CN101928510A - Flatting agent for UV cured leathers and preparation method thereof - Google Patents
Flatting agent for UV cured leathers and preparation method thereof Download PDFInfo
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- CN101928510A CN101928510A CN2010102968112A CN201010296811A CN101928510A CN 101928510 A CN101928510 A CN 101928510A CN 2010102968112 A CN2010102968112 A CN 2010102968112A CN 201010296811 A CN201010296811 A CN 201010296811A CN 101928510 A CN101928510 A CN 101928510A
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Abstract
The invention discloses a flatting agent for UV cured leathers and a preparation method thereof, and belongs to the field of after finishing of coatings, natural leathers, artificial leathers, synthetic leathers and textile fabrics. The flatting agent for the UV cured leathers comprises the following raw materials: 10 to 40 weight parts of prepolymer, 10 to 60 weight parts of active monomers, 2 to 10 weight parts of photoinitiator, 1 to 20 weight parts of coinitiator, 0.5 to 2 weight parts of defoamer, 0.1 to 1 weight part of leveling agent and 2 to 10 weight parts of flatting powder. The flatting agent for the UV cured leathers has the advantages of energy saving, environmental protection, high stability, good flatting effect and stable product quality.
Description
Technical field
The present invention relates to a kind of UV curable leather delustring treatment agent and preparation method thereof, belong to finishing field behind coating, natural leather, leatheroid, synthetic leather, the weaving face fabric.
Background technology
The delustring treatment agent is a kind of novel functional coating, after the coating of delustring treatment agent, can give natural leather, leatheroid, synthetic leather and the weaving face fabric feel of soft exquisiteness naturally, and along with the variation of coated weight can also provide vision benefits such as soft light sensation, haze change.Traditional leather flatting processing mainly comprises following several: 1, oil soluble delustring treatment agent, the normally physical mixture of ordinary resin and mute light powder; 2, water-based delustring treatment agent, the normally physical mixture of water-based PA, PU resin and mute light powder.Oil soluble delustring treatment agent is a class the most traditional the most ancient treatment agent, and the application time is long, the market occupancy is big, and resulting extinction effect is comparatively stable, but solvent usually accounts for more than 70% of delustring treatment agent in oil soluble delustring treatment agent; Water-based delustring treatment agent is the novel product that a class newly developed in recent years substitutes oil soluble delustring treatment agent, the water-based matting agent is solvent with water, comparatively environmental protection, but owing to the affinity difference of water to the mute light powder of difference, stability, the extinction effect of water-based delustring treatment agent are all poor than solvent-borne type usually.
Oil soluble delustring treatment agent contains a large amount of solvents, and in use, there is bigger pollution in the volatilization of solvent and is difficult to relatively environment reclaims; The comparatively environmental protection of water-based matting agent, but poor stability, effect does not usually reach the level that substitutes the oil soluble matting agent fully, and because the evaporation of water enthalpy is big, specific heat capacity is high, needs more power consumption under the use technology identical with oil soluble delustring treatment agent.
Summary of the invention
Technical problem to be solved by this invention provide a kind of technological design rationally, the UV curable leather delustring treatment agent of good, the constant product quality of energy-conserving and environment-protective, good stability, extinction effect.
Another technical problem to be solved by this invention provide a kind of technological design rationally, the preparation method of constant product quality, the free of contamination UV curable leather of course of processing delustring treatment agent.
It is this UV curable leather delustring treatment agent that the present invention solves the problems of the technologies described above the technical scheme that is adopted, and its raw material composition is:
The flatting silica of the flow agent of the defoamer of the aided initiating of the light trigger of the reactive monomer of the prepolymer of 10-40 weight part, 10-60 weight part, 2-10 weight part, 1-20 weight part, 0.5-2 weight part, 0.1-1 weight part, 2-10 weight part.
As preferably, also comprise solvent in the raw material of the present invention, the amount of solvent is the 0-20 weight part, described solvent is in ethanol, Virahol, propyl carbinol, propylene glycol monomethyl ether, ethylene glycol monobutyl ether, methylethylketone, methyl iso-butyl ketone (MIBK), dimethylbenzene, vinyl acetic monomer, N-BUTYL ACETATE, chloroform, acetone, tetracol phenixin, pimelinketone, the tetrahydrofuran (THF), N, one or more mixtures of dinethylformamide, N,N-dimethylacetamide, dioxane, diacetone alcohol, ethylene glycol.
As preferably, prepolymer of the present invention is one or more the mixture in polyester acrylate, amino acrylates, urethane acrylate, bisphenol-a epoxy acrylate, fatty acid modified epoxy acrylate, the epoxy soybean oil acrylate.
As preferably, reactive monomer of the present invention is one or more the mixture in glycol diacrylate, hexanediyl ester, glycol ether diacrylate, Viscoat 295, tetramethylolmethane six acrylate, the pentanediol diacrylate.Play diluting effect and fast reaction speed.
As preferably, light trigger of the present invention is 907, one or more the mixture among ITX, BP, 1173,184, TPO, the OMBB.Main rising caused free radical and desiccation.
As preferably, aided initiating of the present invention is one or more the mixture among P-115, the EDAB.Rise and cooperate the initiator acting in conjunction.
As preferably, defoamer of the present invention is silicone based defoamer, is specially one or more the mixture among HX-2080, Fomax N, the KS-66.
As preferably, flow agent of the present invention is organic silicon modified by polyether, polyether siloxane copolymer, silicone copolymer.
As preferably, flatting silica of the present invention is superfine silicon dioxide, surface modification silicon-dioxide, superfine silicon dioxide is aerosil, the liquid phase silica of median size at the 0.01-5 micron, and surface modification silicon-dioxide is organic modification silicon-dioxide, wax improved silica.
The present invention solves the problems of the technologies described above the preparation method that the technical scheme that is adopted still is a kind of UV curable leather delustring treatment agent, and its processing step is:
A, be the prepolymer of 10-40 weight part with mass ratio, the reactive monomer of 10-60 weight part, the light trigger of 2-10 weight part, the aided initiating of 1-20 weight part, the defoamer of 0.5-2 weight part, the flow agent of 0.1-1 weight part, the flatting silica of 2-10 weight part, the 0-20 weight part, standby;
B, prepolymer, the reactive monomer of 20--100%, initiator, aided initiating, solvent with 20--100%, high-speed stirring, stirring velocity are 800-2000 rev/min, controlled temperature obtains intermediate raw material in that fully dissolving is extremely transparent fully below 70 ℃;
C, in intermediate raw material, add remaining prepolymer, remaining reactive monomer, defoamer, flow agent successively, stirred 5 minutes, add flatting silica, high speed dispersion 30-120 minute then, control speed 400-3500 rev/min, temperature is no more than 70 ℃ in the dispersion process, obtains UV curable leather delustring treatment agent.
The present invention compares with existing technology, has the following advantages and characteristics: (1) preparation method is simple, and the Device-General scope is wide.(2) solid part is high, and according to actual needs, prepared UV curable leather delustring treatment agent solid part can be solvent-free to 100% from 80%; (3) curing speed is fast, curing process is simple to operate, adopts the UV ultraviolet light polymerization, because it is fast not contain solvent more traditional delustring treatment agent set time, and does not need other subsequent techniques; (4) condition of cure is low, equipment is simple, and under the room temperature, control UV ultraviolet lamp intensity can conveniently be regulated curing speed; (5) environmental protection is stable, owing to can accomplish high contain admittedly even the agent of solvent-free relative oil soluble leather flatting, the agent of water-based leather flatting have lower energy consumption advantage, and because UV solidifies is a kind of chemical process, and the Chemical bond mode that is provided is effectively stable more than physical mixed.
Embodiment
The present invention is described in further detail below in conjunction with embodiment, and following examples are explanation of the invention and the present invention is not limited to following examples.
Embodiment 1
Get 15g two functionality polyester acrylates, 55g Viscoat 295,3g benzophenone, 1g tertiary amine acrylate, 0.25gHX-2080,0.25g Fomax N, 0.5g organic silicon modified by polyether flow agent and mix standbyly with 1000 rev/mins speed, guarantee in the mixing process that temperature is lower than 70 ℃; In said mixture, add remaining 15g two functionality polyester acrylates, with 1500 rev/mins speed, dispersing and mixing is even, adds 5g organic modification silicon-dioxide simultaneously, blending dispersion 30 minutes remains that temperature of charge is lower than 70 ℃ in the mixing process.Dispersion finishes, and discharging promptly gets UV curable leather delustring treatment agent.
Embodiment 2
Get 18g bisphenol-a epoxy acrylate, 18g tetramethylolmethane six acrylate, 1g1-hydroxyl cyclohexane phenyl ketone), 1g TPO(2,4,6-trimethylbenzoyl diphenyl phosphine oxide), 1g tertiary amine acrylate, 0.6g KS-66,0.4g polyether siloxane copolymer flow agent, 10g dimethylbenzene, mix standbyly with 800 rev/mins speed, guarantee in the mixing process that temperature is lower than 70 ℃; In said mixture, add 10g glycol diacrylate reactive monomer, 9g N-BUTYL ACETATE, mix with 2000 rev/mins speed, add 3.5g wax improved silica in the mixing process, blending dispersion 45 minutes remains that temperature of charge is lower than 70 ℃ in the mixing process.Dispersion finishes, and discharging promptly gets UV curable leather delustring treatment agent.
Embodiment 3
Get 20g urethane acrylate, 50g glycol ether diacrylate, 2.5g isopropyl thioxanthone, 1g 4-(N, the N-dimethylamino) ethyl benzoate, 1g Fomax N, 0.5g silicone copolymer flow agent, 3.5g N-BUTYL ACETATE, be mixed to transparent evenly standbyly with 600 rev/mins speed, mixing process guarantees that temperature of charge is lower than 70 ℃; In said mixture, add the fatty acid modified epoxy acrylic ester prepolymer of 15g, mix, add the 6.5g superfine silicon dioxide in the mixing process, disperseed 60 minutes, remain that temperature of charge is lower than 70 ℃ in the dispersing and mixing process with 1500 rev/mins speed.Dispersion finishes, and promptly gets UV curable leather delustring treatment agent.
Embodiment 4
Get 8g epoxy soybean oil acrylate, 3g pentanediol diacrylate, 8gOMBB, 10gP-115,5gEDAB, 0. 5gHX-2080,1g Fomax N, 0.3g organic silicon modified by polyether flow agent and mix standbyly with 1000 rev/mins speed, guarantee in the mixing process that temperature is lower than 70 ℃; In said mixture, add 32g bisphenol-a epoxy acrylate, 12 gram glycol ether diacrylates, 5 gram chloroforms, 2 gram acetone, speed with 1500 rev/mins, dispersing and mixing is even, add 2g organic modification silicon-dioxide simultaneously, blending dispersion 30 minutes remains that temperature of charge is lower than 70 ℃ in the mixing process.Dispersion finishes, and discharging promptly gets UV curable leather delustring treatment agent.
Embodiment 5
Get 10g bisphenol-a epoxy acrylate, 5g Viscoat 295,2g1173,2g184,8g tertiary amine acrylate, 1.2g KS-66,0.1g polyether siloxane copolymer flow agent, mix standbyly with 800 rev/mins speed, guarantee in the mixing process that temperature is lower than 70 ℃; In said mixture, add 27g urethane acrylate, 5g Viscoat 295, mix with 2000 rev/mins speed, add 8g wax improved silica in the mixing process, blending dispersion 45 minutes remains that temperature of charge is lower than 70 ℃ in the mixing process.Dispersion finishes, and discharging promptly gets UV curable leather delustring treatment agent.
Embodiment 6
Get 15g amino acrylates, 20g pentanediol diacrylate, 10g isopropyl thioxanthone, 20g 4-(N, the N-dimethylamino) ethyl benzoate, 2g Fomax N, 0.7g silicone copolymer flow agent, 5g dioxane, 5g diacetone alcohol, be mixed to transparent evenly standbyly with 600 rev/mins speed, mixing process guarantees that temperature of charge is lower than 70 ℃; In said mixture, add the fatty acid modified epoxy acrylic ester prepolymer of 10g, 10g Viscoat 295, mix with 1500 rev/mins speed, add the 6g superfine silicon dioxide in the mixing process, disperseed 60 minutes, and remained that temperature of charge was lower than 70 ℃ in the dispersing and mixing process.Dispersion finishes, and promptly gets UV curable leather delustring treatment agent.
Embodiment 7
Get 23g epoxy soybean oil acrylate, 20g pentanediol diacrylate, 20g glycol diacrylate, 5g BP, 6gP-115,0. 5gHX-2080,0.3g Fomax N, 1g organic silicon modified by polyether flow agent and mix standbyly with 1000 rev/mins speed, guarantee in the mixing process that temperature is lower than 70 ℃; Add 4g organic modification silicon-dioxide in said mixture, with 1500 rev/mins speed, dispersing and mixing is even, and blending dispersion 30 minutes remains that temperature of charge is lower than 70 ℃ in the mixing process.Dispersion finishes, and discharging promptly gets UV curable leather delustring treatment agent.
Embodiment 8
Get 8g bisphenol-a epoxy acrylate, 15g Viscoat 295,5g1173,4g184,4g tertiary amine acrylate, 1.8g KS-66,0.8g polyether siloxane copolymer flow agent, mix standbyly with 800 rev/mins speed, guarantee in the mixing process that temperature is lower than 70 ℃; In said mixture, add 2g urethane acrylate, 5g Viscoat 295, mix with 2000 rev/mins speed, add 3g wax improved silica in the mixing process, blending dispersion 45 minutes remains that temperature of charge is lower than 70 ℃ in the mixing process.Dispersion finishes, and discharging promptly gets UV curable leather delustring treatment agent.
Embodiment 9
Get the fatty acid modified epoxy acrylate of 12g, 10g pentanediol diacrylate, 7g isopropyl thioxanthone, 18g 4-(N, the N-dimethylamino) ethyl benzoate, 1.6g Fomax N, 0.6g silicone copolymer flow agent, be mixed to transparent evenly standbyly with 600 rev/mins speed, mixing process guarantees that temperature of charge is lower than 70 ℃; In said mixture, add the 35g Viscoat 295, mix, add the 7g superfine silicon dioxide in the mixing process, disperseed 60 minutes, remain that temperature of charge is lower than 70 ℃ in the dispersing and mixing process with 1500 rev/mins speed.Dispersion finishes, and promptly gets UV curable leather delustring treatment agent.
Embodiment 10
Get 30g amino acrylates, 35g pentanediol diacrylate, 6g isopropyl thioxanthone, 12g 4-(N, the N-dimethylamino) ethyl benzoate, 1.3g Fomax N, 0.9g silicone copolymer flow agent, 10g vinyl acetic monomer, 10g tetracol phenixin, be mixed to transparent evenly standbyly with 600 rev/mins speed, mixing process guarantees that temperature of charge is lower than 70 ℃; In said mixture, add the fatty acid modified epoxy acrylic ester prepolymer of 10g, mix, add the 10g superfine silicon dioxide in the mixing process, disperseed 60 minutes, remain that temperature of charge is lower than 70 ℃ in the dispersing and mixing process with 1500 rev/mins speed.Dispersion finishes, and promptly gets UV curable leather delustring treatment agent.Superfine silicon dioxide described in the above embodiment is aerosil, the liquid phase silica of median size at the 0.01-5 micron.
Among the present invention, it is coolings that prepolymer and reactive monomer divide the main purpose of two interpolations, to reacting basic not influence.
In addition, need to prove, the specific embodiment described in this specification sheets, its prescription, title that technology is named etc. can be different.Allly conceive equivalence or the simple change that described structure, feature and principle are done, be included in the protection domain of patent of the present invention according to patent of the present invention.The technician of the technical field of the invention can make various modifications or replenishes or adopt similar mode to substitute described specific embodiment; only otherwise depart from structure of the present invention or surmount the defined scope of these claims, all should belong to protection scope of the present invention.
Though the present invention with embodiment openly as above; but it is not in order to limit protection scope of the present invention; any technician who is familiar with this technology, change and the retouching done in not breaking away from design of the present invention and scope all should belong to protection scope of the present invention.
Claims (10)
1. UV curable leather delustring treatment agent, its raw material are formed:
The flatting silica of the flow agent of the defoamer of the aided initiating of the light trigger of the reactive monomer of the prepolymer of 10-40 weight part, 10-60 weight part, 2-10 weight part, 1-20 weight part, 0.5-2 weight part, 0.1-1 weight part, 2-10 weight part.
2. UV curable leather delustring treatment agent according to claim 1, it is characterized in that: also comprise solvent in the described raw material, the amount of solvent is the 0-20 weight part, described solvent is in ethanol, Virahol, propyl carbinol, propylene glycol monomethyl ether, ethylene glycol monobutyl ether, methylethylketone, methyl iso-butyl ketone (MIBK), dimethylbenzene, vinyl acetic monomer, N-BUTYL ACETATE, chloroform, acetone, tetracol phenixin, pimelinketone, the tetrahydrofuran (THF), N, one or more mixtures of dinethylformamide, N,N-dimethylacetamide, dioxane, diacetone alcohol, ethylene glycol.
3. UV curable leather delustring treatment agent according to claim 1 is characterized in that: described prepolymer is one or more the mixture in polyester acrylate, amino acrylates, urethane acrylate, bisphenol-a epoxy acrylate, fatty acid modified epoxy acrylate, the epoxy soybean oil acrylate.
4. UV curable leather delustring treatment agent according to claim 1 is characterized in that: described reactive monomer is one or more the mixture in glycol diacrylate, hexanediyl ester, glycol ether diacrylate, Viscoat 295, tetramethylolmethane six acrylate, the pentanediol diacrylate.
5. UV curable leather delustring treatment agent according to claim 1 is characterized in that: described light trigger is 907, one or more the mixture among ITX, BP, 1173,184, TPO, the OMBB.
6. UV curable leather delustring treatment agent according to claim 1 is characterized in that: described aided initiating is one or more the mixture among P-115, the EDAB.
7. UV curable leather delustring treatment agent according to claim 1, it is characterized in that: described defoamer is silicone based defoamer, is specially one or more the mixture among HX-2080, Fomax N, the KS-66.
8. UV curable leather delustring treatment agent according to claim 1, it is characterized in that: described flow agent is organic silicon modified by polyether, polyether siloxane copolymer, silicone copolymer.
9. UV curable leather delustring treatment agent according to claim 1, it is characterized in that: described flatting silica is superfine silicon dioxide, surface modification silicon-dioxide, superfine silicon dioxide is aerosil, the liquid phase silica of median size at the 0.01-5 micron, and surface modification silicon-dioxide is organic modification silicon-dioxide, wax improved silica.
10. the preparation method of a UV curable leather delustring treatment agent as claimed in claim 1, its processing step is:
A, be the prepolymer of 10-40 weight part with mass ratio, the reactive monomer of 10-60 weight part, the light trigger of 2-10 weight part, the aided initiating of 1-20 weight part, the defoamer of 0.5-2 weight part, the flow agent of 0.1-1 weight part, the flatting silica of 2-10 weight part, the 0-20 weight part, standby;
B, prepolymer, the reactive monomer of 20--100%, initiator, aided initiating, solvent with 20--100%, high-speed stirring, stirring velocity are 800-2000 rev/min, controlled temperature obtains intermediate raw material in that fully dissolving is extremely transparent fully below 70 ℃;
C, in intermediate raw material, add remaining prepolymer, remaining reactive monomer, defoamer, flow agent successively, stirred 5 minutes, add flatting silica, high speed dispersion 30-120 minute then, control speed 400-3500 rev/min, temperature is no more than 70 ℃ in the dispersion process, obtains UV curable leather delustring treatment agent.
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| CN2010102968112A CN101928510A (en) | 2010-09-29 | 2010-09-29 | Flatting agent for UV cured leathers and preparation method thereof |
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| CN2010102968112A CN101928510A (en) | 2010-09-29 | 2010-09-29 | Flatting agent for UV cured leathers and preparation method thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102839544A (en) * | 2011-06-20 | 2012-12-26 | 杭州中富彩新材料科技有限公司 | Ultra-foggy ultra-black delustering agent for leather and preparation method thereof |
| CN102898931A (en) * | 2012-09-18 | 2013-01-30 | 无锡市中星工业胶带有限公司 | Matte PC coiled material and preparation method thereof |
| CN103046377A (en) * | 2012-12-28 | 2013-04-17 | 苏州鼎润复合材料有限公司 | Cloudy-surface skin touch-feeling finishing agent for synthetic leather and surface treatment method of synthetic leather |
| WO2014029054A1 (en) * | 2012-08-22 | 2014-02-27 | 江苏宝泽高分子材料股份有限公司 | Skin-touch matte washing and brightening treatment agent for synthetic leather and preparation method thereof |
| CN104017487A (en) * | 2014-06-18 | 2014-09-03 | 湖南松井新材料有限公司 | Ultraviolet-curing matte paint |
| CN104212315A (en) * | 2014-09-19 | 2014-12-17 | 江苏海晟涂料有限公司 | Ultraviolet curing coating and preparation method thereof |
| WO2015196318A1 (en) * | 2014-06-26 | 2015-12-30 | 江苏宝泽高分子材料股份有限公司 | Discoloration polishing treatment agent for synthetic leather and preparation method for the agent |
| CN106700842A (en) * | 2015-11-15 | 2017-05-24 | 惠州市长润发涂料有限公司 | Ultraviolet-curable primer |
| CN106978048A (en) * | 2017-03-29 | 2017-07-25 | 合肥天沃能源科技有限公司 | A kind of energy saving paint and preparation method thereof |
| CN108486294A (en) * | 2018-04-04 | 2018-09-04 | 江西三越新材料有限公司 | UV type leather flatting inorganic agents and preparation method thereof |
| CN111748234A (en) * | 2020-07-07 | 2020-10-09 | 威远达威木业有限公司 | Cationic extinction filler and preparation method thereof |
| CN113308187A (en) * | 2021-04-29 | 2021-08-27 | 江苏利田科技股份有限公司 | Ultraviolet-curing leather hand feeling coating agent and preparation method thereof |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102839544A (en) * | 2011-06-20 | 2012-12-26 | 杭州中富彩新材料科技有限公司 | Ultra-foggy ultra-black delustering agent for leather and preparation method thereof |
| WO2014029054A1 (en) * | 2012-08-22 | 2014-02-27 | 江苏宝泽高分子材料股份有限公司 | Skin-touch matte washing and brightening treatment agent for synthetic leather and preparation method thereof |
| CN102898931B (en) * | 2012-09-18 | 2016-04-13 | 无锡市中星工业胶带有限公司 | A kind of matte PC membrane and preparation method thereof |
| CN102898931A (en) * | 2012-09-18 | 2013-01-30 | 无锡市中星工业胶带有限公司 | Matte PC coiled material and preparation method thereof |
| CN103046377A (en) * | 2012-12-28 | 2013-04-17 | 苏州鼎润复合材料有限公司 | Cloudy-surface skin touch-feeling finishing agent for synthetic leather and surface treatment method of synthetic leather |
| CN104017487A (en) * | 2014-06-18 | 2014-09-03 | 湖南松井新材料有限公司 | Ultraviolet-curing matte paint |
| CN104017487B (en) * | 2014-06-18 | 2017-01-04 | 湖南松井新材料有限公司 | Ultraviolet light cured burnished paint |
| WO2015196318A1 (en) * | 2014-06-26 | 2015-12-30 | 江苏宝泽高分子材料股份有限公司 | Discoloration polishing treatment agent for synthetic leather and preparation method for the agent |
| CN104212315A (en) * | 2014-09-19 | 2014-12-17 | 江苏海晟涂料有限公司 | Ultraviolet curing coating and preparation method thereof |
| CN106700842A (en) * | 2015-11-15 | 2017-05-24 | 惠州市长润发涂料有限公司 | Ultraviolet-curable primer |
| CN106978048A (en) * | 2017-03-29 | 2017-07-25 | 合肥天沃能源科技有限公司 | A kind of energy saving paint and preparation method thereof |
| CN108486294A (en) * | 2018-04-04 | 2018-09-04 | 江西三越新材料有限公司 | UV type leather flatting inorganic agents and preparation method thereof |
| CN111748234A (en) * | 2020-07-07 | 2020-10-09 | 威远达威木业有限公司 | Cationic extinction filler and preparation method thereof |
| CN113308187A (en) * | 2021-04-29 | 2021-08-27 | 江苏利田科技股份有限公司 | Ultraviolet-curing leather hand feeling coating agent and preparation method thereof |
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Application publication date: 20101229 |