CN106978048A - A kind of energy saving paint and preparation method thereof - Google Patents

A kind of energy saving paint and preparation method thereof Download PDF

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Publication number
CN106978048A
CN106978048A CN201710199007.4A CN201710199007A CN106978048A CN 106978048 A CN106978048 A CN 106978048A CN 201710199007 A CN201710199007 A CN 201710199007A CN 106978048 A CN106978048 A CN 106978048A
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China
Prior art keywords
parts
energy saving
pigment
acrylate
monomers
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Application number
CN201710199007.4A
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Chinese (zh)
Inventor
魏芳芳
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Hefei Tiannuo Energy Technology Co Ltd
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Hefei Tiannuo Energy Technology Co Ltd
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Priority to CN201710199007.4A priority Critical patent/CN106978048A/en
Publication of CN106978048A publication Critical patent/CN106978048A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06Unsaturated polyesters having carbon-to-carbon unsaturation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10Epoxy resins modified by unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

A kind of energy saving paint and preparation method thereof, its composition includes epoxy acrylate, butyl acetate, ethylene glycol, sodium alkyl sulfate, urethane acrylate, polyester acrylate, many official's monomers, pigment, levelling agent and dispersant.After the present invention mixes mentioned component, the paint prepared by processing, with good adhesive force, its lower cost for material, energy-saving and emission-reduction in manufacturing process, raw material are few, raw material sources are extensive, and the paint of this times has certain environment protection significance, it is difficult to fade, environment will not be polluted, with good water-fast function, its bright color, surface is smooth, with good practical function.

Description

A kind of energy saving paint and preparation method thereof
Technical field
The invention belongs to decorative materials technology, and in particular to a kind of energy saving paint and preparation method thereof.
Background technology
Paint because of the moistureproof defencive function of its anti-corrosion and decoration function, and favored by finishing person, but it is existing Paint adds the organic solvents such as benzene mostly, and harm to the human body is larger, also environment can be affected, as people are to ring The consciousness of guarantor is more and more stronger, and this is accomplished by a kind of more preferable energy-conservation and the paint of environmental protection.
The content of the invention
It is an object of the invention to provide a kind of energy saving paint and preparation method thereof, the present invention has good adhesive force, its Energy-saving and emission-reduction in lower cost for material, manufacturing process, raw material are few, raw material sources are extensive, and the paint of this times has necessarily Environment protection significance, it is difficult to fade, and environment will not be polluted, and with good water-fast function, its bright color, surface is put down It is sliding, with good practical function.
The invention provides following technical scheme:
A kind of energy saving paint, includes the raw material of following parts by weight:25-32 parts of epoxy acrylate, 21-28 parts of butyl acetate, second It is 20-30 parts of glycol, 25-32 parts of sodium alkyl sulfate, 25-28 parts of urethane acrylate, 24-35 parts of polyester acrylate, many 10-17 parts of 15-20 parts of official's monomer, 10-20 parts of pigment, 12-16 parts of levelling agent and dispersant.
It is preferred that, it is described to include the raw material of following parts by weight:28-30 parts of epoxy acrylate, 24-28 parts of butyl acetate, 22-27 parts of ethylene glycol, 26-30 parts of sodium alkyl sulfate, 26-28 parts of urethane acrylate, 25-31 parts of polyester acrylate, 11-15 parts of many 16-20 parts of official's monomers, 12-17 parts of pigment, 13-16 parts of levelling agent and dispersant.
It is preferred that, it is described to include the raw material of following parts by weight:28 parts of epoxy acrylate, 26 parts of butyl acetate, ethylene glycol 26 parts, 28 parts of sodium alkyl sulfate, 28 parts of urethane acrylate, 30 parts of polyester acrylate, 20 parts of many official's monomers, pigment 15 15 parts of part, 13 parts of levelling agent and dispersant.
It is preferred that, many official's monomers are Pehanorm triacrylate, new penta tetrol triacrylate and two seasons One or more in the acrylate of penta tetrol six, the lower cost for material advantageously reduces cost of manufacture, and the material system Danger will not be produced during standby, the security of preparation process can be improved.
It is preferred that, the pigment is talcum powder or titanium dioxide, and the pigment is one kind in the numerous pigment that can generally add, Appropriate pigment can be added again according to the demand using color.
A kind of preparation method of energy saving paint, comprises the following steps:
Step 1: by epoxy acrylate, butyl acetate, ethylene glycol, sodium alkyl sulfate, urethane acrylate, polyester third Olefin(e) acid ester and the mixing of many official's monomers, obtain mixture one;
Step 2: mixture one is put into reactor, pigment is added, is ground, grind 50min, the speed of grinding is 500r/min, the particle diameter of grinding is less than 2mm;
Step 3: adding levelling agent and dispersant in product after being ground to step 2, the reaction temperature of reactor is 120-150 DEG C, 4-6h is reacted, mixture two is obtained;
Step 4: adding organic solvent into mixture two, the viscosity of mixture two is adjusted, is controlled in 100-120s;
Step 5: step 4 product is filtered with 200-300 mesh filter screens, obtained filtrate as finished product.
It is preferred that, the step 3 is reacted in sealed environment, is conducive to accelerating reaction speed, is shortened manufacturing cycle.
It is preferred that, the step 4 organic solvent is butyl acetate, and the solvent will not produce influence to preparation process, and easily In regulation viscosity, lower cost for material, wide material sources.
The beneficial effects of the invention are as follows:
The many official's monomers added in the present invention can sufficiently slow down the curing rate of paint, and not result in dirt to environment Dye, can improve the viscosity of paint so that the finished product prepared has difficult for drop-off, waterproof and wear-resisting characteristic, extension oil The use time of paint, improves the quality of paint, and reaches the effect of energy-saving and emission-reduction in certain preparation process.
The present invention has energy-saving and emission-reduction in good adhesive force, its lower cost for material, manufacturing process, and raw material are few, original Extensively, the paint of this times has certain environment protection significance to material source, and it is difficult to fade, and environment will not be polluted, had Good water-fast function, its bright color, surface is smooth, with good practical function.
Embodiment
Embodiment 1
A kind of energy saving paint, includes the raw material of following parts by weight:32 parts of epoxy acrylate, 28 parts of butyl acetate, ethylene glycol 30 Part, 32 parts of sodium alkyl sulfate, 28 parts of urethane acrylate, 35 parts of polyester acrylate, 20 parts of many official's monomers, pigment 20 17 parts of part, 16 parts of levelling agent and dispersant.
Many official's monomers are made up of new penta tetrol triacrylate and dipentaerythritol acrylate, and the cost of material is low for this Honest and clean, danger will not be produced by advantageously reducing in cost of manufacture, and the material preparation process, can improve the safety of preparation process Property.
Pigment is talcum powder, and the pigment is one kind in the numerous pigment that can generally add, can be according to use color Demand adds appropriate pigment again.
A kind of preparation method of energy saving paint, comprises the following steps:
Step 1: by epoxy acrylate, butyl acetate, ethylene glycol, sodium alkyl sulfate, urethane acrylate, polyester third Olefin(e) acid ester and the mixing of many official's monomers, obtain mixture one;
Step 2: mixture one is put into reactor, pigment is added, is ground, grind 50min, the speed of grinding is 500r/min, the particle diameter of grinding is less than 2mm;
Step 3: adding levelling agent and dispersant in product after being ground to step 2, the reaction temperature of reactor is 150 DEG C, 6h is reacted, mixture two is obtained;
Step 4: adding organic solvent into mixture two, the viscosity of mixture two is adjusted, is controlled in 120s;
Step 5: step 4 product is filtered with 300 mesh filter screens, obtained filtrate as finished product.
Step 3 is reacted in sealed environment, is conducive to accelerating reaction speed, is shortened manufacturing cycle.
Step 4 organic solvent is butyl acetate, and the solvent will not produce influence to preparation process, and can easily be accommodated viscosity, Lower cost for material, wide material sources.
Embodiment 2
A kind of energy saving paint, includes the raw material of following parts by weight:28 parts of epoxy acrylate, 26 parts of butyl acetate, ethylene glycol 26 Part, 28 parts of sodium alkyl sulfate, 28 parts of urethane acrylate, 30 parts of polyester acrylate, 20 parts of many official's monomers, pigment 15 15 parts of part, 13 parts of levelling agent and dispersant.
Many official's monomers are dipentaerythritol acrylate, and the lower cost for material advantageously reduces cost of manufacture, and Danger will not be produced in the material preparation process, the security of preparation process can be improved.
Pigment is titanium dioxide, and the pigment is one kind in the numerous pigment that can generally add, can be according to use color Demand adds appropriate pigment again.
A kind of preparation method of energy saving paint, comprises the following steps:
Step 1: by epoxy acrylate, butyl acetate, ethylene glycol, sodium alkyl sulfate, urethane acrylate, polyester third Olefin(e) acid ester and the mixing of many official's monomers, obtain mixture one;
Step 2: mixture one is put into reactor, pigment is added, is ground, grind 50min, the speed of grinding is 500r/min, the particle diameter of grinding is less than 2mm;
Step 3: adding levelling agent and dispersant in product after being ground to step 2, the reaction temperature of reactor is 120 DEG C, 4h is reacted, mixture two is obtained;
Step 4: adding organic solvent into mixture two, the viscosity of mixture two is adjusted, is controlled in 100-120s;
Step 5: step 4 product is filtered with 200 mesh filter screens, obtained filtrate as finished product.
Step 3 is reacted in sealed environment, is conducive to accelerating reaction speed, is shortened manufacturing cycle.
Step 4 organic solvent is butyl acetate, and the solvent will not produce influence to preparation process, and can easily be accommodated viscosity, Lower cost for material, wide material sources.
Embodiment 3
A kind of energy saving paint, includes the raw material of following parts by weight:30 parts of epoxy acrylate, 24 parts of butyl acetate, ethylene glycol 22 Part, 30 parts of sodium alkyl sulfate, 28 parts of urethane acrylate, 25 parts of polyester acrylate, 16 parts of many official's monomers, pigment 17 11 parts of part, 16 parts of levelling agent and dispersant.
Many official's monomers are made up of Pehanorm triacrylate and dipentaerythritol acrylate, the material cost Cheap, danger will not be produced by advantageously reducing in cost of manufacture, and the material preparation process, can improve the safety of preparation process Property.
Pigment is titanium dioxide, and the pigment is one kind in the numerous pigment that can generally add, can be according to use color Demand adds appropriate pigment again.
A kind of preparation method of energy saving paint, comprises the following steps:
Step 1: by epoxy acrylate, butyl acetate, ethylene glycol, sodium alkyl sulfate, urethane acrylate, polyester third Olefin(e) acid ester and the mixing of many official's monomers, obtain mixture one;
Step 2: mixture one is put into reactor, pigment is added, is ground, grind 50min, the speed of grinding is 500r/min, the particle diameter of grinding is less than 2mm;
Step 3: adding levelling agent and dispersant in product after being ground to step 2, the reaction temperature of reactor is 120 DEG C, 4h is reacted, mixture two is obtained;
Step 4: adding organic solvent into mixture two, the viscosity of mixture two is adjusted, is controlled in 120s;
Step 5: step 4 product is filtered with 300 mesh filter screens, obtained filtrate as finished product.
Step 3 is reacted in sealed environment, is conducive to accelerating reaction speed, is shortened manufacturing cycle.
Step 4 organic solvent is butyl acetate, and the solvent will not produce influence to preparation process, and can easily be accommodated viscosity, Lower cost for material, wide material sources.
Embodiment 4
A kind of energy saving paint, includes the raw material of following parts by weight:32 parts of epoxy acrylate, 21 parts of butyl acetate, ethylene glycol 30 Part, 25 parts of sodium alkyl sulfate, 28 parts of urethane acrylate, 24 parts of polyester acrylate, 20 parts of many official's monomers, pigment 10 10 parts of part, 16 parts of levelling agent and dispersant.
Many official's monomers are by Pehanorm triacrylate, new penta tetrol triacrylate and the propylene of dipentaerythritol six Acid esters is constituted, the lower cost for material, and danger will not be produced by advantageously reducing in cost of manufacture, and the material preparation process, The security of preparation process can be improved.
Pigment is talcum powder, and the pigment is one kind in the numerous pigment that can generally add, can be according to use color Demand adds appropriate pigment again.
A kind of preparation method of energy saving paint, comprises the following steps:
Step 1: by epoxy acrylate, butyl acetate, ethylene glycol, sodium alkyl sulfate, urethane acrylate, polyester third Olefin(e) acid ester and the mixing of many official's monomers, obtain mixture one;
Step 2: mixture one is put into reactor, pigment is added, is ground, grind 50min, the speed of grinding is 500r/min, the particle diameter of grinding is less than 2mm;
Step 3: adding levelling agent and dispersant in product after being ground to step 2, the reaction temperature of reactor is 120 DEG C, 4h is reacted, mixture two is obtained;
Step 4: adding organic solvent into mixture two, the viscosity of mixture two is adjusted, is controlled in 100s;
Step 5: step 4 product is filtered with 300 mesh filter screens, obtained filtrate as finished product.
Step 3 is reacted in sealed environment, is conducive to accelerating reaction speed, is shortened manufacturing cycle.
Step 4 organic solvent is butyl acetate, and the solvent will not produce influence to preparation process, and can easily be accommodated viscosity, Lower cost for material, wide material sources.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, although with reference to foregoing reality Apply example the present invention is described in detail, for those skilled in the art, it still can be to foregoing each implementation Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic.All essences in the present invention God is with principle, and any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.

Claims (8)

1. a kind of energy saving paint, it is characterised in that include the raw material of following parts by weight:25-32 parts of epoxy acrylate, acetic acid fourth 21-28 parts of ester, 20-30 parts of ethylene glycol, 25-32 parts of sodium alkyl sulfate, 25-28 parts of urethane acrylate, polyester acrylic 10-17 parts of 24-35 parts of ester, 15-20 parts of many official's monomers, 10-20 parts of pigment, 12-16 parts of levelling agent and dispersant.
2. a kind of energy saving paint according to claim 1, it is characterised in that include the raw material of following parts by weight:Epoxy third 28-30 parts of olefin(e) acid ester, 24-28 parts of butyl acetate, 22-27 parts of ethylene glycol, 26-30 parts of sodium alkyl sulfate, polyurethane acroleic acid 26-28 parts of ester, 25-31 parts of polyester acrylate, 16-20 parts of many official's monomers, 12-17 parts of pigment, 13-16 parts of levelling agent and scattered 11-15 parts of agent.
3. a kind of energy saving paint according to claim 1, it is characterised in that include the raw material of following parts by weight:Epoxy third 28 parts of olefin(e) acid ester, 26 parts of butyl acetate, 26 parts of ethylene glycol, 28 parts of sodium alkyl sulfate, 28 parts of urethane acrylate, polyester third 15 parts of 30 parts of olefin(e) acid ester, 20 parts of many official's monomers, 15 parts of pigment, 13 parts of levelling agent and dispersant.
4. a kind of energy saving paint according to claim 1, it is characterised in that many official's monomers are Pehanorm three One or more in acrylate, new penta tetrol triacrylate and dipentaerythritol acrylate.
5. a kind of energy saving paint according to claim 1, it is characterised in that the pigment is talcum powder or titanium dioxide.
6. the preparation method of a kind of energy saving paint described in claim any one of 1-5, it is characterised in that comprise the following steps:
Step 1: by epoxy acrylate, butyl acetate, ethylene glycol, sodium alkyl sulfate, urethane acrylate, polyester third Olefin(e) acid ester and the mixing of many official's monomers, obtain mixture one;
Step 2: mixture one is put into reactor, pigment is added, is ground, grind 50min, the speed of grinding is 500r/min, the particle diameter of grinding is less than 2mm;
Step 3: adding levelling agent and dispersant in product after being ground to step 2, the reaction temperature of reactor is 120-150 DEG C, 4-6h is reacted, mixture two is obtained;
Step 4: adding organic solvent into mixture two, the viscosity of mixture two is adjusted, is controlled in 100-120s;
Step 5: step 4 product is filtered with 200-300 mesh filter screens, obtained filtrate as finished product.
7. the preparation method of a kind of energy saving paint according to claim 6, it is characterised in that the step 3 is in sealing ring Reacted in border.
8. a kind of preparation method of energy saving paint according to claim 6, it is characterised in that the step 4 organic solvent For butyl acetate.
CN201710199007.4A 2017-03-29 2017-03-29 A kind of energy saving paint and preparation method thereof Withdrawn CN106978048A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710199007.4A CN106978048A (en) 2017-03-29 2017-03-29 A kind of energy saving paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710199007.4A CN106978048A (en) 2017-03-29 2017-03-29 A kind of energy saving paint and preparation method thereof

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Publication Number Publication Date
CN106978048A true CN106978048A (en) 2017-07-25

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109054595A (en) * 2018-06-11 2018-12-21 马鞍山中粮生物化学有限公司 A kind of environment protection oil paint and preparation method thereof
CN111826062A (en) * 2020-08-12 2020-10-27 河南恒大欧派门业有限责任公司 Manufacturing method for preparing UV (ultraviolet) moisture-proof sealing paint by utilizing UV sanding dust
CN115074005A (en) * 2022-07-25 2022-09-20 佛山市惟欣科技有限公司 Novel wear-resistant anticorrosive paint and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007046741A1 (en) * 2005-10-18 2007-04-26 Perstorp Specialty Chemicals Ab Dual cure composition
CN101407651A (en) * 2008-11-27 2009-04-15 中国乐凯胶片集团公司 UV curing color decorative coating
CN101412889A (en) * 2008-11-26 2009-04-22 湖南平桂制塑科技实业有限公司 Acrylic ester modified high-weatherability paint and preparation thereof
CN101928510A (en) * 2010-09-29 2010-12-29 杭州中富彩新材料科技有限公司 Flatting agent for UV cured leathers and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007046741A1 (en) * 2005-10-18 2007-04-26 Perstorp Specialty Chemicals Ab Dual cure composition
CN101412889A (en) * 2008-11-26 2009-04-22 湖南平桂制塑科技实业有限公司 Acrylic ester modified high-weatherability paint and preparation thereof
CN101407651A (en) * 2008-11-27 2009-04-15 中国乐凯胶片集团公司 UV curing color decorative coating
CN101928510A (en) * 2010-09-29 2010-12-29 杭州中富彩新材料科技有限公司 Flatting agent for UV cured leathers and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109054595A (en) * 2018-06-11 2018-12-21 马鞍山中粮生物化学有限公司 A kind of environment protection oil paint and preparation method thereof
CN111826062A (en) * 2020-08-12 2020-10-27 河南恒大欧派门业有限责任公司 Manufacturing method for preparing UV (ultraviolet) moisture-proof sealing paint by utilizing UV sanding dust
CN115074005A (en) * 2022-07-25 2022-09-20 佛山市惟欣科技有限公司 Novel wear-resistant anticorrosive paint and preparation method thereof

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