CN109142493B - 一种用于非标记检测4-氯苯酚的光电化学传感器的构建方法 - Google Patents
一种用于非标记检测4-氯苯酚的光电化学传感器的构建方法 Download PDFInfo
- Publication number
- CN109142493B CN109142493B CN201810784146.8A CN201810784146A CN109142493B CN 109142493 B CN109142493 B CN 109142493B CN 201810784146 A CN201810784146 A CN 201810784146A CN 109142493 B CN109142493 B CN 109142493B
- Authority
- CN
- China
- Prior art keywords
- gcn
- chlorophenol
- solution
- photoelectrochemical sensor
- photoelectrochemical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 title claims abstract description 49
- 238000001514 detection method Methods 0.000 title claims abstract description 31
- 238000010276 construction Methods 0.000 title claims abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 9
- 239000011149 active material Substances 0.000 claims abstract description 8
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000243 solution Substances 0.000 claims description 42
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 15
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 14
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- 239000006185 dispersion Substances 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 11
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(I) nitrate Inorganic materials [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 229910052724 xenon Inorganic materials 0.000 claims description 10
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 claims description 10
- 229920000877 Melamine resin Polymers 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 9
- 238000004458 analytical method Methods 0.000 claims description 8
- 229960005070 ascorbic acid Drugs 0.000 claims description 7
- 235000010323 ascorbic acid Nutrition 0.000 claims description 7
- 239000011668 ascorbic acid Substances 0.000 claims description 7
- 239000012265 solid product Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 claims description 5
- 230000007613 environmental effect Effects 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 5
- 229910021642 ultra pure water Inorganic materials 0.000 claims description 5
- 239000012498 ultrapure water Substances 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 101710134784 Agnoprotein Proteins 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 239000010935 stainless steel Substances 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 abstract description 5
- 239000010439 graphite Substances 0.000 abstract description 5
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 2
- 238000000835 electrochemical detection Methods 0.000 abstract description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 12
- 230000000694 effects Effects 0.000 description 8
- 239000002114 nanocomposite Substances 0.000 description 7
- 238000005303 weighing Methods 0.000 description 7
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 6
- 239000007853 buffer solution Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 4
- 239000010453 quartz Substances 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 230000003321 amplification Effects 0.000 description 2
- 239000013256 coordination polymer Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000003199 nucleic acid amplification method Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000011896 sensitive detection Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/416—Systems
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810784146.8A CN109142493B (zh) | 2018-07-17 | 2018-07-17 | 一种用于非标记检测4-氯苯酚的光电化学传感器的构建方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810784146.8A CN109142493B (zh) | 2018-07-17 | 2018-07-17 | 一种用于非标记检测4-氯苯酚的光电化学传感器的构建方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN109142493A CN109142493A (zh) | 2019-01-04 |
CN109142493B true CN109142493B (zh) | 2020-06-26 |
Family
ID=64800848
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810784146.8A Active CN109142493B (zh) | 2018-07-17 | 2018-07-17 | 一种用于非标记检测4-氯苯酚的光电化学传感器的构建方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN109142493B (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109781814B (zh) * | 2019-01-28 | 2021-06-11 | 暨南大学 | 一种光增强电化学传感器及其制备方法和应用 |
CN112816639B (zh) * | 2021-01-06 | 2023-04-11 | 江苏大学 | 一种用于恩诺沙星灵敏检测的光电化学适配体传感器的构建方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106596664A (zh) * | 2016-12-15 | 2017-04-26 | 江苏大学 | 一种氮化碳/卤化氧铋光电复合材料的制备方法及其用途 |
CN107064264A (zh) * | 2017-05-18 | 2017-08-18 | 江苏大学 | 一种用于无酶检测多巴胺的光电化学传感器的构建方法 |
CN107324396A (zh) * | 2017-06-06 | 2017-11-07 | 江苏大学 | 一种基于氧化铁掺杂石墨相氮化碳复合材料的制备方法 |
-
2018
- 2018-07-17 CN CN201810784146.8A patent/CN109142493B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106596664A (zh) * | 2016-12-15 | 2017-04-26 | 江苏大学 | 一种氮化碳/卤化氧铋光电复合材料的制备方法及其用途 |
CN107064264A (zh) * | 2017-05-18 | 2017-08-18 | 江苏大学 | 一种用于无酶检测多巴胺的光电化学传感器的构建方法 |
CN107324396A (zh) * | 2017-06-06 | 2017-11-07 | 江苏大学 | 一种基于氧化铁掺杂石墨相氮化碳复合材料的制备方法 |
Non-Patent Citations (8)
Title |
---|
Construction of Heterostructured g-C3N4/Ag/TiO2 Microspheres with Enhanced Photocatalysis Performance under Visible-Light Irradiation;Chen, Yanfeng et al.;《ACS Applied Materials & Interfaces》;20140827;第6卷(第16期);全文 * |
Exciton–Plasmon Interactions between CdS@g-C3N4 Heterojunction and Au@Ag Nanoparticles Coupled with DNAase-Triggered Signal Amplification: Toward Highly Sensitive Photoelectrochemical Bioanalysis of MicroRNA;Dong, Yu-Xiang et al.;《ACS Sustainable Chemistry & Engineering》;20171106;第5卷(第11期);全文 * |
Facile Gel-Based Morphological Control of Ag/g-C3N4 Porous Nanofibers for Photocatalytic Hydrogen Generation;Wang, Jiangpeng et al.;《ACS Sustainable Chemistry & Engineering》;20171106;第5卷(第11期);全文 * |
H2O2 Assisted Photoelectrocatalytic Oxidation of Ag-Cyanide Complexes at Metal-free g-C3N4 Photoanode with Simultaneous Ag Recovery;Qi, Fanjing et al.;《ACS Sustainable Chemistry & Engineering》;20170605;第5卷(第6期);全文 * |
Photocatalysts based on g-C3N4-encapsulating carbon spheres with high visible light activity for photocatalytic hydrogen evolution;Li, Kui et al.;《Carbon》;20161201;第110卷;全文 * |
Preparation of graphene oxide-wrapped carbon sphere@silver spheres for high performance chlorinated phenols sensor;Gan, Tian et al.;《Journal of Hazardous Materials》;20160125;第302卷;全文 * |
Silver/Silver(II) oxide (Ag/AgO) loaded graphitic carbon nitride microspheres: An effective visible light active photocatalyst for degradation of acidic dyes and bacterial inactivation;Vidyasagar, Devthade et al.;《Applied Catalysis B: Environmental》;20180201;第221卷;全文 * |
The g-C3N4/C2N Nanocomposite: A g-C3N4-Based Water-Splitting Photocatalyst with Enhanced Energy Efficiency;Wang, Huimin et al.;《ChemPhysChem》;20160425;第17卷(第13期);全文 * |
Also Published As
Publication number | Publication date |
---|---|
CN109142493A (zh) | 2019-01-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Saqib et al. | Efficient Electrogenerated Chemiluminescence of Tris (2, 2′-bipyridine) ruthenium (II) with N-Hydroxysulfosuccinimide as a Coreactant for Selective and Sensitive Detection of l-Proline and Mercury (II) | |
Kokulnathan et al. | Synthesis and characterization of zirconium dioxide anchored carbon nanofiber composite for enhanced electrochemical determination of chloramphenicol in food samples | |
Zhang et al. | Electrochemical determination of diphenols and their mixtures at the multiwall carbon nanotubes/poly (3-methylthiophene) modified glassy carbon electrode | |
CN107064264B (zh) | 一种用于无酶检测多巴胺的光电化学传感器的构建方法 | |
Kilele et al. | Ultra-sensitive electrochemical sensor for fenitrothion pesticide residues in fruit samples using IL@ CoFe2O4NPs@ MWCNTs nanocomposite | |
JP4563970B2 (ja) | 農薬を検出する方法およびバイオマイクロセンサ | |
Zheng et al. | The electrochemical behavior and determination of quercetin in choline chloride/urea deep eutectic solvent electrolyte based on abrasively immobilized multi-wall carbon nanotubes modified electrode | |
CN109142493B (zh) | 一种用于非标记检测4-氯苯酚的光电化学传感器的构建方法 | |
Wu et al. | Turn off-on electrochemiluminescence sensor based on MnO2/carboxylated graphitic carbon nitride nanocomposite for ultrasensitive L-cysteine detection | |
CN107727717A (zh) | 多氯联苯光电化学适配体传感器的制备方法及应用 | |
Fereja et al. | Highly sensitive and selective non-enzymatic glucose detection based on indigo carmine/hemin/H 2 O 2 chemiluminescence | |
CN105699368A (zh) | 一种基于二维复合材料构建的双功能过氧化氢无酶传感器的制备方法及应用 | |
CN114487395A (zh) | 一种检测SARS-CoV-2 S蛋白的纳米抗体光电化学免疫传感器的构建方法和用途 | |
Zou et al. | Enzyme biosensors systems based on Co-modification of carbon nanotubes and enzyme for detection of glucose in food | |
CN103336045B (zh) | 有毒物质在线检测及自动报警装置及有毒物质的检测方法 | |
Hou et al. | Multi-walled carbon nanotubes modified glass carbon electrode and its electrocatalytic activity towards oxidation of paracetamol | |
CN111239215B (zh) | 一种磷掺杂多孔碳微球作为氯硝柳胺类氧化酶传感器的制备方法 | |
Koizumi et al. | Kinetics simulation of luminol chemiluminescence based on quantitative analysis of photons generated in electrochemical oxidation | |
Dai et al. | An electrochemical sensor based on AuPd@ Fe x O y nanozymes for a sensitive and in situ quantitative detection of hydrogen peroxide in real samples | |
CN104698053B (zh) | 一种二氧化钛‑碳棒微电极、制备方法及其检测血液中对乙酰氨基酚浓度的应用 | |
CN105806832A (zh) | 一种基于电致化学发光和光电化学双功能的过氧化氢传感器的制备方法及应用 | |
CN105891182B (zh) | 一种对过氧化氢酶定量的方法 | |
CN105823773B (zh) | 一种双功能无酶过氧化氢光电化学传感器的制备方法及应用 | |
CN112461903B (zh) | 一种检测氮掺杂碳量子点的电化学发光方法 | |
Xu et al. | Electrochemiluminescence of luminol at the titanate nanotubes modified glassy carbon electrode |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20201211 Address after: No. 159, Chengjiang Middle Road, Jiangyin City, Wuxi City, Jiangsu Province Patentee after: Jiangyin Intellectual Property Operation Co.,Ltd. Address before: Zhenjiang City, Jiangsu Province, 212013 Jingkou District Road No. 301 Patentee before: JIANGSU University |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20240124 Address after: No. 10, Yingbin Avenue, Dongtai Economic Development Zone, Yancheng City, Jiangsu Province Patentee after: DONGTAI GAOKE TECHNOLOGY INNOVATION PARK Co.,Ltd. Country or region after: China Address before: No. 159, Chengjiang Middle Road, Jiangyin City, Wuxi City, Jiangsu Province Patentee before: Jiangyin Intellectual Property Operation Co.,Ltd. Country or region before: China |