CN109137607A - The paper and preparation method thereof of printing solution and the imitative pearl effect using the solution - Google Patents

The paper and preparation method thereof of printing solution and the imitative pearl effect using the solution Download PDF

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Publication number
CN109137607A
CN109137607A CN201810850034.8A CN201810850034A CN109137607A CN 109137607 A CN109137607 A CN 109137607A CN 201810850034 A CN201810850034 A CN 201810850034A CN 109137607 A CN109137607 A CN 109137607A
Authority
CN
China
Prior art keywords
printing
paper
solution
pearl effect
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810850034.8A
Other languages
Chinese (zh)
Inventor
曾家明
曾志平
吴松恩
钟永红
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FOSHAN GREEN COLOR PRINTING Co Ltd
Original Assignee
FOSHAN GREEN COLOR PRINTING Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FOSHAN GREEN COLOR PRINTING Co Ltd filed Critical FOSHAN GREEN COLOR PRINTING Co Ltd
Priority to CN201810850034.8A priority Critical patent/CN109137607A/en
Publication of CN109137607A publication Critical patent/CN109137607A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/62Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/622Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
    • C08G18/6225Polymers of esters of acrylic or methacrylic acid
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/66Coatings characterised by a special visual effect, e.g. patterned, textured
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/80Paper comprising more than one coating
    • D21H19/82Paper comprising more than one coating superposed
    • D21H19/826Paper comprising more than one coating superposed two superposed coatings, the first applied being pigmented and the second applied being non-pigmented
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of printing solution, including following components and its weight percent: butyl acrylate: 35%-50%, methyl methacrylate, 10%-20%, acrylic acid: 20%-35% and isocyanates: 5%-15%;On the one hand the printing solution protects original coating result, while guaranteeing that printing layer can preferably carry out ink printing;The invention also discloses a kind of paper of imitative pearl effect using the printing solution, its emphasis is, printing solution is coated on the coat of colo(u)r of single copper paper, the surface that precoated shet is formed after solution is solid also has additional printing layer, which has imitative pearl effect and substantially reduce cost;The present invention further disclose it is a kind of implement be easy, richer color, and the preparation method of the paper of imitative pearl effect at low cost may be selected.

Description

The paper and preparation method thereof of printing solution and the imitative pearl effect using the solution
Technical field
The present invention relates to printing solution, and the paper and preparation method thereof of the imitative pearl effect using the solution.
Background technique
Continuous improvement with people to printed matter color quality effect requirements, common printing paper, effect cannot Meets the needs of people are daily.
Summary of the invention
The first object of the present invention is to provide a kind of printing solution, on the one hand which protects original painting Layer effect, while guaranteeing that printing layer can preferably carry out ink printing.
The second object of the present invention is that providing one kind substantially reduces cost, and has the paper of imitative pearl effect.
The third object of the present invention be to provide it is a kind of implement to be easy, richer color, and imitative pearl at low cost may be selected The preparation method of the paper of light effect.
The first object of the present invention is achieved in that a kind of printing solution, characterized in that including following components and its Weight percent: butyl acrylate: 35%-50%, methyl methacrylate, 10%-20%, acrylic acid: 20%-35% and isocyanide Acid esters: 5%-15%.
An object of the present disclosure can also use following technical measures:
The weight percent of the butyl acrylate can be 40% or 45%;The weight percent of the methyl methacrylate can Think 12% or 15%;The weight percent of the acrylic acid is 25% or 30%;The weight percent of the isocyanates be 8% or 12%;Certainly, above-mentioned weight percentage of each component can select appropriate amount of components in corresponding value range according to actual needs, this In will not enumerate.
The second object of the present invention is achieved in that
A kind of paper of the imitative pearl effect using above-mentioned printing solution, including single copper paper are coated on the surface of single copper paper Coat of colo(u)r, characterized in that the printing solution is coated on the coat of colo(u)r, the printing is precoated with solid rear formed of solution Layer, also has additional printing layer in the precoating layer surface.
As a preferred option, the printing layer is one layer of PET film.
The third object of the present invention is achieved in that a kind of preparation method of the paper of imitative pearl effect, characterized in that packet Include following steps:
Step 1, require by weight percentage successively by butyl acrylate, methyl methacrylate and acrylic acid mix and uniformly Stirring keeps the control of mixed material temperature between 50 DEG C -60 DEG C during uniform stirring;
Step 2 continues uniform stirring after requiring addition isocyanates by weight percentage during above-mentioned uniform stirring, and Keep the control of mixed material temperature between 60 DEG C -70 DEG C during uniform stirring;
Step 3 after above-mentioned all mixed materials merge completely, stands to room temperature, can be prepared by the printing solution, spare;
Step 4, is coated with coat of colo(u)r on the surface of single copper paper, and the above-mentioned printing prepared is applied to solution by printing machine On the coat of colo(u)r of single copper paper, printing is handled with solution by the dry tack free of dryer, so that printing is formed after using solution solid Precoated shet, then printing layer is added toward the precoating layer surface, the paper of imitative pearl effect is made.
The technical measures of above-mentioned third purpose can also include:
Further, in the step 1 and step 2, the mixing speed of uniform stirring control respectively 200-300 turn/ Point and 300-500 revs/min, and in step 1, avoiding daylight or ultraviolet light and relative air humidity is less than 50% Under the conditions of, require by weight percentage successively slowly by butyl acrylate, methyl methacrylate and acrylic acid mix and uniformly Stirring.
Further, the printing layer is to be covered with one layer of PET film in precoating layer surface by laminating machine.
Beneficial effects of the present invention are as follows:
(1) printing solution of the invention, butyl acrylate is colourless transparent liquid, not soluble in water, is miscible in ethyl alcohol, second Ether;Acrylic acid and acrylate can be used for synthetic resin, synthetic fibers, super absorbent resin with homopolymerization and copolymerization, polymer; Butyl acrylate, methyl methacrylate and acrylic acid three fusion can be used as water-base resin that comonomer is prepared can be with The advantages of isocyanate curing agent is re-dubbed the solution of coating, this solution be can to make the surface of coating and ink absorbing layer it Between good bonding, stablize.
(2) paper of the imitative pearl effect of the present invention, forms required precoated shet with solution by printing, is then dried to this Processing, and one layer of printing layer is made on precoated shet, in order to make paper effect more preferable, printing layer is preferably that PET film is covered The advantages of film, PET film, is that it has excellent physical property, chemical property and dimensional stability, the transparency, can be recycled Property, original coating result is on the one hand protected, while can guarantee that printing layer can preferably carry out ink printing.
(3) preparation method of the paper of the imitative pearl effect of the present invention, on the basis of not needing the expensive iridescent paper of purchase, printing Factory only needs that this preparation method can be realized using existing printing machine, dryer, aqueous polisher and laminating machine, substantially reduces Production cost, while can achieve the effect that original iridescent paper;Further more, background color also becomes richer by originally very single selection Rich Colour selection, cost are excessive without increasing.
(4) in the case where additionally not increasing printing cost, by improveing manufacture craft, common single copper paper is changed to Property with similar extraordinary iridescent paper, has surface smooth, and reflective sense is stronger, there is the Novel paper of pearly luster lines, this hair Bright one side can improve the aesthetics of former single copper paper, and the texture on surface has the effect of frosted texture, stain strong, it is not easy to fall Color in process of production, does not need additionally to increase excessive material cost, together to a certain extent instead of the use of iridescent paper When in aesthetics more can create more competitive product system for enterprise.
Specific embodiment
Present invention is further described in detail combined with specific embodiments below:
A kind of printing solution, characterized in that including following components and its weight percent: butyl acrylate: 35%-50%, first Base methyl acrylate: 10%-20%, acrylic acid: 20%-35% and isocyanates: 5%-15%;Wherein, the butyl acrylate Weight percent can be 40% or 45%, and the weight percent of the methyl methacrylate can be 12% or 15%, described third The weight percent of olefin(e) acid is 25% or 30%, and the weight percent of the isocyanates is 8% or 12%.
A kind of paper of the imitative pearl effect using above-mentioned printing solution, including single copper paper, on the surface of single copper paper It is coated with coat of colo(u)r, characterized in that the printing solution, the printing solid rear formation of solution are coated on the coat of colo(u)r Precoated shet also has additional printing layer in the precoating layer surface;Wherein, the printing layer is one layer of PET film.
A kind of preparation method of the paper of imitative pearl effect, includes the following steps:
Step 1, require by weight percentage successively by butyl acrylate, methyl methacrylate and acrylic acid mix and uniformly Stirring keeps the control of mixed material temperature between 50 DEG C -60 DEG C during uniform stirring;
Step 2 continues uniform stirring after requiring addition isocyanates by weight percentage during above-mentioned uniform stirring, and Keep the control of mixed material temperature between 60 DEG C -70 DEG C during uniform stirring;
Step 3 after above-mentioned all mixed materials merge completely, stands to room temperature, can be prepared by the printing solution, spare;
Step 4, is coated with coat of colo(u)r on the surface of single copper paper, and the above-mentioned printing prepared is applied to solution by printing machine On the coat of colo(u)r of single copper paper, printing is handled with solution by the dry tack free of dryer, so that printing is formed after using solution solid Precoated shet, then printing layer is added toward the precoating layer surface, the paper of imitative pearl effect is made.
In the step 1 and step 2, the mixing speed of uniform stirring control respectively at 200-300 revs/min and 300-500 revs/min, and in step 1, avoiding daylight or ultraviolet light and condition of the relative air humidity less than 50% Under, it requires by weight percentage successively slowly by the mixing of butyl acrylate, methyl methacrylate and acrylic acid and uniform stirring.
Wherein, the advantages of printing layer is to be covered with one layer of PET film in precoating layer surface by laminating machine, PET film It is that it has excellent physical property, chemical property and dimensional stability, the transparency, recuperability, on the one hand protects original There is coating result, while can guarantee that printing layer can preferably carry out ink printing.

Claims (10)

1. a kind of printing solution, characterized in that including following components and its weight percent: butyl acrylate: 35%-50%, Methyl methacrylate: 10%-20%, acrylic acid: 20%-35% and isocyanates: 5%-15%.
2. printing solution according to claim 1, characterized in that the weight percent of the butyl acrylate can be 40% or 45%.
3. printing solution according to claim 1, characterized in that the weight percent of the methyl methacrylate can be with It is 12% or 15%.
4. printing solution according to claim 1, characterized in that the weight percent of the acrylic acid is 25% or 30%.
5. printing solution according to claim 1, characterized in that the weight percent of the isocyanates is 8% or 12%.
6. a kind of paper using the imitative pearl effect of printing solution as described in claim 1 to 5 is any, including single copper paper, The surface of the list copper paper is coated with coat of colo(u)r, characterized in that the printing solution, the printing are coated on the coat of colo(u)r With the solid rear formation precoated shet of solution, printing layer is also had additional in the precoating layer surface.
7. imitating the paper of pearl effect according to claim 6, characterized in that the printing layer is one layer of PET film.
8. a kind of preparation method for the paper for imitating pearl effect as claimed in claims 6 or 7, characterized in that include the following steps:
Step 1, require by weight percentage successively by butyl acrylate, methyl methacrylate and acrylic acid mix and uniformly Stirring keeps the control of mixed material temperature between 50 DEG C -60 DEG C during uniform stirring;
Step 2 continues uniform stirring after requiring addition isocyanates by weight percentage during above-mentioned uniform stirring, and Keep the control of mixed material temperature between 60 DEG C -70 DEG C during uniform stirring;
Step 3 after above-mentioned all mixed materials merge completely, stands to room temperature, can be prepared by the printing solution, spare;
Step 4, is coated with coat of colo(u)r on the surface of single copper paper, and the above-mentioned printing prepared is applied to solution by printing machine On the coat of colo(u)r of single copper paper, printing is handled with solution by the dry tack free of dryer, so that printing is formed after using solution solid Precoated shet, then printing layer is added toward the precoating layer surface, the paper of imitative pearl effect is made.
9. imitating the preparation method of the paper of pearl effect according to claim 8, characterized in that the step 1 and step 2 In, the mixing speed of uniform stirring is controlled respectively in 200-300 revs/min and 300-500 revs/min, and in step 1, Under conditions of avoiding daylight or ultraviolet light and relative air humidity is less than 50%, require by weight percentage successively slowly By the mixing of butyl acrylate, methyl methacrylate and acrylic acid and uniform stirring.
10. imitating the preparation method of the paper of pearl effect according to claim 8, characterized in that the printing layer is by covering Film machine is covered with one layer of PET film in precoating layer surface.
CN201810850034.8A 2018-07-28 2018-07-28 The paper and preparation method thereof of printing solution and the imitative pearl effect using the solution Pending CN109137607A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810850034.8A CN109137607A (en) 2018-07-28 2018-07-28 The paper and preparation method thereof of printing solution and the imitative pearl effect using the solution

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810850034.8A CN109137607A (en) 2018-07-28 2018-07-28 The paper and preparation method thereof of printing solution and the imitative pearl effect using the solution

Publications (1)

Publication Number Publication Date
CN109137607A true CN109137607A (en) 2019-01-04

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101928512A (en) * 2010-09-02 2010-12-29 哈尔滨工业大学 Water-borne acrylic resin-based two-component surface coating modified solution and preparation method thereof
CN102827520A (en) * 2012-09-12 2012-12-19 惠州艺都影像科技有限公司 Base coating of polyethylene terephthalate (PET) membrane and production process of base coating
CN203284693U (en) * 2013-04-23 2013-11-13 绍兴虎彩激光材料科技有限公司 Iridescent paper
CN107418309A (en) * 2017-07-26 2017-12-01 上海乘鹰新材料有限公司 E-inks printing coating composition with pearl effect and preparation method thereof
CN108192410A (en) * 2017-12-14 2018-06-22 乐凯胶片股份有限公司 A kind of pearly-lustre printable fabric

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101928512A (en) * 2010-09-02 2010-12-29 哈尔滨工业大学 Water-borne acrylic resin-based two-component surface coating modified solution and preparation method thereof
CN102827520A (en) * 2012-09-12 2012-12-19 惠州艺都影像科技有限公司 Base coating of polyethylene terephthalate (PET) membrane and production process of base coating
CN203284693U (en) * 2013-04-23 2013-11-13 绍兴虎彩激光材料科技有限公司 Iridescent paper
CN107418309A (en) * 2017-07-26 2017-12-01 上海乘鹰新材料有限公司 E-inks printing coating composition with pearl effect and preparation method thereof
CN108192410A (en) * 2017-12-14 2018-06-22 乐凯胶片股份有限公司 A kind of pearly-lustre printable fabric

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Application publication date: 20190104