CN106139498A - Water system extinguishment additive agent - Google Patents

Water system extinguishment additive agent Download PDF

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Publication number
CN106139498A
CN106139498A CN201610614265.XA CN201610614265A CN106139498A CN 106139498 A CN106139498 A CN 106139498A CN 201610614265 A CN201610614265 A CN 201610614265A CN 106139498 A CN106139498 A CN 106139498A
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concentration
ammonium
phosphate
sodium
fire
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陈潜
胡亦夏
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    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0028Liquid extinguishing substances
    • A62D1/0035Aqueous solutions
    • A62D1/0042"Wet" water, i.e. containing surfactant
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0064Gels; Film-forming compositions
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0071Foams
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/06Fire-extinguishing compositions; Use of chemical substances in extinguishing fires containing gas-producing, chemically-reactive components

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Fireproofing Substances (AREA)

Abstract

The invention discloses a kind of water system extinguishment additive agent, include and be mixed in proportion formed by fire-extinguishing function concurrently component and anti-resume combustion function ingredients, wherein fire-extinguishing function concurrently component is by refrigerating function component, cover isolation features component, water down the function ingredients that suffocates, block pyric chain function ingredients and emulsifying agent composition thereof, anti-resume combustion function ingredients is by nano-thermal-insulating fire resistant flame retardant material and suspension dispersive agent thereof, water-soluble inorganic flame retardant, radiation-absorbing material, film former forms, described covering isolation features component is the foaming surfactant that foaming characteristic is high, fluorine system surfactant, silicon system surfactant and foam stabilizing additive etc. form.For timber, paper, cotton products, Radix Glycyrrhizae, coal, rubber, nonpolar liquid such as gasoline, kerosene etc.), the fire that causes of the industrial chemicals such as polar liquid (such as methanol, ethanol etc.) and magnesium titanium possess extremely prominent extinguishing effect.

Description

Water system extinguishment additive agent
Technical field
The present invention relates to water system extinguishment additive agent, particularly relate to relate to water for fire extinguishing additive.
Background technology
In water, add some additive be referred to as water system extinguishment additive agent with the extinguishing property improving water.The U.S. is referred to as Water for fire extinguishing additive Water additive agent for fire fighting, and Japan is known as water system fire extinguishing and adds Add agent.Fire constitutes the poisonous dense smoke that threat, particularly fire produce greatly and makes especially the security of the lives and property of the mankind Become the arch-criminal of scene of a fire casualties.Therefore, using fast and effeciently extinguishment product, stamping out a fire in time is that redemption personnel are raw The necessary means of life property loss.In addition along with mankind's pay attention to day by day to environmental conservation, the green fire extinguishing of development environment friend Yu Product is paid attention to by people the most day by day.Theoretical according to fire-fighting Combustion, fire is the combustion reaction of combustible.Need flammable Thing, oxidizer and 3 conditions of incendiary source just can occur.Visible, prevent and control the ultimate principle of fire to destroy burning exactly One or several condition, fire prevention measure to be carried out, once catch fire, implement fire extinguishing way, make flameout, to a certain degree The hazardness of upper reduction fire.When after combustible combustion, it is necessary to take corresponding extinguishing method so that it is stop burning.Fire extinguishing can Put out a fire with the ultimate principle by cooling down, suffocate, isolate, Chemical Inhibition 4 being put out a fire.4 kinds of fire-fighting principles go out different Embodying difference in fire agent, one or more play a role jointly under normal circumstances.By fire in GB GB/T4968-2008 It is divided into A class fire: solid matter fire, B class fire: liquid or fusible solid matter fire, C class fire: gas fire, D class fire: metallic fires and F class fire: animal and plant fat fire 6 types in kitchen.
At present, widely used all kinds of extinguishing chemical product has more or less in terms of extinguishing property or environmental conservation Not enough weary place, and the inhibitory action for fire smoke is very limited.Breathe out dragon series extinguishing chemical due to broken containing freon etc. The material of bad ozone layer, breathes out dragon industry according to international Montreal Protocol and China and eliminates plan, within 2010, proceed by by Step is eliminated.At present, the substitution studies of halon fire agent can be divided into two general orientation: the application that (1) substitutes with other fire extinguishing system is ground Study carefully.As substituted with C02, fine water mist fire-extinguishing system etc.;(2) a kind of new and effective, environmental protection of exploitation, with low cost and energy Enough eliminating the extinguishing chemical of the poisonous dense smoke in the scene of a fire, this is for promoting that the development of domestic and international fire-fighting cause has highly important meaning. Efficiently water system extinguishment additive agent extinguishing mechanism depends on 4 main mechanisms: reduce the surface tension of water, unique amphipathic point Minor structure, fast cooling form and keep microvesicle, interrupt free chain reaction.
Summary of the invention
It is an object of the invention to provide one and can quickly put out solid matter such as timber, withered, hair, fiber crops, paper and system thereof The A class fire of product, and the thing such as liquid or fusible solid such as gasoline, kerosene, diesel oil, crude oil, methanol, ethanol, Colophonium, paraffin The B class fire of matter, and there is the formula composition of the water system extinguishment additive agent of anti-resume combustion usefulness.Owing to A, B class fire relates to day A lot of occasions of often life and production activity, therefore this extinguishing chemical can be used for family's fire extinguishing, urban architecture fire extinguishing, oil depot with The confined spaces such as gas station's fire extinguishing, vehicle naval vessel fire extinguishing, sylvosteppe fire extinguishing, mine fire extinguishing and people's air defense building are prevented The fields such as fire extinguishing.
The technical solution realizing the object of the invention is: a kind of compounding synergetic A, B class water system extinguishment additive agent, by Fire-extinguishing function concurrently component and anti-resume combustion function ingredients application function component are mixed in proportion and form, it is characterised in that: merit of wherein putting out a fire Can component by refrigerating function component, cover isolation features component, water down the function ingredients that suffocates, block pyric chain function ingredients and Emulsifying agent forms, and anti-resume combustion function ingredients is fire-retardant by nano-thermal-insulating fire resistant flame retardant material and suspension dispersive agent thereof, water-soluble inorganic Agent, radiation-absorbing material, film former composition, application function component is by antifreeze, coloring agent, luminous agent, preservative, corrosion inhibiter group Become;Described covering isolation features component is foaming surfactant that foaming characteristic is high, fluorine system surfactant, silicon system surface activity Agent and foam stabilizing additive, it is any one that foaming surfactant includes in sodium lauryl sulphate, dodecyl sodium sulfate, glycine betaine Kind or two or more combination;The concentration of foaming surfactant is 10~30g/L;Fluorine system surfactant dense Degree is l~5ml/L;The concentration of silicon system surfactant is 1~2ml/L;Foam stabilizing additive include polyvinyl alcohol, polyacrylamide, 6501, any one or two or more the combination of albumen, polypeptide Shen, the concentration of foam stabilizing additive is 0. 25~0.5g/ L;The described function ingredients that suffocates includes Inorganic Ammonium and organic amine two parts, and Inorganic Ammonium has ammonium carbonate, ammonium hydrogen carbonate, ammonium chloride and grass Acid ammonium, organic amine includes carbamide, tripolycyanamide and dicyandiamide;Ammonium carbonate, the concentration of ammonium hydrogen carbonate are 20~40g/L, ammonium chloride, The concentration of ammonium oxalate is 20~50g/L, and the concentration of organic amine is 10~70g/L;Described water-soluble inorganic flame retardant includes silicic acid Sodium, Firebrake ZB, phosphate, phosphate mainly have ammonium dihydrogen phosphate, sodium dihydrogen phosphate, ammonium hydrogen phosphate or dibastic sodium phosphate, ammonium phosphate, Sodium phosphate or APP;The concentration of sodium silicate is 0.2~1. Og/L, and boric acid zinc concentration is 0.2~0. 4g/L, di(2-ethylhexyl)phosphate Hydrogen ammonium, the concentration of sodium dihydrogen phosphate are 5~30g/L, and ammonium hydrogen phosphate, the concentration of dibastic sodium phosphate are 10~80g/L, ammonium phosphate, phosphorus Acid sodium, the concentration of APP are 10~50g/L;Described antifreeze includes a, organic antifreeze: ethylene glycol, glycerol, chloroform, One or both or two or more combination in acetone, ether material, b, inorganic antifreeze: barium chloride, sodium chloride, calcium chloride, One or both or two or more combination in ammonium thiocyanate, ammonium sulfate, sodium bromide, magnesium chloride material;Organic antifreeze dense Degree is l~2ml/L, and the concentration of inorganic antifreeze is 10~30g/L;Described corrosion inhibiter includes a, carbonate: sodium carbonate or carbonic acid Potassium, b, acetate: sodium acetate or ammonium carbonate, c, boric acid basin: sodium tetraborate or Borax;The concentration of carbonate is 2~20g/L, vinegar The concentration of hydrochlorate is 2~4g/L, and boratory concentration is 1~2g/L.
Present invention have the advantage that various fire-extinguishing function concurrently component collaborative carries out cooling down, waters down, covers isolation, blocking-up pyric chain The effect such as suffocate and the combustion reaction that quickly stamps out a fire;Add various can combustible surface formed heat-resistant fireproof cover layer Function ingredients, strengthen anti-resume combustion
Performance, poison gas generation amount is few, and personnel escape's chance of surviving increases;The inorganic antifreeze of a large amount of use, without flammability issues, With the addition of luminous agent, marked effect can be played;The extinguishing chemical fire-fighting efficiency of the present invention is high, safe and reliable, Costco Wholesale Non-corrosiveness low, nontoxic,
Can put out a fire to save life and property A class fire and B class fire simultaneously, use wide, can be used for many god's occasion fire extinguishing.And it is possible to accomplish Formula is adjustable, according to concrete use occasion, it is also possible to reduce cost further.
Detailed description of the invention
For making the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with embodiment, the present invention is entered One step describes in detail.
In embodiment of the present invention water system extinguishment additive agent, including the refrigerating function water group containing gross weight 50% to 90% Point.The extinguishing mechanism of the bulk composition water of extinguishing chemical cools down the most exactly, and the steam that water is thermally generated may also operate as watering down Oxygen, the effect of the flame that suffocates, the labile carbonate that is heated, bicarbonate, oxalates, the endothermic decomposition reaction of carbamide also may be used To play cooling effect.
Described covering isolation features component is foaming surfactant that foaming characteristic is high, makes froth bed densification and have resistance Combustion the fluorine system surfactant of function, silicon system surfactant, for maintaining stablizing of foam blanket, in addition it is also necessary to add and have surely The foam stabilizing additive of bubble function, foaming surfactant includes appointing in sodium lauryl sulphate, dodecyl sodium sulfate, glycine betaine Anticipate one or both or two or more combination;The concentration of foaming surfactant is 10~30g/L;Fluorine system surfactant bag Include AF4018-2, AF4018-8J, in 6201 any one or two
Kind or two or more combinations, the concentration of fluorine system surfactant is 1~5ml/L;Silicon system surfactant includes FY- 4903, any one or two or more the combination in FY-4902, FY-F502, FY-F501, Sylgard309, silicon Be the concentration of surfactant be 1~2ml/L;Foam stabilizing additive include polyvinyl alcohol, polyacrylamide, 6501, albumen, in polypeptide Any one or two or more combination, the concentration of foam stabilizing additive is 0. 25~0.5g/L.
The described function ingredients that suffocates includes Inorganic Ammonium and organic amine two parts, and Inorganic Ammonium has ammonium carbonate, ammonium hydrogen carbonate, chlorine Changing ammonium and ammonium oxalate, organic amine includes carbamide, tripolycyanamide and dicyandiamide, organic have carbamide, tripolycyanamide, dicyandiamide etc. It is heated and is easily decomposed to form the compound of the non-combustible gas such as carbon dioxide, steam, ammonia, nitrogen and plays and water down oxygen, suffocate Flame function;Ammonium carbonate, the concentration of ammonium hydrogen carbonate are 20~40g/L, ammonium chloride, ammonium oxalate concentration be 20~50g/L, have The concentration of machine amine is 10~70g/L.Described blocking-up pyric chain function ingredients and emulsifying agent thereof play the burning that suppression has flame so to burn The function of chain reaction, mainly has: a, organophosphorous fire retardant, including triethyl phosphate, tributyl phosphate, triphenyl, One or both or two or more combination, the concentration of organophosphorous fire retardant in tricresyl phosphate, methyl-phosphoric acid dimethyl ester It is 0.2~0. 4ml/L.b, organic halogen fire retardant, including chlorinated paraffin, chlorendic anhydride (HET acid), tetrachlorophthalic anhydride, epoxy chloropropionate One in alkane, three (B mono-chloroethyl) phosphate ester (TCEP), three (Dichloroethyl) phosphate ester, three (chloropropyl) phosphate ester or Two or more combination, the concentration of organic halogen fire retardant is 0.3~0. 5ml/L;C, organic silicon fibre retardant: SFR-10, SFR-100, SFR-1000, FRX-210, polysiloxanes, one or both and two or more combination, the organosilicon of DC RM4-708 The concentration of fire retardant is 0.2~0. 4ml/L;D, because above-mentioned functions component in have water-fast liquid, so needing to add breast Agent is emulsified uniformly system, addible emulsifying agent such as: addible emulsifying agent includes Emulphor FM, OP-10, TX- 10, A-20,6501,6503, one or both or two or more combination in TW60, TW80, span80, the concentration of emulsifying agent is 0. 02~0.04ml/L.
Described nano-thermal-insulating fire resistant flame retardant material and suspension dispersive agent thereof improve the heat-resisting quantity of material, reduce ripe transmission effect Really, producing fire-retardant, heat-blocking action, chemical composition is mainly: a, nano heat insulating material: the asbestos fibre of nanoscale fineness, expansion One or both or two or more combination in perlite, celluar concrete, foam glass, the concentration of nano heat insulating material is 0. 05~0.lg/L.b, nanometer refractory material: the chromium oxide of nanoscale fineness, calcium oxide, lanthana, beryllium oxide, zirconium oxide, oxidation Uranium, cerium oxide, thorium oxide, titanium carbide, ramet, boron nitride, silicon nitride, zirconium boride, titanium boride, hafnium boride, molybdenum disilicide, sulfur Changing one or both or the two or more combination in thorium, cerium sulphide, the concentration of nanometer refractory material is 0. 05~0.lg/L;c、 Nano-meter flame retardants: in the antimony oxide of nanoscale fineness, Antimonic oxide, aluminium hydroxide, aluminium oxide, magnesium oxide, magnesium hydroxide One or both or two or more combination, the concentration of nano-meter flame retardants is 0. 05~0.lg/L;D, the suspension of insoluble solids surpass Dispersant: 12-hydroxy stearic acid and £ mono-caprolactone, terminal carboxyl polyester, many caprolactones polyol complex;Oxirane, ring Ethylene Oxide, oxolane homopolymer and copolymer in one or both or two or more combination, suspension hyper-dispersant dense Degree is 0.1~0. 2ml/L.
Described water-soluble inorganic flame retardant can reduce oxygen and heat to the transmission within combustible, including sodium silicate, boron Acid zinc, phosphate, phosphate mainly has ammonium dihydrogen phosphate, phosphoric acid
Sodium dihydrogen, ammonium hydrogen phosphate or dibastic sodium phosphate, ammonium phosphate, sodium phosphate or APP;The concentration of sodium silicate is 0.2~1. Og/L, boric acid zinc concentration is 0.2~0. 4g/L, and ammonium dihydrogen phosphate, the concentration of sodium dihydrogen phosphate are 5~30g/L, phosphoric acid hydrogen Ammonium, the concentration of dibastic sodium phosphate are 10~80g/L, and ammonium phosphate, sodium phosphate, the concentration of APP are 10~50g/L.Described radiation Absorbing material can block heat radiation, can delay object temperature rising of not catching fire, stop fire spread, inhales including a, infra-red radiation Receive material: one or both or two or more combination .b, ultraviolet in brucite, carborundum, silicon oxide, silicon nitride SiNx radiate Absorbing material: organically water
Poplar ester phenyl ester, oxybenzoic acid phenyl ester, 2,4-DihydroxyBenzophenone, ESCALOL 567,2-hydroxyl Base-4-oxy-octyl benzophenone, 2-(2 ' monohydroxy-3 ', 5 ' one two tertiary phenyl)-5-chlorination benzotriazole, between single benzoic acid Benzodiazepines ester, 2,2 ,-thiobis (4-t-octyl phenol epoxide) nickel, 2,4,6-tri-(2 ' n-butoxyphenyl) one 1,3,5 one triazine And one or both or the two or more combination in the oxide of inorganic cerium and ferrum;The concentration of infrared radiation absorbing material is 0.2~0. 5g/L, the concentration of ultraviolet radiation absorption material is 0.2~0.5g/L.Film former includes a, inorganic film former: Sargassum Acid sodium, sodium carboxymethyl cellulose .b, organic film former, i.e. water uptake expansion material, including low fat pectin, high fat pectin, Apples Glue, pomelo-pectin, blue berry pectin, Fructus Ananadis comosi pectin, oligofructose, oligomeric isomaltose, oligomeric lactose, oligomeric xylose, Semen sojae atricolor are low In the water soluble dietary fibers, or various High hydrophilous resin such as polysaccharide, agar powder, carboxymethyl cellulose one or both or two Plant combination of the above;The concentration of inorganic film former is 0.2~0. 4g/L, and the concentration of organic film former is 0.2~0.5g/L.
Described antifreeze can make extinguishing chemical the most normally use, including a, organic antifreeze: ethylene glycol, the third three One or both in the materials such as alcohol, chloroform, acetone, ether
Or two or more combination, b, inorganic antifreeze: barium chloride, sodium chloride, calcium chloride, ammonium thiocyanate, ammonium sulfate, sodium bromide, One or both or two or more combination in the materials such as magnesium chloride;The concentration of organic antifreeze is 1~2ml/L, inorganic freeze proof The concentration of agent is 10~30g/L.
Described coloring agent can aesthetic appeal, the sign that is used for meeting an urgent need includes, including a, inorganic colourant: copper sulfate, copper chloride, One or both or two or more groups in the materials such as nickel sulfate, Nickel dichloride., cobaltous sulfate, cobaltous chloride, ferric chloride, ferrous chloride Close, b, environmental protection type dye: one or both or two or more groups in the water-soluble dyes such as red, green, blue, Huang, yellowish green, purple Close;The concentration of inorganic colourant is 0.5~1. 5g/L, and the concentration of environmental protection type dye is 0. 02~0.04g/L.Described luminous agent Including a, energy-saving luminous material: send one or both or two or more groups in red, green, blue, Huang, yellowish green, purple light material Close, b, water-soluble fluorescent dye, make system have fluorescent effect, in night or fire hazard aerosol fog environment: fluorescence green, fluorescence rose One or both or two kinds in the materials such as red, fluorescence is bright red, fluorescein close with local soil type;The concentration of energy-saving luminous material is 0. 02~0.05g/L, the concentration of water-soluble fluorescent dye is 2~4mg/L.
Described buffer agent includes a, carbonate: sodium carbonate or potassium carbonate, b, acetate: sodium acetate or ammonium carbonate, c, boric acid Salt: sodium tetraborate or Borax;The concentration of carbonate be 2~
20g/L, the concentration of acetate is 2~4g/L, and boratory concentration is l~2g/L.Described preservative is sodium sulfite, Asia One or both or two or more combination in sodium nitrate, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, calcium propionate, anti- The concentration of rotten agent is 0.2~0. 4g/L.Described corrosion inhibiter is one or both in ammonium molybdate, sodium molybdate, acid ammonium, sodium tungstate
Or two or more combination, the concentration of corrosion inhibiter is 0. 04~0.06g/L.Said components forms class buffer solution and adjusts The component of acidity, and anticorrosion, anticorrosion function ingredients.

Claims (4)

1. a water system extinguishment additive agent, includes and is mixed in proportion is formed by fire-extinguishing function concurrently component and anti-resume combustion function ingredients, It is characterized in that: wherein fire-extinguishing function concurrently component by refrigerating function component, cover isolation features component, water down the function ingredients that suffocates, Blocking pyric chain function ingredients and emulsifying agent composition thereof, anti-resume combustion function ingredients is by nano-thermal-insulating fire resistant flame retardant material and suspension thereof Dispersant, water-soluble inorganic flame retardant, radiation-absorbing material, film former form, application function component by antifreeze, coloring agent, Luminous agent, preservative, corrosion inhibiter form;Described covering isolation features component is foaming surfactant, the fluorine system that foaming characteristic is high Surfactant, silicon system surfactant and foam stabilizing additive, foaming surfactant includes sodium lauryl sulphate, dodecyl Any one or two or more combination in sodium sulfonate, glycine betaine;The concentration of foaming surfactant be 10~ 30g/L;The concentration of fluorine system surfactant is l~5ml/L;The concentration of silicon system surfactant is 1~2ml/L;Foam stabilizing additive Including polyvinyl alcohol, polyacrylamide, 6501, albumen, any one or two or more the combination of polypeptide Shen, surely steep The concentration of auxiliary agent is 0. 25~0.5g/L;The described function ingredients that suffocates includes Inorganic Ammonium and organic amine two parts, and Inorganic Ammonium has carbon Acid ammonium, ammonium hydrogen carbonate, ammonium chloride and ammonium oxalate, organic amine includes carbamide, tripolycyanamide and dicyandiamide;Ammonium carbonate, ammonium hydrogen carbonate Concentration be 20~40g/L, ammonium chloride, the concentration of ammonium oxalate are 20~50g/L, and the concentration of organic amine is 10~70g/L;Described Water-soluble inorganic flame retardant includes sodium silicate, Firebrake ZB, phosphate, and phosphate mainly has ammonium dihydrogen phosphate, sodium dihydrogen phosphate, phosphorus Acid hydrogen ammonium or dibastic sodium phosphate, ammonium phosphate, sodium phosphate or APP;The concentration of sodium silicate is 0.2~1. Og/L, Firebrake ZB Concentration is 0.2~0. 4g/L, ammonium dihydrogen phosphate, the concentration of sodium dihydrogen phosphate are 5~30g/L, ammonium hydrogen phosphate, dibastic sodium phosphate Concentration is 10~80g/L, and ammonium phosphate, sodium phosphate, the concentration of APP are 10~50g/L;Described antifreeze includes a, organic Antifreeze: one or both or the two or more combination in ethylene glycol, glycerol, chloroform, acetone, ether material, b, inorganic anti- Freeze agent: in barium chloride, sodium chloride, calcium chloride, ammonium thiocyanate, ammonium sulfate, sodium bromide, magnesium chloride material one or both or two Plant combination of the above;The concentration of organic antifreeze is l~2ml/L, and the concentration of inorganic antifreeze is 10~30g/L;Described corrosion inhibiter Including a, carbonate: sodium carbonate or potassium carbonate, b, acetate: sodium acetate or ammonium carbonate, c, boric acid basin: sodium tetraborate or Borax; The concentration of carbonate is 2~20g/L, and the concentration of acetate is 2~4g/L, and boratory concentration is 1~2g/L.
Water system extinguishment additive agent the most according to claim 1, it is characterised in that: include containing gross weight 50% to 90% Refrigerating function water component.
Water system extinguishment additive agent the most according to claim 1 and 2, it is characterised in that: described blocking-up pyric chain function ingredients And emulsifying agent mainly has: a, organophosphorous fire retardant, including triethyl phosphate, tributyl phosphate, triphenyl, trimethylbenzene One or both or two or more combination in base phosphate ester, methyl-phosphoric acid dimethyl ester, the concentration of organophosphorous fire retardant be 0.2~ 0. 4ml/L.b, organic halogen fire retardant, including chlorinated paraffin, the acid of chlorendic anhydride HET, tetrachlorophthalic anhydride, epoxychloropropane, three (B mono- Chloroethyl) phosphate ester TCEP, three (Dichloroethyl) phosphate ester, one or both or two kinds in three (chloropropyl) phosphate ester with Upper combination, the concentration of organic halogen fire retardant is 0.3~0. 5ml/L;C, organic silicon fibre retardant: SFR-10, SFR-100, SFR- 1000, one or both and two or more combination, the concentration of organic silicon fibre retardant of FRX-210, polysiloxanes, DC RM4-708 It is 0.2~0. 4ml/L;D, addible emulsifying agent include Emulphor FM, OP-10, TX-10, A-20,6501,6503, TW60, One or both in TW80, span80 become two or more combinations, and the concentration of emulsifying agent is 0.02~0. 04ml/L.
Water system extinguishment additive agent the most according to claim 3, it is characterised in that: described nano-thermal-insulating fire resistant flame retardant material and Its suspension dispersive agent chemical composition is mainly: nano heat insulating material: the asbestos of nanoscale fineness are fine.
CN201610614265.XA 2016-08-01 2016-08-01 Water system extinguishment additive agent Withdrawn CN106139498A (en)

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CN106853281A (en) * 2016-11-25 2017-06-16 南阳师范学院 Carbon dioxide colloidal foam extinguishing chemical and its compound method
CN107029377A (en) * 2017-06-06 2017-08-11 沈阳仁辉消防科技有限公司 One kind concentration high-efficiency fire-extinguishant and preparation method thereof
CN107029378A (en) * 2017-06-06 2017-08-11 沈阳仁辉消防科技有限公司 A kind of preparation method of instant high-performance solid extinguishing chemical
CN107875559A (en) * 2017-12-14 2018-04-06 国网湖南省电力有限公司 Suitable for the water-based extinguishing agent of water mists
CN108421197A (en) * 2018-06-01 2018-08-21 潘洋 A kind of preparation method and application of water-based extinguishing agent
CN109157790A (en) * 2018-10-18 2019-01-08 河南理工大学 New and effective fire extinguishing material of one kind and preparation method thereof
CN109260644A (en) * 2018-11-06 2019-01-25 陈金城 A kind of water-based extinguishing agent and preparation method thereof
CN110898371A (en) * 2019-12-09 2020-03-24 应急管理部天津消防研究所 Green and environment-friendly hydrogel fire extinguishing agent for forest fire extinguishing and preparation method thereof
CN111054008A (en) * 2019-12-24 2020-04-24 李宏伟 Preparation method of gel dry water extinguishing agent
CN111346334A (en) * 2020-03-13 2020-06-30 超猛消防科技(深圳)有限公司 Efficient and environment-friendly water-based fire extinguishing agent
US20220126150A1 (en) * 2019-02-11 2022-04-28 In Cheon Hwang Wetting agent composition for extingushing fires
CN115569342A (en) * 2022-08-26 2023-01-06 广东自由能科技股份有限公司 Production method of high-efficiency fire extinguisher feed liquid and prepared feed liquid
CN115678575A (en) * 2022-11-16 2023-02-03 应急管理部天津消防研究所 Silicon-based cured foam material for quickly blocking forest fire and preparation method thereof
CN116271676A (en) * 2023-03-08 2023-06-23 无锡铁川科技有限公司 Water-based flame-retardant fire-extinguishing agent and preparation method thereof

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Application publication date: 20161123