CN109535523A - A kind of antistatic HDPE plastic formula - Google Patents
A kind of antistatic HDPE plastic formula Download PDFInfo
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- CN109535523A CN109535523A CN201811416619.5A CN201811416619A CN109535523A CN 109535523 A CN109535523 A CN 109535523A CN 201811416619 A CN201811416619 A CN 201811416619A CN 109535523 A CN109535523 A CN 109535523A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of antistatic HDPE plastic formula, the raw material including following parts by weight: 30-50 parts of high-density polyethylene resin, 5-10 parts of antistatic agent, 10-15 parts of organic fiber, 3-8 parts of antioxidant, 4-9 parts of plasticizer, 6-11 parts of Corvic, 3-6 parts of polypropylene, 4-12 parts of synthetic resin, 5-10 parts of UV resistant agent, 6-13 parts of amino resins, 4-8 parts of heat-resistant agent, 2-8 parts of calcium carbonate, 3-9 parts of epoxy resin.HDPE plastic, which is made, in the present invention has antistatic, anti-oxidant, uvioresistant and heat-resisting performance, and intensity is high, and good toughness is wear-resisting, and corrosion-resistant, preparation method is simple.
Description
Technical field
The present invention relates to plastic applications more particularly to a kind of antistatic HDPE plastic formulas.
Background technique
Plastics are to pass through high-molecular compound made of addition polymerization or polycondensation polymerized using monomer as raw material
(macromolecules), ingredient and body styles can freely be changed, by synthetic resin and filler, plasticizer, stabilizer, profit
The additives such as lubrication prescription, colorant composition, the main component of plastics is resin.Resin refers to the high score not yet with various additives mixing
Sub- compound.This noun of resin is initially the lipid secreted out of by animals and plants and gains the name, such as rosin, shellac.Resin accounts for about
The 40%~100% of plastics total weight.The basic performance of plastics depends mainly on the person's character of resin, but additive also plays important work
With.Some plastics are substantially made of synthetic resin, are free of or are contained additive, such as organic glass, polystyrene less, existing
Some plastics mostly cannot be antistatic, cannot satisfy the use demand.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of antistatic HDPE plastic formulas.
A kind of antistatic HDPE plastic formula proposed by the present invention, the raw material including following parts by weight: high density polyethylene (HDPE)
30-50 parts of resin, 5-10 parts of antistatic agent, 10-15 parts of organic fiber, 3-8 parts of antioxidant, 4-9 parts of plasticizer, polyvinyl chloride
6-11 parts of resin, 3-6 parts of polypropylene, 4-12 parts of synthetic resin, 5-10 parts of UV resistant agent, 6-13 parts of amino resins, heat-resistant agent
4-8 parts, 2-8 parts of calcium carbonate, 3-9 parts of epoxy resin；
Preparation method includes the following steps:
S1: to high-density polyethylene resin, antistatic agent, organic fiber, antioxidant, plasticizer, Corvic, poly- third
Alkene, synthetic resin, UV resistant agent, amino resins, heat-resistant agent, calcium carbonate, epoxy resin are weighed；
S2: by high-density polyethylene resin, antistatic agent, organic fiber, antioxidant, plasticizer, the polyvinyl chloride after weighing
Resin, polypropylene, synthetic resin, UV resistant agent, amino resins, heat-resistant agent, calcium carbonate, epoxy resin are successively put mixing into and are stirred
It mixes in machine and is mixed, mixing time 20-40min, blender revolving speed is 800-900r/min, and mixture is made；
S3: electric heating, shearing are carried out to me is mixed, makes mixture melting mixing, then puts melt in extruder into, pass through extrusion
The die head die hole of machine squeezes out, cooling, and machining examines qualification to can be prepared by antistatic HDPE plastic.
Preferably, the raw material including following parts by weight: 32-48 parts of high-density polyethylene resin, has 7-9 parts of antistatic agent
11-14 parts of machine fiber, 4-7 parts of antioxidant, 5-8 parts of plasticizer, 7-10 parts of Corvic, 4-5 parts of polypropylene, synthesis tree
5-11 parts of rouge, 6-11 parts of UV resistant agent, 7-12 parts of amino resins, 5-7 parts of heat-resistant agent, 3-7 parts of calcium carbonate, epoxy resin 4-8
Part.
Preferably, the high-density polyethylene resin, antistatic agent, organic fiber, antioxidant, plasticizer, polychlorostyrene second
Olefine resin, polyacrylic weight ratio are 32-48:7-9:11-14:4-7:5-8:7-10:4-5.
Preferably, the weight of the synthetic resin, UV resistant agent, amino resins, heat-resistant agent, calcium carbonate, epoxy resin
Than for 5-11:6-11:7-12:5-7:3-7:4-8.
Preferably, in the S2, by the high-density polyethylene resin, antistatic agent, organic fiber, anti-oxidant after weighing
Agent, plasticizer, Corvic, polypropylene, synthetic resin, UV resistant agent, amino resins, heat-resistant agent, calcium carbonate, epoxy
Resin is successively put into mixing and blending machine and is mixed, mixing time 22-38min, and blender revolving speed is 820-880r/
Mixture is made in min.
Preferably, in the S1, using electronic balance or continuous electronic weighing balance successively to high-density polyethylene resin, anti-
Electrostatic agent, organic fiber, antioxidant, plasticizer, Corvic, polypropylene, synthetic resin, UV resistant agent, amino
Resin, heat-resistant agent, calcium carbonate, epoxy resin are weighed.
Preferably, it in the S3, is cooled and solidified using the material that recirculated water or air squeeze out extruder.
Preferably, in the S3, material after cooling is placed in machine table, is processed into the size of needs, and to material
The appearance of material is tested.
The beneficial effects of the present invention are:
By higher as raw material hardness, tensile strength and creep properties using high density polyethylene (HDPE)；Wearability, electrical insulating property, toughness and
Cold resistance is preferable；Chemical stability is good, at room temperature, does not dissolve in any organic solvent, the corruption of acid and alkali resistance and various salts
Erosion, by that can have antistatic, anti-oxidant, anti-purple using antistatic agent, antioxidant, UV resistant agent, heat-resistant agent as raw material
Outside line and heat-resisting performance, by that can increase by force by raw material of Corvic, epoxy resin, calcium carbonate and organic fiber
Degree and toughness, HDPE plastic, which is made, in the present invention has antistatic, anti-oxidant, uvioresistant and heat-resisting performance, and intensity is high, toughness
Good, wear-resisting, corrosion-resistant, preparation method is simple.
Specific embodiment
Combined with specific embodiments below the present invention is made further to explain.
Embodiment one
The invention proposes a kind of antistatic HDPE plastic formula, the raw materials including following parts by weight: high-density polyethylene resin
30 parts, 5 parts of antistatic agent, 10 parts of organic fiber, 3 parts of antioxidant, 4 parts of plasticizer, 6 parts of Corvic, polypropylene 3
Part, 4 parts of synthetic resin, 5 parts of UV resistant agent, 6 parts of amino resins, 4 parts of heat-resistant agent, 2 parts of calcium carbonate, 3 parts of epoxy resin；
Preparation method includes the following steps:
S1: to high-density polyethylene resin, antistatic agent, organic fiber, antioxidant, plasticizer, Corvic, poly- third
Alkene, synthetic resin, UV resistant agent, amino resins, heat-resistant agent, calcium carbonate, epoxy resin are weighed；
S2: by high-density polyethylene resin, antistatic agent, organic fiber, antioxidant, plasticizer, the polyvinyl chloride after weighing
Resin, polypropylene, synthetic resin, UV resistant agent, amino resins, heat-resistant agent, calcium carbonate, epoxy resin are successively put mixing into and are stirred
It mixes in machine and is mixed, mixing time 20min, blender revolving speed is 800r/min, and mixture is made；
S3: electric heating, shearing are carried out to me is mixed, makes mixture melting mixing, then puts melt in extruder into, pass through extrusion
The die head die hole of machine squeezes out, cooling, and machining examines qualification to can be prepared by antistatic HDPE plastic.
Embodiment two
The invention proposes a kind of antistatic HDPE plastic formula, the raw materials including following parts by weight: high-density polyethylene resin
35 parts, 6 parts of antistatic agent, 11 parts of organic fiber, 4 parts of antioxidant, 5 parts of plasticizer, 7 parts of Corvic, polypropylene 4
Part, 5 parts of synthetic resin, 6 parts of UV resistant agent, 7 parts of amino resins, 5 parts of heat-resistant agent, 3 parts of calcium carbonate, 4 parts of epoxy resin；
Preparation method includes the following steps:
S1: to high-density polyethylene resin, antistatic agent, organic fiber, antioxidant, plasticizer, Corvic, poly- third
Alkene, synthetic resin, UV resistant agent, amino resins, heat-resistant agent, calcium carbonate, epoxy resin are weighed；
S2: by high-density polyethylene resin, antistatic agent, organic fiber, antioxidant, plasticizer, the polyvinyl chloride after weighing
Resin, polypropylene, synthetic resin, UV resistant agent, amino resins, heat-resistant agent, calcium carbonate, epoxy resin are successively put mixing into and are stirred
It mixes in machine and is mixed, mixing time 25min, blender revolving speed is 830r/min, and mixture is made；
S3: electric heating, shearing are carried out to me is mixed, makes mixture melting mixing, then puts melt in extruder into, pass through extrusion
The die head die hole of machine squeezes out, cooling, and machining examines qualification to can be prepared by antistatic HDPE plastic.
Embodiment three
The invention proposes a kind of antistatic HDPE plastic formula, the raw materials including following parts by weight: high-density polyethylene resin
45 parts, 9 parts of antistatic agent, 14 parts of organic fiber, 7 parts of antioxidant, 8 parts of plasticizer, 10 parts of Corvic, polypropylene 5
Part, 11 parts of synthetic resin, 9 parts of UV resistant agent, 12 parts of amino resins, 7 parts of heat-resistant agent, 7 parts of calcium carbonate, 8 parts of epoxy resin；
Preparation method includes the following steps:
S1: to high-density polyethylene resin, antistatic agent, organic fiber, antioxidant, plasticizer, Corvic, poly- third
Alkene, synthetic resin, UV resistant agent, amino resins, heat-resistant agent, calcium carbonate, epoxy resin are weighed；
S2: by high-density polyethylene resin, antistatic agent, organic fiber, antioxidant, plasticizer, the polyvinyl chloride after weighing
Resin, polypropylene, synthetic resin, UV resistant agent, amino resins, heat-resistant agent, calcium carbonate, epoxy resin are successively put mixing into and are stirred
It mixes in machine and is mixed, mixing time 38min, blender revolving speed is 880r/min, and mixture is made；
S3: electric heating, shearing are carried out to me is mixed, makes mixture melting mixing, then puts melt in extruder into, pass through extrusion
The die head die hole of machine squeezes out, cooling, and machining examines qualification to can be prepared by antistatic HDPE plastic.
Example IV
The invention proposes a kind of antistatic HDPE plastic formula, the raw materials including following parts by weight: high-density polyethylene resin
50 parts, 10 parts of antistatic agent, 15 parts of organic fiber, 8 parts of antioxidant, 9 parts of plasticizer, 11 parts of Corvic, polypropylene 6
Part, 12 parts of synthetic resin, 10 parts of UV resistant agent, 13 parts of amino resins, 8 parts of heat-resistant agent, 8 parts of calcium carbonate, 9 parts of epoxy resin；
Preparation method includes the following steps:
S1: to high-density polyethylene resin, antistatic agent, organic fiber, antioxidant, plasticizer, Corvic, poly- third
Alkene, synthetic resin, UV resistant agent, amino resins, heat-resistant agent, calcium carbonate, epoxy resin are weighed；
S2: by high-density polyethylene resin, antistatic agent, organic fiber, antioxidant, plasticizer, the polyvinyl chloride after weighing
Resin, polypropylene, synthetic resin, UV resistant agent, amino resins, heat-resistant agent, calcium carbonate, epoxy resin are successively put mixing into and are stirred
It mixes in machine and is mixed, mixing time 40min, blender revolving speed is 900r/min, and mixture is made；
S3: electric heating, shearing are carried out to me is mixed, makes mixture melting mixing, then puts melt in extruder into, pass through extrusion
The die head die hole of machine squeezes out, cooling, and machining examines qualification to can be prepared by antistatic HDPE plastic.
The antistatic HDPE plastic as made from embodiment one, two, three, four compared with traditional plastics have it is antistatic,
Anti-oxidant, uvioresistant and heat-resisting performance, intensity is high, and good toughness is wear-resisting, and corrosion-resistant, preparation method is simple.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (8)
1. a kind of antistatic HDPE plastic formula, which is characterized in that the raw material including following parts by weight: high-density polyethylene resin
30-50 parts, 5-10 parts of antistatic agent, 10-15 parts of organic fiber, 3-8 parts of antioxidant, 4-9 parts of plasticizer, Corvic
6-11 parts, 3-6 parts of polypropylene, 4-12 parts of synthetic resin, 5-10 parts of UV resistant agent, 6-13 parts of amino resins, heat-resistant agent 4-8
Part, 2-8 parts of calcium carbonate, 3-9 parts of epoxy resin；
Preparation method includes the following steps:
S1: to high-density polyethylene resin, antistatic agent, organic fiber, antioxidant, plasticizer, Corvic, poly- third
Alkene, synthetic resin, UV resistant agent, amino resins, heat-resistant agent, calcium carbonate, epoxy resin are weighed；
S2: by high-density polyethylene resin, antistatic agent, organic fiber, antioxidant, plasticizer, the polyvinyl chloride after weighing
Resin, polypropylene, synthetic resin, UV resistant agent, amino resins, heat-resistant agent, calcium carbonate, epoxy resin are successively put mixing into and are stirred
It mixes in machine and is mixed, mixing time 20-40min, blender revolving speed is 800-900r/min, and mixture is made；
S3: electric heating, shearing are carried out to me is mixed, makes mixture melting mixing, then puts melt in extruder into, pass through extrusion
The die head die hole of machine squeezes out, cooling, and machining examines qualification to can be prepared by antistatic HDPE plastic.
2. a kind of antistatic HDPE plastic formula according to claim 1, which is characterized in that the original including following parts by weight
Material: 32-48 parts of high-density polyethylene resin, 7-9 parts of antistatic agent, 11-14 parts of organic fiber, 4-7 parts of antioxidant, plasticizer
5-8 parts, 7-10 parts of Corvic, 4-5 parts of polypropylene, 5-11 parts of synthetic resin, 6-11 parts of UV resistant agent, amino resins
7-12 parts, 5-7 parts of heat-resistant agent, 3-7 parts of calcium carbonate, 4-8 parts of epoxy resin.
3. a kind of antistatic HDPE plastic formula according to claim 1, which is characterized in that the high density polyethylene (HDPE) tree
Rouge, antistatic agent, organic fiber, antioxidant, plasticizer, Corvic, polyacrylic weight ratio are 32-48:7-9:
11-14:4-7:5-8:7-10:4-5.
4. a kind of antistatic HDPE plastic formula according to claim 1, which is characterized in that the synthetic resin, anti-purple
Outside line agent, amino resins, heat-resistant agent, calcium carbonate, epoxy resin weight ratio be 5-11:6-11:7-12:5-7:3-7:4-8.
5. a kind of antistatic HDPE plastic formula according to claim 1, which is characterized in that in the S2, after weighing
High-density polyethylene resin, antistatic agent, organic fiber, antioxidant, plasticizer, Corvic, polypropylene, synthesis
Resin, UV resistant agent, amino resins, heat-resistant agent, calcium carbonate, epoxy resin are successively put into carry out mixing in mixing and blending machine and be stirred
It mixes, mixing time 22-38min, blender revolving speed is 820-880r/min, and mixture is made.
6. a kind of antistatic HDPE plastic formula according to claim 1, which is characterized in that in the S1, use electronics
Balance or continuous electronic weighing balance successively to high-density polyethylene resin, antistatic agent, organic fiber, antioxidant, plasticizer,
Corvic, polypropylene, synthetic resin, UV resistant agent, amino resins, heat-resistant agent, calcium carbonate, epoxy resin are claimed
Amount.
7. a kind of antistatic HDPE plastic formula according to claim 1, which is characterized in that in the S3, use circulation
The material that water or air squeeze out extruder cools and solidifies.
8. a kind of antistatic HDPE plastic formula according to claim 1, which is characterized in that in the S3, after cooling
Material be placed in machine table, be processed into the size of needs, and test to the appearance of material.
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| CN201811416619.5A CN109535523A (en) | 2018-11-26 | 2018-11-26 | A kind of antistatic HDPE plastic formula |
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| CN201811416619.5A CN109535523A (en) | 2018-11-26 | 2018-11-26 | A kind of antistatic HDPE plastic formula |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110343401A (en) * | 2019-08-07 | 2019-10-18 | 重庆市腾业塑料制品有限公司 | A kind of food pack and its production method |
| CN110577694A (en) * | 2019-09-27 | 2019-12-17 | 江苏松德生物科技有限公司 | Formula and production process of bottle for high-molecular lubricating liquid |
| CN111793278A (en) * | 2020-07-22 | 2020-10-20 | 上海樱花塑料制品有限公司 | Preparation process and formula of corrosion-resistant ton barrel |
| CN112226002A (en) * | 2020-09-29 | 2021-01-15 | 重庆联祥融合塑业股份有限公司 | Preparation process of wear-resistant antioxidant plastic |
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| CN110343401A (en) * | 2019-08-07 | 2019-10-18 | 重庆市腾业塑料制品有限公司 | A kind of food pack and its production method |
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| CN111793278A (en) * | 2020-07-22 | 2020-10-20 | 上海樱花塑料制品有限公司 | Preparation process and formula of corrosion-resistant ton barrel |
| CN112226002A (en) * | 2020-09-29 | 2021-01-15 | 重庆联祥融合塑业股份有限公司 | Preparation process of wear-resistant antioxidant plastic |
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