CN109054595A - A kind of environment protection oil paint and preparation method thereof - Google Patents
A kind of environment protection oil paint and preparation method thereof Download PDFInfo
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- CN109054595A CN109054595A CN201810596950.3A CN201810596950A CN109054595A CN 109054595 A CN109054595 A CN 109054595A CN 201810596950 A CN201810596950 A CN 201810596950A CN 109054595 A CN109054595 A CN 109054595A
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- mixed liquor
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of environment protection oil paint, the raw material including following parts by weight: epoxy acrylate, urethane acrylate, ethyl acetate, turpentine oil, ethylene glycol, polyacrylamide thickeners, defoaming agent, fire retardant, organosilicon levelling agent and dispersing agent；Using environment protection oil paint prepared by above-mentioned raw materials, the environment protection oil paint produced compared with the prior art can reduce VOC content, and use rear non-toxic and tasteless, non-environmental-pollution, the addition of preservative, fire retardant, sterilization, mould proof effect can be played, and fire protecting performance is superior, has a good application prospect.
Description
Technical field
The present invention relates to decoration material field, more particularly to a kind of environment protection oil paint and preparation method thereof.
Background technique
Paint be it is a kind of can securely be covered on body surface, the chemistry for playing protection, decoration, mark and other specific uses is mixed
Close object coating.VOC, that is, volatile organic compounds has tremendous influence to human health.When the VOC in room reaches a certain concentration
When, people can feel headache, Nausea and vomiting, out of strength etc. in the short time, will appear twitch, stupor when serious, and can hurt people
Liver, kidney, brain and nervous system, cause the serious consequences such as failure of memory.Paint is that fitting-up in the process can not
Or scarce material.Paint used in decoration design for residence process is one of the main source of indoor VOC.Due to living standard
It improves, and environmentally friendly cry grows to even greater heights, requirement of the people to paint for decoration is higher and higher.But paint in the market contains mostly
VOC, it is very big using rear taste, the health of consumer is affected to a certain extent.The development of current coating is made every effort to meet " 4E " original
Then, i.e. economy, efficiency, ecology, the energy, on the basis of this principle, the product structure of building coating could constantly change with it is complete
It is kind.Meanwhile the content of VOC is reduced, it is the total of building coating development to ensure that building coating meets the requirement of Environmental Safety performance
Trend.In order to cooperate this development trend, health, the paint of Environmental Safety are used there is an urgent need to a kind of.
Therefore, the problem of how a kind of environment protection oil paint and preparation method thereof is provided, is those skilled in the art's urgent need to resolve.
Summary of the invention
In view of this, to realize reduction VOC content, using rear non-toxic and tasteless, nothing the present invention provides a kind of environment protection oil paint
The purpose of environmental pollution.
To achieve the goals above, the present invention adopts the following technical scheme:
A kind of environment protection oil paint, the raw material including following parts by weight: 25-32 parts of epoxy acrylate, urethane acrylate
25-28 parts, 6~10 parts of ethyl acetate, 5-10 parts of turpentine oil, 20-30 parts of ethylene glycol, 4~10 parts of polyacrylamide thickeners, disappear
12~20 parts of infusion, 8~15 parts of fire retardant, 3~7 parts of organosilicon levelling agent and 10-17 parts of dispersing agent.
Preferably, epoxy acrylate 25-30 parts, 25-28 parts of urethane acrylate, 6~10 parts of ethyl acetate, turpentine
5-10 parts oily, 20-30 parts of ethylene glycol, 4~10 parts of polyacrylamide thickeners, 12~20 parts of defoaming agent, 8~15 parts of fire retardant,
2.5~5 parts and dispersing agent 10-17 parts of organosilicon levelling agent.
Preferably, 28 parts of epoxy acrylate, 26 parts of urethane acrylate, 8 parts of ethyl acetate, 8 parts of turpentine oil, second two
22 parts of alcohol, 5 parts of polyacrylamide thickeners, 15 parts of defoaming agent, 10 parts of fire retardant, 3 parts of organosilicon levelling agent and 14 parts of dispersing agent.
Preferably, dispersing agent is one of ammonium polyacrylate salt, polycarboxylic acids ammonium salt and polyacrylic acid sodium salt or a variety of
Mixture.
Preferably, fire retardant is inorganic mixing fire retardant or ammonium polyphosphate or magnesium hydroxide.
A kind of preparation method of environment protection oil paint based on above-mentioned raw materials, comprising the following steps:
Step 1: epoxy acrylate, urethane acrylate, ethyl acetate, turpentine oil, ethylene glycol are mixed, true
It is stirred in empty blender, the stirring rod revolution speed 80-100r/min of blender, while the dispersion impeller rotational velocity of blender is
600-2500r/min, stirring 2-3h obtain mixed liquor one；
Step 2: mixed liquor one is added in grinder, 40min is ground, the speed of grinding is 800r/min, of grinding
Grain diameter≤30 μm；
Step 3: the mixed liquor after step 2 is ground is added in reaction kettle, levelling agent and dispersing agent, reaction kettle are added
Reaction temperature be 80-120 DEG C, react 3-5h, obtain mixed liquor two；
It is stirred Step 4: importing mixed liquor two in the de-airing mixer equipped with fire retardant, it is mixed that organic solvent adjusting is added
The viscosity of liquid is closed, is controlled in 90-110s；
Step 5: defoaming agent, polyacrylamide thickeners are added into the mixed liquor that step 4 obtains, with stirring for blender
Mixing bar revolution speed is 18~24r/min, stirs 35~55min, obtains finished product.
It can be seen via above technical scheme that compared with prior art, the present disclosure provides a kind of environment protection oil paint and
Preparation method, the environment protection oil paint produced compared with the prior art can reduce VOC content, and using rear non-toxic and tasteless, acyclic
Border pollution, paint film is water-fast, scrub resistance is good；The addition of preservative, fire retardant can play sterilization, mould proof effect, and prevent fires
Superior performance.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
The invention discloses a kind of environment protection oil paint, have the effect of using rear non-toxic and tasteless, non-environmental-pollution, and anti-corrosion
Agent, the addition of fire retardant can play the role of sterilization, mould proof, fireproof, have a good application prospect.
Embodiment 1
A kind of environment protection oil paint, the raw material including following parts by weight: 25 parts of epoxy acrylate, urethane acrylate 25
Part, 6 parts of ethyl acetate, 5 parts of turpentine oil, 20 parts of ethylene glycol, 4 parts of polyacrylamide thickeners, 12 parts of defoaming agent, 8 parts of fire retardant,
3 parts and 10 parts of dispersing agent of organosilicon levelling agent.
A kind of preparation method of environment protection oil paint based on above-mentioned raw materials, sequentially includes the following steps:
Step 1: epoxy acrylate, urethane acrylate, ethyl acetate, turpentine oil, ethylene glycol are mixed, true
It is stirred in empty blender, the stirring rod revolution speed 80-100r/min of blender, while the dispersion impeller rotational velocity of blender is
600-2500r/min, stirring 2-3h obtain mixed liquor one；
Step 2: mixed liquor one is added in grinder, 40min is ground, the speed of grinding is 800r/min, of grinding
Grain diameter≤30 μm；
Step 3: the mixed liquor after step 2 is ground is added in reaction kettle, levelling agent and dispersing agent, reaction kettle are added
Reaction temperature be 85 DEG C, react 5h, obtain mixed liquor two；
It is stirred Step 4: importing mixed liquor two in the de-airing mixer equipped with fire retardant, it is mixed that organic solvent adjusting is added
The viscosity of liquid is closed, is controlled in 90-110s；
Step 5: defoaming agent, polyacrylamide thickeners are added into the mixed liquor that step 4 obtains, with stirring for blender
Mixing bar revolution speed is 18~24r/min, stirs 35min, obtains finished product.
Embodiment 2
A kind of environment protection oil paint, the raw material including following parts by weight: 28 parts of epoxy acrylate, urethane acrylate 26
Part, 8 parts of ethyl acetate, 8 parts of turpentine oil, 25 parts of ethylene glycol, 6 parts of polyacrylamide thickeners, 15 parts of defoaming agent, fire retardant 10
Part, 5 parts of organosilicon levelling agent and 12 parts of dispersing agent.
A kind of preparation method of environment protection oil paint based on above-mentioned raw materials, sequentially includes the following steps:
Step 1: epoxy acrylate, urethane acrylate, ethyl acetate, turpentine oil, ethylene glycol are mixed, true
It is stirred in empty blender, the stirring rod revolution speed 80-100r/min of blender, while the dispersion impeller rotational velocity of blender is
600-2500r/min, stirring 2-3h obtain mixed liquor one；
Step 2: mixed liquor one is added in grinder, 40min is ground, the speed of grinding is 800r/min, of grinding
Grain diameter≤30 μm；
Step 3: the mixed liquor after step 2 is ground is added in reaction kettle, levelling agent and dispersing agent, reaction kettle are added
Reaction temperature be 100 DEG C, react 4h, obtain mixed liquor two；
It is stirred Step 4: importing mixed liquor two in the de-airing mixer equipped with fire retardant, it is mixed that organic solvent adjusting is added
The viscosity of liquid is closed, is controlled in 90-110s；
Step 5: defoaming agent, polyacrylamide thickeners are added into the mixed liquor that step 4 obtains, with stirring for blender
Mixing bar revolution speed is 18~24r/min, stirs 45min, obtains finished product.
Embodiment 3
A kind of environment protection oil paint, the raw material including following parts by weight: 32 parts of epoxy acrylate, urethane acrylate 28
Part, 10 parts of ethyl acetate, 10 parts of turpentine oil, 30 parts of ethylene glycol, 10 parts of polyacrylamide thickeners, 20 parts of defoaming agent, fire retardant
15 parts, 7 parts of organosilicon levelling agent and 17 parts of dispersing agent.
A kind of preparation method of environment protection oil paint based on above-mentioned raw materials, sequentially includes the following steps:
Step 1: epoxy acrylate, urethane acrylate, ethyl acetate, turpentine oil, ethylene glycol are mixed, true
It is stirred in empty blender, the stirring rod revolution speed 80-100r/min of blender, while the dispersion impeller rotational velocity of blender is
600-2500r/min, stirring 2-3h obtain mixed liquor one；
Step 2: mixed liquor one is added in grinder, 40min is ground, the speed of grinding is 800r/min, of grinding
Grain diameter≤30 μm；
Step 3: the mixed liquor after step 2 is ground is added in reaction kettle, levelling agent and dispersing agent, reaction kettle are added
Reaction temperature be 120 DEG C, react 3h, obtain mixed liquor two；
It is stirred Step 4: importing mixed liquor two in the de-airing mixer equipped with fire retardant, it is mixed that organic solvent adjusting is added
The viscosity of liquid is closed, is controlled in 90-110s；
Step 5: defoaming agent, polyacrylamide thickeners are added into the mixed liquor that step 4 obtains, with stirring for blender
Mixing bar revolution speed is 18~24r/min, stirs 55min, obtains finished product.
Performance detection is carried out to environment protection oil paint made from 1-3 of the embodiment of the present invention, testing result is shown in Table 1.
Table 1
Each embodiment in this specification is described in a progressive manner, the highlights of each of the examples are with other
The difference of embodiment, the same or similar parts in each embodiment may refer to each other.For device disclosed in embodiment
For, since it is corresponded to the methods disclosed in the examples, so being described relatively simple, related place is said referring to method part
It is bright.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention.
Various modifications to these embodiments will be readily apparent to those skilled in the art, as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention
It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one
The widest scope of cause.
Claims (6)
1. a kind of environment protection oil paint, which is characterized in that the raw material including following parts by weight: 25-32 parts of epoxy acrylate, polyurethane
25-28 parts of acrylate, 6-10 parts of ethyl acetate, 5-10 parts of turpentine oil, 20-30 parts of ethylene glycol, polyacrylamide thickeners 4-
10 parts, 12-20 parts of defoaming agent, 6-10 parts of preservative, 8-15 parts of fire retardant, 3-7 parts of organosilicon levelling agent and dispersing agent 10-17
Part.
2. a kind of environment protection oil paint according to claim 1, which is characterized in that the raw material including following parts by weight: epoxy third
25-30 parts of olefin(e) acid ester, 25-27 parts of urethane acrylate, 6-8 parts of ethyl acetate, 5-8 parts of turpentine oil, 20-28 parts of ethylene glycol,
4-7 parts of polyacrylamide thickeners, 12-18 parts of defoaming agent, 6-8 parts of preservative, 8-12 parts of fire retardant, organosilicon levelling agent 3-5
Part and dispersing agent 10-15 parts.
3. a kind of environment protection oil paint according to claim 1, which is characterized in that the raw material including following parts by weight: epoxy third
28 parts of olefin(e) acid ester, 26 parts of urethane acrylate, 8 parts of ethyl acetate, 8 parts of turpentine oil, 22 parts of ethylene glycol, polyacrylamide thickening
5 parts of agent, 15 parts of defoaming agent, 8 parts of preservative, 10 parts of fire retardant, 3 parts of organosilicon levelling agent and 14 parts of dispersing agent.
4. a kind of environment protection oil paint according to claim 1-3, which is characterized in that dispersing agent is ammonium polyacrylate
One of salt, polycarboxylic acids ammonium salt and polyacrylic acid sodium salt or a variety of mixtures.
5. a kind of environment protection oil paint according to claim 1-3, which is characterized in that fire retardant is that inorganic mixing is fire-retardant
Agent or ammonium polyphosphate or magnesium hydroxide.
6. a kind of preparation method of environment protection oil paint, which comprises the following steps:
Step 1: epoxy acrylate, urethane acrylate, ethyl acetate, turpentine oil, ethylene glycol are mixed, stirred in vacuum
It mixes in machine and stirs, the stirring rod revolution speed 80-100r/min of blender, while the dispersion impeller rotational velocity of blender is 600-
2500r/min, stirring 2-3h obtain mixed liquor one；
Step 2: mixed liquor one is added in grinder, 40min is ground, the speed of grinding is 800r/min, and the particle of grinding is straight
Diameter≤30 μm；
Step 3: mixed liquor after step 2 is ground is added in reaction kettle, add levelling agent and dispersing agent, reaction kettle it is anti-
Answering temperature is 80-120 DEG C, reacts 3-5h, obtains mixed liquor two；
It is stirred Step 4: importing mixed liquor two in the de-airing mixer equipped with fire retardant, organic solvent is added and adjusts mixed liquor
Viscosity, control in 90-110s；
Step 5: defoaming agent, polyacrylamide thickeners are added into the mixed liquor that step 4 obtains, with the stirring rod of blender
Revolution speed is 18~24r/min, stirs 35~55min, obtains finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810596950.3A CN109054595A (en) | 2018-06-11 | 2018-06-11 | A kind of environment protection oil paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810596950.3A CN109054595A (en) | 2018-06-11 | 2018-06-11 | A kind of environment protection oil paint and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN109054595A true CN109054595A (en) | 2018-12-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810596950.3A Pending CN109054595A (en) | 2018-06-11 | 2018-06-11 | A kind of environment protection oil paint and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114163917A (en) * | 2021-11-05 | 2022-03-11 | 书香门地集团股份有限公司 | Environment-friendly flame-retardant material for plates and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105255353A (en) * | 2015-10-09 | 2016-01-20 | 安徽嘉年华漆业有限公司 | High-strength impact resistance oil paint |
| CN106978048A (en) * | 2017-03-29 | 2017-07-25 | 合肥天沃能源科技有限公司 | A kind of energy saving paint and preparation method thereof |
| CN107699135A (en) * | 2017-10-25 | 2018-02-16 | 成都森钰泓绿化工程有限公司 | A kind of fireproof flame resistance paint |
| CN107760203A (en) * | 2017-10-25 | 2018-03-06 | 成都森钰泓绿化工程有限公司 | A kind of preparation method of fireproof flame resistance paint |
-
2018
- 2018-06-11 CN CN201810596950.3A patent/CN109054595A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105255353A (en) * | 2015-10-09 | 2016-01-20 | 安徽嘉年华漆业有限公司 | High-strength impact resistance oil paint |
| CN106978048A (en) * | 2017-03-29 | 2017-07-25 | 合肥天沃能源科技有限公司 | A kind of energy saving paint and preparation method thereof |
| CN107699135A (en) * | 2017-10-25 | 2018-02-16 | 成都森钰泓绿化工程有限公司 | A kind of fireproof flame resistance paint |
| CN107760203A (en) * | 2017-10-25 | 2018-03-06 | 成都森钰泓绿化工程有限公司 | A kind of preparation method of fireproof flame resistance paint |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114163917A (en) * | 2021-11-05 | 2022-03-11 | 书香门地集团股份有限公司 | Environment-friendly flame-retardant material for plates and preparation method thereof |
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Application publication date: 20181221 |
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