CN109022016A - A kind of composite fuel oil prepared using waste tire cracked oil - Google Patents
A kind of composite fuel oil prepared using waste tire cracked oil Download PDFInfo
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- CN109022016A CN109022016A CN201811007988.9A CN201811007988A CN109022016A CN 109022016 A CN109022016 A CN 109022016A CN 201811007988 A CN201811007988 A CN 201811007988A CN 109022016 A CN109022016 A CN 109022016A
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- Prior art keywords
- waste tire
- oil
- coal tar
- cracked oil
- tire cracked
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
The invention discloses a kind of composite fuel oils prepared using waste tire cracked oil, the composite fuel oil be by waste tire cracked oil, coal tar and mutual solvent is added, additive is constituted, the mass percent of the dosage of waste tire cracked oil and coal tar in the composite fuel oil are as follows: waste tire cracked oil 40%~60%, coal tar 40%~60%；The additional amount of the mutual solvent is the 1%~3% of waste tire cracked oil and coal tar total weight, and the additional amount of the additive is the 0.1%~0.2% of waste tire cracked oil and coal tar total weight.The present invention is high with calorific value, smell is small, noxious gas emission is small, using waste tire cracked oil as main component, can substantially reduce production cost.
Description
Technical field
The invention belongs to technical field of fuel oil more particularly to a kind of hybrid fuels prepared using waste tire cracked oil
Oil.
Background technique
The ignition oil in present thermal power plant is supplied using No. zero diesel oil by oil company；The price of No. zero diesel oil exists
9000 yuan/ton or so.Currently, our installed capacitys of national thermal power generation are about 7.1 hundred million kilowatts, therefore massive diesel-fuel need to be consumed
For the ignition oil in thermal power plant, the annual ignition oil amount for thermal power plant is at 2,000,000 tons or so；And our states
The import volume of family's only crude oil in 2010 just accounts for 55 ﹪ of domestic demand amount；And explanation is needed further exist for, using No. zero diesel oil
As ignition oil and the industrial kiln oil in thermal power plant, it is superfluous that there are serious capability and performances, that is, uses No. zero diesel oil
As ignition oil and the industrial kiln oil in thermal power plant, multinomial performance index possessed by No. zero diesel oil only only used
In it is seldom；In addition, ignition oil and the industrial kiln oil using diesel oil as thermal power plant, is caused as national strategy
The diesel oil of substance is largely occupied.With increasingly deficient and energy supply the anxiety of resource, this problem also seems more
It is important.
It is well known that universal due to motor vehicle, China's all considerable damaged tire of production quantity every year, but damaged tire is difficult
With processing, dealing with improperly can also generation environment pollution.The characteristics of due to tire material, cannot reduce body by melting or dissolving
Product and recycling commonly use burning to reduce accumulating amount, and the fluid oil generated after waste tyre pyrolytic can be converted into high value
Fuel oil and important chemical products such as alkene and benzene；Therefore, waste tire is re-used, and is split using waste tire
How solution oil produces calorific value height, combustion stablized fuel oil is a urgent problem to be solved.
Summary of the invention
In order to solve the problems in the existing technology, waste tire cracked oil is utilized the purpose of the present invention is to propose to a kind of
The composite fuel oil of preparation, has that heat is supreme, smell is small, at low cost, and the characteristics of flameholding.
In order to achieve the above-mentioned object of the invention, the present invention uses technical solution as described below:
A kind of composite fuel oil prepared using waste tire cracked oil, the composite fuel oil is cracked by waste tire
Simultaneously mutual solvent, additive composition is added in oil, coal tar, the dosage of waste tire cracked oil and coal tar in the composite fuel oil
Mass percent are as follows: waste tire cracked oil 40%~60%, coal tar 40%~60%；The additional amount of the mutual solvent is waste and old wheel
The 1%~3% of tire cracked oil and coal tar total weight, the additional amount of the additive are waste tire cracked oil and coal tar gross weight
The 0.1%~0.2% of amount.
Preferably, in the composite fuel oil dosage of waste tire cracked oil and coal tar mass percent are as follows: it is useless
Old tire cracked oil 40%, coal tar 60%, the additional amount of the mutual solvent are waste tire cracked oil and coal tar total weight
1%, the additional amount of the additive is the 0.1% of waste tire cracked oil and coal tar total weight.
Preferably, in the composite fuel oil dosage of waste tire cracked oil and coal tar mass percent are as follows: it is useless
Old tire cracked oil 50%, coal tar 50%,；The additional amount of the mutual solvent is waste tire cracked oil and coal tar total weight
2, the additional amount of the additive is the 0.15 of waste tire cracked oil and coal tar total weight.
Preferably, in the composite fuel oil dosage of waste tire cracked oil and coal tar mass percent are as follows: it is useless
Old tire cracked oil 60%, coal tar 40%；The additional amount of the mutual solvent be waste tire cracked oil and coal tar total weight 3%,
The additional amount of the additive is the 0.2% of waste tire cracked oil and coal tar total weight.
Preferably, the mutual solvent is surfactant.
Preferably, the surfactant is mixed using 40% pentanediol and 60% ethylene glycol, by mass percentage
Meter.
Preferably, the additive is one of dispersing agent, anti-coking agent, antismoke agent, corrosion inhibiter or any several mixed
It closes.
In the present invention, the waste tire cracked oil and coal tar are immiscible, and mutual solvent, i.e. surface-active is added
Agent (mixing of pentanediol and ethylene glycol) improves stabilization of the invention so that waste tire cracked oil and coal tar mix each other
Property.
Due to the adoption of the above technical scheme, the present invention has following superiority:
Composite fuel oil of the present invention is high with calorific value, smell is small, noxious gas emission is small, is with waste tire cracked oil
Main component can substantially reduce production cost.
Specific embodiment
Below by embodiment, the technical scheme of the present invention will be explained in further detail.
Embodiment 1
A kind of composite fuel oil prepared using waste tire cracked oil, the composite fuel oil is cracked by waste tire
Simultaneously mutual solvent, additive composition is added in oil, coal tar, the dosage of waste tire cracked oil and coal tar in the composite fuel oil
Mass percent are as follows: waste tire cracked oil 40%, coal tar 60%；The additional amount of the mutual solvent be waste tire cracked oil and
The 1% of coal tar total weight, the additional amount of the additive are the 0.1% of waste tire cracked oil and coal tar total weight.
In this embodiment, the mutual solvent uses surfactant, and surfactant uses 40% pentanediol and 60% second
Glycol is mixed, by mass percentage.
The additive is the mixing of dispersing agent, anti-coking agent, antismoke agent, corrosion inhibiter.
Embodiment 2
A kind of composite fuel oil prepared using waste tire cracked oil, the composite fuel oil is cracked by waste tire
Simultaneously mutual solvent, additive composition is added in oil, coal tar, the dosage of waste tire cracked oil and coal tar in the composite fuel oil
Mass percent are as follows: waste tire cracked oil 50%, coal tar 50%；The additional amount of the mutual solvent be waste tire cracked oil and
The 2% of coal tar total weight, the additional amount of the additive are the 0.15% of waste tire cracked oil and coal tar total weight.
In this embodiment, the mutual solvent uses surfactant, and surfactant uses 40% pentanediol and 60% second
Glycol is mixed, by mass percentage.
The additive is the mixing of dispersing agent, anti-coking agent, antismoke agent, corrosion inhibiter.
Embodiment 3
A kind of composite fuel oil prepared using waste tire cracked oil, the composite fuel oil is cracked by waste tire
Simultaneously mutual solvent, additive composition is added in oil, coal tar, the dosage of waste tire cracked oil and coal tar in the composite fuel oil
Mass percent are as follows: waste tire cracked oil 60%, coal tar 40%；The additional amount of the mutual solvent be waste tire cracked oil and
The 3% of coal tar total weight, the additional amount of the additive are the 0.2% of waste tire cracked oil and coal tar total weight.
In this embodiment, the mutual solvent uses surfactant, and surfactant uses 40% pentanediol and 60% second
Glycol is mixed, by mass percentage.
The additive is the mixing of dispersing agent, anti-coking agent, antismoke agent, corrosion inhibiter.
The actual performance index of composite fuel oil in embodiment 1-3 is detected, as a result as shown in the table:
After actual measurement it is found that the composite fuel oil in embodiment 1-3 meets power plant's igniting requirement.
In the present invention, the waste tire cracked oil is the product generated by waste tire through Pintsch process, tool
Production procedure is as follows:
(1) waste tire first passes around the waste and old rubber particle of crushing, isolated 10-20 mesh；
(2) waste and old rubber particle and catalyst are added in pyrolysis furnace and carry out catalytic pyrolysis 20-25 minutes, wherein cracking temperature
It is 350-400 DEG C, cracking pressure is -0.02 megapascal to -0.04 megapascal；The catalyst accounts for the 1- of waste and old rubber particle weight
2%, the catalyst is made of following component: the kaolin of 50-60 parts by weight, the atlapulgite of 20-30 parts by weight, 15-25 weight
Measure the barium chloride or barium sulfate of part, the titanium dioxide of 25-30 parts by weight, the aluminium oxide of 5-10 parts by weight；
(3) high-temperature oil gas and thin carbon black that cracking generates enter high-temperature gas-solid separator, isolate high-temperature oil gas and thin carbon black；It is high
Warm oil gas enters fractionating column and condenses to obtain waste tire cracked oil.
Claims (7)
1. it is a kind of using waste tire cracked oil prepare composite fuel oil, it is characterised in that: the composite fuel oil be by
Simultaneously mutual solvent, additive composition is added in waste tire cracked oil, coal tar, waste tire cracked oil and coal in the composite fuel oil
The mass percent of the dosage of tar are as follows: waste tire cracked oil 40%~60%, coal tar 40%~60%；The mutual solvent adds
Enter 1%~3% that amount is waste tire cracked oil and coal tar total weight, the additional amount of the additive is waste tire cracked oil
With the 0.1%~0.2% of coal tar total weight.
2. the composite fuel oil according to claim 1 prepared using waste tire cracked oil, it is characterised in that: described multiple
Close the mass percent of the dosage of waste tire cracked oil and coal tar in fuel oil are as follows: waste tire cracked oil 40%, coal tar
60%, the additional amount of the mutual solvent is the 1% of waste tire cracked oil and coal tar total weight, and the additional amount of the additive is
The 0.1% of waste tire cracked oil and coal tar total weight.
3. the composite fuel oil according to claim 1 prepared using waste tire cracked oil, it is characterised in that: described multiple
Close the mass percent of the dosage of waste tire cracked oil and coal tar in fuel oil are as follows: waste tire cracked oil 50%, coal tar
50%,；The additional amount of the mutual solvent is the 2 of waste tire cracked oil and coal tar total weight, and the additional amount of the additive is
The 0.15 of waste tire cracked oil and coal tar total weight.
4. the composite fuel oil according to claim 1 prepared using waste tire cracked oil, it is characterised in that: described multiple
Close the mass percent of the dosage of waste tire cracked oil and coal tar in fuel oil are as follows: waste tire cracked oil 60%, coal tar
40%；The additional amount of the mutual solvent is waste tire cracked oil and coal tar total weight 3%, and the additional amount of the additive is useless
The 0.2% of old tire cracked oil and coal tar total weight.
5. the composite fuel oil prepared described in any one of -4 using waste tire cracked oil according to claim 1, feature
Be: the mutual solvent is surfactant.
6. the composite fuel oil according to claim 5 prepared using waste tire cracked oil, it is characterised in that: surface is living
Property agent be mixed using 40% pentanediol and 60% ethylene glycol, by mass percentage.
7. the composite fuel oil prepared described in any one of -4 using waste tire cracked oil according to claim 1, feature
Be: the additive is one of dispersing agent, anti-coking agent, antismoke agent, corrosion inhibiter or any several mixing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811007988.9A CN109022016A (en) | 2018-08-31 | 2018-08-31 | A kind of composite fuel oil prepared using waste tire cracked oil |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811007988.9A CN109022016A (en) | 2018-08-31 | 2018-08-31 | A kind of composite fuel oil prepared using waste tire cracked oil |
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| Publication Number | Publication Date |
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| CN109022016A true CN109022016A (en) | 2018-12-18 |
Family
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| CN201811007988.9A Pending CN109022016A (en) | 2018-08-31 | 2018-08-31 | A kind of composite fuel oil prepared using waste tire cracked oil |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101215481A (en) * | 2008-01-18 | 2008-07-09 | 孙昔铭 | Liquid fuel for boiler and preparation method thereof |
| CN103937564A (en) * | 2014-04-26 | 2014-07-23 | 张军 | Efficient special oil for kiln as well as preparation method of efficient special oil |
| CN106010675A (en) * | 2016-05-17 | 2016-10-12 | 武汉斯奇环保科技有限公司 | Composite fuel oil |
| CN106635189A (en) * | 2016-12-30 | 2017-05-10 | 广西东奇能源技术有限公司 | Coal alcohol-based fuel |
| CN106675672A (en) * | 2016-11-24 | 2017-05-17 | 贵州黔晟新能源实业有限公司 | High-flash-point coal tar alcohol-based fuel and preparation method thereof |
-
2018
- 2018-08-31 CN CN201811007988.9A patent/CN109022016A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101215481A (en) * | 2008-01-18 | 2008-07-09 | 孙昔铭 | Liquid fuel for boiler and preparation method thereof |
| CN103937564A (en) * | 2014-04-26 | 2014-07-23 | 张军 | Efficient special oil for kiln as well as preparation method of efficient special oil |
| CN106010675A (en) * | 2016-05-17 | 2016-10-12 | 武汉斯奇环保科技有限公司 | Composite fuel oil |
| CN106675672A (en) * | 2016-11-24 | 2017-05-17 | 贵州黔晟新能源实业有限公司 | High-flash-point coal tar alcohol-based fuel and preparation method thereof |
| CN106635189A (en) * | 2016-12-30 | 2017-05-10 | 广西东奇能源技术有限公司 | Coal alcohol-based fuel |
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