CN109111993B - Preparation method of wild jujube effective component for cigarettes and application of wild jujube effective component in cigarettes - Google Patents
Preparation method of wild jujube effective component for cigarettes and application of wild jujube effective component in cigarettes Download PDFInfo
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- CN109111993B CN109111993B CN201811175192.4A CN201811175192A CN109111993B CN 109111993 B CN109111993 B CN 109111993B CN 201811175192 A CN201811175192 A CN 201811175192A CN 109111993 B CN109111993 B CN 109111993B
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- 240000008866 Ziziphus nummularia Species 0.000 title claims abstract description 146
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 107
- 238000002360 preparation method Methods 0.000 title abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000000284 extract Substances 0.000 claims abstract description 26
- 238000000926 separation method Methods 0.000 claims abstract description 23
- 238000000605 extraction Methods 0.000 claims abstract description 21
- 150000004676 glycans Chemical class 0.000 claims abstract description 17
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 17
- 239000005017 polysaccharide Substances 0.000 claims abstract description 17
- 238000001556 precipitation Methods 0.000 claims abstract description 17
- 238000000199 molecular distillation Methods 0.000 claims abstract description 13
- 238000001914 filtration Methods 0.000 claims description 18
- 239000004480 active ingredient Substances 0.000 claims description 13
- 238000004821 distillation Methods 0.000 claims description 12
- 239000008399 tap water Substances 0.000 claims description 12
- 235000020679 tap water Nutrition 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 9
- 241000208125 Nicotiana Species 0.000 claims description 7
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 7
- 239000000706 filtrate Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 238000010992 reflux Methods 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 5
- 238000007865 diluting Methods 0.000 claims description 3
- 238000011049 filling Methods 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 238000004090 dissolution Methods 0.000 claims description 2
- 239000000779 smoke Substances 0.000 abstract description 18
- 230000000694 effects Effects 0.000 abstract description 17
- 238000005516 engineering process Methods 0.000 abstract description 9
- 238000013329 compounding Methods 0.000 abstract description 4
- 238000000194 supercritical-fluid extraction Methods 0.000 abstract description 4
- 238000003809 water extraction Methods 0.000 abstract description 2
- 230000035943 smell Effects 0.000 description 19
- 235000013399 edible fruits Nutrition 0.000 description 17
- 235000009508 confectionery Nutrition 0.000 description 11
- 230000008859 change Effects 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 7
- 230000001953 sensory effect Effects 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- MMKRHZKQPFCLLS-UHFFFAOYSA-N ethyl myristate Chemical compound CCCCCCCCCCCCCC(=O)OCC MMKRHZKQPFCLLS-UHFFFAOYSA-N 0.000 description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 6
- 238000000638 solvent extraction Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 206010013911 Dysgeusia Diseases 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 5
- 230000007794 irritation Effects 0.000 description 4
- 239000005639 Lauric acid Substances 0.000 description 3
- 235000021314 Palmitic acid Nutrition 0.000 description 3
- 230000003749 cleanliness Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- FMMOOAYVCKXGMF-MURFETPASA-N ethyl linoleate Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(=O)OCC FMMOOAYVCKXGMF-MURFETPASA-N 0.000 description 3
- FMMOOAYVCKXGMF-UHFFFAOYSA-N linoleic acid ethyl ester Natural products CCCCCC=CCC=CCCCCCCCC(=O)OCC FMMOOAYVCKXGMF-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 229940031016 ethyl linoleate Drugs 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 241000219100 Rhamnaceae Species 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
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- 238000013461 design Methods 0.000 description 1
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- 235000013599 spices Nutrition 0.000 description 1
- 229940098465 tincture Drugs 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/02—Recovery or refining of essential oils from raw materials
- C11B9/025—Recovery by solvent extraction
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B3/00—Preparing tobacco in the factory
- A24B3/12—Steaming, curing, or flavouring tobacco
Abstract
The invention provides a preparation method of a wild jujube significant component for cigarettes and application of the wild jujube significant component in cigarettes. The preparation of the wild jujube effective component comprises the following steps: (1) supercritical CO2 extraction; (2) extracting fragrant components of wild jujube by molecular distillation; (3) extracting wild jujube polysaccharide by water extraction and sectional alcohol precipitation; (4) compounding fragrant components of wild jujube with polysaccharide; the cigarette wild jujube effective component for cigarette with the cigarette application effect superior to the traditional wild jujube extract is developed by adopting the modes of gradual separation, sectional enrichment and proportional combination and combining the supercritical extraction, molecular distillation and sectional alcohol precipitation technologies to extract, separate and combine the cigarette effective components such as aroma components and polysaccharide in the wild jujube, so that the cigarette wild jujube effective component for cigarette with the cigarette application effect superior to the traditional wild jujube extract is developed, and the cigarette wild jujube effective component has the effects of improving cigarette aroma quality, enriching cigarette aroma, obvious style characteristics, fine and soft smoke and good elegant sense in cigarette.
Description
Technical Field
The invention relates to preparation of a cigarette flavor, in particular to a preparation method of a wild jujube effective component for cigarettes and application of the wild jujube effective component in cigarettes.
Background
The wild jujube is mature fruit of wild jujube of arbor of Rhamnaceae, and spices such as wild jujube tincture and wild jujube extract prepared from the wild jujube have the effects of endowing cigarette with characteristic sour aroma, reducing cigarette irritation and the like in cigarettes, and have an important effect on improving the quality of the cigarettes.
At present, the wild jujube extract is developed by adopting a traditional solvent extraction mode, and has a plurality of defects: firstly, an extraction technology: the perfume extraction solvent is single, alcohol extraction or water extraction is usually adopted, and various components in the perfume are extracted simultaneously, so that the functions and effects of various components which cannot be functional can not be fully exerted; second, separation techniques: the separation of different components is a key technology for obtaining high-efficiency components, but the separation of chemical components with different properties needs to be started from selective extraction, and then target components can be selectively separated through technologies such as a chromatography technology, an adsorption technology, a centrifugation technology and the like; thirdly, function identification: different components in the wild jujube extract have interaction such as synergy and inhibition, and the target product can be gradually found out only by stage separation or group separation method for function evaluation.
Disclosure of Invention
The invention provides a preparation method of cigarette wild jujube effective components and application thereof in cigarettes according to the defects of the prior art, the method adopts the modes of gradual separation, sectional enrichment and proportional compounding, combines the technologies of supercritical extraction, molecular distillation and sectional alcohol precipitation, extracts and separates cigarette effective components such as aroma components and polysaccharide in wild jujube, and develops functional wild jujube effective components by combining sensory evaluation of cigarettes, thereby realizing the fine development and comprehensive utilization of wild jujube.
The technical scheme provided by the invention is as follows: the preparation method of the wild jujube effective component for the cigarettes is characterized by comprising the following steps:
(1) taking wild jujube and carrying out supercritical CO2Extracting to obtain fructus Ziziphi Spinosae supercritical extract at 56-60 deg.C under 30-40Mpa, separating kettle I under 10-12Mpa, separating kettle I under 45-50 deg.C under 4-6Mpa, and separating kettle II under 20-25 deg.C;
(2) performing molecular distillation on the wild jujube supercritical extract obtained in the step (1), wherein the distillation temperature is 40-60 ℃, the distillation pressure is controlled at 200-400 Pa, the feeding speed is 1-2 mL/min, the scraper rotation speed is 150-300 r/min, and collecting molecular distillation light components, namely wild jujube light components;
(3) subjecting the wild jujube in the step (1) to supercritical CO2Adding tap water into the extracted residues according to the material ratio of 1: 4-1: 8, heating, refluxing and extracting for 3-5 hours, cooling after extraction, filtering, and concentrating until the relative density is 1.15;
(4) adding 95% ethanol into the concentrated solution obtained in the step (3) according to the mass ratio of 1: 2-1: 4 for precipitation, filtering, adding the filtered solid into tap water for dissolution, adjusting the density to 1.15, adding 50% ethanol according to the mass ratio of 1: 2-1: 4 for secondary precipitation, filtering, and concentrating the filtrate to the relative density of 1.20 to obtain wild jujube polysaccharide;
(5) and (3) uniformly mixing the wild jujube light component in the step (2) and the wild jujube polysaccharide in the step (3) according to a mass ratio of 1: 10-1: 20 to obtain the wild jujube effective component.
The invention provides an application of wild jujube effective components for cigarettes in cigarettes, which comprises the following steps: diluting the wild jujube active ingredient prepared by the method with 70% ethanol solution, spraying onto tobacco shreds, wherein the addition amount of the wild jujube active ingredient is 80-120 ppm, filling the sprayed tobacco shreds into a sealing bag, sealing, balancing in an oven at 60 ℃ for 30min, taking out, cooling, balancing in a constant temperature and humidity cabinet at 25 ℃ for 24 h, and taking out to prepare cigarettes.
The aroma texture of the cigarettes is improved, the richness is improved, the style characteristic change is obvious, and the aftertaste is clean; the wild jujube effective component can endow the cigarette with characteristic smells such as fruit aroma, sweet aroma, baking aroma and the like; the wild jujube effective component obviously increases the sweet smell, baking smell and fruit smell in the smoke when the cigarette is burnt.
Compared with the wild jujube extract prepared by traditional solvent extraction, the wild jujube active ingredient prepared by the invention has the advantages that the characteristic aroma substances such as lauric acid, palmitic acid and the like forming the characteristic acid aroma of the cigarette in the wild jujube active ingredient are obviously increased, and the macromolecular esters such as myristic acid ethyl ester, linoleic acid ethyl ester and the like which bring irritation to the cigarette are obviously reduced. When the wild jujube active component is applied to cigarettes, the aroma and texture of the cigarettes are improved, and the richness, style characteristics and remaining taste cleanliness of the wild jujube active component are superior to those of a wild jujube extract; the characteristic smells such as fruit aroma, sweet aroma, baking aroma and the like of the cigarette are more obvious; so that the sweet aroma, baking aroma and fruit aroma in the smoke are increased more obviously when the cigarette is burnt. The wild jujube active ingredient is applied to cigarettes, the optimal dosage is 80ppm, and the cigarette application effects of improved aroma texture, good richness, obvious style characteristic change, fine and soft smoke and good elegant feeling are achieved under the addition amount.
The invention has the beneficial effects that: the cigarette effective components such as aroma components and polysaccharide in the wild jujube are extracted and separated by adopting a mode of gradual separation, sectional enrichment and proportional compounding and combining supercritical extraction, molecular distillation and sectional alcohol precipitation technologies, and the functional wild jujube effective components are developed by combining sensory evaluation of cigarettes.
Drawings
FIG. 1 is a chart comparing sensory quality of cigarettes with wild jujube extract extracted by solvent and wild jujube effective component in the examples;
FIG. 2 is a chart comparing the odor and flavor of cigarettes with the effective components of wild jujube extracted by solvent and the effective components of wild jujube in the examples;
FIG. 3 is a chart comparing the smoke style of cigarettes with the solvent-extracted wild jujube extract and the wild jujube significant component in the examples.
Detailed Description
The technical problems associated with the present invention will be described in further detail with reference to examples.
Embodiment 1, a preparation method of a wild jujube effective component for cigarettes is characterized by comprising the following steps:
(1) taking a certain amount of wild jujube, and performing supercritical CO2Extracting at 56 deg.C under 30MPa, 10MPa in separation kettle I under 45 deg.C and 4MPa in separation kettle II under 20 deg.C;
(2) performing molecular distillation on the wild jujube supercritical extract obtained in the step (1), wherein the distillation temperature is 40 ℃, the distillation pressure is controlled at 200Pa, the feeding speed is 1mL/min, and the scraper blade rotating speed is 150r/min, so as to obtain a wild jujube light component;
(3) subjecting the wild jujube obtained in the step (1) to supercritical CO2Extracting the extracted residue under reflux, wherein the extraction solvent is tap water, the material ratio is 1:4, the extraction time is 3 hours, the heating temperature is 100 ℃, cooling after extraction, filtering, concentrating to the relative density of 1.15, adding 95% ethanol with the mass ratio of 1:2 for precipitation, filtering, taking the filtered solid, adding the tap water for dissolving, adjusting the density to 1.15, adding 50% ethanol with the mass ratio of 1:2 for precipitation, filtering, concentrating the filtrate to the relative density of 1.20, and obtaining the wild jujube polysaccharide;
(4) and (3) uniformly mixing the wild jujube light component obtained in the step (2) and the wild jujube polysaccharide obtained in the step (3) according to the mass ratio of 1:10 to obtain a wild jujube effective component A.
The wild jujube significant component A prepared in the embodiment 1 is applied to cigarettes, so that the aroma and texture of the cigarettes are improved, the richness is improved, the style characteristic change is obvious, and the aftertaste is clean; the wild jujube effective component can endow the cigarette with characteristic smells such as fruit aroma, sweet aroma, baking aroma and the like; the wild jujube effective component obviously increases the sweet smell, baking smell and fruit smell in the smoke when the cigarette is burnt; the best dosage of the wild jujube effective component in the cigarette is 120ppm, and the cigarette has the application effects of improving aroma texture, improving richness, obviously changing style characteristics, and being fine and soft in smoke and good in elegant feeling under the condition of the addition amount.
Embodiment 2, a preparation method of a wild jujube effective component for cigarettes is characterized by comprising the following steps:
(1) taking a certain amount of wild jujube, and performing supercritical CO2Extracting at 56 deg.C under 40MPa, 12MPa in separation kettle I under 45 deg.C, 6MPa in separation kettle II under 25 deg.C;
(2) performing molecular distillation on the wild jujube supercritical extract obtained in the step (1), wherein the distillation temperature is 40 ℃, the distillation pressure is controlled at 400Pa, the feeding speed is 2mL/min, and the scraper rotating speed is 150r/min, so as to obtain a wild jujube light component;
(3) subjecting the wild jujube obtained in the step (1) to supercritical CO2Extracting the extracted residues under reflux, wherein an extraction solvent is tap water, the material ratio is 1:6, the extraction time is 4 hours, cooling after extraction, filtering, concentrating until the relative density is 1.15, adding 95% ethanol with the mass ratio of 1:3 for precipitation, filtering, adding tap water into the filtered solid for dissolving, adjusting the density to 1.15, adding 50% ethanol with the mass ratio of 1:3 for precipitation, filtering, and concentrating the filtrate until the relative density is 1.20 to obtain the wild jujube polysaccharide;
(4) and (3) uniformly mixing the wild jujube light component in the step (2) and the wild jujube polysaccharide in the step (3) according to the mass ratio of 1:15 to obtain a wild jujube effective component B.
The wild jujube significant component B prepared in the embodiment 2 is applied to cigarettes, so that the aroma and texture of the cigarettes are improved, the richness is improved, the style characteristic change is obvious, and the aftertaste is clean; the wild jujube effective component can endow the cigarette with characteristic smells such as fruit aroma, sweet aroma, baking aroma and the like; the wild jujube effective component obviously increases the sweet smell, baking smell and fruit smell in the smoke when the cigarette is burnt; the best dosage of the wild jujube effective component in the cigarette is 120ppm, and the cigarette has the application effects of improving aroma texture, improving richness, obviously changing style characteristics, and being fine and soft in smoke and good in elegant feeling under the condition of the addition amount.
Embodiment 3, a preparation method of a wild jujube effective component for cigarettes is characterized by comprising the following steps:
(1) taking a certain amount of wild jujube, and performing supercritical CO2Extracting at 58 deg.C under 35MPa, 11MPa in separation kettle I, 48 deg.C in separation kettle I, 5MPa in separation kettle II, and 28 deg.C in separation kettle II;
(2) performing molecular distillation on the wild jujube supercritical extract obtained in the step (1), wherein the distillation temperature is 50 ℃, the distillation pressure is controlled at 300Pa, the feeding speed is 1.5mL/min, and the scraper rotating speed is 200r/min, so as to obtain a wild jujube light component;
(3) subjecting the wild jujube obtained in the step (1) to supercritical CO2Heating and refluxing the extracted residues, wherein the extraction solvent is tap water, and the material ratio is 1:6, extracting for 4 hours, cooling after extraction, filtering, concentrating to a relative density of 1.15, adding 95% ethanol with a mass ratio of 1:4 for precipitation, filtering, taking the filtered solid, adding tap water for dissolving, adjusting the density to 1.15, adding 50% ethanol with a mass ratio of 1:4 for precipitation, filtering, concentrating the filtrate to a relative density of 1.20, and obtaining the wild jujube polysaccharide;
(4) and (3) uniformly mixing the wild jujube light component in the step (2) and the wild jujube polysaccharide in the step (3) according to the mass ratio of 1:15 to obtain a wild jujube effective component C.
The wild jujube significant component C prepared in the embodiment 3 is applied to cigarettes, so that the aroma texture of the cigarettes is improved, the richness is improved, the style characteristic change is obvious, and the aftertaste is clean; the wild jujube effective component can endow the cigarette with characteristic smells such as fruit aroma, sweet aroma, baking aroma and the like; the wild jujube effective component obviously increases the sweet smell, baking smell and fruit smell in the smoke when the cigarette is burnt; the best dosage of the wild jujube effective component in the cigarette is 100ppm, and the cigarette has the application effects of improving aroma texture, improving richness, obviously changing style characteristics, and being fine and soft in smoke and good in elegant feeling under the condition of the addition amount.
Embodiment 4, a preparation method of a wild jujube effective component for cigarettes is characterized by comprising the following steps:
(1) taking a certain amount of wild jujube, and performing supercritical CO2Extracting at 60 deg.C under 40MPa, 12MPa in separation kettle I under 50 deg.C, 6MPa in separation kettle II under 25 deg.C;
(2) performing molecular distillation on the wild jujube supercritical extract obtained in the step (1), wherein the distillation temperature is 60 ℃, the distillation pressure is controlled at 400Pa, the feeding speed is 2mL/min, and the scraper rotating speed is 300r/min, so as to obtain a wild jujube light component;
(3) subjecting the wild jujube obtained in the step (1) to supercritical CO2Heating and refluxing the extracted residues for extraction, wherein the extraction solvent is tap water, the material ratio is 1:8, the extraction time is 5 hours, cooling after extraction, filtering, concentrating until the relative density is 1.15, adding 95% ethanol with the mass ratio of 1:4 for precipitation, filtering, dissolving the filtered solid in the tap water, adjusting the density to 1.15, adding 50% ethanol with the mass ratio of 1:4 for precipitation, filtering, and concentrating the filtrate until the relative density is 1.20 to obtain the wild jujube polysaccharide;
(4) and (3) uniformly mixing the wild jujube light component in the step (2) and the wild jujube polysaccharide in the step (3) according to the mass ratio of 1:20 to obtain a wild jujube effective component D.
The wild jujube significant component D prepared in the embodiment 4 is applied to cigarettes, so that the aroma and the texture of the cigarettes are improved, the richness is improved, the style characteristic change is obvious, and the aftertaste is clean; the wild jujube effective component can endow the cigarette with characteristic smells such as fruit aroma, sweet aroma, baking aroma and the like; the wild jujube effective component obviously increases the sweet smell, baking smell and fruit smell in the smoke when the cigarette is burnt; the best dosage of the wild jujube effective component in the cigarette is 80ppm, and the cigarette has the application effects of improving aroma texture, improving richness, obviously changing style characteristics, and being fine and soft in smoke and good in elegant feeling under the condition of the addition amount.
The aroma components of the wild jujube effective component for the cigarette prepared by the invention are analyzed and compared with the aroma components of the traditional wild jujube extract (solvent extraction), and the aroma component ratio is shown in table 1:
TABLE 1 comparison analysis of aroma components of wild jujube extract and wild jujube active ingredient
As can be seen from table 1, compared with the wild jujube extract prepared by traditional solvent extraction, the characteristic aroma substances such as lauric acid and palmitic acid in the wild jujube active ingredient are obviously increased, and the aroma substances can be well coordinated with cigarettes and can raise the characteristic sour note of cigarettes. Macromolecular esters such as ethyl myristate and ethyl linoleate are obviously reduced, and the substances are prevented from causing irritation to cigarettes.
Diluting the wild jujube active ingredient for the cigarette and the traditional wild jujube extract (solvent extraction) with 70% ethanol solution respectively, spraying the diluted wild jujube active ingredient and the traditional wild jujube extract onto tobacco shreds with the addition of 100ppm, filling the sprayed tobacco shreds into a sealed bag, sealing, balancing in an oven at 60 ℃ for 30min, taking out, cooling, balancing in a constant temperature and humidity cabinet at 25 ℃ for 24 hours, and taking out to prepare the cigarette. The cigarette quality, the cigarette smell and style are shown in figure 1, the cigarette smoke style and the style are shown in figure 2 and figure 3 respectively, and the application effects of the wild jujube extract and the wild jujube effective component in the cigarette are compared and analyzed, and the results show that (shown in figures 1, 2 and 3), the wild jujube effective component is superior to the wild jujube extract in cigarette aroma texture improvement, richness, style characteristics and residual taste cleanliness; the characteristic smells such as fruit aroma, sweet aroma, baking aroma and the like of the cigarette are more obvious; so that the sweet aroma, baking aroma and fruit aroma in the smoke are increased more obviously when the cigarette is burnt.
The wild jujube effective component for the cigarette prepared by the invention is sprayed on tobacco shreds according to different addition amounts to prepare cigarettes, and sensory evaluation is carried out on the cigarettes, wherein the sensory evaluation effects of the different addition amounts are shown in table 2:
TABLE 2 influence of the effective components of wild jujube in different addition amounts on the sensory evaluation effect of cigarette
The sensory evaluation effect of the wild jujube effective component on the cigarettes with different addition amounts is researched, and the result shows that (as shown in table 2) the optimal use amount of the wild jujube effective component in the cigarettes is 80ppm, and the cigarette application effects of improved aroma texture, better richness, obvious style characteristic change, exquisite and soft smoke and good elegant feeling are achieved under the addition amount.
The method adopts the modes of gradual separation, sectional enrichment and proportional compounding, and combines the supercritical extraction, molecular distillation and sectional alcohol precipitation technologies to prepare the wild jujube effective component. Compared with the wild jujube extract prepared by traditional solvent extraction, the wild jujube active ingredient has the advantages that characteristic aroma substances such as lauric acid, palmitic acid and the like forming the characteristic acid aroma of the cigarette are obviously increased, and macromolecular esters such as ethyl myristate and ethyl linoleate which bring irritation to the cigarette are obviously reduced. When the wild jujube active component is applied to cigarettes, the aroma and texture of the cigarettes are improved, and the richness, style characteristics and remaining taste cleanliness of the wild jujube active component are superior to those of a wild jujube extract; the characteristic smells such as fruit aroma, sweet aroma, baking aroma and the like of the cigarette are more obvious; so that the sweet aroma, baking aroma and fruit aroma in the smoke are increased more obviously when the cigarette is burnt. The wild jujube active ingredient is applied to cigarettes, the optimal dosage is 80ppm, and the cigarette application effects of improved aroma texture, good richness, obvious style characteristic change, fine and soft smoke and good elegant feeling are achieved under the addition amount.
The above description is only a detailed description of specific embodiments of the present invention, and should not be taken as limiting the invention, and any modifications, equivalents, improvements, etc. made on the design concept of the present invention should be included in the protection scope of the present invention.
Claims (1)
1. The application of the wild jujube effective component for cigarettes in cigarettes is characterized by comprising the following steps:
(1) taking wild jujube and carrying out supercritical CO2Extracting to obtain fructus Ziziphi Spinosae supercritical extractThe extraction temperature is 56-60 ℃, the extraction pressure is 30-40Mpa, the pressure of a separation kettle I is 10-12Mpa, the temperature of the separation kettle I is 45-50 ℃, the pressure of a separation kettle II is 4-6Mpa, and the temperature of the separation kettle II is 20-25 ℃;
(2) performing molecular distillation on the wild jujube supercritical extract obtained in the step (1), wherein the distillation temperature is 40-50 ℃, the distillation pressure is controlled at 200-400 Pa, the feeding speed is 1-2 mL/min, the scraper rotation speed is 150-300 r/min, and collecting molecular distillation light components, namely wild jujube light components;
(3) subjecting the wild jujube in the step (1) to supercritical CO2Adding tap water into the extracted residues according to the material ratio of 1: 4-1: 8, heating, refluxing and extracting for 3-5 hours, cooling after extraction, filtering, and concentrating until the relative density is 1.15;
(4) adding 95% ethanol into the concentrated solution obtained in the step (3) according to the mass ratio of 1: 2-1: 4 for precipitation, filtering, adding the filtered solid into tap water for dissolution, adjusting the density to 1.15, adding 50% ethanol according to the mass ratio of 1: 2-1: 4 for secondary precipitation, filtering, and concentrating the filtrate to the relative density of 1.20 to obtain wild jujube polysaccharide;
(5) uniformly mixing the wild jujube light component in the step (2) and the wild jujube polysaccharide in the step (4) according to a mass ratio of 1: 10-1: 20 to obtain a wild jujube effective component;
(6) and (3) diluting the wild jujube active ingredient prepared in the step (5) with 70% ethanol solution, spraying onto tobacco shreds, wherein the addition amount of the wild jujube active ingredient is 80ppm, filling the sprayed tobacco shreds into a sealing bag, sealing, balancing in an oven at 60 ℃ for 30min, taking out, cooling, balancing in a constant temperature and humidity cabinet at 25 ℃ for 24 hours, and taking out to prepare the cigarette.
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| CN113907393B (en) * | 2021-09-28 | 2023-09-12 | 深圳市真味生物科技有限公司 | Method for preparing tobacco-flavor electronic atomized liquid through wet grinding |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101942361A (en) * | 2010-09-28 | 2011-01-12 | 河南省新郑金叶香料有限公司 | Jujube flavor base, and preparation method and application thereof |
| CN103146483A (en) * | 2013-03-21 | 2013-06-12 | 红云红河烟草(集团)有限责任公司 | Pelargonium roseum extract and application of extract in cigarette |
| CN103965370A (en) * | 2014-05-20 | 2014-08-06 | 河南中烟工业有限责任公司 | Method for extracting and purifying Chinese date polysaccharide and application of Chinese date polysaccharide serving as tobacco humectant |
| CN104939306A (en) * | 2015-07-03 | 2015-09-30 | 广西中烟工业有限责任公司 | New method for obtaining red date extractive and application in cigarettes |
| CN105176680A (en) * | 2015-08-26 | 2015-12-23 | 谢晓亮 | Ziziphus jujube fragrant water and preparation method thereof |
| CN107541342A (en) * | 2017-10-24 | 2018-01-05 | 江西中烟工业有限责任公司 | A kind of preparation method and applications of tobacco aromaticss |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150030706A1 (en) * | 2012-03-13 | 2015-01-29 | Consejo Superior De Investigaciones Cientificas (Csic) | Use of essential oils, supercritical extracts and aqueous residues generated during a process for obtaining organic extracts from the artemisia absinthium l. plant |
-
2018
- 2018-10-10 CN CN201811175192.4A patent/CN109111993B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101942361A (en) * | 2010-09-28 | 2011-01-12 | 河南省新郑金叶香料有限公司 | Jujube flavor base, and preparation method and application thereof |
| CN103146483A (en) * | 2013-03-21 | 2013-06-12 | 红云红河烟草(集团)有限责任公司 | Pelargonium roseum extract and application of extract in cigarette |
| CN103965370A (en) * | 2014-05-20 | 2014-08-06 | 河南中烟工业有限责任公司 | Method for extracting and purifying Chinese date polysaccharide and application of Chinese date polysaccharide serving as tobacco humectant |
| CN104939306A (en) * | 2015-07-03 | 2015-09-30 | 广西中烟工业有限责任公司 | New method for obtaining red date extractive and application in cigarettes |
| CN105176680A (en) * | 2015-08-26 | 2015-12-23 | 谢晓亮 | Ziziphus jujube fragrant water and preparation method thereof |
| CN107541342A (en) * | 2017-10-24 | 2018-01-05 | 江西中烟工业有限责任公司 | A kind of preparation method and applications of tobacco aromaticss |
Non-Patent Citations (1)
| Title |
|---|
| 酸枣浸膏挥发性成分分析及在卷烟加香中的应用;寇天舒等;《湖北农业科学》;20160831;第55卷(第16期);第4265-4268,4279页 * |
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