CN107899174A - A kind of water-soluble foam fire-extinguishing composite - Google Patents
A kind of water-soluble foam fire-extinguishing composite Download PDFInfo
- Publication number
- CN107899174A CN107899174A CN201711251683.8A CN201711251683A CN107899174A CN 107899174 A CN107899174 A CN 107899174A CN 201711251683 A CN201711251683 A CN 201711251683A CN 107899174 A CN107899174 A CN 107899174A
- Authority
- CN
- China
- Prior art keywords
- sodium
- aqueous solution
- water
- mass parts
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0028—Liquid extinguishing substances
- A62D1/005—Dispersions; Emulsions
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0071—Foams
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Dispersion Chemistry (AREA)
- Fire-Extinguishing Compositions (AREA)
Abstract
The invention discloses a kind of water-soluble foam fire-extinguishing composite, by the foaming agent of 10 12 mass parts, the stabilizer of 4 11 mass parts, 29 43 mass parts hydrophobic solid particle, remaining is the mixture of aqueous solution composition, and the foaming agent is polyurethane or N, N dinitrosopentamethlyene tetramine；The stabilizer is ferric trichloride, and the hydrophobic solid particle is mixtures one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle；The solvent of the aqueous solution is water, and solute is sodium chloride, one or more mixtures in sodium acetate trihydrate, sodium carbonate, potassium hyperchlorate, diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate.Extinguishing chemical provided by the invention can uniformly adhere on oily matter, and uncovered region can quickly be carried out the combination of free property by foaming agent, coating, the indispensable oxygen that isolation burning needs are formed, the physical isolation between combustible and oxygen is formed, has haveed the function that fire extinguishing.
Description
Technical field
The present invention relates to fire-fighting quipment field, the extinguishing chemical field more particularly, to put out a fire, is a kind of water specifically
Dissolubility foam fire-fighting composition.
Background technology
Fire extinguisher is a kind of portable Fire extinguisher.Chemical substance is placed in fire extinguisher, to rescue fire extinguishing calamity.Fire extinguisher is
One of common fireproofing installation, is stored in public place or the place of fire may occur, filling in different types of fire extinguisher
Component it is different, be to aim at different fire alarms and set.It must be noted that during use in order to avoid producing minus effect and causing danger.
Existing extinguishing chemical mainly has two kinds of a foam and dry powder, and two kinds of extinguishing chemicals respectively have a quality, going out in dry powder extinguisher
Ammonium phosphate salt is filled in fiery agent to be used to put out a fire dry and be easy to flow attritive powder by tool fire extinguishing effectiveness machine salt a small amount of additive through dry
Dry, crushing, the fire-fighting of mixing micro-solid powder group kind extensively using extinguishing chemical and are mainly used for fire extinguisher except metallic fires of putting out a fire to save life and property
BC dry powder fire extinguishing agents (sodium acid carbonate) ABC dry powder (ammonium phosphate salt) two class as the outer dry powder fire extinguishing agent of special dry powdered extinguishing chemical is made dry up
Powder machine salt volatility solution thing produces free radical with burning journey fuel or property group hairization suppresses negative catalyst and makes combustion chain reaction
Disconnected fire extinguishing；Two by dry powder powder fall the reaction of combustion things surface outgoingization and the glassy coating isolating oxygen of high temperature action shape layer is into asphyxia
Put out a fire another external dilution oxygen, play certain cooling effect.Fire foam is a kind of small volume, what surface was surrounded by liquid
Bubble population, proportion is between 0.001~0.5.Since the proportion of foam is far smaller than the proportion of general flammable liquid, thus can be with
The surface of liquid is floated on, forms a foam blanket.Meanwhile foam has certain viscosity again, can be adhered to general
The surface of flammable solid.The foam blanket that fire foam is formed on comburant surface, can make comburant surface and air insulated.
The prior art：Chinese invention patent application, application number：201210236483.6 Publication No.：102772877A,
A kind of extinguishing chemical is disclosed, the extinguishing chemical is made of the raw material of following each component：0.1-0.2 parts of organic silicone oil, carbamide 2-3
Part, 3.5-4.5 parts of ammonium phosphate, 6.1-6.2 parts of potassium hyperchlorate, 32-35 parts of concentrated latex, 11-12 parts of water.The fire extinguishing of the present invention
Agent, can make up the deficiency of general extinguishing chemical, and cost of manufacture is relatively low, and raw material is easy to get, and the making raw material of extinguishing chemical is harmless,
Do not pollute, securely and reliably.
Different due to occurring the condition of a disaster of fire in actual life, the fire that different materials occurs not only wants specific aim
Selection fire-extinguishing apparatus, more it is noted that selection extinguishing chemical, so could more preferably, faster, safer stamps out a fire.
The content of the invention
It is an object of the invention to provide a kind of water-soluble foam fire-extinguishing composite, dry-chemical fire extinguishing of the prior art is solved
The problem of device is not easy to put out oiliness fire and relatively low fire foam fire-fighting efficiency.
The present invention is achieved through the following technical solutions：
A kind of water-soluble foam fire-extinguishing composite, by the foaming agent of 10-12 mass parts, the stabilizer of 4-11 mass parts, 29-43 matter
The hydrophobic solid particle of part is measured, remaining is the mixture of aqueous solution composition, and the foaming agent is polyurethane or N, N dinitroso
Five methine tetramines；The stabilizer is ferric trichloride, and the hydrophobic solid particle is magnesium hydroxide particles, titanium dioxide silicon grain
One or more mixture in son, calcium carbonate particle；The solvent of the aqueous solution is water, and solute is sodium chloride, three water acetic acid
One or more mixtures in sodium, sodium carbonate, potassium hyperchlorate, diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate.
Preferably, the constituent mass content of magnesium hydroxide particles is respectively 20%-25% in the hydrophobic solid particle, and two
The constituent content of silicon oxide particle is respectively 35%-42%, remaining is calcium carbonate particle.
Preferably, the aqueous solution is made of the water of 50%-55% mass and the solute of 45%-50%, and a in the solute
Constituent mass percentage composition is respectively：Sodium chloride, sodium acetate trihydrate, sodium carbonate, potassium hyperchlorate 15.5%-22.3%, phosphoric acid
Hydrogen diammonium is 30%-45%, ammonium phosphate 5%-8%, remaining is sodium phosphate.
In order to further improve the fire-fighting efficiency of oiliness extinguishing chemical, the present invention further provides following scheme：
A kind of water-soluble foam fire-extinguishing composite, by the foaming agent of 10-12 mass parts, the stabilizer of 4-11 mass parts, 29-43 matter
The hydrophobic solid particle of part is measured, remaining is the mixture of aqueous solution composition, and the foaming agent is polyurethane or N, N dinitroso
Five methine tetramines；The stabilizer is ferric trichloride, and the hydrophobic solid particle is magnesium hydroxide particles, titanium dioxide silicon grain
One or more mixture in son, calcium carbonate particle；The solvent of the aqueous solution is water, and solute is sodium chloride, three water acetic acid
One or more mixtures in sodium, sodium carbonate, potassium hyperchlorate, diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, the foaming agent
Mass parts be 7 parts, the mass parts of stabilizer are 6 parts, and the mass parts of hydrophobic solid particle are 40 parts, remaining is aqueous solution
Mixture, the solute of the aqueous solution are sodium chloride, sodium acetate trihydrate, sodium carbonate, potassium hyperchlorate and diammonium hydrogen phosphate with 1：1
The mixture of ratio mixing；The mass parts of the foaming agent are 6 parts, and the mass parts of stabilizer are 5 parts, hydrophobic solid particle
Mass parts are 35 parts, remaining is the mixture of aqueous solution, the solute of the aqueous solution is sodium chloride, sodium acetate trihydrate, sodium carbonate,
Potassium hyperchlorate and sodium phosphate are with 2：The mixture of 1 ratio mixing.
Yet further, the mass parts of the foaming agent are 5 parts, and the mass parts of stabilizer are 4 parts, hydrophobic solid particle
Mass parts be 32 parts, remaining is the mixture of aqueous solution, and the solute of the aqueous solution is sodium chloride, sodium acetate trihydrate, carbonic acid
Sodium, potassium hyperchlorate and diammonium hydrogen phosphate are with 1：The mixture of 3 ratio mixing.
It is further preferred that the mass parts of the foaming agent are 8 parts, the mass parts of stabilizer are 7 parts, hydrophobic solid grain
The mass parts of son are 38 parts, remaining is the mixture of aqueous solution, and the solute of the aqueous solution is sodium chloride, sodium acetate trihydrate, carbon
Sour sodium, potassium hyperchlorate and sodium phosphate are with 5：The mixture of 2 ratio mixing.
Compared with prior art, the present invention haing the following advantages and beneficial effect：
Extinguishing chemical provided by the invention can uniformly adhere on oily matter, and foaming agent can quickly will be uncovered
Region carry out the combination of free property, form coating, the indispensable oxygen that isolation burning needs, forms between combustible and oxygen
Physical isolation, haveed the function that fire extinguishing.Since the present invention is by the way of aqueous solution is mixed with hydrophobic particle thing, so
Under the injection of fire extinguisher or other fire extinguishing jet devices, combustible surface can be more uniformly adhered to, it is more efficient
Realize large area put out a fire.
Embodiment
The present invention is described in further detail with reference to embodiment, but the implementation of the present invention is not limited to this.
Embodiment 1：
A kind of water-soluble foam fire-extinguishing composite, by the foaming agent of 10-12 mass parts, the stabilizer of 4-11 mass parts, 29-43 matter
The hydrophobic solid particle of part is measured, remaining is the mixture of aqueous solution composition, and the foaming agent is polyurethane or N, N dinitroso
Five methine tetramines；The stabilizer is ferric trichloride, and the hydrophobic solid particle is magnesium hydroxide particles, titanium dioxide silicon grain
One or more mixture in son, calcium carbonate particle；The solvent of the aqueous solution is water, and solute is sodium chloride, three water acetic acid
One or more mixtures in sodium, sodium carbonate, potassium hyperchlorate, diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate.
In the case of any constituent content ratio in the present embodiment, it the experiment proved that, the mixed solution of 2L is placed in
In sealing container, and apply 1.8-2.0 atmospheric pressure, sustained firing experiment is carried out with a diameter of 3 millimeters of gun slot, it is sustainable
Injection -164 seconds 125 seconds.Burning for surface area for 0.2 square metre of liquid gasoline, sustained firing 2-2.8 seconds can be complete
Put out, the burning to surface area for 1 square of liquid gasoline, is in the angle sustained firing no more than 20 ° along combustible surface
It can put out within 5-8 seconds.
Under the same conditions, above-mentioned experiment is carried out using the dry powder extinguisher of in the market purchase, it is flat for 0.2 for surface area
The burning of the liquid gasoline of square rice, sustained firing can be put out for 3-4.2 seconds completely, be 1 square of liquid gasoline to surface area
Burning, is in more than the 15 seconds still visible naked lights of angle sustained firing no more than 20 ° along combustible surface, and dry powder extinguisher is deposited
In shifting situation, it is impossible to disposably extinguish the blaze, string fire easily occur, secondary situation about igniting occurs.
Under the same conditions, above-mentioned experiment is carried out using the foam annihilator of in the market purchase, it is flat for 0.2 for surface area
The burning of the liquid gasoline of square rice, sustained firing can be put out for 2.7-3.6 seconds completely, to the liquid gasoline that surface area is 1 square
Burning, be in that all standing can be realized in fluid surface within 8-12 second no more than 20 ° of angle sustained firing along combustible surface, general
Naked light is put out, but its consumption is 1.3 quilts of consumption quality of the present invention.
It follows that employed in the present embodiment fire extinguishing component mixture under the action of high pressure to oiliness combustible
Fire put out a fire relative to existing dry powder extinguisher and foam annihilator be respectively provided with prominent substantive distinguishing features and significantly into
Step, and by fire-extinguishing apparatus to be a variety of, as long as the pressure provided not less than 1.5 atmospheric pressure can put out a fire, user
Just, effect is good.
Embodiment 2：
A kind of water-soluble foam fire-extinguishing composite, by the foaming agent of 10-12 mass parts, the stabilizer of 4-11 mass parts, 29-43 matter
The hydrophobic solid particle of part is measured, remaining is the mixture of aqueous solution composition, and the foaming agent is polyurethane or N, N dinitroso
Five methine tetramines；The stabilizer is ferric trichloride, and the hydrophobic solid particle is magnesium hydroxide particles, titanium dioxide silicon grain
One or more mixture in son, calcium carbonate particle；The solvent of the aqueous solution is water, and solute is sodium chloride, three water acetic acid
One or more mixtures in sodium, sodium carbonate, potassium hyperchlorate, diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, the foaming agent
Mass parts be 7 parts, the mass parts of stabilizer are 6 parts, and the mass parts of hydrophobic solid particle are 40 parts, remaining is aqueous solution
Mixture, the solute of the aqueous solution are sodium chloride, sodium acetate trihydrate, sodium carbonate, potassium hyperchlorate and diammonium hydrogen phosphate with 1：1
The mixture of ratio mixing；The mass parts of the foaming agent are 6 parts, and the mass parts of stabilizer are 5 parts, hydrophobic solid particle
Mass parts are 35 parts, remaining is the mixture of aqueous solution, the solute of the aqueous solution is sodium chloride, sodium acetate trihydrate, sodium carbonate,
Potassium hyperchlorate and sodium phosphate are with 2：The mixture of 1 ratio mixing.
Foamite mixture 2L described in the present embodiment is placed in sealing container, and applies 2.5 atmospheric pressure, with diameter
Sustained firing experiment, sustainable injection 106 seconds are carried out for 3 millimeters of gun slots.
It it is 3 millimeters to depth, area is that 0.5 square metre of diesel combustion naked light carries out putting out experiment, of the present invention
Extinguishing chemical carries out sustained firing 3 times along with diesel oil plane included angle for 30 ° of direction, and the time put out a fire completely is respectively 3.6 seconds,
3.4 seconds, 3.7 seconds, average attack time was 3.53 seconds.
Under the same conditions, above-mentioned experiment is carried out using the dry powder extinguisher of in the market purchase, still by injection direction with
The direction that diesel oil plane included angle is 30 ° carries out sustained firing 3 times, and the time put out a fire completely is respectively 5.2 seconds, 4.8 seconds, and 4.93
Second, average attack time is 4.98 seconds.
Under the same conditions, above-mentioned experiment is carried out using the foam annihilator of in the market purchase, still by injection direction with
The direction that diesel oil plane included angle is 30 ° carries out sustained firing 3 times, and the time put out a fire completely is respectively 4.5 seconds, 4.1 seconds, 4 seconds, is put down
Equal attack time is 4.2 seconds.
It follows that the extinguishing chemical of the present invention is defined, to be subjected to the same test under the same conditions, the present invention
The effect of the extinguishing chemical of offer has prominent substantive distinguishing features, and show due to existing dry powder fire extinguishing agent and fire foam
Write progress.
The above, is only presently preferred embodiments of the present invention, not does limitation in any form to the present invention, it is every according to
Any simply modification, the equivalent variations made according to the technical spirit of the present invention to above example, each fall within the protection of the present invention
Within the scope of.
Claims (5)
1. a kind of water-soluble foam fire-extinguishing composite, it is characterised in that by the foaming agent of 10-12 mass parts, 4-11 mass parts
The hydrophobic solid particle of stabilizer, 29-43 mass parts, remaining is the mixture of aqueous solution composition, and the foaming agent is poly- ammonia
Ester or N, N dinitrosopentamethlyene tetramine；The stabilizer is ferric trichloride, and the hydrophobic solid particle is magnesium hydroxide
One or more mixture in particle, silicon dioxide granule, calcium carbonate particle；The solvent of the aqueous solution is water, and solute is
It is one or more mixed in sodium chloride, sodium acetate trihydrate, sodium carbonate, potassium hyperchlorate, diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate
Compound.
A kind of 2. water-soluble foam fire-extinguishing composite according to claim 1, it is characterised in that the hydrophobic solid grain
The constituent mass content of magnesium hydroxide particles is respectively 20%-25% in son, and the constituent content of silicon dioxide granule is respectively 35%-
42%, remaining is calcium carbonate particle.
3. a kind of water-soluble foam fire-extinguishing composite according to claim 1, it is characterised in that the aqueous solution is by 50%-
The water of 55% mass and the solute composition of 45%-50%, and a constituent mass percentage composition is respectively in the solute：Sodium chloride,
Sodium acetate trihydrate, sodium carbonate, potassium hyperchlorate 15.5%-22.3%, diammonium hydrogen phosphate 30%-45%, ammonium phosphate 5%-8%, its
Remaining is sodium phosphate.
A kind of 4. water-soluble foam fire-extinguishing composite according to claim 1, it is characterised in that the quality of the foaming agent
Part is 7 parts, and the mass parts of stabilizer are 6 parts, and the mass parts of hydrophobic solid particle are 40 parts, remaining is the mixing of aqueous solution
Thing, the solute of the aqueous solution are sodium chloride, sodium acetate trihydrate, sodium carbonate, potassium hyperchlorate and diammonium hydrogen phosphate with 1：1 ratio
The mixture of mixing.
A kind of 5. water-soluble foam fire-extinguishing composite according to claim 1, it is characterised in that the quality of the foaming agent
Part is 6 parts, and the mass parts of stabilizer are 5 parts, and the mass parts of hydrophobic solid particle are 35 parts, remaining is the mixing of aqueous solution
Thing, the solute of the aqueous solution are sodium chloride, sodium acetate trihydrate, sodium carbonate, potassium hyperchlorate and sodium phosphate with 2：1 ratio mixing
Mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711251683.8A CN107899174A (en) | 2017-12-01 | 2017-12-01 | A kind of water-soluble foam fire-extinguishing composite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711251683.8A CN107899174A (en) | 2017-12-01 | 2017-12-01 | A kind of water-soluble foam fire-extinguishing composite |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107899174A true CN107899174A (en) | 2018-04-13 |
Family
ID=61849671
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711251683.8A Pending CN107899174A (en) | 2017-12-01 | 2017-12-01 | A kind of water-soluble foam fire-extinguishing composite |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107899174A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108721822A (en) * | 2018-06-01 | 2018-11-02 | 厦门泰消防科技开发有限公司 | A kind of sea water resistance fire foam |
| CN114437580A (en) * | 2022-03-29 | 2022-05-06 | 深圳添德景行科技有限公司 | Graphene composite magnesium hydroxide modified fire retardant for fire fighting and preparation method thereof |
| CN115942980A (en) * | 2020-06-22 | 2023-04-07 | 雅托普罗德克株式会社 | Foam fire extinguishing agent |
-
2017
- 2017-12-01 CN CN201711251683.8A patent/CN107899174A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108721822A (en) * | 2018-06-01 | 2018-11-02 | 厦门泰消防科技开发有限公司 | A kind of sea water resistance fire foam |
| CN115942980A (en) * | 2020-06-22 | 2023-04-07 | 雅托普罗德克株式会社 | Foam fire extinguishing agent |
| CN114437580A (en) * | 2022-03-29 | 2022-05-06 | 深圳添德景行科技有限公司 | Graphene composite magnesium hydroxide modified fire retardant for fire fighting and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU2414273C2 (en) | Extinguishant, method for making thereof and method of fire extinguishing | |
| CN102179023B (en) | Novel fire extinguishing method | |
| CN105688360A (en) | Class-A fire extinguishing agent | |
| CN105688361A (en) | Fire extinguishing agent for fire of Class B | |
| CN107899174A (en) | A kind of water-soluble foam fire-extinguishing composite | |
| CN103751940B (en) | Polynary D class powder extinguishing agent is in the application in magnesium metal and sodium metal fire of going out | |
| CN107952205A (en) | A kind of fire-extinguishing composite for liquid fire | |
| CN106621159A (en) | Super-fine dry powder fire extinguishing agent | |
| EP3755438A1 (en) | Fire extinguishing powder, for a, b, c, d, f and k class fires and its application in suppression of catastrophic fires, the absorption of oil and its derivatives and revitalization of land degradation caused by fire | |
| CN107970552A (en) | A kind of fire-extinguishing composite based on phosphoric acid dry powder | |
| CN107899170A (en) | A kind of extinguishing chemical fire-retardant based on hydrophobic particles | |
| CN107899171A (en) | A kind of phosphoric acid class dry powder fire extinguishing agent | |
| CN107252542A (en) | A kind of extinguishing chemical with discrete adhesive force | |
| CN107252537A (en) | A kind of extinguishing chemical for being used to put out liquid oily matter fire | |
| CN107961481A (en) | A kind of fire foam based on acid solution | |
| CN107252553A (en) | The extinguishing chemical that a kind of use hydrotalcite particle makes | |
| CN107252544A (en) | A kind of acid solution extinguishing chemical | |
| CN107252538A (en) | A kind of extinguishing chemical with ultra-fine hydrophobic particles | |
| CN107252539A (en) | A kind of cover type completely cuts off extinguishing chemical | |
| CN107961482A (en) | A kind of extinguishing chemical made of ammonium dihydrogen phosphate dry powder | |
| CN107899172A (en) | A kind of multipurpose extinguishing chemical prepared based on modified sodium salt dry powder | |
| CN107952200A (en) | A kind of adhesiveness fire-retardant combination | |
| CN107252547A (en) | A kind of multipurpose extinguishing chemical | |
| CN107952207A (en) | A kind of fire-retardant combination based on titanium dioxide | |
| CN103977528A (en) | Extinguishing agent for forest fire |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180413 |