, the content of water can be the 30~45% of red glaze.
In one embodiment, by each component of red glaze ball mill ball milling, adds water, obtain bright red glaze slip.Ball milling fineness
It can be 325 mesh screen residues 0.5%.
In the case where not influencing the object of the invention, other components can also be contained in red glaze or bright red glaze slip, such as
Sodium carboxymethylcellulose, sodium tripolyphosphate etc..
It is disclosed a kind of preparation method of Ceramic Tiles.The technique that Fig. 1 shows the preparation method of an embodiment of the present invention
Flow chart.As shown in Figure 1, firstly, preparing green body.Green body can be prepared according to a conventional method by well known ceramic raw material, such as successively
Progress blank ball milling, granulation of dusting, press is dry-pressing formed, dry kiln is dry, obtains dry base.Dry base moisture can for 0.4% with
It is interior.
In one embodiment, the formula composition of green body are as follows: selected sodium mountain flour 5%, medium temperature sand 15%, low temperature sodium sand 15%, nation's sand
18%, Shaoguan ball clay 6% washes ball clay 12%, calcines bauxite 4%, black talc 1%, potassium aloxite 15%, raw ore mud 4%, bentonite
3.5%, waterglass 0.8%, reinforcing agent 0.2%, diluent 0.5%.Its chemical component includes: SiO2: 64.5~66%, Al2O3: 22~
25%、Fe2O3: 0.4~0.7%, TiO2: 0.25~0.35%, CaO:0.25~0.35%, MgO:0.5~0.80%, K2O:2.0~
2.4%、Na2O:2.6~3.0% burns and loses: 4.5~5.5%.Use such green body wider with firing range, at 1200 DEG C
Under firing temperature, porcelain, water absorption rate it can reach 0.1% or less completely.
Then red glaze is applied on green body.In one embodiment, by the glazing in a manner of glaze spraying or leaching glaze of above-mentioned bright red glaze slip.
Glaze spraying glazing process parameter can are as follows: specific gravity 1.40~1.50, weight are 450~650g/m2.Had using the glazing parameter glaze layer
Certain thickness can cover the color of bottom base completely, and glaze layer has enough colorant amounts.
Then, clear frit is applied.By applying clear frit, the high temperature viscosity of firing temperature and glaze layer can be reduced, in high temperature rank
Section is convenient for the mobile aggregation of colorant.
In one embodiment, clear frit chemical component includes SiO2: 55~60%, Al2O3: 11~15%, Fe2O3: 0.1~
0.3%、TiO2: 0.1~0.3%, CaO:9~13%, MgO:2~4%, K2O:2.5~4.0%, Na2O:3~5.0%, ZnO:2~4%,
It burns and loses: 5~7%.By using the clear frit, the high temperature viscosity of firing temperature and glaze layer can be reduced, is convenient for color in hot stage
The mobile aggregation of material, while colorant color development is more gorgeous.
The modes glazing such as glaze spraying or leaching glaze can be used in clear frit.Glazing process parameter can are as follows: specific gravity 1.40~1.55, weight
For 450~650 g/m2.Using the glazing parameter process, simple, parameter is easy to stable, and glaze is smooth after firing.
Then, it is burnt into.Low temperature fast firing can be used, for example, firing period can be 40~60 minutes, highest firing temperature
Degree can be 1200~1220 DEG C.
Then, it can be polished, be classified.
Fig. 2 shows the brick face effect pictures of the resulting Ceramic Tiles of an embodiment of the present invention, and the brick-red color development of the ceramics is bright-coloured,
And colorant has aggregation, suspension effect, has preferable artistic decorative effect, can be used as ornament materials applied to house ornamentation field.
Enumerate embodiment further below with the present invention will be described in detail.It will similarly be understood that following embodiment is served only for this
Invention is further described, and should not be understood as limiting the scope of the invention, those skilled in the art is according to this hair
Some nonessential modifications and adaptations that bright above content is made all belong to the scope of protection of the present invention.Following examples are specific
Technological parameter etc. is also only an example in OK range, i.e. those skilled in the art can be done properly by the explanation of this paper
In the range of select, and do not really want to be defined in hereafter exemplary specific value.
Embodiment 1
Step 1: preparing red glaze parent glaze, potassium feldspar 25% according to the proportion, and kaolin 10% burns talcum 6%, calcite
15%, quartz sand 30%, zinc oxide 4%, zirconium silicate 5%, barium carbonate 5%, (cadmium sulfoselenide of zirconium silicate package is big for additional Red pigment
Red stain is bought from Foshan big thousand colour glaze Co., Ltd) 10%.With ball mill ball milling, add water 40%, 325 mesh screen residues 0.5%.
Step 2: red glaze, glaze specific gravity 1.50, glaze spraying 500g/ are sprayed in adobe after the drying by the way of glaze spraying
m2。
Step 3: spray clear frit, the chemical component of clear frit includes: SiO2: 57.6%, Al2O3: 11.28%, Fe2O3:
0.16%、TiO2: 0.12%, CaO:11.56%, MgO:3.00%, K2O:2.91%, Na2O:3.62%, ZnO:3.25% burn and lose:
6.5%.Glaze spraying parameter are as follows: specific gravity 1.50, glaze volume 600g/m2。
Step 4: roller kilns are rapidly fired to.1210 DEG C of maximum sintering temperature, firing period 60min.
Step 5: polishing classification.
The brick face effect picture of gained Ceramic Tiles is as shown in Figure 2.The product is rapidly fired to work by glaze spraying or leaching glaze, roller kilns
Skill, firing period 60min, 1210 DEG C of maximum sintering temperature, Red pigment is independently assembled in sintering process and suspension is presented
Effect has preferable artistic decorative effect, can be used as ornament materials applied to house ornamentation field.
Embodiment 2
Substantially with embodiment 1, the difference is that, the formula of red glaze are as follows: potassium feldspar 23.5%, kaolin 10.5% are burnt
Talcum 7%, calcite 16%, quartz sand 30%, zinc oxide 3.5%, zirconium silicate 5.5%, barium carbonate 4%, additional Red pigment 9%.
The brick face effect picture of gained Ceramic Tiles is as shown in Figure 3.Red pigment is independently assembled in sintering process and is presented outstanding
Floating effect, color development is bright-coloured, has preferable artistic decorative effect.
Embodiment 3
Substantially with embodiment 1, the difference is that, the formula of red glaze are as follows: potassium feldspar 26%, kaolin 11% burn talcum
5%, calcite 14%, quartz sand 32%, zinc oxide 2%, zirconium silicate 6%, barium carbonate 4%, additional Red pigment 13%.
The brick face effect picture of gained Ceramic Tiles is as shown in Figure 4.Red pigment is independently assembled in sintering process and is presented outstanding
Floating effect, color development is bright-coloured, has preferable artistic decorative effect.
Claims (7)
1. a kind of preparation method of Ceramic Tiles characterized by comprising apply red glaze on green body, apply clear frit, then burn
At,
The red glaze includes base glaze and Red pigment, and the base glaze includes: potassium feldspar 22 by mass percentage
~26%, kaolin 8~12% burns talcum 5~8%, calcite 13~18%, quartz sand 25~35%, zinc oxide 2~5%, zirconium silicate
3~8%, barium carbonate 4~7%；The Red pigment is the 8~15% of the quality of the base glaze,
The chemical component of the clear frit includes: SiO2: 55~60%, Al2O3: 11~15%, Fe2O3: 0.1~0.3%, TiO2:
0.1~0.3%, CaO:9~13%, MgO:2~4%, K2O:2.5~4.0%, Na2O:3.0~5.0%, ZnO:2~4% burn and lose: 5~
7%,
The Red pigment is independently assembled in sintering process and the effect of suspension is presented.
2. preparation method according to claim 1, which is characterized in that the base glaze include: by mass percentage,
Potassium feldspar 25%, kaolin 10% burn talcum 6%, calcite 15%, quartz sand 30%, zinc oxide 4%, zirconium silicate 5%, barium carbonate 5%；
The Red pigment is the 10% of the quality of the base glaze.
3. preparation method according to claim 1, which is characterized in that the red glaze is applied using glaze spraying or leaching glaze mode
Glaze, glaze spraying technological parameter are as follows: specific gravity 1.40~1.50, weight are 450~650g/m2。
4. preparation method according to claim 1, which is characterized in that clear frit is using glaze spraying or leaching glaze mode glazing, spray
Glaze handicraft parameter are as follows: specific gravity 1.40~1.55, weight are 450~650 g/m2。
5. preparation method according to claim 1, which is characterized in that the chemical component of the green body includes: SiO2: 64.5
~66%, Al2O3: 22~25%, Fe2O3: 0.4~0.7%, TiO2: 0.25~0.35%, CaO:0.25~0.35%, MgO:0.5~
0.80%、K2O:2.0~2.4%, Na2O:2.6~3.0% burns and loses: 4.5~5.5%.
6. preparation method according to any one of claim 1 to 5, which is characterized in that maximum sintering temperature be 1200~
1220 DEG C, firing period is 40~60 minutes.
7. a kind of Ceramic Tiles as made from preparation method described in any one of claims 1 to 6.
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