CN109082028A - A kind of preparation method for wrapping up metal PVC roll material - Google Patents
A kind of preparation method for wrapping up metal PVC roll material Download PDFInfo
- Publication number
- CN109082028A CN109082028A CN201810718580.6A CN201810718580A CN109082028A CN 109082028 A CN109082028 A CN 109082028A CN 201810718580 A CN201810718580 A CN 201810718580A CN 109082028 A CN109082028 A CN 109082028A
- Authority
- CN
- China
- Prior art keywords
- parts
- added
- pvc
- roll material
- wrapping
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/092—Polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
The present invention discloses a kind of preparation method for wrapping up metal PVC roll material, including following operating procedure: (1) after mixing dysprosia, gallium oxide, aluminium oxide, lanthana, ball-milling treatment, then obtained powder is pressed and molded, after sintering processes, it is crushed to 80-100 mesh again, intensive is made；(2) thulium chloride, cerium chloride are added into water, after being mixed evenly, dodecenylsuccinic acid di-potassium is added thereto, after being mixed evenly, isothermal holding, after going upper aqueous layer, intensive is added thereto, is mixed evenly, PVC modifier is made；(3) polyvinyl chloride resin, PVC modifier, antioxidant, plasticizer, inorganic filler are added into high-speed mixer, after over-mastication, tabletting, cutting processing, finished product.PVC roll material produced by the present invention, pliability is high, and tensile strength is high, is suitble to package metal to use, while having excellent wear-resisting property, greatly extends the service life of knitting.
Description
Technical field
The invention belongs to PVC roll material preparation technical fields, and in particular to a kind of preparation side for wrapping up metal PVC roll material
Method.
Background technique
Knitting refers to the product that people or machine are woven, the usually material with wicker, reed etc. with excellent toughness, with
The development of high polymer material technology and metal knitted technology, occur PVC package metal knitting, be first to compile metal
After being made into type, upper PVC roll material then is wound in metallic surface again, and knitting obtained is durable, waterproof, anticorrosion, resistance to
Ageing properties are excellent, such as outdoor chair lift, desk, tea table mostly use the method to be made greatly.But there is PVC for such knitting
The mechanical property of coiled material is poor, and especially tensile strength is lower and wear-resisting property is poor, causes the service life of knitting shorter.
Summary of the invention
In order to solve the above technical problem, the present invention provides a kind of preparation methods for wrapping up metal PVC roll material.
The present invention is achieved by the following technical solutions.
A kind of preparation method for wrapping up metal PVC roll material, including following operating procedure:
(1) by weight, 26-33 parts of dysprosias, 37-42 parts of gallium oxides, 46-55 parts of aluminium oxide, 1-4 parts of lanthanas are mixed
Afterwards, then obtained powder is pressed and molded by ball-milling treatment, after sintering processes, then be crushed to 80-100 mesh, is made and is reinforced
Agent；
(2) by weight, 14-19 parts of thulium chlorides, 23-26 parts of cerium chlorides are added into 140-190 parts of water, are mixed equal
After even, 40-48 parts of dodecenylsuccinic acid di-potassiums are added thereto, after being mixed evenly, are heated to 88-92 DEG C, heat preservation
After processing 3-4 hours, after going upper aqueous layer, 280-320 portions of intensives is added thereto, are mixed evenly, obtained PVC changes
Property agent；
(3) by weight, by 96-105 parts of polyvinyl chloride resins, 13-16 parts of PVC modifiers, 0.4-0.8 parts of antioxidant, 3-4 parts of increasings
Modeling agent, 10-16 parts of inorganic fillers are added into high-speed mixer, after over-mastication, tabletting, cutting processing, finished product.
Specifically, in above-mentioned steps (1), the temperature of sintering processes is 1400-1450 DEG C, and the time of sintering processes is 5-6
Hour.
Specifically, in above-mentioned steps (2), inorganic filler is precipitated calcium carbonate.
Specifically, in above-mentioned steps (3), temperature when tabletting is 145-150 DEG C, heating time 5min, pressure 12-
14MPa。
From the above technical scheme, it can be seen that the beneficial effects of the present invention are:
A kind of preparation method for wrapping up metal PVC roll material provided by the invention, easy to operate, low in cost, PVC roll obtained
Material, pliability is high, and tensile strength is high, is suitble to package metal to use, while having excellent wear-resisting property, greatly extends volume
The service life of fabric.Wherein, PVC modifier obtained in step (2), intensive and rare earth element synergistic effect therein
Afterwards, polyvinyl chloride resin consistency after molding can be effectively promoted, promotes the stability of PVC material dimensional network structure, and then effectively
Improve the tensile strength and wear-resisting property of PVC roll material obtained.
Specific embodiment
The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention.Reality used in the examples
The condition of applying can be for further adjustments according to the condition of producer, and unaccounted implementation condition is usually conventional laboratory conditions.
Embodiment 1
A kind of preparation method for wrapping up metal PVC roll material, including following operating procedure:
(1) by weight, after 26 parts of dysprosias, 37 parts of gallium oxides, 46 parts of aluminium oxide, 1 part of lanthana being mixed, at ball milling
Then obtained powder is pressed and molded by reason, after sintering processes, then be crushed to 80 mesh, and intensive is made；
(2) by weight, 14 parts of thulium chlorides, 23 parts of cerium chlorides are added into 140 parts of water, after being mixed evenly, Xiang Qi
40 parts of dodecenylsuccinic acid di-potassiums of middle addition, after being mixed evenly, after being heated to 88 DEG C, isothermal holding 3 hours, go
After upper aqueous layer, 280 portions of intensives are added thereto, are mixed evenly, PVC modifier is made；
(3) by weight, by 96 parts of polyvinyl chloride resins, 13 parts of PVC modifiers, 0.4 part of antioxidant, 3 parts of plasticizer, 10 parts it is inorganic
Filler is added into high-speed mixer, after over-mastication, tabletting, cutting processing, finished product.
Specifically, in above-mentioned steps (1), the temperature of sintering processes is 1400 DEG C, and the time of sintering processes is 5 hours.
Specifically, in above-mentioned steps (2), inorganic filler is precipitated calcium carbonate.
Specifically, in above-mentioned steps (3), temperature when tabletting is 145 DEG C, heating time 5min, pressure 12MPa.
Embodiment 2
A kind of preparation method for wrapping up metal PVC roll material, including following operating procedure:
(1) by weight, after 30 parts of dysprosias, 40 parts of gallium oxides, 50 parts of aluminium oxide, 3 parts of lanthanas being mixed, at ball milling
Then obtained powder is pressed and molded by reason, after sintering processes, then be crushed to 90 mesh, and intensive is made；
(2) by weight, 16 parts of thulium chlorides, 25 parts of cerium chlorides are added into 170 parts of water, after being mixed evenly, Xiang Qi
44 parts of dodecenylsuccinic acid di-potassiums of middle addition, after being mixed evenly, after being heated to 90 DEG C, isothermal holding 3.5 hours,
After going upper aqueous layer, 300 portions of intensives are added thereto, are mixed evenly, PVC modifier is made；
(3) by weight, by 100 parts of polyvinyl chloride resins, 15 parts of PVC modifiers, 0.6 part of antioxidant, 3 parts of plasticizer, 14 parts it is inorganic
Filler is added into high-speed mixer, after over-mastication, tabletting, cutting processing, finished product.
Specifically, in above-mentioned steps (1), the temperature of sintering processes is 1430 DEG C, and the time of sintering processes is 5.5 hours.
Specifically, in above-mentioned steps (2), inorganic filler is precipitated calcium carbonate.
Specifically, in above-mentioned steps (3), temperature when tabletting is 148 DEG C, heating time 5min, pressure 13MPa.
Embodiment 3
A kind of preparation method for wrapping up metal PVC roll material, including following operating procedure:
(1) by weight, after 33 parts of dysprosias, 42 parts of gallium oxides, 55 parts of aluminium oxide, 4 parts of lanthanas being mixed, at ball milling
Then obtained powder is pressed and molded by reason, after sintering processes, then be crushed to 100 mesh, and intensive is made；
(2) by weight, 19 parts of thulium chlorides, 26 parts of cerium chlorides are added into 190 parts of water, after being mixed evenly, Xiang Qi
48 parts of dodecenylsuccinic acid di-potassiums of middle addition, after being mixed evenly, after being heated to 92 DEG C, isothermal holding 4 hours, go
After upper aqueous layer, 320 portions of intensives are added thereto, are mixed evenly, PVC modifier is made；
(3) by weight, by 105 parts of polyvinyl chloride resins, 16 parts of PVC modifiers, 0.8 part of antioxidant, 4 parts of plasticizer, 16 parts it is inorganic
Filler is added into high-speed mixer, after over-mastication, tabletting, cutting processing, finished product.
Specifically, in above-mentioned steps (1), the temperature of sintering processes is 1450 DEG C, and the time of sintering processes is 6 hours.
Specifically, in above-mentioned steps (2), inorganic filler is precipitated calcium carbonate.
Specifically, in above-mentioned steps (3), temperature when tabletting is 150 DEG C, heating time 5min, pressure 14MPa.
Comparative example 1
Intensive obtained in the step of PVC modifier in step (3) is substituted for equivalent (1), remaining operating procedure and reality
It is identical to apply example 1.
PVC roll material is made with the method for each embodiment and comparative example respectively, then tests its properties, test result is such as
Shown in table 1:
The performance test of 1 PVC roll material of table
As shown in Table 1, PVC roll material made from the present embodiment, tensile strength is high, and hardness is high, effectively extends making for knitting
Use the service life.
Certainly, the above description is not a limitation of the present invention, and the present invention is also not limited to the example above, the art
Those of ordinary skill, within the essential scope of the present invention, variation, change, addition or the replacement made all should belong to the present invention
Protection scope.
Claims (4)
1. a kind of preparation method for wrapping up metal PVC roll material, which is characterized in that including following operating procedure:
(1) by weight, 26-33 parts of dysprosias, 37-42 parts of gallium oxides, 46-55 parts of aluminium oxide, 1-4 parts of lanthanas are mixed
Afterwards, then obtained powder is pressed and molded by ball-milling treatment, after sintering processes, then be crushed to 80-100 mesh, is made and is reinforced
Agent；
(2) by weight, 14-19 parts of thulium chlorides, 23-26 parts of cerium chlorides are added into 140-190 parts of water, are mixed equal
After even, 40-48 parts of dodecenylsuccinic acid di-potassiums are added thereto, after being mixed evenly, are heated to 88-92 DEG C, heat preservation
After processing 3-4 hours, after going upper aqueous layer, 280-320 portions of intensives is added thereto, are mixed evenly, obtained PVC changes
Property agent；
(3) by weight, by 96-105 parts of polyvinyl chloride resins, 13-16 parts of PVC modifiers, 0.4-0.8 parts of antioxidant, 3-4 parts of increasings
Modeling agent, 10-16 parts of inorganic fillers are added into high-speed mixer, after over-mastication, tabletting, cutting processing, finished product.
2. a kind of preparation method for wrapping up metal PVC roll material according to claim 1, which is characterized in that above-mentioned steps
(1) in, the temperature of sintering processes is 1400-1450 DEG C, and the time of sintering processes is 5-6 hours.
3. a kind of preparation method for wrapping up metal PVC roll material according to claim 1, which is characterized in that above-mentioned steps
(2) in, inorganic filler is precipitated calcium carbonate.
4. a kind of preparation method for wrapping up metal PVC roll material according to claim 1, which is characterized in that above-mentioned steps
(3) in, temperature when tabletting is 145-150 DEG C, heating time 5min, pressure 12-14MPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810718580.6A CN109082028B (en) | 2018-07-03 | 2018-07-03 | Preparation method of PVC (polyvinyl chloride) coiled material for wrapping metal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810718580.6A CN109082028B (en) | 2018-07-03 | 2018-07-03 | Preparation method of PVC (polyvinyl chloride) coiled material for wrapping metal |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109082028A true CN109082028A (en) | 2018-12-25 |
| CN109082028B CN109082028B (en) | 2020-12-11 |
Family
ID=64837250
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810718580.6A Active CN109082028B (en) | 2018-07-03 | 2018-07-03 | Preparation method of PVC (polyvinyl chloride) coiled material for wrapping metal |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109082028B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110408147A (en) * | 2019-08-01 | 2019-11-05 | 无锡天竺滑导电器制造有限公司 | A kind of heat-resisting anti-aging PVC pipe and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1844294A (en) * | 2006-04-24 | 2006-10-11 | 江阴市华宏橡塑厂 | Coloured PVC waterproof roll and its preparation method |
| CN105419161A (en) * | 2015-12-21 | 2016-03-23 | 潍坊市宏源防水材料有限公司 | Environment-friendly PVC (Polyvinyl Chloride) waterproof roll and preparation method thereof |
| JP2016198878A (en) * | 2015-04-07 | 2016-12-01 | 株式会社サンエス | Grind stone, processing device and processing method of workpiece |
| CN107603063A (en) * | 2017-09-26 | 2018-01-19 | 苏州富通高新材料科技股份有限公司 | A kind of technique for preparing special-shaped sheet material |
-
2018
- 2018-07-03 CN CN201810718580.6A patent/CN109082028B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1844294A (en) * | 2006-04-24 | 2006-10-11 | 江阴市华宏橡塑厂 | Coloured PVC waterproof roll and its preparation method |
| JP2016198878A (en) * | 2015-04-07 | 2016-12-01 | 株式会社サンエス | Grind stone, processing device and processing method of workpiece |
| CN105419161A (en) * | 2015-12-21 | 2016-03-23 | 潍坊市宏源防水材料有限公司 | Environment-friendly PVC (Polyvinyl Chloride) waterproof roll and preparation method thereof |
| CN107603063A (en) * | 2017-09-26 | 2018-01-19 | 苏州富通高新材料科技股份有限公司 | A kind of technique for preparing special-shaped sheet material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110408147A (en) * | 2019-08-01 | 2019-11-05 | 无锡天竺滑导电器制造有限公司 | A kind of heat-resisting anti-aging PVC pipe and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109082028B (en) | 2020-12-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103788409A (en) | Wear-resistant surface modified calcium carbonate filler | |
| ITMI20011062A1 (en) | FLUOROELASTOMERIC COMPOSITIONS | |
| CN104277415A (en) | Long-acting antibacterial amino molding compound | |
| CN102206390A (en) | Modification method for reinforcing polytetrafluoroethylene material through ekonol and aramid fiber | |
| CN103287004A (en) | Composite impermeable cloth for salt pond and preparation method thereof | |
| CN109082028A (en) | A kind of preparation method for wrapping up metal PVC roll material | |
| CN105440547A (en) | High-strength heat-resistant polyethylene tube material | |
| JP2011526948A5 (en) | ||
| CN103421261A (en) | Super-thick high-elasticity polytetrafluoroethylene sealing plate and production method thereof | |
| CN108084506A (en) | A kind of ageing-resistant native rubber composite material | |
| CN103772744B (en) | A kind of PVC sodium polyacrylate/triethanolamine modified calcium carbonate filler | |
| CN104403276A (en) | High-temperature-resistant and abrasion-resistant macromolecular material | |
| CN104708874A (en) | Formula for preparing environment-friendly plastic water hose | |
| CN107126085A (en) | A kind of corrosion resistant inner container of electric pressure cooker and its preparation technology | |
| CN104830029A (en) | High-temperature-resistant and abrasion-resistant high-polymer material | |
| KR101829449B1 (en) | Composition for fluororubber having excellent mechanical strength | |
| KR101262307B1 (en) | Chlorinated polyethylene resin and molded article manufactured using composition having the resin | |
| CN104910506B (en) | A kind of manufacture method of environment protection multifunctional macromolecule health material and its derived product | |
| CN108752789A (en) | A kind of chromoplastic material product and preparation method thereof | |
| CN104559053A (en) | Modified epoxy resin and application thereof | |
| CN103773104A (en) | Lanthanum oxide modified calcium carbonate filler for coating | |
| CN106883538A (en) | A kind of high pressure resistant exotic material and its preparation technology | |
| CN104877311A (en) | High-temperature-resistant and wear-resistant high-molecular material | |
| CN110845773A (en) | Preparation method of modified wear-resistant heat-resistant ECO rubber tube | |
| CN104419345A (en) | Rubber tackifier |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A preparation method of PVC coil for wrapping metal Effective date of registration: 20211029 Granted publication date: 20201211 Pledgee: Funan SME financing Company limited by guarantee Pledgor: FUNAN FUCHANG HENGYE GRAFTS Co.,Ltd. Registration number: Y2021980011579 |