CN109135860A - The preprocess method of biomass - Google Patents

The preprocess method of biomass Download PDF

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Publication number
CN109135860A
CN109135860A CN201810951551.4A CN201810951551A CN109135860A CN 109135860 A CN109135860 A CN 109135860A CN 201810951551 A CN201810951551 A CN 201810951551A CN 109135860 A CN109135860 A CN 109135860A
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CN
China
Prior art keywords
clast
biomass
wet crumb
preprocess method
carried out
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810951551.4A
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Chinese (zh)
Inventor
沈显华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhu Flame Biomass Energy Technology Co Ltd
Original Assignee
Wuhu Flame Biomass Energy Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuhu Flame Biomass Energy Technology Co Ltd filed Critical Wuhu Flame Biomass Energy Technology Co Ltd
Priority to CN201810951551.4A priority Critical patent/CN109135860A/en
Publication of CN109135860A publication Critical patent/CN109135860A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The present invention relates to biomass fuel production technical fields, are more particularly to a kind of preprocess method of biomass;Include the following steps: that biomass material is cut off or be crushed by (1), obtains particle size range in the clast of 10-60mm;(2) cyclonic separation is carried out to gained clast and pulse dust removal is handled;(3) clast is washed with recirculated water, and adjusts the moisture content of clast to 10-30%;(4) supercritical CO is carried out to gained wet crumb2Explosion treatment;(5) microwave drying treatment is carried out to clast water content≤10% to wet crumb;(6) clast was crushed to 100 mesh.The present invention is cleaned by hydro-thermal process, overcritical explosion treatment, reduces alkali metal element content, softening wood fibre, to reduce slagging phenomenon and to facilitate feeding.

Description

The preprocess method of biomass
Technical field
The present invention relates to biomass fuel production technical fields, are more particularly to a kind of preprocess method of biomass.
Background technique
Biomass moulding solid fuel is a kind of environment-friendly fuel with wide application prospect, and production technology includes powder Broken, removal of impurities, extruding, drying, cooling, quality inspection, packaging and other steps.Currently, being deposited in the production process of biomass moulding solid fuel Have in following problem to be solved: one is in the collection and transportational process of lignin raw material, be inevitably mixed into containing SiO2Silt, while agricultural crop straw can absorb a certain amount of alkali metal element during the growth process, these elements with salt or The forms such as oxide are present in biomass body.When stalk biomass solid molding fuel burns in boiler, alkali gold Belong to the eutectic that low melting point is generated with silicon dioxde reaction, it is eutectiferous to there is the fusing point for reducing stalk ash content, make straw ash Glassy hard clinker is easily formed, boiler inner wall face is condensed in, generates the dust stratification and clogging problems being difficult to clean off.The second is not With biomass material there are larger difference in the performances such as moisture content, hardness, crush resistance, by the mistake of biomass extrusion molding Cheng Zhong, biomass how steady and continuous feeding solid fuel molding machine be influence stalk solid molding fuel development bottleneck it One.
Summary of the invention
According to the above-mentioned deficiencies of the prior art, the technical problem to be solved by the present invention is to propose a kind of pre- place of biomass Reason method is cleaned by hydro-thermal process, overcritical explosion treatment, reduces alkali metal element content, softening wood fibre, so as to It reduces slagging phenomenon and facilitates feeding.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention are as follows: a kind of preprocess method of biomass, packet Include following steps:
(1) biomass material is cut off or is crushed, obtain particle size range in the clast of 10-60mm;
(2) cyclonic separation is carried out to gained clast and pulse dust removal is handled;
(3) clast is washed with recirculated water, and adjusts the moisture content of clast to 10-30%;
(4) supercritical CO is carried out to gained wet crumb2Explosion treatment;
(5) microwave drying treatment is carried out to clast water content≤10% to wet crumb;
(6) clast was crushed to 100 mesh.
Further, the water temperature of the recirculated water is 60-75 DEG C.
Further, the specific method of the step (4) is that clast is heated to 80-120 DEG C, is passed through CO2, set pressure Rapid release after 10-15MPa, 30-120 minutes.
Further, the microwave drying treatment step in the step (5) are as follows:
1) adjusting unit mass microwave irradiation power is 200-600w/kg wet crumb, and wet crumb temperature is made to rise to 70-80 ℃;
2) adjusting unit mass microwave irradiation power is 0.8-1.2kw/kg wet crumb, and wet crumb temperature is made to rise to 100- 120 DEG C, isothermal holding to clast water content≤10%.
Further, the biomass material includes woody waste and/or draft class waste.
Further, the woody waste in sawdust, wood shavings, sawdust, bark, branch, leaf, bamboo at least It is a kind of;The draft class waste in agricultural crop straw, shell, corncob, wheat bran, peanut shell, bagasse at least one Kind.
The beneficial effects of the present invention are: cutoff process can be distributed more uniform raw material convenient for formation length, to control Moisture processed and temperature.Cyclonic separation and pulse dust removal can tentatively remove a large amount of impurity that raw material is collected with carried in storage and transport process. Hydro-thermal process can soften sawdust, make cellulose, hemicellulose, lignin swollen, strenuous exercise provides space for molecule.It is super to face Boundary CO2Explosion treatment can remove the substances such as pectic substance, make lignin in viscous state, and hemicellulose loses connection effect, sawdust modeling Property increase.Microwave treatment can make fierce collision mutually between sawdust interior molecules, and heating efficiency is high, thermal effectiveness is uniform.Through this After the method processing that invention provides, the alkali metal such as Na, K in sawdust
Constituent content is low, and the impurity contents such as sandstone are low, after biomass solid formed fuel is made, the ash content fusing point of fuel Height is not susceptible to dust stratification and clogging problems.In addition, being stripped of the sawdust volume reduction, quality softening after drying of pectic substance, drop Low feeding difficulty.
Specific embodiment
Below by the description to embodiment, the shape of for example related each component of a specific embodiment of the invention, structure It makes, the mutual alignment between each section and connection relationship, the effect of each section and working principle, manufacturing process and the side of operating with Method etc., is described in further detail, completeer to help those skilled in the art to have inventive concept of the invention, technical solution Whole, accurate and deep understanding.
Embodiment 1: the pretreatment of biomass
(1) biomass material is cut off or is crushed, obtain particle size range in the clast of 10-60mm;
(2) cyclonic separation is carried out to gained clast and pulse dust removal is handled;
(3) clast is washed with 60-75 DEG C of circulating hot water, and adjusts the moisture content of clast to 10-30%;
(4) gained wet crumb is heated to 80-120 DEG C, is passed through CO2, pressure 10-15MPa is set, it is fast after 30-120 minutes Fast release;
(5) microwave drying treatment is carried out to wet crumb:
1) adjusting unit mass microwave irradiation power is 200-600w/kg wet crumb, and wet crumb temperature is made to rise to 70-80 ℃;
2) adjusting unit mass microwave irradiation power is 0.8-1.2kw/kg wet crumb, and wet crumb temperature is made to rise to 100- 120 DEG C, isothermal holding to clast water content≤10%;
(6) clast was crushed to 100 mesh.
The biomass material is sawdust, wood shavings, sawdust.
Embodiment 2: the pretreatment of biomass
Using the method for embodiment 1, difference
Be: the biomass material is the mixture being made of bark, branch, leaf.
Embodiment 3: the pretreatment of biomass
Using the method for embodiment 1, the difference is that: the biomass material is bamboo.
Embodiment 4: the pretreatment of biomass
Using the method for embodiment 1, the difference is that: the biomass material is by straw, corncob, bagasse group At mixture.
Embodiment 5: the pretreatment of biomass
Using the method for embodiment 1, the difference is that: the biomass material is to be made of shell, wheat bran, peanut shell Mixture.
The present invention is exemplarily described above, it is clear that present invention specific implementation is not subject to the restrictions described above, As long as using the improvement for the various unsubstantialities that the inventive concept and technical scheme of the present invention carry out, or not improved this is sent out Bright conception and technical scheme directly apply to other occasions, within the scope of the present invention.Protection of the invention Range should be determined by the scope of protection defined in the claims.

Claims (6)

1. a kind of preprocess method of biomass, which comprises the steps of:
(1) biomass material is cut off or is crushed, obtain particle size range in the clast of 10-60mm;
(2) cyclonic separation is carried out to gained clast and pulse dust removal is handled;
(3) clast is washed with recirculated water, and adjusts the moisture content of clast to 10-30%;
(4) supercritical CO is carried out to gained wet crumb2Explosion treatment;
(5) microwave drying treatment is carried out to clast water content≤10% to wet crumb;
(6) clast was crushed to 100 mesh.
2. the preprocess method of biomass according to claim 1, it is characterised in that: the water temperature of the recirculated water is 60- 75℃。
3. the preprocess method of biomass according to claim 1, it is characterised in that: the specific method of the step (4) For clast is heated to 80-120 DEG C, it is passed through CO2, set pressure 10-15MPa, rapid release after 30-120 minutes.
4. the preprocess method of biomass according to claim 1, it is characterised in that: the microwave in the step (5) is dry Dry processing step are as follows:
1) adjusting unit mass microwave irradiation power is 200-600w/kg wet crumb, and wet crumb temperature is made to rise to 70-80 DEG C;
2) adjusting unit mass microwave irradiation power is 0.8-1.2kw/kg wet crumb, and wet crumb temperature is made to rise to 100-120 DEG C, Isothermal holding is to clast water content≤10%.
5. the preprocess method of biomass according to claim 1, it is characterised in that: the biomass material includes woody Class waste and/or draft class waste.
6. the preprocess method of biomass according to claim 5, it is characterised in that: the woody waste is selected from wood At least one of bits, wood shavings, sawdust, bark, branch, leaf, bamboo;The draft class waste is selected from agricultural crop straw, fruit At least one of shell, corncob, wheat bran, peanut shell, bagasse.
CN201810951551.4A 2018-08-21 2018-08-21 The preprocess method of biomass Pending CN109135860A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810951551.4A CN109135860A (en) 2018-08-21 2018-08-21 The preprocess method of biomass

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810951551.4A CN109135860A (en) 2018-08-21 2018-08-21 The preprocess method of biomass

Publications (1)

Publication Number Publication Date
CN109135860A true CN109135860A (en) 2019-01-04

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109734483A (en) * 2019-02-19 2019-05-10 安徽瑞虎肥业有限公司 A kind of preprocess method of biomass fertilizers
CN110499200A (en) * 2019-07-11 2019-11-26 西安交通大学 A kind of processing of stalk fuel and collection system and method
CN110697805A (en) * 2019-09-26 2020-01-17 杭州金溢建设集团有限公司 River channel algae separation and bio-fertilizer treatment method

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104212530A (en) * 2014-09-25 2014-12-17 江南大学 Method for producing solid fuel by exploding biomass waste through flue gas

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104212530A (en) * 2014-09-25 2014-12-17 江南大学 Method for producing solid fuel by exploding biomass waste through flue gas

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109734483A (en) * 2019-02-19 2019-05-10 安徽瑞虎肥业有限公司 A kind of preprocess method of biomass fertilizers
CN110499200A (en) * 2019-07-11 2019-11-26 西安交通大学 A kind of processing of stalk fuel and collection system and method
CN110697805A (en) * 2019-09-26 2020-01-17 杭州金溢建设集团有限公司 River channel algae separation and bio-fertilizer treatment method
CN110697805B (en) * 2019-09-26 2021-11-09 杭州金溢建设集团有限公司 River channel algae separation and bio-fertilizer treatment method

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