CN108752789A - A kind of chromoplastic material product and preparation method thereof - Google Patents
A kind of chromoplastic material product and preparation method thereof Download PDFInfo
- Publication number
- CN108752789A CN108752789A CN201810535368.6A CN201810535368A CN108752789A CN 108752789 A CN108752789 A CN 108752789A CN 201810535368 A CN201810535368 A CN 201810535368A CN 108752789 A CN108752789 A CN 108752789A
- Authority
- CN
- China
- Prior art keywords
- chromoplastic
- accounts
- chromoplastic material
- material product
- percentage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
- C09K9/02—Organic tenebrescent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/10—Non-macromolecular compounds
- C09K2211/1018—Heterocyclic compounds
- C09K2211/1025—Heterocyclic compounds characterised by ligands
- C09K2211/1088—Heterocyclic compounds characterised by ligands containing oxygen as the only heteroatom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The present invention discloses a kind of chromoplastic material product and preparation method thereof, the chromoplastic material is by plastic body, colour-changing agent, photochromic material, oxidant and combination of stabilizers form, the photochromic material is that spiral shell adjoins class material of muttering, the plastic body accounts for the 35%-50% of the chromoplastic material mass percent, the colour-changing agent accounts for the 10%-15% of the chromoplastic material mass percent, the photochromic material accounts for the 5%-10% of the chromoplastic material mass percent, the oxidant accounts for the 3%-5% of the chromoplastic material mass percent, the stabilizer accounts for the 35%-40% of the chromoplastic material mass percent.The present invention provides a kind of chromoplastic material product, has the advantages that nontoxic and beautiful novel.
Description
Technical field
The present invention relates to a kind of chromoplastic material product and preparation method thereof more particularly to a kind of chromoplastic materials of life.
Background technology
Plastics are the high-molecular compound { polymer (polymer) } of synthesis, and can be described as macromolecule or giant molecule
(macromolecules), the plastics (plastics) or resin (resin) and being generally commonly called as, can freely change body
Pattern.It is the material using raw material monomer to synthesize or condensation reaction is polymerized, by synthetic resin and filler, plasticizer, steady
Determine the additives such as agent, lubricant, colorant composition.According to American Society for Testing Materials's definition, plastics be it is a kind of with
High molecular weight organic substancess material as main component, solid shape is presented when machining for it, manufacture and it is processed
Cheng Zhong can borrow flowing (flow) to carry out moulding.Therefore, understand through thus illustrating that we can obtain following items：1. it is high
Molecular organic compound, 2. it can with a variety of kenels exist such as liquid solid colloidal solution, 3. it can shape
(moldable), 4. types are various, because different monomers and its composition can synthesize different plastics, 5. widely used products
Diversification is presented.6. having different property.7. different processing methods (processingmethod), plastics and tree can be used
The two nouns of fat are also often used with.Plastics can divide into thermosetting property and two class of thermoplasticity, the former can not refigure use, the latter
It can duplication of production again and again.There are two types of types substantially for the high molecular structure of plastics：The first is linear structure；Second is build knot
Structure.
Invention content
A kind of chromoplastic material product of present invention offer and preparation method thereof has the advantages that nontoxic and beautiful novel.
The technical scheme is that：The chromoplastic material product is by plastic body, colour-changing agent, photochromic material
Material, oxidant and combination of stabilizers form, and the photochromic material is that spiral shell adjoins class material of muttering, the plastic products ontology
The 35%-50% of the chromoplastic material quality of item percentage is accounted for, the colour-changing agent accounts for the chromoplastic material product matter
The 10%-15% of percentage is measured, the photochromic material accounts for the 5%- of the chromoplastic material quality of item percentage
10%, the oxidant accounts for the 3%-5% of the chromoplastic material quality of item percentage, and the stabilizer accounts for described
The 35%-40% of chromoplastic material quality of item percentage
In a preferred embodiment of the invention, the stabilizer is liquid calcium zinc stabilizer, is in pale yellowish oil
Liquid.
In a preferred embodiment of the invention, the plastic body accounts for the chromoplastic material amount percentage
50%, the colour-changing agent accounts for the 10% of the chromoplastic material amount percentage, and the photochromic material accounts for the change
The 10% of color amount of plastic percentage, the stabilizer account for the 30% of the chromoplastic material amount percentage.
Specific implementation mode
The preferred embodiments of the present invention will be described in detail below so that advantages and features of the invention can be easier to by
It will be appreciated by those skilled in the art that so as to make a clearer definition of the protection scope of the present invention.
Wherein, the stabilizer is liquid calcium zinc stabilizer, is in pale yellowish oil liquid.Zinc stabilizer is by calcium salt, zinc
Salt, lubricant, antioxidant etc. are synthesized for key component using special combination process.It can not only replace lead cadmium salt class and have
The toxic stabilizers such as machine tin class, and there is fairly good thermal stability, photostability and the transparency and tinting strength, tinting power.Practice card
Bright, in polyvinyl chloride resin product, processing performance is good, and heat stabilization is equivalent to lead salt stabilizer, is a kind of good nontoxic steady
Determine agent.Liquid calcium zinc stabilizer usually has larger solubility, and has good dispersibility in PVC resin powder, to saturating
The influence of lightness is also far smaller than powder stabilizer.But the risk that liquid stabilisers have precipitation is larger.Selection is needed to be suitble to
Solvent.There are good dispersibility, compatibility, a processing fluidity, wide adaptability, product surface finish is excellent；Thermal stability is excellent
Good, initial stage form and aspect are small, no precipitation phenomenon；Without heavy metal and other toxic components, no sulfation；The Congo red testing time
It is long, there is excellent electrical insulating property, free from admixture to have efficient weatherability；Applied widely, highly practical, dosage is few, has more
It is functional.
It further illustrates, the off-color material of the light is that spiral shell adjoins class material of muttering, and spiral shell adjoins that mutter be organic photochromic material
One of middle research and earliest, the widest system of application, under ultraviolet light, colourless spiral shell adjoins the fracture of the mono- O keys of C in muttering structure
Open loop, molecule locally rotate and to form a coplanar merocyanine structure with crying to make an uproar and develop the color, and absorption spectrum is accordingly red
It moves.Under the action of visible light or heat, open loop body can be returned to spirane structure again.The rupture time of mono- O keys of C is in picosecond,
Color change is exceedingly fast.But merocyanine stores a few minutes to a few hours and will be automatically converted to colourless loop coil knot at room temperature
Structure, in addition, photochemistry side reaction can occur in stining inverse process, to influence the cycle-index of reversible transition, these deficiency limits
Spiral shell processed adjoins the application muttered in terms of photochemical molecular lock.
The specific implementation mode of the present invention, but scope of protection of the present invention is not limited thereto, any to be familiar with this field
Within the technical scope disclosed by the invention, changes or substitutions that can be made without creative work should all be contained technical staff
Lid is within protection scope of the present invention.Therefore, protection scope of the present invention should be to protect model defined by claims
Subject to enclosing.
Claims (3)
1. a kind of chromoplastic material product and preparation method thereof, it is characterised in that：The chromoplastic material product be by plastic body,
Colour-changing agent, photochromic material, oxidant and combination of stabilizers form, and the photochromic material is that spiral shell adjoins class material of muttering,
The plastic products ontology accounts for the 35%-50% of the chromoplastic material quality of item percentage, and the colour-changing agent accounts for institute
The 10%-15% for the chromoplastic material quality of item percentage stated, the photochromic material account for the chromoplastic material product
The 5%-10% of mass percent, the oxidant accounts for the 3%-5% of the chromoplastic material quality of item percentage, described
Stabilizer account for the 35%-40% of the chromoplastic material quality of item percentage.
2. chromoplastic material product process formula according to claim 1, it is characterised in that：The stabilizer is liquid calcium
Zinc stabilizer is in pale yellowish oil liquid.
3. chromoplastic material product process formula according to claim 1, it is characterised in that：The plastic products ontology accounts for
The 50% of the chromoplastic material product amount percentage, the colour-changing agent account for the chromoplastic material product amount percentage
10%, the photochromic material accounts for the 10% of the chromoplastic material product amount percentage, and the stabilizer accounts for described
Chromoplastic material product amount percentage 30%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810535368.6A CN108752789A (en) | 2018-05-30 | 2018-05-30 | A kind of chromoplastic material product and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810535368.6A CN108752789A (en) | 2018-05-30 | 2018-05-30 | A kind of chromoplastic material product and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108752789A true CN108752789A (en) | 2018-11-06 |
Family
ID=64003867
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810535368.6A Pending CN108752789A (en) | 2018-05-30 | 2018-05-30 | A kind of chromoplastic material product and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108752789A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109251554A (en) * | 2018-11-22 | 2019-01-22 | 遵义宏龙塑料有限责任公司 | Chromoplastic material process recipe |
| CN115368693A (en) * | 2022-09-30 | 2022-11-22 | 金发科技股份有限公司 | High-hardness gradient transparent PVC material and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102644125A (en) * | 2012-04-10 | 2012-08-22 | 山东银鹰化纤有限公司 | Method for preparing polychromatic viscose fibers |
| CN102993613A (en) * | 2012-07-16 | 2013-03-27 | 上海甘田光学材料有限公司 | Photochromic material as well as preparation method and application of photochromic material |
| CN103275509A (en) * | 2013-06-21 | 2013-09-04 | 苏州新区特氟龙塑料制品厂 | Color-changing plastic |
| CN103304912A (en) * | 2012-03-06 | 2013-09-18 | 上海百理物业管理有限公司 | Noctilucent plastic product |
| CN105111768A (en) * | 2015-09-18 | 2015-12-02 | 南通联恒新材料有限公司 | Technical formula of color changing plastic |
-
2018
- 2018-05-30 CN CN201810535368.6A patent/CN108752789A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103304912A (en) * | 2012-03-06 | 2013-09-18 | 上海百理物业管理有限公司 | Noctilucent plastic product |
| CN102644125A (en) * | 2012-04-10 | 2012-08-22 | 山东银鹰化纤有限公司 | Method for preparing polychromatic viscose fibers |
| CN102993613A (en) * | 2012-07-16 | 2013-03-27 | 上海甘田光学材料有限公司 | Photochromic material as well as preparation method and application of photochromic material |
| CN103275509A (en) * | 2013-06-21 | 2013-09-04 | 苏州新区特氟龙塑料制品厂 | Color-changing plastic |
| CN105111768A (en) * | 2015-09-18 | 2015-12-02 | 南通联恒新材料有限公司 | Technical formula of color changing plastic |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109251554A (en) * | 2018-11-22 | 2019-01-22 | 遵义宏龙塑料有限责任公司 | Chromoplastic material process recipe |
| CN115368693A (en) * | 2022-09-30 | 2022-11-22 | 金发科技股份有限公司 | High-hardness gradient transparent PVC material and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR102024491B1 (en) | PBAT resin composition | |
| CN108752789A (en) | A kind of chromoplastic material product and preparation method thereof | |
| CN104592757A (en) | High-flowability glass-fiber-reinforced polyphenyl thioether composite material based on nano forming technology | |
| CN111607213A (en) | Polycarbonate material and preparation method and application thereof | |
| WO2017152597A1 (en) | Pbat resin composition | |
| CN103865194A (en) | Application of environment-friendly calcium-zinc stabilizer on heavy-caliber PVC tubular product and PVC tubular product prepared by using stabilizer | |
| KR101100453B1 (en) | Thermoplastic Resin Composition Having Superior Flame Retardany, Coloring Property And Scratch-resistance | |
| CN109535523A (en) | A kind of antistatic HDPE plastic formula | |
| Fu et al. | A zinc Schiff base complex as high‐efficiency stabilizer for flexible poly (vinyl chloride) against thermal degradation | |
| CN109251554A (en) | Chromoplastic material process recipe | |
| CN103709684A (en) | High impact thermoplastic alloy for electronic and electric components and preparation method thereof | |
| CN105111768A (en) | Technical formula of color changing plastic | |
| CN103275509A (en) | Color-changing plastic | |
| CN105295242A (en) | Hydrotalcite composite environmental protection stabilizer for PVC, and preparation method thereof | |
| CN109401317B (en) | High-temperature-resistant color modified polyphenylene sulfide material and preparation method and application thereof | |
| KR101292350B1 (en) | Thermoplastic Resin Composition Having Superior Flame Retardany, Coloring Property And ScratchResistance | |
| CN115181392B (en) | Metal spraying-free ABS material with low humidity and heat aging resistance and low precipitation and preparation method thereof | |
| CN114163797A (en) | Yellow polycarbonate/styrene resin alloy composition and preparation method and application thereof | |
| CN114316755A (en) | Low-temperature curing low-light plane powder coating composition and coating thereof | |
| CN109735054B (en) | Smoke-inhibiting benzoxazine resin composition and preparation method thereof | |
| CN109054363A (en) | A kind of canned motor pump pump housing and its processing method | |
| CN107381510B (en) | A kind of production technology of rubber high quality insoluble sulphur | |
| CN105295249A (en) | Hydrotalcite-rare earth composite environmental protection stabilizer for PVC, and preparation method thereof | |
| KR100379882B1 (en) | Flame Retardant ABS Resin Composition | |
| US3538026A (en) | Process for preparing a stain-resistant molding composition comprising dry blending melamine per se and melamine-formaldehyde molding powder |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20181106 |