CN109111993A - A kind of preparation method of the effective component of cigarette wild jujube and its application in cigarette - Google Patents
A kind of preparation method of the effective component of cigarette wild jujube and its application in cigarette Download PDFInfo
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- CN109111993A CN109111993A CN201811175192.4A CN201811175192A CN109111993A CN 109111993 A CN109111993 A CN 109111993A CN 201811175192 A CN201811175192 A CN 201811175192A CN 109111993 A CN109111993 A CN 109111993A
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- wild jujube
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- effective component
- jujube
- component
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- 240000008866 Ziziphus nummularia Species 0.000 title claims abstract description 122
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 103
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000000284 extract Substances 0.000 claims abstract description 38
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000000926 separation method Methods 0.000 claims abstract description 20
- 150000004676 glycans Chemical class 0.000 claims abstract description 17
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 17
- 239000005017 polysaccharide Substances 0.000 claims abstract description 17
- 238000000199 molecular distillation Methods 0.000 claims abstract description 13
- 238000001556 precipitation Methods 0.000 claims abstract description 7
- 238000000605 extraction Methods 0.000 claims description 35
- 238000001914 filtration Methods 0.000 claims description 16
- 241000208125 Nicotiana Species 0.000 claims description 10
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 10
- 239000000654 additive Substances 0.000 claims description 10
- 230000000996 additive effect Effects 0.000 claims description 10
- 239000008399 tap water Substances 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 9
- 235000019441 ethanol Nutrition 0.000 claims description 9
- 238000012869 ethanol precipitation Methods 0.000 claims description 9
- 235000020679 tap water Nutrition 0.000 claims description 9
- 238000004090 dissolution Methods 0.000 claims description 6
- 238000004821 distillation Methods 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 238000010992 reflux Methods 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 239000012141 concentrate Substances 0.000 claims description 2
- 241001247821 Ziziphus Species 0.000 abstract description 19
- 239000002304 perfume Substances 0.000 abstract description 19
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 17
- 230000000694 effects Effects 0.000 abstract description 17
- 239000003546 flue gas Substances 0.000 abstract description 17
- 239000000796 flavoring agent Substances 0.000 abstract description 8
- 235000019634 flavors Nutrition 0.000 abstract description 8
- 238000005516 engineering process Methods 0.000 abstract description 7
- 230000011218 segmentation Effects 0.000 abstract description 7
- 238000013329 compounding Methods 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 230000001737 promoting effect Effects 0.000 abstract description 2
- 235000009508 confectionery Nutrition 0.000 description 16
- 239000003205 fragrance Substances 0.000 description 15
- 235000013599 spices Nutrition 0.000 description 13
- 239000002904 solvent Substances 0.000 description 10
- 230000001953 sensory effect Effects 0.000 description 7
- 230000035943 smell Effects 0.000 description 7
- MMKRHZKQPFCLLS-UHFFFAOYSA-N ethyl myristate Chemical compound CCCCCCCCCCCCCC(=O)OCC MMKRHZKQPFCLLS-UHFFFAOYSA-N 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 230000007794 irritation Effects 0.000 description 4
- 241001062472 Stokellia anisodon Species 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- FMMOOAYVCKXGMF-MURFETPASA-N ethyl linoleate Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(=O)OCC FMMOOAYVCKXGMF-MURFETPASA-N 0.000 description 3
- 229940031016 ethyl linoleate Drugs 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 3
- FMMOOAYVCKXGMF-UHFFFAOYSA-N linoleic acid ethyl ester Natural products CCCCCC=CCC=CCCCCCCCC(=O)OCC FMMOOAYVCKXGMF-UHFFFAOYSA-N 0.000 description 3
- 230000033764 rhythmic process Effects 0.000 description 3
- 238000000638 solvent extraction Methods 0.000 description 3
- 239000005639 Lauric acid Substances 0.000 description 2
- 238000010835 comparative analysis Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 244000147568 Laurus nobilis Species 0.000 description 1
- 235000017858 Laurus nobilis Nutrition 0.000 description 1
- 241000219100 Rhamnaceae Species 0.000 description 1
- 235000005212 Terminalia tomentosa Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012675 alcoholic extract Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 210000000697 sensory organ Anatomy 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229940098465 tincture Drugs 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/02—Recovery or refining of essential oils from raw materials
- C11B9/025—Recovery by solvent extraction
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B3/00—Preparing tobacco in the factory
- A24B3/12—Steaming, curing, or flavouring tobacco
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Seasonings (AREA)
- Manufacture Of Tobacco Products (AREA)
Abstract
The present invention provides a kind of preparation method of effective component of cigarette wild jujube and its applications in cigarette.The preparation of the effective component of wild jujube includes the following steps: (1) SCF-CO 2；(2) wild jujube aroma component is extracted in molecular distillation；(3) water mentions segmentation alcohol precipitation and extracts wild jujube polysaccharide；(4) wild jujube aroma component is compounded with polysaccharide；The present invention is by the way of gradually separation, segmentation enrichment and ratio compounding, in conjunction with supercritical extract, molecular distillation, segmentation alcohol precipitation technology, separation and compounding are extracted to effective components of cigarette such as aroma component, polysaccharide in wild jujube, realize the fining exploitation and comprehensive utilization of wild jujube, develop the effective component of cigarette wild jujube that a kind of cigarette application effect is better than traditional zizyphus jujube extract, which has the effect of promoting cigarette flavor matter in cigarette, rich cigarette perfume, style and features are obvious, flue gas is fine and smooth soft and elegant sense well.
Description
Technical field
The present invention relates to the preparation method of the preparation of tobacco aromaticss, in particular to a kind of effective component of cigarette wild jujube and its
Application in cigarette.
Background technique
Wild jujube is Rhamnaceae arbor wild jujube ripening fruits, is being rolled up with fragrance such as the wild jujube tincture of wild jujube preparation, zizyphus jujube extracts
Have the effects that assign cigarette feature sour in cigarette, reduce cigarette irritation, is played an important role for promoting cigarette quality.
Currently, the exploitation of zizyphus jujube extract still uses the traditional approach of solvent extraction, there are many deficiencies: first, extraction
Technology: fragrance extractant is single, generallys use alcoholic extract or water extraction, and various components extract simultaneously in fragrance, cannot
Give full play to the various functions and effect for being unable to functional component；Second, isolation technics: the separation of heterogeneity is to obtain efficiently
The key technology of component, however chemical component of different nature separation is needed since selective extraction, then passes through chromatography skill
The technologies such as art, adsorption technology, centrifugation could Selective Separation target components；Third, function identify: different groups in zizyphus jujube extract
Divide and need to separate step by step in the presence of interaction, functional evaluation such as collaboration, inhibition, or is grouped separation method could gradually find out mesh
Mark product.
Summary of the invention
A kind of present invention insufficient preparation method that the effective component of cigarette wild jujube is provided and its in cigarette according to prior art
In application, this method using gradually separation, segmentation enrichment and ratio compounding by the way of, in conjunction with supercritical extract, molecular distillation,
It is segmented alcohol precipitation technology, separation is extracted to effective components of cigarette such as aroma component, polysaccharide in wild jujube, is commented in conjunction with cigarette sense organ
Valence develops the effective component of functional wild jujube, to realize the fining exploitation and comprehensive utilization of wild jujube.
A kind of technical solution provided by the invention: preparation method of the effective component of cigarette wild jujube, it is characterised in that packet
Include following steps:
(1) wild jujube is taken to carry out supercritical CO2Wild jujube supercritical extract is obtained by extraction, 56-60 DEG C of extraction temperature, extracts
Pressure power 30-40Mpa, separation reactor I pressure 10-12Mpa, 45-50 DEG C of separation reactor I temperature, II pressure 4-6Mpa of separating still, separation
20-25 DEG C of II temperature of kettle；
(2) the wild jujube supercritical extract of step (1) is subjected to molecular distillation, 40~60 DEG C of vapo(u)rizing temperature, distillation is pressed
Power control collects light group of molecular distillation in 200~400Pa, 1~2mL/min of charging rate, scraper plate 150~300r/min of revolving speed
Divide i.e. wild jujube light component；
(3) by wild jujube supercritical CO in step (1)2Residue extracted is added according to the ratio of material ratio 1:4~1:8
Tap water heating refluxing extraction 3~5 hours, cooling after extraction, filtering, being concentrated into relative density is 1.15；
(4) 95% ethyl alcohol of concentration will be added according to the ratio that mass ratio is 1:2~1:4 in the concentrate in step (3) to sink
It forms sediment, filtering takes filtered solid that tap water dissolution is added, and adjusts density to 1.15,1:2~1:4 is added according still further to mass ratio
50% ethyl alcohol secondary precipitation of concentration, filtering, filtrate is concentrated into relative density 1.20, obtains wild jujube polysaccharide；
(5) the wild jujube polysaccharide in the wild jujube light component and step (3) in step (2) according to 1:10~1:20 mass ratio
It is uniformly mixed, obtains the effective component of wild jujube.
A kind of application of the effective component of cigarette wild jujube provided by the invention in cigarette: the wild jujube for taking the above method to prepare is aobvious
Component is imitated, after the dilution of 70% ethanol solution, is sprayed on pipe tobacco, the additive amount of the effective component of wild jujube is 80~120ppm, will
Pipe tobacco after sprinkling, which is fitted into hermetic bag, to be sealed, in an oven 60 DEG C of balance 30min, cooling after taking-up, in climatic chamber
25 DEG C balance 24 hours, and cigarette is made after taking-up.
So that cigarette flavor texture is promoted, rich to improve, style and features variation is obvious, and pleasant impression becomes clean；Wild jujube is aobvious
Effect component can assign the features such as cigarette fruity, fragrant and sweet, baking perfume (or spice) and smell perfume (or spice)；When the effective component of wild jujube makes cigarette burning in flue gas
Fragrant and sweet, baking perfume and fruity increase more apparent.
The present invention prepares the effective component of wild jujube compared with traditional solvent extracts the zizyphus jujube extract of preparation, and effective group of wild jujube
The characteristic perfumes substances such as lauric acid, the palmitinic acid of cigarette feature sour rhythm are formed in point to obviously increase, and carry out irritation to tobacco rolling belt
The macromoleculars esters such as ethyl myristate, ethyl linoleate significantly reduce.It is applied in cigarette, the effective component of wild jujube is to cigarette
The promotion of fragrance texture, rich, style and features, pleasant impression clean degree are better than zizyphus jujube extract；Assign cigarette fruity, fragrant and sweet, baking
The features such as roasting perfume (or spice) are smelt fragrant more obvious；So that when cigarette burning in flue gas it is fragrant and sweet, bake fragrant and fruity increase and become apparent from.Wild jujube
Effective component is applied in cigarette, optimum amount 80ppm, under this additive amount have fragrance texture promoted, it is rich improve,
Style and features variation is obvious, the fine and smooth soft and elegant cigarette application effect felt of flue gas.
Beneficial effects of the present invention: the present invention is faced by the way of gradually separation, segmentation enrichment and ratio compounding in conjunction with super
Boundary's extraction, molecular distillation, segmentation alcohol precipitation technology extract point the effective components of cigarette such as aroma component, polysaccharide in wild jujube
From in conjunction with cigarette sensory evaluation, developing the effective component of functional wild jujube, which has in cigarette promotes cigarette flavor
Matter, rich cigarette perfume, style and features are obvious, flue gas is fine and smooth soft and the elegant effect felt, to realize the fining of wild jujube
Exploitation and comprehensive utilization.
Detailed description of the invention
Fig. 1 is that solvent extracts zizyphus jujube extract object and the effective component Sensory Quality of Cigarette comparison diagram of wild jujube in embodiment
Table；
Fig. 2 is that the effective component cigarette of wild jujube that solvent extracts in zizyphus jujube extract object and embodiment smells fragrant breeze lattice comparison diagram
Table；
Fig. 3 is that the effective component cigarette smoke style of wild jujube that solvent extracts in zizyphus jujube extract and embodiment compares chart.
Specific embodiment
Related technical problem of the invention is described in further detail below with reference to embodiment.
Embodiment 1, a kind of preparation method of the effective component of cigarette wild jujube, it is characterised in that include the following steps:
(1) a certain amount of wild jujube is taken, supercritical CO is carried out2Extraction, 56 DEG C of extraction temperature, extracting pressure 30Mpa, separating still
I pressure 10Mpa, separation reactor I temperature 45 C, II pressure 4Mpa of separating still, 20 DEG C of II temperature of separating still；
(2) the wild jujube supercritical extract of step (1) is subjected to molecular distillation, 40 DEG C of vapo(u)rizing temperature, distillation pressure controls
Wild jujube light component is obtained in 200Pa, charging rate 1mL/min, scraper plate revolving speed 150r/min；
(3) by step (1) wild jujube supercritical CO2Residue extracted carries out refluxing extraction, and Extraction solvent is tap water, object
Material is than being 1:4, and extraction time is 3 hours, and heating temperature is 100 DEG C, and cooling after extraction, filtering, being concentrated into relative density is
1.15,95% ethanol precipitation that mass ratio is 1:2 is added, filtering takes filtered solid that tap water dissolution is added, adjusts density
To 1.15,50% ethanol precipitation of 1:2 is added, is filtered, filtrate is concentrated into relative density 1.20, obtains wild jujube polysaccharide；
(4) the wild jujube light component of step (2) and step (3) wild jujube polysaccharide are uniformly mixed according to the mass ratio of 1:10, are obtained sour
The effective component A of jujube.
The effective component A of the wild jujube prepared in embodiment 1 is applied in cigarette, so that cigarette flavor texture is promoted, is enriched
Property improve, style and features variation is obvious, and pleasant impression becomes clean；The effective component of wild jujube can assign cigarette fruity, fragrant and sweet, baking perfume (or spice) etc.
Feature smells perfume (or spice)；When the effective component of wild jujube makes cigarette burning in flue gas it is fragrant and sweet, bake fragrant and fruity increase it is more apparent；Wild jujube is aobvious
Imitating optimum amount of the component in cigarette is 120ppm, there is fragrance texture to be promoted under this additive amount, it is rich improve, wind
Lattice changing features are obvious, flue gas is fine and smooth soft and the elegant cigarette application effect felt.
Embodiment 2, a kind of preparation method of the effective component of cigarette wild jujube, it is characterised in that include the following steps:
(1) a certain amount of wild jujube is taken, supercritical CO is carried out2Extraction, 56 DEG C of extraction temperature, extracting pressure 40Mpa, separating still
I pressure 12Mpa, separation reactor I temperature 45 C, II pressure 6Mpa of separating still, 25 DEG C of II temperature of separating still；
(2) the wild jujube supercritical extract of step (1) is subjected to molecular distillation, 40 DEG C of vapo(u)rizing temperature, distillation pressure controls
Wild jujube light component is obtained in 400Pa, charging rate 2mL/min, scraper plate revolving speed 150r/min；
(3) by step (1) wild jujube supercritical CO2Residue extracted carries out refluxing extraction, and Extraction solvent is tap water, object
For material than being 1:6, extraction time is 4 hours, and cooling after extraction, filtering, being concentrated into relative density is 1.15, and it is 1 that mass ratio, which is added:
3 95% ethanol precipitation, filtering take filtered solid that tap water dissolution is added, and adjust density to 1.15, add 1:3's
50% ethanol precipitation, filtering, filtrate are concentrated into relative density 1.20, obtain wild jujube polysaccharide；
(4) the wild jujube polysaccharide in the wild jujube light component and step (3) in step (2) mixes equal according to the mass ratio of 1:15
It is even, obtain the effective component B of wild jujube.
The effective component B of the wild jujube prepared in embodiment 2 is applied in cigarette, so that cigarette flavor texture is promoted, is enriched
Property improve, style and features variation is obvious, and pleasant impression becomes clean；The effective component of wild jujube can assign cigarette fruity, fragrant and sweet, baking perfume (or spice) etc.
Feature smells perfume (or spice)；When the effective component of wild jujube makes cigarette burning in flue gas it is fragrant and sweet, bake fragrant and fruity increase it is more apparent；Wild jujube is aobvious
Imitating optimum amount of the component in cigarette is 120ppm, there is fragrance texture to be promoted under this additive amount, it is rich improve, wind
Lattice changing features are obvious, flue gas is fine and smooth soft and the elegant cigarette application effect felt.
Embodiment 3, a kind of preparation method of the effective component of cigarette wild jujube, it is characterised in that include the following steps:
(1) a certain amount of wild jujube is taken, supercritical CO is carried out2Extraction, 58 DEG C of extraction temperature, extracting pressure 35Mpa, separating still
I pressure 11Mpa, 48 DEG C of separation reactor I temperature, II pressure 5Mpa of separating still, 28 DEG C of II temperature of separating still；
(2) the wild jujube supercritical extract of step (1) is subjected to molecular distillation, 50 DEG C of vapo(u)rizing temperature, distillation pressure controls
Wild jujube light component is obtained in 300Pa, charging rate 1.5mL/min, scraper plate revolving speed 200r/min；
(3) by step (1) wild jujube supercritical CO2Residue extracted carries out heating and refluxing extraction, and Extraction solvent is originally
Water, material ratio 1:6, extraction time is 4 hours, cooling after extraction, filtering, and being concentrated into relative density is 1.15, and quality is added
Than 95% ethanol precipitation for 1:4, filtering takes filtered solid that tap water dissolution is added, and adjusts density to 1.15, adds
50% ethanol precipitation of 1:4, filtering, filtrate are concentrated into relative density 1.20, obtain wild jujube polysaccharide；
(4) the wild jujube polysaccharide of the wild jujube light component in step (2) and step (3) is uniformly mixed according to the mass ratio of 1:15,
Obtain the effective component C of wild jujube.
The effective component C of the wild jujube prepared in embodiment 3 is applied in cigarette, so that cigarette flavor texture is promoted, is enriched
Property improve, style and features variation is obvious, and pleasant impression becomes clean；The effective component of wild jujube can assign cigarette fruity, fragrant and sweet, baking perfume (or spice) etc.
Feature smells perfume (or spice)；When the effective component of wild jujube makes cigarette burning in flue gas it is fragrant and sweet, bake fragrant and fruity increase it is more apparent；Wild jujube is aobvious
Imitating optimum amount of the component in cigarette is 100ppm, there is fragrance texture to be promoted under this additive amount, it is rich improve, wind
Lattice changing features are obvious, flue gas is fine and smooth soft and the elegant cigarette application effect felt.
Embodiment 4, a kind of preparation method of the effective component of cigarette wild jujube, it is characterised in that include the following steps:
(1) a certain amount of wild jujube is taken, supercritical CO is carried out2Extraction, 60 DEG C of extraction temperature, extracting pressure 40Mpa, separation
Kettle I pressure 12Mpa, separation reactor I temperature 50 C, II pressure 6Mpa of separating still, 25 DEG C of II temperature of separating still；
(2) the wild jujube supercritical extract of step (1) is subjected to molecular distillation, 60 DEG C of vapo(u)rizing temperature, distillation pressure controls
Wild jujube light component is obtained in 400Pa, charging rate 2mL/min, scraper plate revolving speed 300r/min；
(3) by step (1) wild jujube supercritical CO2Residue extracted carries out heating and refluxing extraction, and Extraction solvent is originally
Water, material ratio 1:8, extraction time is 5 hours, cooling after extraction, filtering, and being concentrated into relative density is 1.15, and quality is added
Than 95% ethanol precipitation for 1:4, filtering takes filtered solid that tap water dissolution is added, and adjusts density to 1.15, adds
50% ethanol precipitation of 1:4, filtering, filtrate are concentrated into relative density 1.20, obtain wild jujube polysaccharide；
(4) the wild jujube polysaccharide in the wild jujube light component and step (3) in step (2) mixes equal according to the mass ratio of 1:20
It is even, obtain the effective component D of wild jujube.
The effective component D of the wild jujube prepared in embodiment 4 is applied in cigarette, so that cigarette flavor texture is promoted, is enriched
Property improve, style and features variation is obvious, and pleasant impression becomes clean；The effective component of wild jujube can assign cigarette fruity, fragrant and sweet, baking perfume (or spice) etc.
Feature smells perfume (or spice)；When the effective component of wild jujube makes cigarette burning in flue gas it is fragrant and sweet, bake fragrant and fruity increase it is more apparent；Wild jujube is aobvious
Imitating optimum amount of the component in cigarette is 80ppm, there is fragrance texture to be promoted under this additive amount, it is rich improve, style
Changing features are obvious, flue gas is fine and smooth soft and the elegant cigarette application effect felt.
By the fragrance component of the effective component of cigarette wild jujube prepared by the present invention and traditional zizyphus jujube extract object (solvent extraction)
Analysis comparison is carried out, fragrance component comparison is as shown in table 1:
The fragrance component comparative analysis of 1 zizyphus jujube extract of table and the effective component of wild jujube
By in table 1 it is found that compared with traditional solvent extracts the zizyphus jujube extract of preparation, laurel in the effective component of wild jujube
The characteristic perfumes substance such as acid, palmitinic acid obviously increases, these aroma substances can be good at coordinating with cigarette, and express cigarette
The sour rhythm of feature.The macromoleculars esters such as ethyl myristate, ethyl linoleate significantly reduce, it is therefore prevented that these substances are to cigarette
Bring irritation.
By the effective component of cigarette wild jujube prepared by the present invention and traditional zizyphus jujube extract object (solvent extraction) respectively with 70%
After ethanol solution dilution, it is sprayed on pipe tobacco, the pipe tobacco after sprinkling is fitted into hermetic bag and seals by additive amount 100ppm,
60 DEG C of balance 30min in an oven, it is cooling after taking-up, it is balanced 24 hours for 25 DEG C in climatic chamber, cigarette is made after taking-up.
It smokes panel test respectively, Sensory Quality of Cigarette comparison is as shown in Figure 1, cigarette smells the comparison of fragrant breeze lattice as shown in Fig. 2, cigarette smoke wind
Lattice comparison as shown in figure 3, comparative analysis zizyphus jujube extract and application effect of the effective component of wild jujube in cigarette, as a result, it has been found that
(as shown in Figure 1, Figure 2 and Fig. 3), the effective component of wild jujube to the promotion of cigarette flavor texture, rich, style and features, pleasant impression clean degree all
Better than zizyphus jujube extract；The features such as imparting cigarette fruity, fragrant and sweet, baking perfume (or spice) are smelt fragrant more obvious；So that flue gas when cigarette burning
In it is fragrant and sweet, bake fragrant and fruity increase and become apparent from.
Cigarette prepared by the present invention is sprayed on pipe tobacco with the effective component of wild jujube according to Different adding amount, preparation is in cigarette,
And sensory evaluation is carried out to it, the sensory evaluation effect of Different adding amount is as shown in table 2:
Influence of the effective component of wild jujube of 2 Different adding amount of table to cigarette sensory evaluation effect
The effective component of wild jujube of Different adding amount is had studied to cigarette sensory evaluation effect, the results showed that (such as table 2) wild jujube
Optimum amount of the effective component in cigarette be 80ppm, under this additive amount have fragrance texture promoted, it is rich improve, wind
Lattice changing features are obvious, flue gas is fine and smooth soft and the elegant cigarette application effect felt.
The present invention using gradually separation, segmentation enrichment and ratio compounding by the way of, in conjunction with supercritical extract, molecular distillation and
It is segmented alcohol precipitation technology, prepares the effective component of wild jujube.Compared with traditional solvent extracts the zizyphus jujube extract of preparation, effective group of wild jujube
The characteristic perfumes substances such as lauric acid, the palmitinic acid of cigarette feature sour rhythm are formed in point to obviously increase, and carry out irritation to tobacco rolling belt
The macromoleculars esters such as ethyl myristate, ethyl linoleate significantly reduce.It is applied in cigarette, the effective component of wild jujube is to cigarette
The promotion of fragrance texture, rich, style and features, pleasant impression clean degree are better than zizyphus jujube extract；Assign cigarette fruity, fragrant and sweet, baking
The features such as roasting perfume (or spice) are smelt fragrant more obvious；So that when cigarette burning in flue gas it is fragrant and sweet, bake fragrant and fruity increase and become apparent from.Wild jujube
Effective component is applied in cigarette, optimum amount 80ppm, under this additive amount have fragrance texture promoted, it is rich improve,
Style and features variation is obvious, the fine and smooth soft and elegant cigarette application effect felt of flue gas.
The foregoing is merely the detailed descriptions of specific embodiments of the present invention, do not limit the present invention with this, all at this
Made any modifications, equivalent replacements, and improvements etc. in the mentality of designing of invention, should be included in protection scope of the present invention it
It is interior.
Claims (2)
1. a kind of preparation method of the effective component of cigarette wild jujube, it is characterised in that include the following steps:
(1) wild jujube is taken to carry out supercritical CO2It is obtained by extraction wild jujube supercritical extract, 56-60 DEG C of extraction temperature, extracting pressure
30-40Mpa, separation reactor I pressure 10-12Mpa, 45-50 DEG C of separation reactor I temperature, II pressure 4-6Mpa of separating still, II temperature of separating still
20-25 DEG C of degree；
(2) the wild jujube supercritical extract of step (1) is subjected to molecular distillation, 40~60 DEG C of vapo(u)rizing temperature, distillation pressure control
In 200~400Pa, 1~2mL/min of charging rate, scraper plate 150~300r/min of revolving speed, collect molecular distillation light component is system
Wild jujube light component；
(3) by wild jujube supercritical CO in step (1)2Tap water is added according to the ratio of material ratio 1:4~1:8 in residue extracted
Heating and refluxing extraction 3~5 hours, cooling after extraction, filtering, being concentrated into relative density is 1.15；
(4) 95% ethanol precipitation of concentration, mistake will be added according to the ratio that mass ratio is 1:2~1:4 in the concentrate in step (3)
Filter takes filtered solid that tap water dissolution is added, and adjusts density to 1.15, the concentration of 1:2~1:4 is added according still further to mass ratio
50% ethyl alcohol secondary precipitation, filtering, filtrate are concentrated into relative density 1.20, obtain wild jujube polysaccharide；
(5) the wild jujube polysaccharide in the wild jujube light component and step (3) in step (2) mixes equal according to the mass ratio of 1:10~1:20
It is even, obtain the effective component of wild jujube.
2. the effective component of cigarette wild jujube prepared by a kind of preparation method of effective component of cigarette wild jujube according to claim 1
Application in cigarette, it is characterised in that: the effective component of wild jujube for taking the above method to prepare, after the dilution of 70% ethanol solution,
It being sprayed on pipe tobacco, the additive amount of the effective component of wild jujube is 80~120ppm, the pipe tobacco after sprinkling is fitted into hermetic bag and is sealed,
60 DEG C of balance 30min in an oven, it is cooling after taking-up, it is balanced 24 hours for 25 DEG C in climatic chamber, cigarette is made after taking-up.
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