CN109085710A - A kind of toning glass and preparation method thereof with effectiveness - Google Patents
A kind of toning glass and preparation method thereof with effectiveness Download PDFInfo
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- CN109085710A CN109085710A CN201811207486.0A CN201811207486A CN109085710A CN 109085710 A CN109085710 A CN 109085710A CN 201811207486 A CN201811207486 A CN 201811207486A CN 109085710 A CN109085710 A CN 109085710A
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- uvioresistant
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- ink
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- 239000011521 glass Substances 0.000 title claims abstract description 66
- 238000002360 preparation method Methods 0.000 title claims abstract description 36
- 239000011347 resin Substances 0.000 claims abstract description 59
- 229920005989 resin Polymers 0.000 claims abstract description 59
- 229910052751 metal Inorganic materials 0.000 claims abstract description 53
- 239000002184 metal Substances 0.000 claims abstract description 53
- 239000000758 substrate Substances 0.000 claims abstract description 46
- 239000000463 material Substances 0.000 claims abstract description 27
- 239000004973 liquid crystal related substance Substances 0.000 claims abstract description 23
- 239000010410 layer Substances 0.000 claims description 178
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 54
- 239000004020 conductor Substances 0.000 claims description 44
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 42
- 229920000728 polyester Polymers 0.000 claims description 42
- 239000003795 chemical substances by application Substances 0.000 claims description 35
- 239000000052 vinegar Substances 0.000 claims description 28
- 239000000377 silicon dioxide Substances 0.000 claims description 27
- 229910052709 silver Inorganic materials 0.000 claims description 21
- 239000004332 silver Substances 0.000 claims description 21
- 235000012239 silicon dioxide Nutrition 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 15
- 238000003851 corona treatment Methods 0.000 claims description 14
- 238000002347 injection Methods 0.000 claims description 14
- 239000007924 injection Substances 0.000 claims description 14
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 13
- 230000005540 biological transmission Effects 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 7
- 230000002776 aggregation Effects 0.000 claims description 7
- 238000004220 aggregation Methods 0.000 claims description 7
- 230000032683 aging Effects 0.000 claims description 7
- 239000000908 ammonium hydroxide Substances 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 7
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 7
- 239000011229 interlayer Substances 0.000 claims description 7
- 239000011259 mixed solution Substances 0.000 claims description 7
- 238000000465 moulding Methods 0.000 claims description 7
- 238000007747 plating Methods 0.000 claims description 7
- 238000007639 printing Methods 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- 238000007711 solidification Methods 0.000 claims description 7
- 230000008023 solidification Effects 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 239000004408 titanium dioxide Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 13
- 230000005855 radiation Effects 0.000 abstract description 11
- 238000003854 Surface Print Methods 0.000 abstract description 8
- 208000027418 Wounds and injury Diseases 0.000 abstract description 8
- 230000006378 damage Effects 0.000 abstract description 8
- 208000014674 injury Diseases 0.000 abstract description 8
- 230000036541 health Effects 0.000 abstract description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- 230000004888 barrier function Effects 0.000 description 5
- 235000013399 edible fruits Nutrition 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- 230000008859 change Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 235000019774 Rice Bran oil Nutrition 0.000 description 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- GRPQBOKWXNIQMF-UHFFFAOYSA-N indium(3+) oxygen(2-) tin(4+) Chemical class [Sn+4].[O-2].[In+3] GRPQBOKWXNIQMF-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/1313—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells specially adapted for a particular application
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/66—Units comprising two or more parallel glass or like panes permanently secured together
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/133509—Filters, e.g. light shielding masks
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1343—Electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/24—Structural elements or technologies for improving thermal insulation
- Y02A30/249—Glazing, e.g. vacuum glazing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B80/00—Architectural or constructional elements improving the thermal performance of buildings
- Y02B80/22—Glazing, e.g. vaccum glazing
Landscapes
- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Mathematical Physics (AREA)
- Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Laminated Bodies (AREA)
- Joining Of Glass To Other Materials (AREA)
Abstract
The invention discloses a kind of toning glass with effectiveness, including uvioresistant substrate, resin layer is bonded on the upside of uvioresistant substrate, liquid crystal material layer is equipped in the upside of resin layer, it is uniformly placed with several grooves on the resin layer, also disclose a kind of preparation method of toning glass with effectiveness, a kind of toning glass with effectiveness of the present invention, using invaginating metal grid electrode, performance is stablized, it is cheap, the careful naked eyes of lines are invisible, with excellent dimming function, metal grill is alternatively arranged as electromagnetic shielding film except having electrode function, with effectiveness, toning glass outer electromagnetic wave influence and injury can effectively be shielded；Metal grill design diversity and surface printing nano ink diversity can effectively increase the exterior decorative effect and practicability of toning glass; ultraviolet radiation can effectively be obstructed using uvioresistant design; protect human health, the working environment strong suitable for ultraviolet radiation and area.
Description
Technical field
The present invention relates to toning glass technology field, specifically a kind of toning glass and its system with effectiveness
Preparation Method.
Background technique
Photo chromic glass refer to illumination, temperature, electric field or electric current, surface pressure etc. change under certain conditions color and with
The variation of condition and occur to change accordingly, reversibly automatically restore to the glass of original state again after application condition disappears
Glass, also referred to as dimming glass.Photo chromic glass changes the transmission characteristic of itself with the variation of external environment, can be realized to sun spoke
Effective control of energy is penetrated, to reach energy-efficient purpose.Photo chromic glass changes mechanism by glass performance and is broadly divided into light-induced variable
Color glass, thermochromism glass, electrochomeric glass and power cause photo chromic glass.Wherein, photic, electrochomeric glass especially by
The concern of curtain wall industry personage.Then restore its original face when changing its color under the irradiation of appropriate wavelength light, and removing light source
The glass of color.Also known as photochromic glass or photochromic glass.Photo chromic glass is made of the addition photochromic material in glass raw material.
Conventional photo chromic glass is to constitute conductive substrates by transparent conductive materials such as tin indium oxides, has the function of structure and list
One, high square resistance and the defects of high cost, is not able to satisfy the use demand of modernization.
Summary of the invention
The purpose of the present invention is to provide a kind of toning glass and preparation method thereof with effectiveness, to solve
The problems mentioned above in the background art.
To achieve the above object, the invention provides the following technical scheme:
A kind of toning glass with effectiveness, including uvioresistant substrate, the uvioresistant substrate upside are bonded with tree
Rouge layer, the upside of resin layer be equipped with liquid crystal material layer, be uniformly placed with several grooves on the resin layer, inside grooves by
Under supreme be successively placed with nano metal conductive material layer, metallic conducting material and ink decorative layer.
Further, the uvioresistant substrate includes uvioresistant poly ester layer and is arranged on the two sides of uvioresistant poly ester layer
Silica coating, the uvioresistant poly ester layer be polyester base in disperse anti ultraviolet agent, anti ultraviolet agent includes nanometer titanium dioxide
Titanium and nano zine oxide.
Further, the silica coating passes through rotary process plated film on uvioresistant polyester layer by silicon dioxide gel
It is formed.
Further, the weight content of anti ultraviolet agent is 3-5wt% in the uvioresistant poly ester layer.
Further, the weight proportion of nano-titanium dioxide and nano zine oxide is 1:1-3:1 in the anti ultraviolet agent.
Further, the resin layer is uvioresistant high light transmission resin, and the nano metal conductive material layer is nano silver
Conductive ink layer, the material of metallic conducting material are filamentary silver, and ink decorative layer is nano ink layer.
A kind of preparation method of the toning glass with effectiveness, specifically includes the following steps:
S1, preparation uvioresistant substrate；
S2, in uvioresistant substrate upper surface binding resin layer；
S3, mold is made as needed；
S4, texture is carried out on the resin layer using the mold made in step S3 transfer to form groove structure；
S5, Nano silver conductive ink, filamentary silver, nano ink are successively filled in the groove structure in step S4 according to design, according to
Secondary formation nano metal conductive material layer, metallic conducting material and ink decorative layer form conducting wire grid；
S6, liquid crystal material layer will be formed in liquid crystal injection metal grid electrode interlayer by the way of vacuum injection.
Further, the step S1 specifically includes the following steps:
The preparation of S11, uvioresistant poly-vinegar layer: anti ultraviolet agent is dispersed in poly-vinegar base by situ aggregation method, is prepared anti-
Ultraviolet PET slice；
S12, sided corona treatment: sided corona treatment is carried out to the two sides of the step S11 uvioresistant poly-vinegar layer obtained；
The preparation of S13, silicon dioxide gel: using ethyl orthosilicate, dehydrated alcohol and water as raw material, using ammonium hydroxide as catalyst,
Stirring mixes it uniformly at 20 DEG C, and then mixed solution is put into closed container, constant temperature ageing；
S14, rotary plating: under rotational case, the corona treated surface in uvioresistant poly-vinegar layer is added dropwise in colloidal sol, is then accelerated
It rotates and keeps, uvioresistant substrate is obtained after solidification.
Further, in the step S4, texture transfer specifically is carried out by the way of exposing UV resin.
Further, in the step S5, specifically by the way of intaglio printing by Nano silver conductive ink, filamentary silver, receive
Rice bran oil ink successively fills in groove structure, and molding is sintered after filling.
Compared with prior art, the beneficial effects of the present invention are:
1, using invaginating metal grid electrode, performance is stable, cheap, and the careful naked eyes of lines are invisible, has excellent
Dimming function.
2, metal grill is alternatively arranged as electromagnetic shielding film except having electrode function, has effectiveness, can effectively shield
Cover toning glass outer electromagnetic wave influence and injury.
3, metal grill design diversity and surface printing nano ink diversity can effectively increase the appearance of toning glass
Decorative effect and practicability.
4, ultraviolet radiation can effectively be obstructed using uvioresistant design, protects human health, be suitable for ultraviolet radiation
Strong working environment and area.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram of toning glass with effectiveness.
In figure:
1- uvioresistant substrate, 2- resin layer, 3- liquid crystal material layer, 4- nano metal conductive material layer, 5- metallic conducting material,
6- ink decorative layer.
Specific embodiment
In order to deepen the understanding of the present invention, the present invention will be described in further detail with reference to the examples below, implements below
Example for explaining only the invention, is not intended to limit the scope of the present invention..
Embodiment 1
Referring to Fig. 1, a kind of toning glass with effectiveness, including uvioresistant substrate 1, the uvioresistant substrate 1
Upside is bonded with resin layer 2, is equipped with liquid crystal material layer 3 in the upside of resin layer 2, is uniformly placed with several on resin layer 2
Groove is successively placed with nano metal conductive material layer 4, metallic conducting material 5 and ink filling in inside grooves from the bottom to top
Adorn layer 6；
The uvioresistant substrate 1 includes uvioresistant poly ester layer and the silicon dioxide film being arranged on the two sides of uvioresistant poly ester layer
Layer, the uvioresistant poly ester layer are to disperse anti ultraviolet agent in polyester base, and anti ultraviolet agent includes nano-titanium dioxide and nano oxidized
Zinc；
By silicon dioxide gel, by rotary process, the plated film on uvioresistant polyester layer is formed the silica coating；
The weight content of anti ultraviolet agent is 3wt% in the uvioresistant poly ester layer；
The weight proportion of nano-titanium dioxide and nano zine oxide is 1:1 in the anti ultraviolet agent；
The resin layer 2 is uvioresistant high light transmission resin, and the nano metal conductive material layer 4 is Nano silver conductive ink layer,
The material of metallic conducting material 5 is filamentary silver, and ink decorative layer is nano ink layer；
A kind of preparation method of the toning glass with effectiveness, specifically includes the following steps:
S1, preparation uvioresistant substrate 1；
S2, in 1 upper surface binding resin layer 2 of uvioresistant substrate；
S3, mold is made as needed；
S4, it texture is carried out on resin layer 2 using the mold made in step S3 transfers to form groove structure；
S5, Nano silver conductive ink, filamentary silver, nano ink are successively filled in the groove structure in step S4 according to design, according to
Secondary formation nano metal conductive material layer 4, metallic conducting material 5 and ink decorative layer 6 form conducting wire grid；
S6, liquid crystal material layer 4 will be formed in liquid crystal injection metal grid electrode interlayer by the way of vacuum injection；
The step S1 specifically includes the following steps:
The preparation of S11, uvioresistant poly-vinegar layer: anti ultraviolet agent is dispersed in poly-vinegar base by situ aggregation method, is prepared anti-
Ultraviolet PET slice；
S12, sided corona treatment: sided corona treatment is carried out to the two sides of the step S11 uvioresistant poly-vinegar layer obtained；
The preparation of S13, silicon dioxide gel: using ethyl orthosilicate, dehydrated alcohol and water as raw material, using ammonium hydroxide as catalyst,
Stirring mixes it uniformly at 20 DEG C, and then mixed solution is put into closed container, constant temperature ageing；
S14, rotary plating: under rotational case, the corona treated surface in uvioresistant poly-vinegar layer is added dropwise in colloidal sol, is then accelerated
It rotates and keeps, uvioresistant substrate 1 is obtained after solidification；
In the step S4, texture transfer specifically is carried out by the way of exposing UV resin；
In the step S5, specifically Nano silver conductive ink, filamentary silver, nano ink are successively filled by the way of intaglio printing
Molding is sintered in groove structure, after filling.
In the present embodiment, using invaginating metal grid electrode, performance is stable, cheap, and the careful naked eyes of lines can not
See that there is excellent dimming function, metal grill is alternatively arranged as electromagnetic shielding film except having electrode function, has electromagnetic shielding effect
Fruit can effectively shield toning glass outer electromagnetic wave influence and injury；Metal grill design diversity and surface printing nanometer oil
Black diversity can effectively increase the exterior decorative effect and practicability of toning glass, can absorbing wavelength be effectively 30nm-100nm
Ultraviolet light, effectively barrier ultraviolet radiation.
Embodiment 2
Referring to Fig. 1, a kind of toning glass with effectiveness, including uvioresistant substrate 1, the uvioresistant substrate 1
Upside is bonded with resin layer 2, is equipped with liquid crystal material layer 3 in the upside of resin layer 2, is uniformly placed with several on resin layer 2
Groove is successively placed with nano metal conductive material layer 4, metallic conducting material 5 and ink filling in inside grooves from the bottom to top
Adorn layer 6；
The uvioresistant substrate 1 includes uvioresistant poly ester layer and the silicon dioxide film being arranged on the two sides of uvioresistant poly ester layer
Layer, the uvioresistant poly ester layer are to disperse anti ultraviolet agent in polyester base, and anti ultraviolet agent includes nano-titanium dioxide and nano oxidized
Zinc；
By silicon dioxide gel, by rotary process, the plated film on uvioresistant polyester layer is formed the silica coating；
The weight content of anti ultraviolet agent is 3.5wt% in the uvioresistant poly ester layer；
The weight proportion of nano-titanium dioxide and nano zine oxide is 1.5:1 in the anti ultraviolet agent；
The resin layer 2 is uvioresistant high light transmission resin, and the nano metal conductive material layer 4 is Nano silver conductive ink layer,
The material of metallic conducting material 5 is filamentary silver, and ink decorative layer is nano ink layer；
A kind of preparation method of the toning glass with effectiveness, specifically includes the following steps:
S1, preparation uvioresistant substrate 1；
S2, in 1 upper surface binding resin layer 2 of uvioresistant substrate；
S3, mold is made as needed；
S4, it texture is carried out on resin layer 2 using the mold made in step S3 transfers to form groove structure；
S5, Nano silver conductive ink, filamentary silver, nano ink are successively filled in the groove structure in step S4 according to design, according to
Secondary formation nano metal conductive material layer 4, metallic conducting material 5 and ink decorative layer 6 form conducting wire grid；
S6, liquid crystal material layer 4 will be formed in liquid crystal injection metal grid electrode interlayer by the way of vacuum injection；
The step S1 specifically includes the following steps:
The preparation of S11, uvioresistant poly-vinegar layer: anti ultraviolet agent is dispersed in poly-vinegar base by situ aggregation method, is prepared anti-
Ultraviolet PET slice；
S12, sided corona treatment: sided corona treatment is carried out to the two sides of the step S11 uvioresistant poly-vinegar layer obtained；
The preparation of S13, silicon dioxide gel: using ethyl orthosilicate, dehydrated alcohol and water as raw material, using ammonium hydroxide as catalyst,
Stirring mixes it uniformly at 20 DEG C, and then mixed solution is put into closed container, constant temperature ageing；
S14, rotary plating: under rotational case, the corona treated surface in uvioresistant poly-vinegar layer is added dropwise in colloidal sol, is then accelerated
It rotates and keeps, uvioresistant substrate 1 is obtained after solidification；
In the step S4, texture transfer specifically is carried out by the way of exposing UV resin；
In the step S5, specifically Nano silver conductive ink, filamentary silver, nano ink are successively filled by the way of intaglio printing
Molding is sintered in groove structure, after filling.
In the present embodiment, using invaginating metal grid electrode, performance is stable, cheap, and the careful naked eyes of lines can not
See that there is excellent dimming function, metal grill is alternatively arranged as electromagnetic shielding film except having electrode function, has electromagnetic shielding effect
Fruit can effectively shield toning glass outer electromagnetic wave influence and injury；Metal grill design diversity and surface printing nanometer oil
Black diversity can effectively increase the exterior decorative effect and practicability of toning glass, can absorbing wavelength be effectively 100nm-
The ultraviolet light of 170nm, effectively barrier ultraviolet radiation.
Embodiment 3
Referring to Fig. 1, a kind of toning glass with effectiveness, including uvioresistant substrate 1, the uvioresistant substrate 1
Upside is bonded with resin layer 2, is equipped with liquid crystal material layer 3 in the upside of resin layer 2, is uniformly placed with several on resin layer 2
Groove is successively placed with nano metal conductive material layer 4, metallic conducting material 5 and ink filling in inside grooves from the bottom to top
Adorn layer 6；
The uvioresistant substrate 1 includes uvioresistant poly ester layer and the silicon dioxide film being arranged on the two sides of uvioresistant poly ester layer
Layer, the uvioresistant poly ester layer are to disperse anti ultraviolet agent in polyester base, and anti ultraviolet agent includes nano-titanium dioxide and nano oxidized
Zinc；
By silicon dioxide gel, by rotary process, the plated film on uvioresistant polyester layer is formed the silica coating；
The weight content of anti ultraviolet agent is 4wt% in the uvioresistant poly ester layer；
The weight proportion of nano-titanium dioxide and nano zine oxide is 2:1 in the anti ultraviolet agent；
The resin layer 2 is uvioresistant high light transmission resin, and the nano metal conductive material layer 4 is Nano silver conductive ink layer,
The material of metallic conducting material 5 is filamentary silver, and ink decorative layer is nano ink layer；
A kind of preparation method of the toning glass with effectiveness, specifically includes the following steps:
S1, preparation uvioresistant substrate 1；
S2, in 1 upper surface binding resin layer 2 of uvioresistant substrate；
S3, mold is made as needed；
S4, it texture is carried out on resin layer 2 using the mold made in step S3 transfers to form groove structure；
S5, Nano silver conductive ink, filamentary silver, nano ink are successively filled in the groove structure in step S4 according to design, according to
Secondary formation nano metal conductive material layer 4, metallic conducting material 5 and ink decorative layer 6 form conducting wire grid；
S6, liquid crystal material layer 4 will be formed in liquid crystal injection metal grid electrode interlayer by the way of vacuum injection；
The step S1 specifically includes the following steps:
The preparation of S11, uvioresistant poly-vinegar layer: anti ultraviolet agent is dispersed in poly-vinegar base by situ aggregation method, is prepared anti-
Ultraviolet PET slice；
S12, sided corona treatment: sided corona treatment is carried out to the two sides of the step S11 uvioresistant poly-vinegar layer obtained；
The preparation of S13, silicon dioxide gel: using ethyl orthosilicate, dehydrated alcohol and water as raw material, using ammonium hydroxide as catalyst,
Stirring mixes it uniformly at 20 DEG C, and then mixed solution is put into closed container, constant temperature ageing；
S14, rotary plating: under rotational case, the corona treated surface in uvioresistant poly-vinegar layer is added dropwise in colloidal sol, is then accelerated
It rotates and keeps, uvioresistant substrate 1 is obtained after solidification；
In the step S4, texture transfer specifically is carried out by the way of exposing UV resin；
In the step S5, specifically Nano silver conductive ink, filamentary silver, nano ink are successively filled by the way of intaglio printing
Molding is sintered in groove structure, after filling.
In the present embodiment, using invaginating metal grid electrode, performance is stable, cheap, and the careful naked eyes of lines can not
See that there is excellent dimming function, metal grill is alternatively arranged as electromagnetic shielding film except having electrode function, has electromagnetic shielding effect
Fruit can effectively shield toning glass outer electromagnetic wave influence and injury；Metal grill design diversity and surface printing nanometer oil
Black diversity can effectively increase the exterior decorative effect and practicability of toning glass, can absorbing wavelength be effectively 170nm-
The ultraviolet light of 240nm, effectively barrier ultraviolet radiation.
Embodiment 4
Referring to Fig. 1, a kind of toning glass with effectiveness, including uvioresistant substrate 1, the uvioresistant substrate 1
Upside is bonded with resin layer 2, is equipped with liquid crystal material layer 3 in the upside of resin layer 2, is uniformly placed with several on resin layer 2
Groove is successively placed with nano metal conductive material layer 4, metallic conducting material 5 and ink filling in inside grooves from the bottom to top
Adorn layer 6；
The uvioresistant substrate 1 includes uvioresistant poly ester layer and the silicon dioxide film being arranged on the two sides of uvioresistant poly ester layer
Layer, the uvioresistant poly ester layer are to disperse anti ultraviolet agent in polyester base, and anti ultraviolet agent includes nano-titanium dioxide and nano oxidized
Zinc；
By silicon dioxide gel, by rotary process, the plated film on uvioresistant polyester layer is formed the silica coating；
The weight content of anti ultraviolet agent is 4.5wt% in the uvioresistant poly ester layer；
The weight proportion of nano-titanium dioxide and nano zine oxide is 2.5:1 in the anti ultraviolet agent；
The resin layer 2 is uvioresistant high light transmission resin, and the nano metal conductive material layer 4 is Nano silver conductive ink layer,
The material of metallic conducting material 5 is filamentary silver, and ink decorative layer is nano ink layer；
A kind of preparation method of the toning glass with effectiveness, specifically includes the following steps:
S1, preparation uvioresistant substrate 1；
S2, in 1 upper surface binding resin layer 2 of uvioresistant substrate；
S3, mold is made as needed；
S4, it texture is carried out on resin layer 2 using the mold made in step S3 transfers to form groove structure；
S5, Nano silver conductive ink, filamentary silver, nano ink are successively filled in the groove structure in step S4 according to design, according to
Secondary formation nano metal conductive material layer 4, metallic conducting material 5 and ink decorative layer 6 form conducting wire grid；
S6, liquid crystal material layer 4 will be formed in liquid crystal injection metal grid electrode interlayer by the way of vacuum injection；
The step S1 specifically includes the following steps:
The preparation of S11, uvioresistant poly-vinegar layer: anti ultraviolet agent is dispersed in poly-vinegar base by situ aggregation method, is prepared anti-
Ultraviolet PET slice；
S12, sided corona treatment: sided corona treatment is carried out to the two sides of the step S11 uvioresistant poly-vinegar layer obtained；
The preparation of S13, silicon dioxide gel: using ethyl orthosilicate, dehydrated alcohol and water as raw material, using ammonium hydroxide as catalyst,
Stirring mixes it uniformly at 20 DEG C, and then mixed solution is put into closed container, constant temperature ageing；
S14, rotary plating: under rotational case, the corona treated surface in uvioresistant poly-vinegar layer is added dropwise in colloidal sol, is then accelerated
It rotates and keeps, uvioresistant substrate 1 is obtained after solidification；
In the step S4, texture transfer specifically is carried out by the way of exposing UV resin；
In the step S5, specifically Nano silver conductive ink, filamentary silver, nano ink are successively filled by the way of intaglio printing
Molding is sintered in groove structure, after filling.
In the present embodiment, using invaginating metal grid electrode, performance is stable, cheap, and the careful naked eyes of lines can not
See that there is excellent dimming function, metal grill is alternatively arranged as electromagnetic shielding film except having electrode function, has electromagnetic shielding effect
Fruit can effectively shield toning glass outer electromagnetic wave influence and injury；Metal grill design diversity and surface printing nanometer oil
Black diversity can effectively increase the exterior decorative effect and practicability of toning glass, can absorbing wavelength be effectively 240nm-
The ultraviolet light of 320nm, effectively barrier ultraviolet radiation.
Embodiment 5
Referring to Fig. 1, a kind of toning glass with effectiveness, including uvioresistant substrate 1, the uvioresistant substrate 1
Upside is bonded with resin layer 2, is equipped with liquid crystal material layer 3 in the upside of resin layer 2, is uniformly placed with several on resin layer 2
Groove is successively placed with nano metal conductive material layer 4, metallic conducting material 5 and ink filling in inside grooves from the bottom to top
Adorn layer 6；
The uvioresistant substrate 1 includes uvioresistant poly ester layer and the silicon dioxide film being arranged on the two sides of uvioresistant poly ester layer
Layer, the uvioresistant poly ester layer are to disperse anti ultraviolet agent in polyester base, and anti ultraviolet agent includes nano-titanium dioxide and nano oxidized
Zinc；
By silicon dioxide gel, by rotary process, the plated film on uvioresistant polyester layer is formed the silica coating；
The weight content of anti ultraviolet agent is 5wt% in the uvioresistant poly ester layer；
The weight proportion of nano-titanium dioxide and nano zine oxide is 3:1 in the anti ultraviolet agent；
The resin layer 2 is uvioresistant high light transmission resin, and the nano metal conductive material layer 4 is Nano silver conductive ink layer,
The material of metallic conducting material 5 is filamentary silver, and ink decorative layer is nano ink layer；
A kind of preparation method of the toning glass with effectiveness, specifically includes the following steps:
S1, preparation uvioresistant substrate 1；
S2, in 1 upper surface binding resin layer 2 of uvioresistant substrate；
S3, mold is made as needed；
S4, it texture is carried out on resin layer 2 using the mold made in step S3 transfers to form groove structure；
S5, Nano silver conductive ink, filamentary silver, nano ink are successively filled in the groove structure in step S4 according to design, according to
Secondary formation nano metal conductive material layer 4, metallic conducting material 5 and ink decorative layer 6 form conducting wire grid；
S6, liquid crystal material layer 4 will be formed in liquid crystal injection metal grid electrode interlayer by the way of vacuum injection；
The step S1 specifically includes the following steps:
The preparation of S11, uvioresistant poly-vinegar layer: anti ultraviolet agent is dispersed in poly-vinegar base by situ aggregation method, is prepared anti-
Ultraviolet PET slice；
S12, sided corona treatment: sided corona treatment is carried out to the two sides of the step S11 uvioresistant poly-vinegar layer obtained；
The preparation of S13, silicon dioxide gel: using ethyl orthosilicate, dehydrated alcohol and water as raw material, using ammonium hydroxide as catalyst,
Stirring mixes it uniformly at 20 DEG C, and then mixed solution is put into closed container, constant temperature ageing；
S14, rotary plating: under rotational case, the corona treated surface in uvioresistant poly-vinegar layer is added dropwise in colloidal sol, is then accelerated
It rotates and keeps, uvioresistant substrate 1 is obtained after solidification；
In the step S4, texture transfer specifically is carried out by the way of exposing UV resin；
In the step S5, specifically Nano silver conductive ink, filamentary silver, nano ink are successively filled by the way of intaglio printing
Molding is sintered in groove structure, after filling.
In the present embodiment, using invaginating metal grid electrode, performance is stable, cheap, and the careful naked eyes of lines can not
See that there is excellent dimming function, metal grill is alternatively arranged as electromagnetic shielding film except having electrode function, has electromagnetic shielding effect
Fruit can effectively shield toning glass outer electromagnetic wave influence and injury；Metal grill design diversity and surface printing nanometer oil
Black diversity can effectively increase the exterior decorative effect and practicability of toning glass, can absorbing wavelength be effectively 320nm-
The ultraviolet light of 400nm, effectively barrier ultraviolet radiation.
A kind of toning glass with effectiveness of the present invention, using invaginating metal grid electrode, performance is stable,
Cheap, the careful naked eyes of lines are invisible, have excellent dimming function, and metal grill is alternatively arranged as except having electrode function
Electromagnetic shielding film has effectiveness, can effectively shield toning glass outer electromagnetic wave influence and injury；Metal grill is set
Meter diversity and surface printing nano ink diversity can effectively increase the exterior decorative effect and practicability of toning glass, use
Uvioresistant design can effectively obstruct ultraviolet radiation, protect human health, the working environment strong suitable for ultraviolet radiation
And area.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and what is described in the above embodiment and the description is only the present invention
Principle, various changes and improvements may be made to the invention without departing from the spirit and scope of the present invention, these variation and
Improvement is both fallen in the range of claimed invention.The present invention claims protection scope by appended claims and its
Equivalent defines.
Claims (10)
1. a kind of toning glass with effectiveness, including uvioresistant substrate (1), which is characterized in that the uvioresistant
Resin layer (2) are bonded on the upside of substrate (1), are equipped with liquid crystal material layer (3) in the upside of resin layer (2), on resin layer (2)
It is even to be placed with several grooves, it is successively placed with nano metal conductive material layer (4), metallic conduction from the bottom to top in inside grooves
Material layer (5) and ink decorative layer (6).
2. a kind of toning glass with effectiveness according to claim 1, which is characterized in that the uvioresistant
Substrate (1) includes uvioresistant poly ester layer and the silica coating that is arranged on the two sides of uvioresistant poly ester layer, the anti-purple
Outer polyester layer is to disperse anti ultraviolet agent in polyester base, and anti ultraviolet agent includes nano-titanium dioxide and nano zine oxide.
3. a kind of toning glass with effectiveness according to claim 1, which is characterized in that the titanium dioxide
By silicon dioxide gel, by rotary process, the plated film on uvioresistant polyester layer is formed silicon film.
4. a kind of toning glass with effectiveness according to claim 1, which is characterized in that the uvioresistant
The weight content of anti ultraviolet agent is 3-5wt% in polyester layer.
5. a kind of toning glass with effectiveness according to claim 1, which is characterized in that the uvioresistant
The weight proportion of nano-titanium dioxide and nano zine oxide is 1:1-3:1 in agent.
6. a kind of toning glass with effectiveness according to claim 1, which is characterized in that the resin layer
It (2) is uvioresistant high light transmission resin, the nano metal conductive material layer (4) is Nano silver conductive ink layer, metallic conduction material
The material of the bed of material (5) is filamentary silver, and ink decorative layer (6) is nano ink layer.
7. a kind of preparation method of the toning glass with effectiveness, which is characterized in that specifically includes the following steps:
S1, preparation uvioresistant substrate (1)；
S2, in uvioresistant substrate (1) upper surface binding resin layer (2)；
S3, mold is made as needed；
S4, it texture is carried out on resin layer (2) using the mold made in step S3 transfers to form groove structure；
S5, Nano silver conductive ink, filamentary silver, nano ink are successively filled in the groove structure in step S4 according to design, according to
Secondary formation nano metal conductive material layer (4), metallic conducting material (5) and ink decorative layer (6) form conductor wire road network
Lattice；
S6, liquid crystal material layer (4) will be formed in liquid crystal injection metal grid electrode interlayer by the way of vacuum injection.
8. a kind of preparation method of toning glass with effectiveness according to claim 7, which is characterized in that
The step S1 specifically includes the following steps:
The preparation of S11, uvioresistant poly-vinegar layer: anti ultraviolet agent is dispersed in poly-vinegar base by situ aggregation method, is prepared anti-
Ultraviolet PET slice；
S12, sided corona treatment: sided corona treatment is carried out to the two sides of the step S11 uvioresistant poly-vinegar layer obtained；
The preparation of S13, silicon dioxide gel: using ethyl orthosilicate, dehydrated alcohol and water as raw material, using ammonium hydroxide as catalyst,
Stirring mixes it uniformly at 20 DEG C, and then mixed solution is put into closed container, constant temperature ageing；
S14, rotary plating: under rotational case, the corona treated surface in uvioresistant poly-vinegar layer is added dropwise in colloidal sol, is then accelerated
It rotates and keeps, obtain uvioresistant substrate (1) after solidification.
9. a kind of preparation method of toning glass with effectiveness according to claim 7, which is characterized in that
In the step S4, texture transfer specifically is carried out by the way of exposing UV resin.
10. a kind of preparation method of toning glass with effectiveness according to claim 7, feature exist
In specifically Nano silver conductive ink, filamentary silver, nano ink being successively filled by the way of intaglio printing in the step S5
Molding is sintered in groove structure, after filling.
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| CN201811207486.0A CN109085710A (en) | 2018-10-17 | 2018-10-17 | A kind of toning glass and preparation method thereof with effectiveness |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109922645A (en) * | 2019-03-06 | 2019-06-21 | 苏州蓝沛光电科技有限公司 | Transparency electromagnetic wave shield film structure and preparation method thereof |
| CN110836072A (en) * | 2019-11-28 | 2020-02-25 | 怀化市吉驷玻璃有限公司 | Environment-friendly energy-saving hollow glass |
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| CN106995282A (en) * | 2017-04-28 | 2017-08-01 | 江苏秀强玻璃工艺股份有限公司 | Golden yellow pattern printing ambetti of metal-like and preparation method thereof |
| CN206911687U (en) * | 2017-05-02 | 2018-01-23 | 比亚迪股份有限公司 | Glass decoration film, ambetti and electronic product |
| CN208780944U (en) * | 2018-10-17 | 2019-04-23 | 吴江友鑫新材料科技有限公司 | A kind of toning glass with effectiveness |
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| US20030042045A1 (en) * | 2001-08-28 | 2003-03-06 | Koskenmaki David C. | Embedded electrical traces and method for making |
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| CN110836072A (en) * | 2019-11-28 | 2020-02-25 | 怀化市吉驷玻璃有限公司 | Environment-friendly energy-saving hollow glass |
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