CN109206938B - A kind of natural brown dyestuff - Google Patents
A kind of natural brown dyestuff Download PDFInfo
- Publication number
- CN109206938B CN109206938B CN201811018233.9A CN201811018233A CN109206938B CN 109206938 B CN109206938 B CN 109206938B CN 201811018233 A CN201811018233 A CN 201811018233A CN 109206938 B CN109206938 B CN 109206938B
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- dyeing
- water
- dyestuff
- fabric
- natural brown
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B61/00—Dyes of natural origin prepared from natural sources, e.g. vegetable sources
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0096—Purification; Precipitation; Filtration
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/14—Wool
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
Abstract
The present invention relates to a kind of natural brown dyestuffs, using brown mushroom as raw material, it is mixed according to water with brown mushroom fructification powder ratio for 6: 1 (v/w), to 30~45min of above-mentioned mixed liquor heating water bath, to treated, 7000~10000rpm of mixed liquor is centrifuged 10~15min, take supernatant spare, residue adds water to mention again once according to same method, will mix to obtain stock staining solution for supernatant twice.Fabric is excluded into interfibrous air, the ratio 1: 1 (v/v) of stock staining solution and water in advance with distilled water wetting 20min using when, dyeing pH is 2~4, bath raio 1: 30,60~95 DEG C of dyeing temperature, 80~120min is kept the temperature, washes 3 times, soaps after dyeing.Dyestuff of the present invention is harmless to the human body, and preparation process is simple, environmental protection and energy saving, and dyeing course cleaning, fabric color is securely good, in textile industry application value with higher.
Description
The application is the divisional application of following application: application No. is CN201610546613.4；The applying date is in July, 2016
8 days；Entitled a kind of natural brown dyestuff and its preparation method and application.
Technical field
The present invention relates to natural dye and its applied technical field, in particular to a kind of natural brown dyestuff.
Background technique
With the arrival of low-carbon, green living, the ecological requirements of textile are continuously improved in people.It is some to be harmful to the human body
Synthetic dyestuffs it is gradually disabled, natural dye is concerned by people and favors again！Natural dye not only ecological, environmental protective,
And also there is certain healthcare function while assigning textile graceful color naturally, it is ecological textile exploitation in recent years
One of Main way.
Patent application CN105504867A discloses a kind of fabric plant containing natural dyestuff, it is characterised in that its raw material is
The petal of Red Weigela Florida A.DC crushes after drying petal, and the ethanol solution or pH that mass concentration 40~70% is added are 4~5
Acidic aqueous solution, the two are mixed by 1: 20~50 weight ratio, keep 60~120 minutes in 40~60 DEG C of temperature, thereafter
Filtering, filtrate are evaporated under reduced pressure in 60 DEG C, then are concentrated, recycles ethyl alcohol, and distillate is dried at a temperature of 40 DEG C, obtain it is powdered or
The Direct-type Red Weigela Florida A.DC dyestuff of flat crystal.
Patent application CN105153742A discloses a kind of technique that natural dye is prepared using plant petals, and feature exists
In: the following steps are included: 1) step is dry；2) step crushes；3) it mixes；4) it extracts；5) it filters；6) it distills；7) two steps are dry.
Patent application CN103665926A discloses the preparation and its application of a kind of natural semen cuscutae dye.First by plant Tu
Silk crush, 5~20 times of pH be 9~11 aqueous slkali (sodium hydroxide), 90~100 DEG C, soaked under the conditions of 70~80min
It mentions, filters to obtain natural dye stoste；Again by the concentration of natural dye stoste, solidification, crushing, powdered natural dye is obtained.
Brown mushroom is under the jurisdiction of Basidiomycetes, and Agaricales, Agaricus edibilis, Agaricus is a kind of mutation of agaricus bisporus.Its pigment
It is a kind of by-product of brown mushroom factory, purposes is not yet developed.The brown mushroom dyestuff natural dye novel as one kind,
Safe and nontoxic, resourceful, preparation and application correlative study in terms of dyestuff have not been reported.
Summary of the invention
It is high the purpose of the present invention is using brown mushroom as raw material, providing safe and efficient one kind, clean and environmental protection, resource utilization
Natural dye and its preparation method and application.
The technical solution adopted in the present invention is as follows:
A kind of natural brown dyestuff, using brown mushroom as raw material, preparation method includes the following steps: according to water and brown mushroom
Massee fruiting bodies powder art ratio is 6: 1 (v/w) mixing, to 30~45min of above-mentioned mixed liquor heating water bath, to treated mixed liquor
7000~10000rpm is centrifuged 10~15min, takes supernatant spare, residue adds water to mention again once according to same method, will twice
Supernatant mixes to obtain stock staining solution.
Preferably, the temperature of the heating water bath is 100 DEG C.
By natural brown application of the present invention in the dyeing of fabric, following colouring method can be used: fabric is preparatory
20min is soaked with distilled water, excludes interfibrous air, the ratio 1: 1 (v/v) of stock staining solution and water, dyeing pH is 2~4, bath
Than (fabric: dye liquor) 1: 30,60~95 DEG C of dyeing temperature, 80~120min is kept the temperature, washes 3 times, soaps after dyeing.
Fabric of the present invention is preferably wool fabric, other fabrics can also be used dyestuff of the present invention to be dyed.
The utility model has the advantages that
The present invention is raw material using resourceful brown mushroom, and purification pigment obtains natural brown dyestuff, and dyestuff is maximum
Fabric color of the absorbing wavelength after 256nm, dyeing is securely good.Brown mushroom natural dye is harmless to the human body, preparation process
Simply, environmental protection and energy saving, dyeing course cleaning, in textile industry application value with higher.Dyestuff of the present invention is without adding salt to promote
Dye, for the fastness to rubbing of the wool fabric after brown mushroom natural dye dying up to 4~5, fastness to soaping is 4~5, resistance to
Light fastness is 3, as a kind of pure natural dyestuff, wide market.
Detailed description of the invention
Fig. 1: the ultraviolet spectra of natural brown dyestuff of the present invention in water.
Specific embodiment
The present invention is further discussed below below by specific embodiment.Unless stated otherwise, it is not described in embodiment
Technological means can be realized with mode known in those skilled in the art.In addition, embodiment be interpreted as it is illustrative
, the range being not intended to limit the present invention, the spirit and scope of the invention are limited only by the claims that follow.For art technology
For personnel, under the premise of without departing substantially from spirit and scope of the present invention, to material component, dosage, the ruler in these embodiments
Very little, shape progress various modifications, replacement, improvement also belong to protection scope of the present invention, and specific defined by the present invention
Parameter should have admissible error range.
Embodiment 1
The preparation of natural brown dyestuff.
It is mixed according to water with brown mushroom fructification powder ratio for 6: 1 (v/w), to 100 DEG C of heating water baths of above-mentioned mixed liquor
30min, to treated, mixed liquor 7000rpm is centrifuged 10min, takes supernatant spare, residue same method is mentioned again once, by two
Secondary supernatant mixes to obtain stock staining solution.This stock staining solution uv absorption spectra is shown in Fig. 1 curve.
Embodiment 2
Fabric soaks 20min with distilled water in advance, excludes interfibrous air, 1: the 1 (v/ of ratio of stock staining solution and water
V), dyeing pH is 2, bath raio 1: 30,95 DEG C of dyeing temperature, keeps the temperature 80min, washes 3 times, soap after dyeing.Sheep after measured
The color fastness measurement result of wool fabric is as shown in table 1.
1 pigment fastness test result table of table
Embodiment 3
Fabric soaks 20min with distilled water in advance, excludes interfibrous air, 1: the 1 (v/ of ratio of stock staining solution and water
V), dyeing pH is 3, bath raio 1: 30,60 DEG C of dyeing temperature, keeps the temperature 120min, washes 3 times, soap after dyeing.Sheep after measured
The color fastness measurement result of wool fabric is as shown in table 2.
2 pigment fastness test result table of table
Embodiment 4
Fabric soaks 20min with distilled water in advance, excludes interfibrous air, the ratio 1: 1 (v/v) of extracting solution and water,
Dyeing pH is 4, bath raio 1: 30,80 DEG C of dyeing temperature, keeps the temperature 100min, washes 3 times, soap after dyeing.Wool after measured
The color fastness measurement result of fabric is as shown in table 3.
3 pigment fastness test result table of table
Test method is respectively according to following standard in above embodiments:
Rub resistance (unlubricated friction, wet rub) color fastness is referring to GB/T 3920-2008, and fastness to soaping is referring to GB/T 3921-
2008, colour fasteness to sunlight is measured referring to GB/T 8427-2008.
Claims (5)
1. a kind of natural brown dyestuff, which is characterized in that using brown mushroom as raw material, preparation method include the following steps: according to
Water is that 6: 1 (v/w) are mixed with brown mushroom fructification powder ratio, to above-mentioned mixed liquor heating water bath, is heated at 100 DEG C of temperature
30min, to treated, mixed liquor 7000rpm is centrifuged 10min, takes supernatant spare, residue adds water to mention again according to same method
Once, stock staining solution will be mixed to obtain for supernatant twice.
2. natural brown dyestuff according to claim 1, which is characterized in that the natural brown dyestuff promotees dye so that salt is not added
Mode be used for fabric dyeing.
3. natural brown dyestuff according to claim 2, which is characterized in that the fabric is wool fabric.
4. natural brown dyestuff according to claim 2, which is characterized in that the natural brown dyestuff is used in the following manner
In textile dyeing:
Fabric soaks 20min with distilled water in advance, excludes interfibrous air, the ratio 1: 1 (v/v) of stock staining solution and water, dye
Color pH is 2~4, bath raio 1: 30,60~95 DEG C of dyeing temperature, keeps the temperature 80~120min, washes 3 times, soap after dyeing.
5. natural brown dyestuff according to claim 4, which is characterized in that the natural brown dyestuff is used for textile dyeing
It afterwards, is 3 grades according to the colour fasteness to sunlight of GB/T 8427-2008.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811018233.9A CN109206938B (en) | 2016-07-08 | 2016-07-08 | A kind of natural brown dyestuff |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610546613.4A CN106189346B (en) | 2016-07-08 | 2016-07-08 | A kind of natural brown dyestuff and its preparation method and application |
| CN201811018233.9A CN109206938B (en) | 2016-07-08 | 2016-07-08 | A kind of natural brown dyestuff |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610546613.4A Division CN106189346B (en) | 2016-07-08 | 2016-07-08 | A kind of natural brown dyestuff and its preparation method and application |
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| Publication Number | Publication Date |
|---|---|
| CN109206938A CN109206938A (en) | 2019-01-15 |
| CN109206938B true CN109206938B (en) | 2019-10-15 |
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| CN201610546613.4A Active CN106189346B (en) | 2016-07-08 | 2016-07-08 | A kind of natural brown dyestuff and its preparation method and application |
| CN201811018233.9A Active CN109206938B (en) | 2016-07-08 | 2016-07-08 | A kind of natural brown dyestuff |
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| CN113550156B (en) * | 2021-02-04 | 2023-04-07 | 浙江金昌特种纸股份有限公司 | Preparation method of brown dragon silk dyed by dye |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103155784A (en) * | 2011-12-09 | 2013-06-19 | 天津市金三农农业科技开发有限公司 | Cultural method for brown mushroom cultispecies |
| CN104829734A (en) * | 2014-10-10 | 2015-08-12 | 沈阳市粮油食品科学研究所 | Method of producing pigment, protein, polysaccharide and dietary fiber from dry lentinula edodes |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1040042A (en) * | 1988-08-05 | 1990-02-28 | 谢静波 | The extracting method of natural brown pigment |
| CN101007905A (en) * | 2007-01-22 | 2007-08-01 | 江苏省江大绿康生物工程技术研究有限公司 | Method of extracting and preparing Ma chestnut shell brown pigment |
| CN102732049B (en) * | 2012-06-04 | 2014-03-12 | 华中科技大学 | Method for preparing and extracting carotenoid from microbial thalli |
| CN105038300A (en) * | 2015-07-10 | 2015-11-11 | 珲春界三国农业有限公司 | Method for extracting yellow pigment from physalis alkekengi fruits |
| CN105062129A (en) * | 2015-08-11 | 2015-11-18 | 重庆都好生物科技有限公司 | Method for extracting anthocyanins from mulberries |
| CN105131644A (en) * | 2015-10-08 | 2015-12-09 | 嘉兴市欣纺纺织品有限公司 | Extracting method and dyeing method for sappan plant dye |
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2016
- 2016-07-08 CN CN201610546613.4A patent/CN106189346B/en active Active
- 2016-07-08 CN CN201811018233.9A patent/CN109206938B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103155784A (en) * | 2011-12-09 | 2013-06-19 | 天津市金三农农业科技开发有限公司 | Cultural method for brown mushroom cultispecies |
| CN104829734A (en) * | 2014-10-10 | 2015-08-12 | 沈阳市粮油食品科学研究所 | Method of producing pigment, protein, polysaccharide and dietary fiber from dry lentinula edodes |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106189346A (en) | 2016-12-07 |
| CN109206938A (en) | 2019-01-15 |
| CN106189346B (en) | 2018-10-30 |
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