CN109133892A - Imitation Rock Porcelain Tiles brighten synthetic material and its preparation method and application with zirconium matter - Google Patents

Imitation Rock Porcelain Tiles brighten synthetic material and its preparation method and application with zirconium matter Download PDF

Info

Publication number
CN109133892A
CN109133892A CN201811290756.9A CN201811290756A CN109133892A CN 109133892 A CN109133892 A CN 109133892A CN 201811290756 A CN201811290756 A CN 201811290756A CN 109133892 A CN109133892 A CN 109133892A
Authority
CN
China
Prior art keywords
parts
synthetic material
imitation rock
carbonate
porcelain tiles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811290756.9A
Other languages
Chinese (zh)
Inventor
韩强
王美兰
许行强
王慧颖
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU MINUOFU NANO MATERIALS CO Ltd
Original Assignee
JIANGSU MINUOFU NANO MATERIALS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGSU MINUOFU NANO MATERIALS CO Ltd filed Critical JIANGSU MINUOFU NANO MATERIALS CO Ltd
Priority to CN201811290756.9A priority Critical patent/CN109133892A/en
Publication of CN109133892A publication Critical patent/CN109133892A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/04—Clay; Kaolin
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605—Treating the starting powders individually or as mixtures
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0009—Pigments for ceramics
    • C09C1/0012—Pigments for ceramics containing zirconium and silicon
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3284—Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3409—Boron oxide, borates, boric acids, or oxide forming salts thereof, e.g. borax
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/442—Carbonates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/443—Nitrates or nitrites

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Finishing Walls (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention belongs to ceramic technology fields, and in particular to Imitation Rock Porcelain Tiles brighten synthetic material and its preparation method and application with zirconium matter.Selected silica flour, commercial alumina, potassium carbonate, sodium carbonate, potassium nitrate, zirconium silicate, zinc oxide, barium carbonate, boric acid, magnesium carbonate, precipitated calcium carbonate；The fineness requirement 80-200 mesh of various raw materials is uniformly mixed by said ratio, is put into frit tank furnace and is melted through 1600 DEG C, and particle of the high-temp liquid after melting fully reacting after water quick cooling is synthetic material.The Imitation Rock Porcelain Tiles brighten the purposes of synthetic material with zirconium matter, are used to prepare Imitation Rock Porcelain Tiles.Imitation Rock Porcelain Tiles provided by the invention brighten synthetic material and its preparation method and application with zirconium matter, the whiteness of Imitation Rock Porcelain Tiles green body can not only be made to be increased to 80 degree, and green body also has translucency, ceramic tile reaches the white body with beautiful texture, radioactive element is not exceeded, promotes the class turned to porcelain.

Description

Imitation Rock Porcelain Tiles brighten synthetic material and its preparation method and application with zirconium matter
Technical field
The invention belongs to ceramic technology fields, and in particular to Imitation Rock Porcelain Tiles with zirconium matter brighten synthetic material and preparation method thereof and Purposes.
Background technique
Traditional Imitation Rock Porcelain Tiles green body is mainly by natural minerals such as feldspar, kaolin, quartz sand, wollastonite, pyrophillite, talcums Composition can add suitable brightening agent zirconium silicate to increase Baidu, and natural mineral raw is anyway selected, finishing all can Containing coloring oxides such as a certain amount of iron, titaniums, the whiteness that Imitation Rock Porcelain Tiles green body is reduced with membership of these coloring oxides, even if The zirconium silicate of whitening effect is added, the whiteness of green body is also extremely difficult to 60 degree of whiteness.Since zirconium silicate has radioactivity, greatly The introducing of amount zirconium silicate can cause the radioactivity of Imitation Rock Porcelain Tiles green body exceeded.
Summary of the invention
In view of the above technical problems, the present invention provide a kind of Imitation Rock Porcelain Tiles with zirconium matter brighten synthetic material and preparation method thereof and Purposes improves the whiteness of adobe body, and brick body environmental protection does not have radioactive substance.
The specific technical proposal is:
Imitation Rock Porcelain Tiles brighten synthetic material with zirconium matter, are prepared from the following raw materials:
The weight batching range of various raw materials:
Silica flour: 60-70 parts；
Aluminium oxide: 5-12 parts；
Zirconium silicate: 5-10 parts；
Potassium carbonate: 3-8 parts；
Zinc oxide: 2-5 parts；
Sodium carbonate: 3-6 parts；
Potassium nitrate: 2-4 parts；
Barium carbonate: 2-4 parts；
Magnesium carbonate: 2-4 parts；
Boric acid: 2-5 parts.
The Imitation Rock Porcelain Tiles brighten the preparation method of synthetic material, including following procedure with zirconium matter:
Selected silica flour, commercial alumina, potassium carbonate, sodium carbonate, potassium nitrate, zirconium silicate, zinc oxide, barium carbonate, boric acid, carbonic acid Magnesium, precipitated calcium carbonate；
The fineness requirement 80-200 mesh of various raw materials is uniformly mixed by said ratio, is put into frit tank furnace and is melted through 1600 DEG C, melts Particle of the high-temp liquid after water quick cooling after changing fully reacting is synthetic material.
The Imitation Rock Porcelain Tiles brighten the purposes of synthetic material with zirconium matter, are used to prepare Imitation Rock Porcelain Tiles, above-mentioned synthetic material are added high Ridge soil, enter ball mill and add water for ball milling, up to fineness after drying-granulating agent base powder, press-molding is made after be burnt into, firing temperature 1200- 1230℃。
Imitation Rock Porcelain Tiles provided by the invention brighten synthetic material and its preparation method and application with zirconium matter, can not only make Imitation Rock Porcelain Tiles The whiteness of green body is increased to 80 degree, and green body also has translucency, and ceramic tile reaches the white body with beautiful texture, radioactivity Element is not exceeded, promotes the class turned to porcelain.
Specific embodiment
It is described in conjunction with the embodiments the specific technical solution of the present invention.
Imitation Rock Porcelain Tiles brighten synthetic material with zirconium matter, are prepared from the following raw materials:
The weight batching range of various raw materials:
Silica flour: 60-70 parts；
Aluminium oxide: 5-12 parts；
Zirconium silicate: 5-10 parts；
Potassium carbonate: 3-8 parts；
Zinc oxide: 2-5 parts；
Sodium carbonate: 3-6 parts；
Potassium nitrate: 2-4 parts；
Barium carbonate: 2-4 parts；
Magnesium carbonate: 2-4 parts；
Boric acid: 2-5 parts.
Imitation Rock Porcelain Tiles brighten the preparation method of synthetic material with zirconium matter, which is characterized in that including following procedure: selected quartz Powder, commercial alumina, potassium carbonate, sodium carbonate, potassium nitrate, zirconium silicate, zinc oxide, barium carbonate, boric acid, magnesium carbonate, lightweight carbonic acid Calcium；The fineness requirement 80-200 mesh of various raw materials is uniformly mixed by said ratio, is put into frit tank furnace and is melted through 1600 DEG C, melts Particle of the high-temp liquid after water quick cooling after changing fully reacting is synthetic material.
The synthetic material substantially chemical composition are as follows:
1 chemical constituent of table (mass percent)
SiO2 70-80%
Al2O3 8-12%
B2O3 1-2%
KNaO 5-10%
ZrO2 2-5%
BaO 1-3%
ZnO 1-3%
CaO 2-5%
MgO 1-2%
Imitation Rock Porcelain Tiles brighten synthetic material preparation Imitation Rock Porcelain Tiles with zirconium matter, and kaolin is added in above-mentioned synthetic material, according to parts by weight, 30 parts of selected kaolin, 70 parts of synthetic material.Enter ball mill and add water for ball milling, up to fineness after drying-granulating agent base powder, press is made It is burnt into after molding, 1200-1230 DEG C of firing temperature.

Claims (3)

1. Imitation Rock Porcelain Tiles brighten synthetic material with zirconium matter, which is characterized in that be prepared from the following raw materials:
The weight batching range of various raw materials:
Silica flour: 60-70 parts；
Aluminium oxide: 5-12 parts；
Zirconium silicate: 5-10 parts；
Potassium carbonate: 3-8 parts；
Zinc oxide: 2-5 parts；
Sodium carbonate: 3-6 parts；
Potassium nitrate: 2-4 parts；
Barium carbonate: 2-4 parts；
Magnesium carbonate: 2-4 parts；
Boric acid: 2-5 parts.
2. the preparation method that Imitation Rock Porcelain Tiles according to claim 1 brighten synthetic material with zirconium matter, which is characterized in that including with Lower process:
Selected silica flour, commercial alumina, potassium carbonate, sodium carbonate, potassium nitrate, zirconium silicate, zinc oxide, barium carbonate, boric acid, carbonic acid Magnesium, precipitated calcium carbonate；
The fineness requirement 80-200 mesh of various raw materials is uniformly mixed by said ratio, is put into frit tank furnace and is melted through 1600 DEG C, melts Particle of the high-temp liquid after water quick cooling after changing fully reacting is synthetic material.
3. the purposes that Imitation Rock Porcelain Tiles according to claim 1 brighten synthetic material with zirconium matter, which is characterized in that be used to prepare porcelain Matter brick, by above-mentioned synthetic material be added kaolin, enter ball mill and add water for ball milling, up to fineness after drying-granulating agent be made base powder, pressure It is burnt into after machine molding, 1200-1230 DEG C of firing temperature.
CN201811290756.9A 2018-10-31 2018-10-31 Imitation Rock Porcelain Tiles brighten synthetic material and its preparation method and application with zirconium matter Pending CN109133892A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811290756.9A CN109133892A (en) 2018-10-31 2018-10-31 Imitation Rock Porcelain Tiles brighten synthetic material and its preparation method and application with zirconium matter

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811290756.9A CN109133892A (en) 2018-10-31 2018-10-31 Imitation Rock Porcelain Tiles brighten synthetic material and its preparation method and application with zirconium matter

Publications (1)

Publication Number Publication Date
CN109133892A true CN109133892A (en) 2019-01-04

Family

ID=64807331

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811290756.9A Pending CN109133892A (en) 2018-10-31 2018-10-31 Imitation Rock Porcelain Tiles brighten synthetic material and its preparation method and application with zirconium matter

Country Status (1)

Country Link
CN (1) CN109133892A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114349482A (en) * 2021-12-14 2022-04-15 泉州市利芝新材料科技有限公司 Method for preparing ceramic blank whitening composite zirconium by using zirconium-containing refractory brick leftover material and application thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103011767A (en) * 2012-12-25 2013-04-03 青岛科技大学 Sanitary ceramic body
CN103011765A (en) * 2012-12-25 2013-04-03 青岛科技大学 Flux system for sintering ceramic body in liquid phase and preparation method thereof
CN103159462A (en) * 2011-12-09 2013-06-19 沈阳浩松陶瓷有限公司 Production process for jade spar crystallized high-grade ceramic tile
US20150299036A1 (en) * 2012-11-20 2015-10-22 Ljerka Ukrainczyk Method of making three dimensional glass ceramic article
CN105948505A (en) * 2016-06-23 2016-09-21 叶国强 Preparation method for lead-zinc-silver tailing low-temperature-sintered encaustic brick glaze
CN106336249A (en) * 2016-08-29 2017-01-18 佛山市高明区明城镇新能源新材料产业技术创新中心 Antibacterial and anti-static ceramic tile and preparing method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103159462A (en) * 2011-12-09 2013-06-19 沈阳浩松陶瓷有限公司 Production process for jade spar crystallized high-grade ceramic tile
US20150299036A1 (en) * 2012-11-20 2015-10-22 Ljerka Ukrainczyk Method of making three dimensional glass ceramic article
CN103011767A (en) * 2012-12-25 2013-04-03 青岛科技大学 Sanitary ceramic body
CN103011765A (en) * 2012-12-25 2013-04-03 青岛科技大学 Flux system for sintering ceramic body in liquid phase and preparation method thereof
CN105948505A (en) * 2016-06-23 2016-09-21 叶国强 Preparation method for lead-zinc-silver tailing low-temperature-sintered encaustic brick glaze
CN106336249A (en) * 2016-08-29 2017-01-18 佛山市高明区明城镇新能源新材料产业技术创新中心 Antibacterial and anti-static ceramic tile and preparing method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114349482A (en) * 2021-12-14 2022-04-15 泉州市利芝新材料科技有限公司 Method for preparing ceramic blank whitening composite zirconium by using zirconium-containing refractory brick leftover material and application thereof

Similar Documents

Publication Publication Date Title
CN107417115B (en) Method for manufacturing high-hardness high-wear-resistance glaze
CN102584341B (en) Glaze slip for sanitary ceramics and preparation method for glaze slip
US7892997B2 (en) Glaze compositions
CN104926281B (en) A kind of preparation method of inexpensive ultrawhite ceramic tile
CN100447111C (en) Crystalline glaze of iron, zinc and augite and its material compounding process
CN111253072A (en) Ceramic glaze with good wear resistance and high hardness and preparation method thereof
CN106431365A (en) Ultrawhite polished tile and preparation method thereof
CN100528799C (en) Super-white polished brick
CN101659567A (en) Furnace transmutation decoration glazed brick and production technology
CN106977097B (en) Raw glaze for transparent high-gloss medium-temperature hard porcelain and preparation method thereof
CN102180659A (en) Talcum building ceramic brick and manufacturing method thereof
CN102134167A (en) Low-temperature melting block finished glaze and preparation method thereof
CN108423993B (en) Meteorite glaze for building pottery and application method thereof
CN105330158A (en) Glaze of brunet ceramic and preparation method of glaze
CN102020459B (en) Feldspar-free ecological daily fine porcelain and manufacturing method thereof
CN110452020A (en) It is a kind of to introduce black matrix flash glaze ceramics and its manufacture craft prepared by quartz mine tailings
CN107619256A (en) A kind of matt ancient architecture porcelain and its preparation technology
CN102399090A (en) Lightweight vitreous foamed ceramic
CN109650848A (en) It is a kind of from raw glaze enamel porcelain pug and use its technique for preparing enamel porcelain
CN104446657A (en) Dry granular additive for full polishing of ceramic tiles and preparation method of dry granular additive
CN106365673A (en) Low-temperature quick burning daily ceramic and production process thereof
CN105294057A (en) Preparation process for ultrathin ceramic brick
CN106277792B (en) A kind of emerald blueness glaze and its method for cooking
CN109133892A (en) Imitation Rock Porcelain Tiles brighten synthetic material and its preparation method and application with zirconium matter
CN101643354B (en) Production method of lithium non-expansion heat-resistant ceramic

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20190104

WD01 Invention patent application deemed withdrawn after publication