CN109157790A - New and effective fire extinguishing material of one kind and preparation method thereof - Google Patents
New and effective fire extinguishing material of one kind and preparation method thereof Download PDFInfo
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- CN109157790A CN109157790A CN201811214393.0A CN201811214393A CN109157790A CN 109157790 A CN109157790 A CN 109157790A CN 201811214393 A CN201811214393 A CN 201811214393A CN 109157790 A CN109157790 A CN 109157790A
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- fire extinguishing
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- extinguishing material
- effective fire
- phosphate
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Classifications
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/06—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires containing gas-producing, chemically-reactive components
Abstract
The invention belongs to field of material technology of putting out a fire, disclose a kind of new and effective fire extinguishing material, it is consisted of the following components in percentage by weight: surfactant 5%-10%, thickener 0.5%-2%, fire retardant 2%-10%, antifreezing agent 5%-20%, inorganic salts 5%-10%, urea 6%-15%, disodium ethylene diamine tetraacetate 2%-10%, remaining is water.Selected raw material are safe and non-toxic in fire extinguishing material provided by the invention, and environmental sound is at low cost；It not only can effectively stamp out a fire, moreover it is possible to cover a protective layer in body surface, prevent re-ignition.
Description
Technical field
The invention belongs to field of material technology of putting out a fire, and are related to new and effective fire extinguishing material of one kind and preparation method thereof.
Background technique
Extinguishing chemical is to refer to effectively destroy burning condition, terminates the substance of burning.It is divided into liquid by its state feature
Extinguishing chemical, solid extinguishing agent and gas extinguishing agent three categories.Liquid extinguisher specifically includes that water and water based fire suppressant, and foam goes out
Fiery agent etc.；Solid extinguishing agent specifically includes that aerosol extinguishing agent, dry powder fire extinguishing agent etc.；Gas extinguishing agent specifically includes that titanium dioxide
Carbon extinguishing chemical, carbon tetrachloride extinguishing chemical, heptafluoro-propane extinguishing chemical, halon alternative, inert gas agent etc..
It is widely used currently on the market to be still fire foam and dry powder fire extinguishing agent, it is put out a fire using fire foam
Afterwards, the remaining a large amount of foams in scene of fire are difficult to dispose, while polluting environment, cause permanently to influence；The anti-re-ignition of dry powder fire extinguishing agent
Ability is poor, and easily causes secondary pollution.
Summary of the invention
The purpose of the present invention is to provide a kind of new and effective fire extinguishing material, safe and non-toxic, environmental sound is at low cost.
To achieve the above object, the invention adopts the following technical scheme:
A kind of new and effective fire extinguishing material, consists of the following components in percentage by weight: surfactant 5%-10%, thickener
0.5%-2%, fire retardant 2%-10%, antifreezing agent 5%-20%, inorganic salts 5%-10%, urea 6%-15%, disodium ethylene diamine tetraacetate 2%-
10%, remaining is water.
Further, the surfactant is lauryl sodium sulfate, neopelex, alkyl-glucoside
Or one of fatty glyceride or a variety of.
Further, the thickener be soluble starch, gelatin, sodium alginate, casein, guar gum, chitosan, Ah
Draw one of uncle's natural gum or xanthan gum or a variety of.
Further, the fire retardant is phosphate toluene diphenyl ester, tricresyl phosphate, triphenyl phosphate or phosphoric acid -2-
One of ethylhexyl diphenyl ester is a variety of.
Further, the antifreezing agent is one of calcium chloride, sodium acetate or magnesium chloride or a variety of.
Further, the inorganic salts are in potassium carbonate, sodium bicarbonate, tripotassium phosphate, tertiary sodium phosphate or disodium bicarbonate
It is one or more.
The present invention also provides the preparation methods of the new and effective fire extinguishing material of above-mentioned one kind, comprising the following steps: according to above-mentioned
Weight percent weighs material, successively puts into the water that temperature is 30 DEG C -45 DEG C, uniform stirring to material is completely dissolved；It will be upper
It states the solution that step obtains to be filtered, is packed into container, normal temperature storage after being then allowed to stand 3 hours.
Compared with prior art, the beneficial effects of the present invention are:
1. fire extinguishing material provided by the invention be suitable for A class solid fire, selected raw material are safe and non-toxic, to environment without
Evil, it is at low cost；It not only can effectively stamp out a fire, moreover it is possible to cover a protective layer in body surface, prevent re-ignition.
2. the surfactant added in present invention fire extinguishing material, it is possible to increase the contact surface of raw material and water；Heated point of urea
The ammonia and carbon dioxide generated is solved, the oxygen near fire can be effectively diluted, have the function of fire smothering.
3. tradition fire extinguishing material antifreezing agent generally use ethylene glycol, fire extinguishing when it is readily volatilized easily by human body suck and in
Poison, and antifreezing agent of the present invention will not generate toxic gas in fire extinguishing procedure, and chlorine element can reduce the quantity of free radical, effectively
Inhibit burning；In addition, organic phosphates fire retardant can generate structure more stable crosslinking shape solid matter or carburization zone when heated,
On the one hand polymer can be prevented further to be pyrolyzed, the thermal decomposition generation that it on the other hand can be prevented internal enters gas phase and participates in combustion
Burning process.
Specific embodiment
The following examples are intended to illustrate the invention, but is not used to limit the scope of protection of the present invention.Unless otherwise specified, real
Apply the conventional means that technological means used in example is well known to those skilled in the art.Test method in following embodiments, such as
It is conventional method without special instruction.
Reagent in the present invention: lauryl sodium sulfate is purchased from the sub- safe joint Chemical Co., Ltd. of Wuxi City, soluble starch
Purchased from Jining Heng Tai Chemical Co., Ltd., tricresyl phosphate dimethylbenzene is purchased from Zhangjiagang Ya Rui Chemical Co., Ltd., and calcium chloride is purchased from
Qinghai source of iron Mei Ye Co., Ltd, sodium bicarbonate are purchased from Xi'an Tian Mao Chemical Co., Ltd., and urea has purchased from Xi'an Tian Mao chemical industry
Limit company, disodium ethylene diamine tetraacetate are purchased from Xi'an Tian Mao Chemical Co., Ltd., and fatty glyceride is purchased from Shandong Binzhou Jin Sheng
New material Science and Technology Ltd., casein are purchased from the prosperous Chemical Industry Science Co., Ltd of Tianjin auspicious sign, phosphoric acid -2- ethylhexyl hexichol
Ester is purchased from Zhangjiagang Ya Rui Chemical Co., Ltd., and sodium acetate is purchased from Xi'an Tian Mao Chemical Co., Ltd., and tertiary sodium phosphate is purchased from Xi'an
Tian Mao Chemical Co., Ltd., neopelex are purchased from mountain purchased from the sub- safe joint Chemical Co., Ltd. of Wuxi City, guar gum
Dong You Rong Biotechnology Co., Ltd, tricresyl phosphate are purchased from Guangdong Weng Jiang chemical reagent Co., Ltd, disodium bicarbonate purchase
From Shanghai Er Chemical Co., Ltd., chitosan is purchased from Shanghai Chinese blue chemistry Science and Technology Ltd., and potassium chloride is auspicious purchased from Tianjin
Rui Xin Chemical Industry Science Co., Ltd, alkyl-glucoside is purchased from the sub- safe joint Chemical Co., Ltd. of Wuxi City, gum arabic purchase
From the prosperous Chemical Industry Science Co., Ltd of Tianjin auspicious sign.
Embodiment 1
A kind of new and effective fire extinguishing material, consists of the following components in percentage by weight: lauryl sodium sulfate 7%, and solubility is formed sediment
Powder 1%, tricresyl phosphate-diphenyl ester 3%, calcium chloride 6%, sodium bicarbonate 8%, urea 10%, disodium ethylene diamine tetraacetate 5%, water 60%.
The preparation method of the above-mentioned new and effective fire extinguishing material of one kind, comprising the following steps: claim according to above-mentioned weight percent
Material is taken, is successively put into the water that temperature is 30 DEG C -45 DEG C, uniform stirring to material is completely dissolved；Above-mentioned steps are obtained
Solution is filtered, and is packed into container, normal temperature storage after being then allowed to stand 3 hours.
Embodiment 2
A kind of new and effective fire extinguishing material, consists of the following components in percentage by weight: fatty glyceride 5%, casein 1%,
2 ethyl hexyl diphenyl phosphate 2%, sodium acetate 5%, tertiary sodium phosphate 5%, urea 6%, disodium ethylene diamine tetraacetate 2%, water 74%.
The preparation method of the above-mentioned new and effective fire extinguishing material of one kind, comprising the following steps: claim according to above-mentioned weight percent
Material is taken, is successively put into the water that temperature is 30 DEG C -45 DEG C, uniform stirring to material is completely dissolved；Above-mentioned steps are obtained
Solution is filtered, and is packed into container, normal temperature storage after being then allowed to stand 3 hours.
Embodiment 3
A kind of new and effective fire extinguishing material, consists of the following components in percentage by weight: neopelex 8%, guar gum
0.5%, tricresyl phosphate 5%, sodium acetate 8%, disodium bicarbonate 6%, urea 8%, disodium ethylene diamine tetraacetate 5%, water 59.5%.
The preparation method of the above-mentioned new and effective fire extinguishing material of one kind, comprising the following steps: claim according to above-mentioned weight percent
Material is taken, is successively put into the water that temperature is 30 DEG C -45 DEG C, uniform stirring to material is completely dissolved；Above-mentioned steps are obtained
Solution is filtered, and is packed into container, normal temperature storage after being then allowed to stand 3 hours.
Embodiment 4
A kind of new and effective fire extinguishing material, consists of the following components in percentage by weight: neopelex 7%, guar gum
2%, tricresyl phosphate 8%, calcium chloride 10%, disodium bicarbonate 8%, urea 12%, disodium ethylene diamine tetraacetate 8%, water 45%.
Embodiment 5
A kind of new and effective fire extinguishing material, consists of the following components in percentage by weight: neopelex 10%, crust
Amine 1.5%, triphenyl phosphate 5%, potassium chloride 6%, sodium bicarbonate 8%, urea 15%, disodium ethylene diamine tetraacetate 5%, water 49.5%.
Embodiment 6
A kind of new and effective fire extinguishing material, consists of the following components in percentage by weight: alkyl-glucoside 10%, Arab tree
Glue 1%, tricresyl phosphate 7%, sodium acetate 15%, disodium bicarbonate 10%, urea 15%, disodium ethylene diamine tetraacetate 10%, water
32%。
Embodiment 7
A kind of new and effective fire extinguishing material, consists of the following components in percentage by weight: neopelex 10%, xanthan
Glue 1%, 2 ethyl hexyl diphenyl phosphate 6%, sodium acetate 20%, disodium bicarbonate 8%, urea 10%, disodium ethylene diamine tetraacetate
8%, water 37%.
Embodiment 8
A kind of new and effective fire extinguishing material, consists of the following components in percentage by weight: surfactant 10%, thickener 2%, phosphorus
Sour toluene-diphenyl ester 5%, antifreezing agent 15%, inorganic salts 10%, urea 7%, disodium ethylene diamine tetraacetate 8%, water 43%.Wherein surface
Activating agent is lauryl sodium sulfate and alkyl glucoside, and the two mass ratio is 1:1；Thickener is soluble starch and alginic acid
Sodium, the two mass ratio are 2:1；Antifreezing agent is calcium chloride and magnesium chloride, and the two mass ratio is 1:1；Inorganic salts are potassium carbonate, carbonic acid
Hydrogen sodium and tripotassium phosphate, three's mass ratio are 1:2:1.
Embodiment 9
A kind of new and effective fire extinguishing material, consists of the following components in percentage by weight: surfactant 8%, thickener 1.5%,
Fire retardant 4%, antifreezing agent 15%, inorganic salts 10%, urea 7%, disodium ethylene diamine tetraacetate 8%, water 46.5%.Wherein surfactant
For lauryl sodium sulfate, neopelex and alkyl glucoside, three's mass ratio is 1:1:1；Thickener is solvable
Property starch and sodium alginate, the two mass ratio is 3:1；Fire retardant is tricresyl phosphate-diphenyl ester and tricresyl phosphate, the two matter
Amount is than being 1:1；Antifreezing agent is calcium chloride and magnesium chloride, and the two mass ratio is 2:1；Inorganic salts be potassium carbonate and tripotassium phosphate, two
Person's mass ratio is 2:1.
Embodiment 10
A kind of new and effective fire extinguishing material, consists of the following components in percentage by weight: surfactant 9%, thickener 1.5%,
Fire retardant 4%, antifreezing agent 15%, inorganic salts 9%, urea 7%, disodium ethylene diamine tetraacetate 8%, water 46.5%.Wherein surfactant
For lauryl sodium sulfate, neopelex and alkyl glucoside, three's mass ratio is 1:1:1；Thickener is solvable
Property starch, gelatin and sodium alginate, three's mass ratio be 1:1:1；Fire retardant is tricresyl phosphate-diphenyl ester, tricresyl phosphate
And triphenyl phosphate, three's mass ratio are 1:1:1；Antifreezing agent is calcium chloride and magnesium chloride, and the two mass ratio is 1:1；Inorganic salts
For potassium carbonate, sodium bicarbonate and tripotassium phosphate, three's mass ratio is 1:1:1.
The embodiment of the above, only presently preferred embodiments of the present invention, is only used to explain the present invention, not limit
The scope of the present invention processed to those of ordinary skill in the art certainly can be according to skill disclosed in this specification
Art content makes other embodiments easily by way of replacing or changing, therefore all made in the principle of the present invention
Changes and improvements etc., should be included in scope of the present invention patent.
Claims (7)
1. a kind of new and effective fire extinguishing material, which is characterized in that consist of the following components in percentage by weight: surfactant
5%-10%, thickener 0.5%-2%, fire retardant 2%-10%, antifreezing agent 5%-20%, inorganic salts 5%-10%, urea 6%-15%, ethylenediamine
Tetraacethyl disodium 2%-10%, remaining is water.
2. a kind of new and effective fire extinguishing material according to claim 1, which is characterized in that the surfactant is 12
One of sodium alkyl sulfate, neopelex, alkyl-glucoside or fatty glyceride are a variety of.
3. a kind of new and effective fire extinguishing material according to claim 1, which is characterized in that the thickener is soluble forms sediment
One of powder, gelatin, sodium alginate, casein, guar gum, chitosan, gum arabic or xanthan gum are a variety of.
4. a kind of new and effective fire extinguishing material according to claim 1, which is characterized in that the fire retardant is tricresyl phosphate
One of diphenyl ester, tricresyl phosphate, triphenyl phosphate or 2 ethyl hexyl diphenyl phosphate are a variety of.
5. a kind of new and effective fire extinguishing material according to claim 1, which is characterized in that the antifreezing agent be calcium chloride,
One of sodium acetate or magnesium chloride are a variety of.
6. a kind of new and effective fire extinguishing material according to claim 1, which is characterized in that the inorganic salts be potassium carbonate,
One of sodium bicarbonate, tripotassium phosphate, tertiary sodium phosphate or disodium bicarbonate are a variety of.
7. the described in any item one kind of claim 1 ~ 6 it is new and effective fire extinguishing material preparation method, which is characterized in that including with
Lower step: weight percent described in accordance with the claim 1 weighs material, successively puts into the water that temperature is 30 DEG C -45 DEG C,
Even stirring to material is completely dissolved；The solution that above-mentioned steps are obtained is filtered, and is packed into container after being then allowed to stand 3 hours,
Normal temperature storage.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811214393.0A CN109157790A (en) | 2018-10-18 | 2018-10-18 | New and effective fire extinguishing material of one kind and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811214393.0A CN109157790A (en) | 2018-10-18 | 2018-10-18 | New and effective fire extinguishing material of one kind and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN109157790A true CN109157790A (en) | 2019-01-08 |
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ID=64878671
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811214393.0A Pending CN109157790A (en) | 2018-10-18 | 2018-10-18 | New and effective fire extinguishing material of one kind and preparation method thereof |
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| CN (1) | CN109157790A (en) |
Cited By (3)
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|---|---|---|---|---|
| CN110302489A (en) * | 2019-07-22 | 2019-10-08 | 北京利新泰奇科技有限公司 | A kind of antifreeze water-based extinguishing agent of environmental-protection flame-retardant |
| CN113018754A (en) * | 2019-12-25 | 2021-06-25 | 应急管理部消防产品合格评定中心 | Universal high-stability foam extinguishing agent |
| KR102599335B1 (en) * | 2023-08-02 | 2023-11-07 | 염도영 | Extinguishing Agent Built-in Type Battery Module |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110302489A (en) * | 2019-07-22 | 2019-10-08 | 北京利新泰奇科技有限公司 | A kind of antifreeze water-based extinguishing agent of environmental-protection flame-retardant |
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| CN113018754A (en) * | 2019-12-25 | 2021-06-25 | 应急管理部消防产品合格评定中心 | Universal high-stability foam extinguishing agent |
| KR102599335B1 (en) * | 2023-08-02 | 2023-11-07 | 염도영 | Extinguishing Agent Built-in Type Battery Module |
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Application publication date: 20190108 |