CN109130404B - 一种复合丝绸布料及其制备方法 - Google Patents

一种复合丝绸布料及其制备方法 Download PDF

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CN109130404B
CN109130404B CN201810957310.0A CN201810957310A CN109130404B CN 109130404 B CN109130404 B CN 109130404B CN 201810957310 A CN201810957310 A CN 201810957310A CN 109130404 B CN109130404 B CN 109130404B
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silk
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cotton
composite
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CN109130404A (zh
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潘建新
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Huzhou Chengde Silk Co ltd
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Abstract

本发明公开了一种复合丝绸布料及其制备方法，布料包括由经纱和纬纱交织呈的基体层，所述经纱包括下述重量配比的材料制成：蚕丝50‑60份、氨纶20‑30份、粘胶20‑30份，所述纬纱包括下述重量配比的材料制成：蚕丝30‑40份、棉40‑50份、羊毛30‑40份；所述基体层的上下两侧均通过导电纤维缝合有带抗菌颗粒的网格层。布料的制备方法为先将蚕丝、粘胶和氨纶制得经纱，并去杂质处理；再将蚕丝、棉、羊毛制得纬纱，并去杂质处理，然后将经纱和纬纱制得基体层，然后选择在抗菌剂中浸泡后的聚氨酯纤维制得网格层，并填充纳米银抗菌颗粒，最后通过导电纤维缝制而成。本发明具有保暖性好、弹性佳、不易起皱、抗菌效果好的特点。

Description

一种复合丝绸布料及其制备方法
技术领域
本发明涉及一种复合丝绸布料，特别是一种复合丝绸布料及其制备方法。
背景技术
面料是制成衣物或饰物的基础材料，面料的性能将直接影响着衣物或饰物的性能。随着人们生活水平的提高，人们对衣物或饰物的性能要求也越来越高，除了要求衣物或饰物具备美观、舒适的性能外，还对衣物或饰物提出了更高的要求，单一的面料已经无法满足人们对衣物或饰物的要求。丝绸是以蚕丝为原料纺织而成的各种丝织物的统称。它可被用来制作各种服装、被套等面料，它的特征是轻薄、合身、柔软、滑爽、透气、色彩绚丽，富有光泽，高贵典雅，穿著舒适，但保暖性不佳、弹性不够，容易起皱，且还容易受到有害菌体的污染，使面料变质，不易保存。因此，现有技术中的丝绸面料，存在保暖性不佳、弹性不够、容易起皱、抗菌效果较差的问题。
发明内容
本发明的目的在于，提供一种复合丝绸布料及其制备方法。本发明具有保暖性好、弹性佳、不易起皱、抗菌效果好的特点。
本发明的技术方案：一种复合丝绸布料，包括基体层，基体层由经纱和纬纱交织而成，所述经纱为蚕丝、粘胶混纺后包覆在氨纶表面的包芯纱，所述经纱包括下述重量配比的材料制成：蚕丝50-60份、氨纶20-30份、粘胶20-30份，所述纬纱为蚕丝、棉混纺后加捻卷绕在氨纶表面的包覆丝，所述纬纱包括下述重量配比的材料制成：蚕丝30-40份、棉40-50份、羊毛30-40份；所述基体层的上下两侧均设有由聚氨酯纤维编织而成的网格层，网格层的网孔内设有抗菌颗粒；所述网格层和基体层通过导电纤维缝合。
前述的复合丝绸布料中，所述导电纤维采用碳素复合纤维。
前述的复合丝绸布料中，所述基体层与网格层的厚度之比为3:1。
前述的复合丝绸布料中，所述氨纶的截面为五角星形，相邻边角之间圆弧过渡，五个角为圆角。采用五角星形的异形截面，吸湿排汗效果好，采用圆弧过渡和圆角，结构稳定，减少加工难度，提高产品成品率。
上述的复合丝绸布料的制备方法，包括以下步骤：
A、将蚕丝与粘胶先混纺，混纺的络纱速度为450-550m/min，形成丝/粘胶混纺纤维，然后将丝/粘胶混纺纤维包覆在氨纶的表面，得A品；
B、将A品置于水浴容器内，加入纯碱0.5-1g、精炼剂3-5g、35％硅酸钠0.1-0.3g、浴比为1:30-35，温度为90-100℃，时间为60-90min，得B品；
C、将蚕丝与精梳棉混纺，混纺的络纱速度为450-550m/min，形成丝/棉混纺纤维，然后将丝/棉混纺纤维呈螺旋状加捻卷绕在氨纶的表面，得C品；
D、将C品置于PH为6-8的水浴容器内，加入生物酶0.3-1.2g/l和双氧水，按照浴比为1:15-20进行煮漂，煮漂温度35-40℃，煮漂时间30-45min，然后加入0.5-0.7g/l的纯碱，调节ph为8.5-10，升高温度为80-90℃，得D品；
E、将B品作为经纱，将D品作为纬纱进行织造，得E品；
F、选择聚氨酯纤维作为原料，先在50-60℃温度的抗菌剂中浸渍0.5-6h，并用超声波进行震荡，然后取出烘干，再采用大圆机交织织造成网格状，得F品；
G、通过磁控溅射技术将纳米银抗菌颗粒填充在F品的网格孔内，得G品；
H、采用导电纤维将H品缝制在E品的上下两侧面，得成品。
前述的制备方法中，所述C品的捻度为650T/S。
前述的制备方法中，所述步骤F中的抗菌剂包括银离子抗菌剂、铜离子抗菌剂和锌离子抗菌剂。
前述的制备方法中，所述步骤B为，将A品置于水浴容器内，加入纯碱0.8g、精炼剂4g、35％硅酸钠0.2g、浴比为1:33，温度为95℃，时间为80min，得B品。
前述的制备方法中，所述步骤D为将C品置于PH为7的水浴容器内，加入生物酶3％和双氧水，按照浴比为1:18进行煮漂，煮漂温度36℃，煮漂时间35min，然后加入0.6g/l的纯碱，调节ph为9，升高温度为88℃，得D品。
与现有技术相比，本发明将蚕丝、粘胶、氨纶制成丝/粘胶/氨纶复合丝，作为经纱，将蚕丝、棉、羊毛制成丝/棉/羊毛复合丝，作为纬纱，梭织制成基体层，既不失蚕丝的光泽、舒适性和悬垂性，又可以增加织物的弹性、透气性、吸湿保暖性和抗皱性能，耐穿性能好；通过在基体层的两侧设置了由聚氨酯纤维编织成的网格层，使得织物具有良好的抗皱性能，且网格层内设置了抗菌颗粒，提高织物的抗菌能力，延长织物的保存时间；通过导线纤维将网格层和基体层连接，使得织物具有良好的抗静电性能，且结构稳定，不易分离，提高穿着的安全性和耐穿、耐洗性能。
上述织物的制备工艺，减少毛羽和棉结，清洁纤维表面，提高织造性能；去除棉纤维中的杂质，脱去丝胶的同时，保证蚕丝的强度，还减少对羊毛纤维的损伤，减少毛羽，改善丝胶颣节，使得布面光洁，手感柔软，提高织物的服用性能；并用含有抗菌剂的聚氨酯纤维制成网格层，并在网格层上填充纳米银抗菌颗，操作方便，易于实现工业化，与纤维的结合性好，使得网格层上形成致密的抗菌层，抗菌效果好，增强了织物的使用寿命，因此，本发明具有保暖性好、弹性佳、不易起皱、抗菌效果好的特点。
具体实施方式
下面结合实施例对本发明作进一步的说明，但并不作为对本发明限制的依据。
实施例1。
一种复合丝绸布料，包括基体层，基体层由经纱和纬纱交织而成，所述经纱为蚕丝、粘胶混纺后包覆在氨纶表面的包芯纱，所述经纱包括下述重量配比的材料制成：蚕丝50-60份、氨纶20-30份、粘胶20-30份，所述纬纱为蚕丝、棉混纺后加捻卷绕在羊毛表面的包覆丝，所述纬纱包括下述重量配比的材料制成：蚕丝30-40份、棉40-50份、羊毛30-40份；所述基体层的上下两侧均设有由聚氨酯纤维编织而成的网格层，网格层的网孔内设有抗菌颗粒；所述网格层和基体层通过导电纤维缝合。
所述导电纤维采用碳素复合纤维。
所述基体层与网格层的厚度之比为3:1。
所述氨纶的截面为五角星形，相邻边角之间圆弧过渡，五个角为圆角。
一种复合丝绸布料的制备方法，包括以下步骤：
A、将蚕丝与粘胶先混纺，混纺的络纱速度为450-550m/min，形成丝/粘胶混纺纤维，然后将丝/粘胶混纺纤维在细纱机上包覆在氨纶的表面，得A品；
B、将A品置于水浴容器内，加入纯碱0.5-1g、精炼剂3-5g、35％硅酸钠0.1-0.3g、浴比为1:30-35，温度为90-100℃，时间为60-90min，得B品；
C、将蚕丝与精梳棉混纺，混纺的络纱速度为450-550m/min，形成丝/棉混纺纤维，然后将丝/棉混纺纤维在倍捻机上呈螺旋状加捻卷绕在羊毛的表面，捻度为650T/S，得C品；
D、将C品置于PH为6-8的水浴容器内，加入生物酶0.3-1.2g/l和双氧水，按照浴比为1:15-20进行煮漂，煮漂温度35-40℃，煮漂时间30-45min，然后加入0.5-0.7g/l的纯碱，调节ph为8.5-10，升高温度为80-90℃，得D品；
E、将B品作为经纱，将D品作为纬纱进行织造，得E品；
F、选择聚氨酯纤维作为原料，先在50-60℃温度的抗菌剂中浸渍0.5-6h，抗菌剂包括银离子抗菌剂、铜离子抗菌剂和锌离子抗菌剂，并用超声波进行震荡，然后取出烘干，再采用大圆机交织织造成网格状，得F品；
G、通过磁控溅射技术将纳米银抗菌颗粒填充在F品的网格孔内，得G品；
H、采用导电纤维将H品缝制在E品的上下两侧面，得成品。
实施例2。
一种复合丝绸布料，包括基体层，基体层由经纱和纬纱交织而成，所述经纱为蚕丝、粘胶混纺后包覆在氨纶表面的包芯纱，所述经纱包括下述重量配比的材料制成：蚕丝55份、氨纶23份、粘胶25份，所述纬纱为蚕丝、棉混纺后加捻卷绕在羊毛表面的包覆丝，所述纬纱包括下述重量配比的材料制成：蚕丝35份、棉45份、羊毛35份；所述基体层的上下两侧均设有由聚氨酯纤维编织而成的网格层，网格层的网孔内设有抗菌颗粒；所述网格层和基体层通过导电纤维缝合。
所述导电纤维采用碳素复合纤维。
所述基体层与网格层的厚度之比为3:1。
所述氨纶的截面为五角星形，相邻边角之间圆弧过渡，五个角为圆角。
一种复合丝绸布料的制备方法，包括以下步骤：
A、将蚕丝与粘胶先混纺，混纺的络纱速度为500m/min，形成丝/粘胶混纺纤维，然后将丝/粘胶混纺纤维在细纱机上包覆在氨纶的表面，得A品；
B、将A品置于水浴容器内，加入纯碱0.5-1g、精炼剂3-5g、35％硅酸钠0.1-0.3g、浴比为1:30-35，温度为90-100℃，时间为60-90min，得B品；
C、将蚕丝与精梳棉混纺，混纺的络纱速度为450-550m/min，形成丝/棉混纺纤维，然后将丝/棉混纺纤维在倍捻机上呈螺旋状加捻卷绕在羊毛的表面，捻度为650T/S，得C品；
D、将C品置于PH为6-8的水浴容器内，加入生物酶0.3-1.2g/l和双氧水0.3-1ml/l，按照浴比为1:15-20进行煮漂，煮漂温度35-40℃，煮漂时间30-45min，然后加入0.5-0.7g/l的纯碱，调节ph为8.5-10，升高温度为80-90℃，得D品；
E、将B品作为经纱，将D品作为纬纱进行织造，得E品；
F、选择聚氨酯纤维作为原料，先在50-60℃温度的抗菌剂中浸渍0.5-6h，抗菌剂包括银离子抗菌剂、铜离子抗菌剂和锌离子抗菌剂，并用超声波进行震荡，然后取出烘干，再采用大圆机交织织造成网格状，得F品；
G、通过磁控溅射技术将纳米银抗菌颗粒填充在F品的网格孔内，得G品；
H、采用导电纤维将H品缝制在E品的上下两侧面，得成品。

Claims (8)

1.一种复合丝绸布料，其特征在于：包括基体层，基体层由经纱和纬纱交织而成，所述经纱为蚕丝、粘胶混纺后包覆在氨纶表面的包芯纱，所述经纱包括下述重量配比的材料：蚕丝50-60份、氨纶20-30份、粘胶20-30份，所述纬纱为蚕丝、棉混纺后加捻卷绕在羊毛表面的包覆丝，所述纬纱包括下述重量配比的材料：蚕丝30-40份、棉40-50份、羊毛30-40份；所述基体层的上下两侧均设有由聚氨酯纤维编织而成的网格层，网格层的网孔内设有抗菌颗粒；所述网格层和基体层通过导电纤维缝合；
该布料的制备方法，包括以下步骤：
A、将蚕丝与粘胶先混纺，混纺的络纱速度为450-550m/min，形成丝/粘胶混纺纤维，然后将丝/粘胶混纺纤维包覆在氨纶的表面，得A品；
B、将A品置于水浴容器内，加入纯碱0.5-1g、精炼剂3-5g、35％硅酸钠0.1-0.3g、浴比为1:30-35，温度为90-100℃，时间为60-90min，得B品；
C、将蚕丝与精梳棉混纺，混纺的络纱速度为450-550m/min，形成丝/棉混纺纤维，然后将丝/棉混纺纤维呈螺旋状加捻卷绕在羊毛的表面，得C品；
D、将C品置于pH为6-8的水浴容器内，加入生物酶0.3-1.2g/l和双氧水，按照浴比为1:15-20进行煮漂，煮漂温度35-40℃，煮漂时间30-45min，然后加入0.5-0.7g/l的纯碱，调节pH为8.5-10，升高温度为80-90℃，得D品；
E、将B品作为经纱，将D品作为纬纱进行织造，得E品；
F、选择聚氨酯纤维作为原料，先在50-60℃的抗菌剂中浸渍0.5-6h，并用超声波进行震荡，然后取出烘干，再采用大圆机交织织造成网格状，得F品；
G、通过磁控溅射技术将纳米银抗菌颗粒填充在F品的网格孔内，得G品；
H、采用导电纤维将G品缝制在E品的上下两侧面，得成品。
2.根据权利要求1所述的一种复合丝绸布料，其特征在于：所述导电纤维采用碳素复合纤维。
3.根据权利要求1所述的一种复合丝绸布料，其特征在于：所述基体层与网格层的厚度之比为3:1。
4.根据权利要求1所述的一种复合丝绸布料，其特征在于：所述氨纶的截面为五角星形，相邻边角之间圆弧过渡，五个角为圆角。
5.根据权利要求1所述的一种复合丝绸布料，其特征在于：所述C品的捻度为650T/S。
6.根据权利要求1所述的一种复合丝绸布料，其特征在于：所述步骤F中的抗菌剂包括银离子抗菌剂、铜离子抗菌剂和锌离子抗菌剂。
7.根据权利要求1所述的一种复合丝绸布料，其特征在于：所述步骤B为，将A品置于水浴容器内，加入纯碱0.8g、精炼剂4g、35％硅酸钠0.2g、浴比为1:33，温度为95℃，时间为80min，得B品。
8.根据权利要求1所述的一种复合丝绸布料，其特征在于：所述步骤D为将C品置于pH为7的水浴容器内，加入生物酶0.3g/l和双氧水，按照浴比为1:18进行煮漂，煮漂温度36℃，煮漂时间35min，然后加入0.6g/l的纯碱，调节pH为9，升高温度为88℃，得D品。
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