CN109022531A - A kind of recycling treatment utilizes the process of water hyacinth - Google Patents

A kind of recycling treatment utilizes the process of water hyacinth Download PDF

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Publication number
CN109022531A
CN109022531A CN201810728154.0A CN201810728154A CN109022531A CN 109022531 A CN109022531 A CN 109022531A CN 201810728154 A CN201810728154 A CN 201810728154A CN 109022531 A CN109022531 A CN 109022531A
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water hyacinth
biogas
stalk
fermentation
recycling treatment
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Inventor
朱海瀛
崔瑞萍
马晓辉
吴蒙
项丽君
田亚军
黄维
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Tiancheng Environment Protection Technology Co Ltd Zhonggang Group
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Tiancheng Environment Protection Technology Co Ltd Zhonggang Group
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Priority to CN201810728154.0A priority Critical patent/CN109022531A/en
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    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P39/00Processes involving microorganisms of different genera in the same process, simultaneously
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00Other organic fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F9/00Fertilisers from household or town refuse
    • C05F9/04Biological compost
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P5/00Preparation of hydrocarbons or halogenated hydrocarbons
    • C12P5/02Preparation of hydrocarbons or halogenated hydrocarbons acyclic
    • C12P5/023Methane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biotechnology (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Molecular Biology (AREA)
  • Processing Of Solid Wastes (AREA)
  • Fertilizers (AREA)

Abstract

The invention belongs to ecological protections and offal treatment to utilize technical field; disclose the process that a kind of recycling treatment utilizes water hyacinth; include: pretreatment: water hyacinth being stacked, break process after draining; it is beaten by beater; water hyacinth slurries are obtained, stalk progress pulverization process is obtained into stalk powder;It mixes quenched: water hyacinth slurries is mixed with stalk powder, the biogas slurry after adding strain and fermentation carries out modifier treatment, obtains quenched mixture;Anaerobic fermentation: anaerobic fermentation processing is carried out to quenched mixture, obtains biogas and fermentation liquid;Biogas utilization: purification utilization is carried out to biogas;It is separated by solid-liquid separation: fermentation liquid is separated by solid-liquid separation, obtain biogas residue and biogas slurry, biogas slurry is used to mix quenched;Compost treatment: biogas residue and stalk powder are subjected to hybrid composting processing.The present invention provides the processes that a kind of efficient recycling treatment utilizes water hyacinth, and resource utilization is high, and product species are abundant, without secondary pollution.

Description

A kind of recycling treatment utilizes the process of water hyacinth
Technical field
The present invention relates to ecological protections and offal treatment to utilize technical field, in particular to a kind of recycling treatment utilizes The process of water hyacinth.
Background technique
Water hyacinth (also known as water lettuce, scientific name: Eichhornia crassipes) is that one kind originates in South America Amazon River basin to belong to rain long A kind of floatability water plant that flower section's Water hyacinth belongs to.Water hyacinth was once once being introduced by many countries, and it is each to be distributed widely in the world Ground is also put into one of big Alien invasive species in the world hundred.Water hyacinth breeding rapidly, inhibits or influences the growth of other species, breaks Bad ecological diversity easily causes local area ecological deterioration, species single;It influences gas exchanges in atmosphere and water, reduces light To water body penetration power, benthon growth is influenced, water body CO is increased2Concentration reduces output of aquatic products and quality;It can also block up simultaneously River is filled in, shipping, excretion, agricultural and water conservancy etc. are influenced.
Nutrients, such as where such as nitrogen, phosphorus, potassium and crude protein rich in, crude fibre, crude fat simultaneously in water hyacinth Reason is concerned using water hyacinth.
In the prior art, the reuse method of water hyacinth is more single, past although certain reconstituted products can be obtained Toward that can generate more reluctant by-products, resource utilization is low, and the production cycle is longer, and easily causes secondary pollution.
A kind of recycling treatment using water hyacinth technique, it can be achieved that water hyacinth be effectively treated and resource utilization, can Biomass energy biogas and organic fertilizer are generated, resource utilization rate is high, and biogas production capacity is big, and without sewage discharge is without secondary pollution.
Summary of the invention
The present invention provides the process that a kind of recycling treatment utilizes water hyacinth, realizes the efficient process and money of water hyacinth Source integrates regeneration, can produce biomass energy biogas and organic fertilizer, resource utilization rate is high, and biogas production capacity is big, no dirt Water discharge, it is without secondary pollution.
In order to solve the above technical problems, the present invention provides the process that a kind of recycling treatment utilizes water hyacinth, packet It includes:
Pretreatment: water hyacinth is stacked, break process after draining, is beaten by beater, water hyacinth slurries are obtained, by straw Stalk carries out pulverization process and obtains stalk powder;
Mix quenched: the water hyacinth slurries mixed with the stalk powder, add strain and fermentation after biogas slurry into Row modifier treatment obtains quenched mixture;
Anaerobic fermentation: anaerobic fermentation processing is carried out to the quenched mixture, obtains biogas and fermentation liquid;
Biogas utilization: purification utilization is carried out to the biogas;
It is separated by solid-liquid separation: the fermentation liquid is separated by solid-liquid separation, obtain biogas residue and biogas slurry, the biogas slurry is used for described mixed It closes quenched;
Compost treatment: the biogas residue and the stalk powder are subjected to hybrid composting processing.
Further, in the pretreatment, the water hyacinth stacked, after draining moisture control 91%~ 95%.
Further, in the pretreatment, the stalk is one of corn stover, wheat stalk, rice straw Or it is several.
Further, the moisture content of straws control is 20%~50%.
Further, the water hyacinth, the stalk after crushing size controlling in 1cm and following.
Further, the solid content of the quenched mixture is 7%~10%.
Further, in the mixing is quenched, the C/N in addition nitrogenous fertilizer adjustment mixture is 20~30:1;Mixing is adjusted Matter stage hydraulic detention time is 1~2 day.
Further, the strain includes: acetobacter, bacillus subtilis and saccharomycete;
Effective total viable count is 2~10 × 10 in strain7Cfu/ml, strain add quality and the water hyacinth butt and institute The ratio for stating the gross mass of stalk butt is 5~10:1000.
Further, the anaerobic fermentation uses wet type intermediate temperature anaerobic fermentation, and fermentation temperature is 35 DEG C, hydraulic detention time It is 25~30 days;Biogas residue moisture content after the fermentation liquid is separated by solid-liquid separation is 70%~75%, and the biogas residue and the stalk are broken Moisture content is 50%~60% after the mixing of end.
Further, the period of the compost treatment is 25~30 days;
In composting treatment process, periodically carries out blast aeration and machinery turns over throwing.
One or more technical solutions provided in the embodiments of the present application have at least the following technical effects or advantages:
1) recycling treatment provided in the embodiment of the present application is using the process of water hyacinth, it can be achieved that having for water hyacinth Effect processing solves the problems, such as that waters water hyacinth ecology is encroached on;
2) accomplish resource utilization while handling water hyacinth, generate biomass energy biogas and organic fertilizer, recycling Utilization rate is high;
3) high solid content, high organic content stalk addition avoid water hyacinth as single raw material carry out anaerobism hair The limitation of ferment and compost can significantly reduce the moisture content of reaction mixture, increase organic loading, and then improve anaerobic gas generation effect Rate increases biogas production capacity, while the total addition level of stalk is few, and is easier to obtain;
4) cellulose and hemicellulose in water hyacinth and stalk can be improved in the reflux immersion treatment of the addition of strain and biogas slurry Plain degradation rate, and then improve organic matter degradation rate and biogas production capacity, and the short period individually mixing it is quenched can significantly shorten after The reaction time of continuous anaerobic fermentation;
5) biogas slurry all reflux use, without sewage discharge, biogas residue is fabricated to organic fertilizer, without secondary pollution in overall process.
Detailed description of the invention
Fig. 1 is flow chart of the recycling treatment provided by the invention using the process of water hyacinth.
Specific embodiment
The process that the embodiment of the present application utilizes water hyacinth by providing a kind of recycling treatment, realizes the height of water hyacinth Effect processing and resource comprehensive regeneration can produce biomass energy biogas and organic fertilizer, and resource utilization rate is high, and biogas produces Can be big, without sewage discharge is without secondary pollution.
In order to better understand the above technical scheme, in conjunction with appended figures and specific embodiments to upper It states technical solution to be described in detail, it should be understood that the specific features in the embodiment of the present invention and embodiment are to the application skill The detailed description of art scheme, rather than the restriction to technical scheme, in the absence of conflict, the embodiment of the present application And the technical characteristic in embodiment can be combined with each other.
Referring to Fig. 1, a kind of recycling treatment utilizes the process of water hyacinth, comprising:
Pretreatment: water hyacinth is stacked, break process after draining, is beaten by beater, water hyacinth slurries are obtained, by straw Stalk carries out pulverization process and obtains stalk powder;
Mix quenched: the water hyacinth slurries mixed with the stalk powder, add strain and fermentation after biogas slurry into Row modifier treatment obtains quenched mixture;
Anaerobic fermentation: anaerobic fermentation processing is carried out to the quenched mixture, obtains biogas and fermentation liquid;
Biogas utilization: purification utilization is carried out to the biogas;
It is separated by solid-liquid separation: the fermentation liquid is separated by solid-liquid separation, obtain biogas residue and biogas slurry, the biogas slurry is used for described mixed It closes quenched;
Compost treatment: the biogas residue and the stalk powder are subjected to hybrid composting processing.
Specifically, in the pretreatment, the water hyacinth stacked, after draining moisture control 91%~ 95%.The stalk is one or more of corn stover, wheat stalk, rice straw.The moisture content of straws control exists 20%~50%.The water hyacinth, the stalk after crushing size controlling in 1cm and following.
Further, the solid content of the quenched mixture is 7%~10%.In the mixing is quenched, nitrogenous fertilizer is added Adjusting the C/N in mixture is 20~30:1;Mixing quenched stage hydraulic detention time is 1~2 day.
Further, the strain includes: acetobacter, bacillus subtilis and saccharomycete;Effective viable bacteria in strain Sum is 2~10 × 107Cfu/ml, strain add the ratio of the gross mass of quality and the water hyacinth butt and the stalk butt Example is 5~10:1000.
In general, the anaerobic fermentation uses wet type intermediate temperature anaerobic fermentation, and fermentation temperature is 35 DEG C, hydraulic detention time It is 25~30 days;Biogas residue moisture content after the fermentation liquid is separated by solid-liquid separation is 70%~75%, and the biogas residue and the stalk are broken Moisture content is 50%~60% after the mixing of end.
Further, the period of the compost treatment is 25~30 days;In composting treatment process, air blast exposure is periodically carried out Gas and machinery turn over throwing.
It will be illustrated below by specific scheme.
The embodiment of the present application is reduced the moisture content of reaction mixture by addition stalk, increases organic loading, and strain is passed through Addition and the reflux immersion treatment of biogas slurry improve organic matter degradation rate and biogas production capacity, not only reduced the reaction time but also increased Organic loading and biogas production capacity;Under equal conditions, compared to the anaerobic fermentation of the high cellulose contents material such as conventional water hyacinth, stalk Processing, anaerobic fermentation reaction time reduce 5~20 days, and organic matter degradation rate improves 5%~10%, and organic matter factor of created gase improves 5%~15%;It is suitble to 5~500 ton/days for the treatment of scale, is especially suitable for fairly large industrialization/industrial applications.
Embodiment one:
Water hyacinth after salvaging is stacked naturally at vacant lot, moisture content is 93%~95% after natural draining, then It is in slurry through broken, mashing;It is that 35%~50% corn stalk powder is broken into the≤powder of 1cm by moisture content;Water hyacinth is starched It is 7%~8% that biogas slurry after liquid, corn stover powder and anaerobic fermentation, which is mixed jointly to mixture solid content, while adding nitrogen It is 20~25:1 that fertilizer, which adjusts C/N, and (strain includes acetobacter, bacillus subtilis, saccharomycete to addition strain, in strain effectively Total viable count is 2~7 × 107Cfu/ml), strain addition quality and water hyacinth butt, stalk butt gross mass ratio are 5~7: 1000;Mixing quenched good mixture hydraulic detention time is 1.5 days.
Mixture after stopping 1.5 days carries out anaerobic fermentation, and fermentation temperature is 35 DEG C, and hydraulic detention time is 25 days.
It is utilized after the purified processing of biogas that anaerobic fermentation generates.
Biogas residue moisture content of the fermentation liquid after being separated by solid-liquid separation after anaerobism is 73%~75%, with smashed corn stover Moisture content is 55%~60% after powder mixing, carries out aerobic compost after mixing, periodically carries out blast aeration and machinery turns over throwing, heap Fertile process cycle is 25 days, is finally made organic fertilizer.Embodiment two:
Water hyacinth after salvaging is stacked naturally at stockyard, moisture content is 91%~93% after natural draining, then It is in slurry through broken, mashing;It is that 30%~35% wheat stalk is ground into the≤powder of 1cm by moisture content;Water hyacinth is starched It is 9%~10% that biogas slurry after liquid, wheat stalk powder and anaerobic fermentation, which is mixed jointly to mixture solid content, while adding nitrogen It is 25~30:1 that fertilizer, which adjusts C/N, and (strain includes acetobacter, bacillus subtilis, saccharomycete to addition strain, in strain effectively Total viable count is 5~10 × 107Cfu/ml), strain addition quality and water hyacinth butt, stalk butt gross mass ratio for 7~ 10:1000;Mixing quenched good mixture hydraulic detention time is 2 days.
Mixture after stopping 2 days carries out anaerobic fermentation, and fermentation temperature is 35 DEG C, and hydraulic detention time is 27 days.
It is utilized after the purified processing of biogas that anaerobic fermentation generates.
Biogas residue moisture content of the fermentation liquid after being separated by solid-liquid separation after anaerobism is 70%~73%, with smashed wheat stalk Moisture content is 50%~55% after powder mixing, carries out aerobic compost after mixing, periodically carries out blast aeration and machinery turns over throwing, heap Fertile process cycle is 27 days, is finally made organic fertilizer.
It should be noted last that the above specific embodiment is only used to illustrate the technical scheme of the present invention and not to limit it, Although being described the invention in detail referring to example, those skilled in the art should understand that, it can be to the present invention Technical solution be modified or replaced equivalently, without departing from the spirit and scope of the technical solution of the present invention, should all cover In the scope of the claims of the present invention.

Claims (10)

1. the process that a kind of recycling treatment utilizes water hyacinth characterized by comprising
Pretreatment: water hyacinth being stacked, break process after draining, be beaten by beater, obtain water hyacinth slurries, by stalk into Row pulverization process obtains stalk powder;
It mixes quenched: the water hyacinth slurries is mixed with the stalk powder, the biogas slurry after adding strain and fermentation is adjusted Matter processing, obtains quenched mixture;
Anaerobic fermentation: anaerobic fermentation processing is carried out to the quenched mixture, obtains biogas and fermentation liquid;
Biogas utilization: purification utilization is carried out to the biogas;
It is separated by solid-liquid separation: the fermentation liquid is separated by solid-liquid separation, obtain biogas residue and biogas slurry, the biogas slurry is used for the mixing and is adjusted Matter;
Compost treatment: the biogas residue and the stalk powder are subjected to hybrid composting processing.
2. the process that recycling treatment as described in claim 1 utilizes water hyacinth, it is characterised in that: in the pretreatment In, the water hyacinth stacked, after draining moisture control 91%~95%.
3. the process that recycling treatment as described in claim 1 utilizes water hyacinth, it is characterised in that: in the pretreatment In, the stalk is one or more of corn stover, wheat stalk, rice straw.
4. the process that recycling treatment as claimed in claim 3 utilizes water hyacinth, it is characterised in that: the stalk is aqueous Rate is controlled 20%~50%.
5. as the described in any item recycling treatments of Claims 1 to 4 utilize the process of water hyacinth, it is characterised in that: institute State water hyacinth, the stalk after crushing size controlling in 1cm and following.
6. the process that recycling treatment as described in claim 1 utilizes water hyacinth, it is characterised in that: the quenched mixing The solid content of object is 7%~10%.
7. the process that recycling treatment as described in claim 1 utilizes water hyacinth, it is characterised in that: adjusted in the mixing In matter, the C/N in addition nitrogenous fertilizer adjustment mixture is 20~30:1;Mixing quenched stage hydraulic detention time is 1~2 day.
8. the process that recycling treatment as described in claim 1 utilizes water hyacinth, which is characterized in that the strain package It includes: acetobacter, bacillus subtilis and saccharomycete;
Effective total viable count is 2~10 × 10 in strain7Cfu/ml, strain add quality and the water hyacinth butt and the straw The ratio of the gross mass of stalk butt is 5~10:1000.
9. the process that recycling treatment as described in claim 1 utilizes water hyacinth, it is characterised in that: the anaerobic fermentation Using wet type intermediate temperature anaerobic fermentation, fermentation temperature is 35 DEG C, and hydraulic detention time is 25~30 days;The fermentation liquid is separated by solid-liquid separation Biogas residue moisture content afterwards is 70%~75%, and moisture content is 50%~60% after the biogas residue is mixed with the stalk powder.
10. the process that recycling treatment as described in claim 1 utilizes water hyacinth, it is characterised in that: at the compost The period of reason is 25~30 days;
In composting treatment process, periodically carries out blast aeration and machinery turns over throwing.
CN201810728154.0A 2018-07-05 2018-07-05 A kind of recycling treatment utilizes the process of water hyacinth Pending CN109022531A (en)

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CN109650950A (en) * 2019-01-29 2019-04-19 环创(厦门)科技股份有限公司 The recycling treatment process of water hyacinth
CN114349549A (en) * 2022-01-30 2022-04-15 生态环境部南京环境科学研究所 Low-carbon-emission treatment method for aquatic plant residues

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CN109650950A (en) * 2019-01-29 2019-04-19 环创(厦门)科技股份有限公司 The recycling treatment process of water hyacinth
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