CN109103301B - 一种多晶硅表面微纳复合结构的制备方法 - Google Patents
一种多晶硅表面微纳复合结构的制备方法 Download PDFInfo
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- CN109103301B CN109103301B CN201811003225.7A CN201811003225A CN109103301B CN 109103301 B CN109103301 B CN 109103301B CN 201811003225 A CN201811003225 A CN 201811003225A CN 109103301 B CN109103301 B CN 109103301B
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- silicon wafer
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- 229910021420 polycrystalline silicon Inorganic materials 0.000 title claims abstract description 69
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000002114 nanocomposite Substances 0.000 title claims abstract description 15
- 229910052751 metal Inorganic materials 0.000 claims abstract description 33
- 239000002184 metal Substances 0.000 claims abstract description 33
- 238000005530 etching Methods 0.000 claims abstract description 24
- 238000000151 deposition Methods 0.000 claims abstract description 13
- 150000002500 ions Chemical class 0.000 claims abstract description 11
- 238000005516 engineering process Methods 0.000 claims abstract description 10
- 239000002086 nanomaterial Substances 0.000 claims abstract description 6
- 238000001259 photo etching Methods 0.000 claims abstract description 4
- 239000000243 solution Substances 0.000 claims description 34
- 229920002120 photoresistant polymer Polymers 0.000 claims description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 238000004140 cleaning Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 8
- 230000008021 deposition Effects 0.000 claims description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 238000001755 magnetron sputter deposition Methods 0.000 claims description 4
- 229920005591 polysilicon Polymers 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 4
- 101710134784 Agnoprotein Proteins 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- 229910052786 argon Inorganic materials 0.000 claims description 3
- XMPZTFVPEKAKFH-UHFFFAOYSA-P ceric ammonium nitrate Chemical compound [NH4+].[NH4+].[Ce+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O XMPZTFVPEKAKFH-UHFFFAOYSA-P 0.000 claims description 3
- 229910003460 diamond Inorganic materials 0.000 claims description 3
- 239000010432 diamond Substances 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 238000007747 plating Methods 0.000 claims description 3
- 238000005477 sputtering target Methods 0.000 claims description 3
- 239000013077 target material Substances 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 15
- 229910052710 silicon Inorganic materials 0.000 abstract description 15
- 239000010703 silicon Substances 0.000 abstract description 15
- 229910021418 black silicon Inorganic materials 0.000 abstract description 6
- 230000003197 catalytic effect Effects 0.000 abstract description 4
- 238000003486 chemical etching Methods 0.000 abstract description 3
- 238000005215 recombination Methods 0.000 abstract description 3
- 230000006798 recombination Effects 0.000 abstract description 3
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 238000005459 micromachining Methods 0.000 abstract description 2
- 229910000510 noble metal Inorganic materials 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract 2
- 230000007797 corrosion Effects 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 238000001039 wet etching Methods 0.000 description 4
- 238000001020 plasma etching Methods 0.000 description 3
- 238000001312 dry etching Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002082 metal nanoparticle Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000002310 reflectometry Methods 0.000 description 2
- 238000000992 sputter etching Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005566 electron beam evaporation Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
- H01L31/1804—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof comprising only elements of Group IV of the Periodic Table
- H01L31/182—Special manufacturing methods for polycrystalline Si, e.g. Si ribbon, poly Si ingots, thin films of polycrystalline Si
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/546—Polycrystalline silicon PV cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Engineering & Computer Science (AREA)
- Electromagnetism (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Weting (AREA)
- Silicon Compounds (AREA)
- Photovoltaic Devices (AREA)
Abstract
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CN201811003225.7A CN109103301B (zh) | 2018-08-30 | 2018-08-30 | 一种多晶硅表面微纳复合结构的制备方法 |
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CN201811003225.7A CN109103301B (zh) | 2018-08-30 | 2018-08-30 | 一种多晶硅表面微纳复合结构的制备方法 |
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CN109103301A CN109103301A (zh) | 2018-12-28 |
CN109103301B true CN109103301B (zh) | 2020-07-07 |
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CN113299776A (zh) * | 2021-04-09 | 2021-08-24 | 桂林电子科技大学 | 一种增强太阳能电池光吸收的微纳混合结构及制备方法 |
CN113223952B (zh) * | 2021-04-28 | 2022-10-28 | 华虹半导体(无锡)有限公司 | 包含sgt结构的器件的制作方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6329296B1 (en) * | 2000-08-09 | 2001-12-11 | Sandia Corporation | Metal catalyst technique for texturing silicon solar cells |
CN1710705A (zh) * | 2005-07-05 | 2005-12-21 | 华中科技大学 | 一种硅湿法刻蚀工艺 |
CN102447011A (zh) * | 2011-12-15 | 2012-05-09 | 华中科技大学 | 用于制造太阳能电池光阳极的方法及其产品 |
CN103456804A (zh) * | 2013-09-24 | 2013-12-18 | 上海大学 | 在多晶硅上形成倒金字塔型多孔表面纳米织构的方法及制备短波增强型太阳电池的方法 |
CN104393114A (zh) * | 2014-11-17 | 2015-03-04 | 中国电子科技集团公司第四十八研究所 | 一种微纳复合绒面结构的多晶黑硅制备方法 |
-
2018
- 2018-08-30 CN CN201811003225.7A patent/CN109103301B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6329296B1 (en) * | 2000-08-09 | 2001-12-11 | Sandia Corporation | Metal catalyst technique for texturing silicon solar cells |
CN1710705A (zh) * | 2005-07-05 | 2005-12-21 | 华中科技大学 | 一种硅湿法刻蚀工艺 |
CN102447011A (zh) * | 2011-12-15 | 2012-05-09 | 华中科技大学 | 用于制造太阳能电池光阳极的方法及其产品 |
CN103456804A (zh) * | 2013-09-24 | 2013-12-18 | 上海大学 | 在多晶硅上形成倒金字塔型多孔表面纳米织构的方法及制备短波增强型太阳电池的方法 |
CN104393114A (zh) * | 2014-11-17 | 2015-03-04 | 中国电子科技集团公司第四十八研究所 | 一种微纳复合绒面结构的多晶黑硅制备方法 |
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