CN109206639A - 改性塑料色母粒及其制备方法 - Google Patents
改性塑料色母粒及其制备方法 Download PDFInfo
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- CN109206639A CN109206639A CN201810968467.3A CN201810968467A CN109206639A CN 109206639 A CN109206639 A CN 109206639A CN 201810968467 A CN201810968467 A CN 201810968467A CN 109206639 A CN109206639 A CN 109206639A
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- pigments
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- amide resin
- masterbatch
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- 239000004594 Masterbatch (MB) Substances 0.000 title claims abstract description 80
- 239000004033 plastic Substances 0.000 title claims abstract description 43
- 229920003023 plastic Polymers 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 36
- 229920005989 resin Polymers 0.000 claims abstract description 88
- 239000011347 resin Substances 0.000 claims abstract description 83
- 239000000049 pigment Substances 0.000 claims abstract description 60
- 239000004743 Polypropylene Substances 0.000 claims abstract description 55
- 150000001408 amides Chemical class 0.000 claims abstract description 55
- -1 polypropylene Polymers 0.000 claims abstract description 55
- 229920001155 polypropylene Polymers 0.000 claims abstract description 55
- 239000000945 filler Substances 0.000 claims abstract description 47
- 244000068988 Glycine max Species 0.000 claims abstract description 30
- 235000010469 Glycine max Nutrition 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 102000015636 Oligopeptides Human genes 0.000 claims abstract description 29
- 108010038807 Oligopeptides Proteins 0.000 claims abstract description 29
- 239000004519 grease Substances 0.000 claims abstract description 18
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 14
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 14
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004014 plasticizer Substances 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 8
- QTKPMCIBUROOGY-UHFFFAOYSA-N 2,2,2-trifluoroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)F QTKPMCIBUROOGY-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims description 45
- 238000010792 warming Methods 0.000 claims description 25
- 239000007788 liquid Substances 0.000 claims description 16
- 238000002844 melting Methods 0.000 claims description 15
- 230000008018 melting Effects 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 238000005406 washing Methods 0.000 claims description 11
- 238000001914 filtration Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 7
- 238000010008 shearing Methods 0.000 claims description 7
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 6
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 6
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 6
- 239000008158 vegetable oil Substances 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 5
- 235000019483 Peanut oil Nutrition 0.000 claims description 4
- 239000000312 peanut oil Substances 0.000 claims description 4
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 4
- 235000019482 Palm oil Nutrition 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- 235000019198 oils Nutrition 0.000 claims description 3
- 239000002540 palm oil Substances 0.000 claims description 3
- 238000007127 saponification reaction Methods 0.000 claims description 3
- 239000002383 tung oil Substances 0.000 claims description 3
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims 1
- 150000002978 peroxides Chemical class 0.000 claims 1
- 239000006185 dispersion Substances 0.000 abstract description 12
- 229920000642 polymer Polymers 0.000 abstract description 11
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract description 11
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 abstract description 8
- 239000002270 dispersing agent Substances 0.000 abstract description 8
- 229910052731 fluorine Inorganic materials 0.000 abstract description 8
- 239000011737 fluorine Substances 0.000 abstract description 8
- 238000006116 polymerization reaction Methods 0.000 abstract description 7
- 150000001336 alkenes Chemical class 0.000 abstract description 4
- 238000009826 distribution Methods 0.000 abstract description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract description 4
- 230000015556 catabolic process Effects 0.000 description 13
- 238000006731 degradation reaction Methods 0.000 description 13
- 238000004040 coloring Methods 0.000 description 12
- 244000005700 microbiome Species 0.000 description 10
- 239000003963 antioxidant agent Substances 0.000 description 9
- 230000003078 antioxidant effect Effects 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 238000004132 cross linking Methods 0.000 description 7
- 229920002401 polyacrylamide Polymers 0.000 description 7
- 238000000354 decomposition reaction Methods 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 239000003086 colorant Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000000813 microbial effect Effects 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 150000008065 acid anhydrides Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000003549 soybean oil Substances 0.000 description 3
- 235000012424 soybean oil Nutrition 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 2
- 229940092714 benzenesulfonic acid Drugs 0.000 description 2
- 239000004595 color masterbatch Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 125000004205 trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 description 2
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- SRLOPAUVNCLFFG-UHFFFAOYSA-N NC(=O)C=C.CC(=C)C(=O)OCC(F)(F)F Chemical compound NC(=O)C=C.CC(=C)C(=O)OCC(F)(F)F SRLOPAUVNCLFFG-UHFFFAOYSA-N 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
Abstract
Description
实施例4 | 实施例5 | 实施例6 | 实施例7 | 实施例8 | |
10天 | 18.3% | 18.5% | 19.1% | 13.5% | 0.3% |
20天 | 31.6% | 30.5% | 35.3% | 20.7% | 0.5% |
30天 | 64.2% | 67.5% | 72.1% | 31.5% | 0.6% |
40天 | 91.4% | 92.3% | 97.7% | 42.6% | 0.6% |
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201810968467.3A CN109206639B (zh) | 2018-08-23 | 2018-08-23 | 改性塑料色母粒及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201810968467.3A CN109206639B (zh) | 2018-08-23 | 2018-08-23 | 改性塑料色母粒及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN109206639A true CN109206639A (zh) | 2019-01-15 |
CN109206639B CN109206639B (zh) | 2019-06-28 |
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CN201810968467.3A Active CN109206639B (zh) | 2018-08-23 | 2018-08-23 | 改性塑料色母粒及其制备方法 |
Country Status (1)
Country | Link |
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CN (1) | CN109206639B (zh) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5512465B2 (zh) * | 1977-07-06 | 1980-04-02 | ||
CN102558680A (zh) * | 2011-12-29 | 2012-07-11 | 海尔科化工程塑料国家工程研究中心股份有限公司 | 抗菌色母 |
CN103694683A (zh) * | 2013-12-28 | 2014-04-02 | 宁波金富亮塑料科技有限公司 | 一种尼龙用色母粒 |
CA2945688A1 (en) * | 2014-03-14 | 2015-09-17 | University Of Guelph | Renewable replacements for carbon black in composites and methods of making and using thereof |
CN106589914A (zh) * | 2016-11-03 | 2017-04-26 | 苏州圣鑫莱新材料有限公司 | 一种纳米pa色母粒 |
-
2018
- 2018-08-23 CN CN201810968467.3A patent/CN109206639B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5512465B2 (zh) * | 1977-07-06 | 1980-04-02 | ||
CN102558680A (zh) * | 2011-12-29 | 2012-07-11 | 海尔科化工程塑料国家工程研究中心股份有限公司 | 抗菌色母 |
CN103694683A (zh) * | 2013-12-28 | 2014-04-02 | 宁波金富亮塑料科技有限公司 | 一种尼龙用色母粒 |
CA2945688A1 (en) * | 2014-03-14 | 2015-09-17 | University Of Guelph | Renewable replacements for carbon black in composites and methods of making and using thereof |
CN106589914A (zh) * | 2016-11-03 | 2017-04-26 | 苏州圣鑫莱新材料有限公司 | 一种纳米pa色母粒 |
Also Published As
Publication number | Publication date |
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CN109206639B (zh) | 2019-06-28 |
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Effective date of registration: 20190604 Address after: 264200 Weixing Road-3-1, Weishan Town, Weihai Lingang Economic and Technological Development Zone, Weihai City, Shandong Province Applicant after: WEIHAI WEIYING PLASTIC Co.,Ltd. Address before: 312456 No. 21 Huatang Village, Jinting Town, Shengzhou City, Shaoxing City, Zhejiang Province Applicant before: SHENGZHOU ZHONGMING NEW MATERIAL TECHNOLOGY CO.,LTD. |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
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Denomination of invention: Modified plastic masterbatch and its preparation method Effective date of registration: 20210122 Granted publication date: 20190628 Pledgee: Shandong Wendeng Rural Commercial Bank Co.,Ltd. Pledgor: WEIHAI WEIYING PLASTIC Co.,Ltd. Registration number: Y2021980000621 |
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Date of cancellation: 20230214 Granted publication date: 20190628 Pledgee: Shandong Wendeng Rural Commercial Bank Co.,Ltd. Pledgor: WEIHAI WEIYING PLASTIC Co.,Ltd. Registration number: Y2021980000621 |
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Denomination of invention: Modified plastic color masterbatch and its preparation method Effective date of registration: 20230227 Granted publication date: 20190628 Pledgee: Shandong Wendeng Rural Commercial Bank Co.,Ltd. Pledgor: WEIHAI WEIYING PLASTIC Co.,Ltd. Registration number: Y2023980033608 |
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Granted publication date: 20190628 Pledgee: Shandong Wendeng Rural Commercial Bank Co.,Ltd. Pledgor: WEIHAI WEIYING PLASTIC Co.,Ltd. Registration number: Y2023980033608 |
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Denomination of invention: Modified plastic masterbatch and its preparation method Granted publication date: 20190628 Pledgee: Shandong Wendeng Rural Commercial Bank Co.,Ltd. Pledgor: WEIHAI WEIYING PLASTIC Co.,Ltd. Registration number: Y2024980006121 |
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