CN109122715A - 过一硫酸氢钾复合杀菌剂 - Google Patents

过一硫酸氢钾复合杀菌剂 Download PDF

Info

Publication number
CN109122715A
CN109122715A CN201710500878.5A CN201710500878A CN109122715A CN 109122715 A CN109122715 A CN 109122715A CN 201710500878 A CN201710500878 A CN 201710500878A CN 109122715 A CN109122715 A CN 109122715A
Authority
CN
China
Prior art keywords
potassium hydrogen
hydrogen peroxymonosulfate
compound disinfectant
disinfection
disinfectant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710500878.5A
Other languages
English (en)
Inventor
刘保良
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dezhou Green Energy Water Treatment Technology Co Ltd
Original Assignee
Dezhou Green Energy Water Treatment Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dezhou Green Energy Water Treatment Technology Co Ltd filed Critical Dezhou Green Energy Water Treatment Technology Co Ltd
Priority to CN201710500878.5A priority Critical patent/CN109122715A/zh
Publication of CN109122715A publication Critical patent/CN109122715A/zh
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/02Sulfur; Selenium; Tellurium; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/76Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/003Wastewater from hospitals, laboratories and the like, heavily contaminated by pathogenic microorganisms
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/02Specific form of oxidant
    • C02F2305/023Reactive oxygen species, singlet oxygen, OH radical
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/04Surfactants, used as part of a formulation or alone

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

过一硫酸氢钾复合杀菌剂,以重量百分含量表示,由过一硫酸氢钾复合盐20%~50%;二氯异氰尿酸钠40%~70%;氯化钠3%~10%;六偏磷酸钠3%~10%和十二烷基苯磺酸钠1%~10%组成。本发明过一硫酸氢钾复合杀菌剂将活性氧型杀菌消毒剂和含氯杀菌消毒剂集成于一体,可稳定有效地对水体进行持续杀菌,广泛用于医院污水、生活污水和自来水的消毒杀菌。

Description

过一硫酸氢钾复合杀菌剂
技术领域
本发明涉及水体杀菌消毒技术领域,具体涉及一种过一硫酸氢钾复合杀菌剂。
背景技术
水的消毒就是用化学和物理方法杀灭水中的病原体,以防止疾病传染,维护人群健康。目前一般使用的水体消毒剂类别有:氯化消毒类消毒剂:液氯,漂白粉,漂白粉精,次氯酸钠,二氯异氰尿酸钠,三氯异氰尿酸和氯胺类。此类消毒剂的原理为制剂溶于水中,水解产生次氯酸,利用次氯酸对细菌病毒等破坏作用进行消毒。其缺点为与有机物反应产生多种消毒副产物,有致癌、致畸、致突变作用;对人体生殖产生毒性等,持续稳定杀菌能力较弱。二氧化氯,杀菌广谱高效。二氧化氯消毒产生的主要副产物ClO2会危害人体血液、生殖发育等,而且使用时需现场制备,原料为盐酸对操作人员的呼吸系统伤害极大;由此可见,降低消毒液中二氧化氯含量可以有效减少具有致癌、致突变的副产物,避免对人体产生毒性。
发明内容
本发明针对现有技术的不足,提供了一种过一硫酸氢钾复合杀菌剂。
本发明解决其技术问题所采用的技术方案是:
一种过一硫酸氢钾复合杀菌剂,以重量百分含量表示,由过一硫酸氢钾复合盐20%~50%;二氯异氰尿酸钠40%~70%;氯化钠3%~10%;六偏磷酸钠3%~10%和十二烷基苯磺酸钠1%~10%组成。
本发明过一硫酸氢钾复合杀菌剂的工作原理是:过一硫酸氢钾复合盐为一种活性氧型杀菌消毒剂,二氯异氰尿酸钠为一种含氯杀菌消毒剂,活性氧型杀菌消毒剂和含氯杀菌消毒剂在活化剂氯化钠、稳定剂六偏磷酸钠和表面活性剂十二烷基苯磺酸钠作用下,在水中产生链式反应可释放高能量、高活性的硫酸根自由基和强氧化含氯衍生物,使得消毒粉在原水消毒后的遗传毒性远远低于传统的消毒粉;活性物质体积小,穿透力强,扩散到病原体细胞表面,破坏微生物的细胞膜的通透性屏障,使细胞内容物流失,产生的羟基自由基,作用于DNA 的磷酸二酯键而导致其断裂,干扰病原体DNA 和RNA 的合成,氧化病原体,使得菌体蛋白质变性凝固,从而杀灭病原微生物,可强力杀灭细菌芽孢、细菌繁殖体、真菌等各种致病性微生物,对肝炎病毒有特效杀灭作用,快速杀灭并强力抑制循环水、冷却塔、水池等系统的蓝绿藻、红藻、海藻等藻类植物有效成分持久性较强,可确保水体中含有足够的杀菌余量,可以起到持续杀菌的作用。
本发明过一硫酸氢钾复合杀菌剂将活性氧型杀菌消毒剂和含氯杀菌消毒剂集成于一体,可稳定有效地对水体进行持续杀菌,广泛用于医院污水、生活污水和自来水的消毒杀菌。
具体实施方式
一种过一硫酸氢钾复合杀菌剂,以重量百分含量表示,由过一硫酸氢钾复合盐20%~50%;二氯异氰尿酸钠40%~70%;氯化钠3%~10%;六偏磷酸钠3%~10%和十二烷基苯磺酸钠1%~10%组成。
本发明过一硫酸氢钾复合杀菌剂的工作原理是:过一硫酸氢钾复合盐为一种活性氧型杀菌消毒剂,二氯异氰尿酸钠为一种含氯杀菌消毒剂,活性氧型杀菌消毒剂和含氯杀菌消毒剂在活化剂氯化钠、稳定剂六偏磷酸钠和表面活性剂十二烷基苯磺酸钠作用下,在水中产生链式反应可释放高能量、高活性的硫酸根自由基和强氧化含氯衍生物,使得消毒粉在原水消毒后的遗传毒性远远低于传统的消毒粉;活性物质体积小,穿透力强,扩散到病原体细胞表面,破坏微生物的细胞膜的通透性屏障,使细胞内容物流失,产生的羟基自由基,作用于DNA 的磷酸二酯键而导致其断裂,干扰病原体DNA 和RNA 的合成,氧化病原体,使得菌体蛋白质变性凝固,从而杀灭病原微生物,可强力杀灭细菌芽孢、细菌繁殖体、真菌等各种致病性微生物,对肝炎病毒有特效杀灭作用,快速杀灭并强力抑制循环水、冷却塔、水池等系统的蓝绿藻、红藻、海藻等藻类植物有效成分持久性较强,可确保水体中含有足够的杀菌余量,可以起到持续杀菌的作用。

Claims (1)

1.一种过一硫酸氢钾复合杀菌剂,其特征是以重量百分含量表示,由过一硫酸氢钾复合盐20%~50%;二氯异氰尿酸钠40%~70%;氯化钠3%~10%;六偏磷酸钠3%~10%和十二烷基苯磺酸钠1%~10%组成。
CN201710500878.5A 2017-06-27 2017-06-27 过一硫酸氢钾复合杀菌剂 Pending CN109122715A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710500878.5A CN109122715A (zh) 2017-06-27 2017-06-27 过一硫酸氢钾复合杀菌剂

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710500878.5A CN109122715A (zh) 2017-06-27 2017-06-27 过一硫酸氢钾复合杀菌剂

Publications (1)

Publication Number Publication Date
CN109122715A true CN109122715A (zh) 2019-01-04

Family

ID=64805290

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710500878.5A Pending CN109122715A (zh) 2017-06-27 2017-06-27 过一硫酸氢钾复合杀菌剂

Country Status (1)

Country Link
CN (1) CN109122715A (zh)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109553144A (zh) * 2019-01-21 2019-04-02 德州绿能水处理科技有限公司 天然生物抑藻澄清剂
CN111202090A (zh) * 2020-02-17 2020-05-29 四川水王子环境科技有限公司 一种医院污水消毒粉及其制备方法和使用方法
CN111226982A (zh) * 2020-02-17 2020-06-05 四川水王子环境科技有限公司 一种污水消毒粉及其制备方法和使用方法
CN111675294A (zh) * 2020-06-05 2020-09-18 沈小燕 一种用于污水的可降解杀菌剂
CN114794091A (zh) * 2022-03-15 2022-07-29 北京可佳永好科贸有限公司 一种低温消毒粉剂及其制备方法和应用

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86104098A (zh) * 1986-11-11 1988-05-25 李世新 含氯消毒精
CN101528035A (zh) * 2005-12-16 2009-09-09 威廉·D·桑德森 固体生物杀灭组合物和密封生物杀灭制品
CN102017996A (zh) * 2009-09-11 2011-04-20 上海家化联合股份有限公司 下水管道养护剂
CN102265904A (zh) * 2011-06-03 2011-12-07 宋海鹏 复合过硫酸氢钾消毒剂及其制造工艺
JP2014047467A (ja) * 2012-08-29 2014-03-17 Nissan Chem Ind Ltd 井戸の洗浄方法及び井戸用洗浄剤組成物
CN104206413A (zh) * 2014-08-20 2014-12-17 张光荣 一种用于血液透析机清洗消毒的消毒液及其制备方法
CN104585232A (zh) * 2015-01-28 2015-05-06 威海百克环保工程有限公司 用于医院及养殖污水消毒的复合消毒粉剂
CN104719336A (zh) * 2015-02-02 2015-06-24 山东威高药业股份有限公司 一种低腐蚀性单过硫酸氢钾复合盐消毒剂
CN105217769A (zh) * 2014-06-10 2016-01-06 成都润兴消毒药业有限公司 能杀灭粪大肠菌群、降低cod的污水处理剂及制备方法
CN105394081A (zh) * 2015-12-30 2016-03-16 成都润兴消毒药业有限公司 一种单过硫酸氢钾复合盐消毒粉
CN106305715A (zh) * 2016-08-19 2017-01-11 鄄城康泰化工有限公司 一种二氯异氰尿酸钠消毒片及其制备方法
CN106342884A (zh) * 2016-08-29 2017-01-25 连云港永荣生物科技有限公司 一种生活饮用水消毒粉
CN106376595A (zh) * 2016-08-28 2017-02-08 连云港永荣生物科技有限公司 一种安全环保的污水消毒粉
CN106811336A (zh) * 2015-11-30 2017-06-09 常州西品科技有限公司 家用清洁剂

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86104098A (zh) * 1986-11-11 1988-05-25 李世新 含氯消毒精
CN101528035A (zh) * 2005-12-16 2009-09-09 威廉·D·桑德森 固体生物杀灭组合物和密封生物杀灭制品
CN102017996A (zh) * 2009-09-11 2011-04-20 上海家化联合股份有限公司 下水管道养护剂
CN102265904A (zh) * 2011-06-03 2011-12-07 宋海鹏 复合过硫酸氢钾消毒剂及其制造工艺
JP2014047467A (ja) * 2012-08-29 2014-03-17 Nissan Chem Ind Ltd 井戸の洗浄方法及び井戸用洗浄剤組成物
CN105217769A (zh) * 2014-06-10 2016-01-06 成都润兴消毒药业有限公司 能杀灭粪大肠菌群、降低cod的污水处理剂及制备方法
CN104206413A (zh) * 2014-08-20 2014-12-17 张光荣 一种用于血液透析机清洗消毒的消毒液及其制备方法
CN104585232A (zh) * 2015-01-28 2015-05-06 威海百克环保工程有限公司 用于医院及养殖污水消毒的复合消毒粉剂
CN104719336A (zh) * 2015-02-02 2015-06-24 山东威高药业股份有限公司 一种低腐蚀性单过硫酸氢钾复合盐消毒剂
CN106811336A (zh) * 2015-11-30 2017-06-09 常州西品科技有限公司 家用清洁剂
CN105394081A (zh) * 2015-12-30 2016-03-16 成都润兴消毒药业有限公司 一种单过硫酸氢钾复合盐消毒粉
CN106305715A (zh) * 2016-08-19 2017-01-11 鄄城康泰化工有限公司 一种二氯异氰尿酸钠消毒片及其制备方法
CN106376595A (zh) * 2016-08-28 2017-02-08 连云港永荣生物科技有限公司 一种安全环保的污水消毒粉
CN106342884A (zh) * 2016-08-29 2017-01-25 连云港永荣生物科技有限公司 一种生活饮用水消毒粉

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109553144A (zh) * 2019-01-21 2019-04-02 德州绿能水处理科技有限公司 天然生物抑藻澄清剂
CN111202090A (zh) * 2020-02-17 2020-05-29 四川水王子环境科技有限公司 一种医院污水消毒粉及其制备方法和使用方法
CN111226982A (zh) * 2020-02-17 2020-06-05 四川水王子环境科技有限公司 一种污水消毒粉及其制备方法和使用方法
CN111675294A (zh) * 2020-06-05 2020-09-18 沈小燕 一种用于污水的可降解杀菌剂
CN114794091A (zh) * 2022-03-15 2022-07-29 北京可佳永好科贸有限公司 一种低温消毒粉剂及其制备方法和应用

Similar Documents

Publication Publication Date Title
CN109122715A (zh) 过一硫酸氢钾复合杀菌剂
Borkow Using copper to fight microorganisms
CN105394081A (zh) 一种单过硫酸氢钾复合盐消毒粉
CA2829449A1 (en) A stable composition of hoci, processes for its production and uses thereof
CN108617650A (zh) 一种复合杀菌剂及其制备方法
CN107624785A (zh) 一种低腐蚀性单过硫酸氢钾复合盐消毒剂
WO2007070861A1 (en) Binary compositions and methods for sterilization
CN110235902A (zh) 活性氧消毒粉
CN103891727A (zh) 一种稳定的复方卤素有机消毒剂的制备方法
CN115176809A (zh) 包含次氯酸的抗微生物剂
Wu et al. Inactivation and subsequent reactivation of Aspergillus species by the combination of UV and monochloramine: Comparisons with UV/chlorine
KR101297712B1 (ko) 차아염소산수에 대두 단백질을 포함하는 살균 소독제
CN110012904A (zh) 一种三氯异氰尿酸泡腾消毒片及其制备方法
CN107920532A (zh) 具有抗内生孢子功效的抗微生物组合物
CN101006782A (zh) 一种稳定型高电位含氯消毒液的制备方法
CN1190533A (zh) 杀植物病原微生物组合物,其制备方法及应用
KR20140065566A (ko) 미산성 차아염소산수를 함유하는 식물병 방제용 조성물 및 이를 이용한 식물병 방제 방법
CN106689194A (zh) 一种缓释消毒水
CN103125510A (zh) 复方邻苯二甲醛聚季铵盐阳离子表面活性剂消毒剂及其制备与应用
RU2438991C2 (ru) Состав и способ обеззараживания и обезвреживания воды
JP2004002229A (ja) 殺菌方法
CN106857669A (zh) 含有苹果酸的家庭用消毒片
Yildiz et al. Stabilised hypochlorous acid: a new therapeutic strategy against dangerous parasitic eye infection agent Acanthamoeba spp
CN106689198A (zh) 一种复方过氧化氢消毒剂及其制备方法和应用
CN106212468B (zh) 一种含苯并烯氟菌唑和几丁聚糖的杀菌组合物

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20190104

RJ01 Rejection of invention patent application after publication