CN106010675A - Composite fuel oil - Google Patents

Composite fuel oil Download PDF

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Publication number
CN106010675A
CN106010675A CN201610325155.1A CN201610325155A CN106010675A CN 106010675 A CN106010675 A CN 106010675A CN 201610325155 A CN201610325155 A CN 201610325155A CN 106010675 A CN106010675 A CN 106010675A
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China
Prior art keywords
fuel oil
oil
additive
composite fuel
agent
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CN201610325155.1A
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Chinese (zh)
Inventor
许晗珅
范德胜
刘国清
罗乾坤
杨铁
朱晖
何田
杨太勇
丁厂长
吴志强
熊建覃
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Wuhan Siqi Environmental Protection Technology Co Ltd
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Wuhan Siqi Environmental Protection Technology Co Ltd
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Priority to CN201610325155.1A priority Critical patent/CN106010675A/en
Publication of CN106010675A publication Critical patent/CN106010675A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/106—Liquid carbonaceous fuels containing additives mixtures of inorganic compounds with organic macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1216—Inorganic compounds metal compounds, e.g. hydrides, carbides
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    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1886—Carboxylic acids; metal salts thereof naphthenic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/196—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof
    • C10L1/1966—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof poly-carboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/221—Organic compounds containing nitrogen compounds of uncertain formula; reaction products where mixtures of compounds are obtained
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
    • C10L1/2437—Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L2300/00—Mixture of two or more additives covered by the same group of C10L1/00 - C10L1/308
    • C10L2300/20—Mixture of two components

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention discloses composite fuel oil and belongs to the technical field of petrochemical engineering. The composite fuel oil is prepared from, in percentage by mass, 40%-70% of fossil fuel oil, 20%-30% of solvent oil, 0-25% of gutter oil and 0-10% of coal tar, 1 permillage of an additive is further added to the composite fuel oil, and the additive is a mixture of a compatilizer, an anti-smoke agent, an anti-coking agent, an antioxidant and a pour point depressant in mass ratio being (1-10) : (1-10) : (1-10) : (0-1) : (0-1). High-viscosity and high-solidifying-point fossil fuel oil and low-viscosity and low-solidifying-point solvent oil are composited, the additive is added, and the combustion characteristics such as viscosity, flash points and the like of fuel oil are improved. The composite fuel oil is possibly applied to a power station, a cement plant, a glass factory and other industries to replace light diesel oil or heavy oil, is economical and realizes sustainable development.

Description

A kind of composite fuel oil
Technical field
The invention belongs to technical field of petrochemical industry, more particularly to a kind of composite fuel oil.
Background technology
Fuel oil is the widely used a kind of Fossil fuel of industrial quarters, but owing to its viscosity is high, solidifying Point is high, uses difficulty, is not accepted by kiln (including power plant boiler).These kilns Stove is still continuing with the 0# light diesel fuel of high-quality, even vehicle light diesel fuel.Thermal power plant pot Stove startup stage, even also use light diesel fuel energetically continuing in the operation phase, great majority are also It is to use high-quality automobile-used 0# light diesel fuel, uses the sole purpose of light diesel fuel to burn exactly light diesel fuel, Obtain its heat, but high-quality light diesel fuel is relatively costly, adds production cost.
Chinese invention patent application (application publication number: CN102382690A, Shen Qing Publication day: 2012-03-21) disclose the patent literary composition of the production method of entitled a kind of environment-friendlyrenewable renewable fuel oil Offer.This production method disclose the composition of product and proportioning be bio oil (60wt%～70wt%), Crude carbinol (10wt%～15wt%), coal tar (18.051wt%～21.949wt%), ferrocene (0.001wt%～0.002wt%), sodium hydroxide (1wt%～2wt%), camphor powder (0.05wt%～0.1wt%) and acetone (0.949wt%～0.898wt%).The product environmental protection of the present invention, Main component bio oil is the product liquid that fast pyrogenation agriculture and forestry organic waste material obtains, and has renewable Property, is mainly used in Industrial Boiler, Industrial Stoves and restaurant's cooking stove combustion heat supplying it can also be used to heat Power plant combustion generates electricity.But selling price is about 2000$/ton, far above commercially available heavy oil and bavin The price of oil, and combustion heat value is about 20MJ/kg, is difficult to industrialization.
Summary of the invention
For solving above-mentioned technical problem, the invention discloses a kind of composite fuel oil.By changing Stone fuel oil and solvent naphtha adds specialty additive, the hybrid fuel oil viscosity obtained, solidifying The key index such as solid point, flash-point, close to light diesel fuel, therefore can substitute light diesel fuel for industry pot In stove and Industrial Stoves.
The composite fuel oil of the present invention, by mass percentage, including Fossil fuel oil 40～70%, Solvent naphtha 20～30%, waste oil 0～25% and coal tar 0～10%, described composite fuel oil is also Including the additive of 1 ‰, the described additive ratio that is mass fraction is for compatilizer: anti-fumicants: anti- Coking agent: antioxidant: pour-point depressant=1～10:1～10:1～10:0～1:0～the mixture of 1.
Specifically, composite fuel oil by mass percentage, including Fossil fuel oil 60%, solvent Oil 30% and waste oil 10%, the additive ratio that is mass fraction is for compatilizer: anti-fumicants: resistive connection Burnt agent: antioxidant: the mixture of pour-point depressant=10:6:4:1:1.
Specifically, composite fuel oil by mass percentage, including Fossil fuel oil 70% and solvent Oil 30%, the additive ratio that is mass fraction is for compatilizer: anti-fumicants: anti-coking agent: antioxidation The mixture of agent=10:8:5:1.
Specifically, composite fuel oil by mass percentage, including Fossil fuel oil 50%, solvent Oil 20%, waste oil 25% and coal tar 5%, the additive ratio that is mass fraction is for compatilizer: Anti-fumicants: anti-coking agent: antioxidant: the mixture of pour-point depressant=10:5:5:1:1.
Technology as the present invention is preferred, and described compatilizer is that maleic anhydride stem grafting polyolefin is elastic Body, maleated ethylene vinyl acetate copolyme and maleic anhydride grafting low density polyethylene One or both in alkene.
Technology as the present invention is preferred, and described anti-fumicants is naphthenate, ethylhexanoate salt, table Face activating agent is uniformly mixed, and mass fraction is than naphthenate: ethylhexanoate salt: live in surface Property agent=2:2:1, described surfactant is ionic surfactant, described ion-type surface Activating agent is stearic acid, one or both in dodecylbenzene sodium sulfonate.
Technology as the present invention is preferred, described anti-coking agent be Potassium metaperiodate., potassium permanganate, One or both in ferrocene, methanol.
Technology as the present invention is preferred, and described antioxidant is tea polyphenol-palmitate, is obstructed One or both in phenol, amino-compound, described pour-point depressant is in methanol, ethylhexanoate salt A kind of.
Fossil fuel oil in the present invention is industrial heavy oil, and solvent naphtha is that Shandong region rising sun occasion go out Factory's oil.
The beneficial effects of the present invention is:
1, the present invention is by high viscosity, Fossil fuel oil and low viscosity, the low-freezing of high-solidification point Solvent naphtha is combined, and improves fuel oil viscosity, flash-point etc. and uses characteristic, makes compound combustion Material oil substitute light diesel fuel or heavy oil in power plant, cement plant, the application of the industry such as glass factory become May and economical, it is achieved sustainable development.
2, the oil of the Fossil fuel in the present invention or waste oil are made without deep processing, only need to carry out Simple filtration, dehydration, production cost is low so that the cost performance of fuel oil is high, with fossil Class light diesel fuel, heavy oil are compared, and using effect is the poorest, and price but has extremely strong competitiveness, can For using unit to bring considerable economic benefit.
3, the present invention adds additive in the compound oil of Fossil fuel oil and solvent naphtha, solves Oil layering, the burning problem such as over-emitting black exhaust, coking, and the stable in properties of the composite fuel oil produced, Calorific value is higher, reaches 30～42MJ/kg.
Detailed description of the invention
In order to preferably explain the present invention, it is further elucidated with the present invention below in conjunction with specific embodiment Main contents, but present disclosure is not limited solely to following example.
Embodiment 1
A kind of composite fuel oil, by mass percentage, including Fossil fuel oil 60%, solvent naphtha 30%, waste oil 10%, and composite fuel oil also includes the additive of 1 ‰, additive is matter Amount portion rate is compatilizer: anti-fumicants: anti-coking agent: antioxidant: pour-point depressant=10:6:4:1:1 Mixture, compatilizer is maleic anhydride stem grafting polyolefin elastomer the most in this embodiment, anti- Fumicants be mass fraction than naphthenate: ethylhexanoate salt: the mixture of surfactant=2:2:1, Surfactant prioritizing selection dodecylbenzene sodium sulfonate, anti-coking agent is Potassium metaperiodate., anti- Oxidant is tea polyphenol-palmitate, pour-point depressant prioritizing selection methanol, the compound combustion prepared The calorific value of material oil reaches 38.6MJ/kg, and kinematic viscosity is 6.0mm2, condensation point is-1.0 DEG C.
Embodiment 2
A kind of composite fuel oil, by mass percentage, including Fossil fuel oil 70%, solvent naphtha 30% and the additive of 1 ‰, additive is mass fraction than for compatilizer: anti-fumicants: resistive connection Burnt agent: the mixture of antioxidant=10:8:5:1, compatilizer is preferably Malaysia in the present embodiment Anhydride grafted ethylene-vinyl acetate co-polymer, anti-fumicants be mass fraction than naphthenate: different Caprylate: the mixture of surfactant=2:2:1, surfactant prioritizing selection stearic acid, Coking agent is potassium permanganate, and antioxidant is hindered phenol, and pour-point depressant is ethylhexanoate salt, is prepared into To the calorific value of composite fuel oil reach 41.2MJ/kg, and kinematic viscosity is 5.5mm2, condensation point It it is 0 DEG C.
Embodiment 3
A kind of composite fuel oil, by mass percentage, including Fossil fuel oil 50%, solvent naphtha 20%, waste oil 25%, coal tar 5% and the additive of 1 ‰, additive is mass fraction Ratio is compatilizer: anti-fumicants: anti-coking agent: antioxidant: pour-point depressant=10:5:5:1:1's is mixed Compound, and compatilizer be preferably maleic anhydride grafting Low Density Polyethylene, anti-fumicants is mass parts Number is than naphthenate: ethylhexanoate salt: the mixture of surfactant=2:2:1, surfactant For stearic acid and the mixture of dodecylbenzene sodium sulfonate, anti-coking agent is dicyclopentadiene Ferrum, antioxidant is amino-compound, and pour-point depressant is methanol, the composite fuel oil prepared Calorific value reach 34.6MJ/kg, and kinematic viscosity is 3.0mm2, condensation point is-2.0 DEG C.
Embodiment 4
A kind of composite fuel oil, by mass percentage, including Fossil fuel oil 40%, solvent naphtha 25%, waste oil 25%, coal tar 10% and the additive of 1 ‰, additive is mass fraction Ratio is compatilizer: anti-fumicants: anti-coking agent: antioxidant: pour-point depressant=10:5:5:1:1's is mixed Compound, and compatilizer preferably compatilizer is maleic anhydride stem grafting polyolefin elastomer and maleic acid The mixture of acid anhydride grafted ethene-vinyl acetate co-polymer, anti-fumicants is naphthenate, isooctyl acid Salt, surfactant uniformly mix and make, and mass fraction is than naphthenate: ethylhexanoate salt: Surfactant=2:2:1, surfactant is the mixing of stearic acid and dodecylbenzene sodium sulfonate Thing, anti-coking agent is methanol, and antioxidant is the mixture of tea polyphenol-palmitate and hindered phenol, Pour-point depressant is ethylhexanoate salt, and the calorific value of the composite fuel oil prepared reaches 31.6MJ/kg, And kinematic viscosity is 4.5mm2, condensation point is-1.5 DEG C.
Embodiment 5
A kind of composite fuel oil, by mass percentage, including Fossil fuel oil 55%, solvent naphtha 20%, waste oil 20%, coal tar 5% and the additive of 1 ‰, additive is mass fraction Ratio is compatilizer: anti-fumicants: anti-coking agent: antioxidant: pour-point depressant=10:5:5:1:1's is mixed Compound, and compatilizer is preferably maleic anhydride stem grafting polyolefin elastomer and maleic anhydride grafting is low The mixture of density polyethylene, anti-fumicants is that naphthenate, ethylhexanoate salt, surfactant are equal Even mixing and make, and mass fraction is than naphthenate: ethylhexanoate salt: surfactant=2:2:1, Surfactant is the mixture of stearic acid and dodecylbenzene sodium sulfonate, and anti-coking agent is dimerization Cyclopentadiene ferrum, antioxidant is amino-compound, and pour-point depressant is methanol, and prepare answers The calorific value closing fuel oil reaches 36.6MJ/kg, and kinematic viscosity is 5.0mm2, condensation point is 0 DEG C.
Table 1 is the use standard of light diesel fuel；
Table 2 is the performance test of the composite fuel oil that embodiment 1 to embodiment 5 prepares.
Wherein use instrument is:
Dalian intelligent instrumentation company limited DZY-002 close flash point determinator,
DZY-003D measured for petroleum product distillation device,
DZY-008 density gauge (densimeter method),
Zibo Zi Fen Instrument Ltd. YDN100 type automatic kinematic viscosity analyzer.
The use standard of table 1 light diesel fuel
The performance test results of the composite fuel oil of table 2 embodiment 1～embodiment 5 preparation
From Table 2, it can be seen that the combustion heat value of composite fuel oil reaches 30～42MJ/kg, though More slightly lower than the calorific value of daily Fossil fuel, but the Fossil fuel oil used or waste oil are not Needing to carry out deep processing, only need to simply filter, be dehydrated, production cost is low so that combustion The cost performance of material oil is high.
Above example is only optimal citing, and is not the limit to embodiments of the present invention Fixed.In addition to the implementation, the present invention also has other embodiments.All employing equivalents or The technical scheme that equivalent transformation is formed, all falls within the protection domain of application claims.

Claims (8)

1. a composite fuel oil, it is characterised in that: by mass percentage, fire including fossil Material oil 40～70%, solvent naphtha 20～30%, waste oil 0～25% and coal tar 0～10%, institute Stating the additive that composite fuel oil also includes 1 ‰, described additive is that mass fraction ratio is for compatible Agent: anti-fumicants: anti-coking agent: antioxidant: pour-point depressant=1～10:1～10:1～10:0～1:0～1 Mixture.
Composite fuel oil the most according to claim 1, it is characterised in that: hybrid fuel Oil by mass percentage, including Fossil fuel oil 60%, solvent naphtha 30% and waste oil 10%, Additive is mass fraction than for compatilizer: anti-fumicants: anti-coking agent: antioxidant: pour point depression The mixture of agent=10:6:4:1:1.
Composite fuel oil the most according to claim 1, it is characterised in that: hybrid fuel By mass percentage, including Fossil fuel oil 70% and solvent naphtha 30%, additive is quality to oil Portion rate is compatilizer: anti-fumicants: anti-coking agent: the mixture of antioxidant=10:8:5:1.
Composite fuel oil the most according to claim 1, it is characterised in that: hybrid fuel Oil by mass percentage, including Fossil fuel oil 50%, solvent naphtha 20%, waste oil 25% and Coal tar 5%, the additive ratio that is mass fraction is for compatilizer: anti-fumicants: anti-coking agent: anti- Oxidant: the mixture of pour-point depressant=10:5:5:1:1.
5., according to the composite fuel oil described in claim 1 or 2 or 3 or 4, its feature exists In: described compatilizer be maleic anhydride stem grafting polyolefin elastomer, maleic anhydride grafted ethene- Vinyl acetate co-polymer and maleic anhydride grafting Low Density Polyethylene in one or both.
6., according to the composite fuel oil described in claim 1 or 2 or 3 or 4, its feature exists It is that naphthenate, ethylhexanoate salt, surfactant are uniformly mixed in: described anti-fumicants, And mass fraction is than naphthenate: ethylhexanoate salt: surfactant=2:2:1, live in described surface Property agent is ionic surfactant.
7., according to the composite fuel oil described in claim 1 or 2 or 3 or 4, its feature exists In: described anti-coking agent is in Potassium metaperiodate., potassium permanganate, ferrocene, methanol One or both.
8., according to the composite fuel oil described in claim 1 or 2 or 3 or 4, its feature exists In: described antioxidant is the one in tea polyphenol-palmitate, hindered phenol, amino-compound Or two kinds, described pour-point depressant is the one in methanol, ethylhexanoate salt.
CN201610325155.1A 2016-05-17 2016-05-17 Composite fuel oil Pending CN106010675A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109022016A (en) * 2018-08-31 2018-12-18 洛阳华燃石化科技有限公司 A kind of composite fuel oil prepared using waste tire cracked oil

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102676245A (en) * 2012-05-02 2012-09-19 杭州炬腾燃料油有限公司 Composite fuel oil and preparation method thereof
CN102719284A (en) * 2012-05-07 2012-10-10 深圳中兴新源环保股份有限公司 Renewable swill-cooked dirty fuel oil
US20130000184A1 (en) * 2009-12-24 2013-01-03 Clariant Finance (Bvi) Limited Multifunctional Cooling Additives For Middle Distillates, Having An Improved Flow Capability
CN103627456A (en) * 2013-11-19 2014-03-12 济南开发区星火科学技术研究院 Environment-friendly composite fuel oil additive and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130000184A1 (en) * 2009-12-24 2013-01-03 Clariant Finance (Bvi) Limited Multifunctional Cooling Additives For Middle Distillates, Having An Improved Flow Capability
CN102676245A (en) * 2012-05-02 2012-09-19 杭州炬腾燃料油有限公司 Composite fuel oil and preparation method thereof
CN102719284A (en) * 2012-05-07 2012-10-10 深圳中兴新源环保股份有限公司 Renewable swill-cooked dirty fuel oil
CN103627456A (en) * 2013-11-19 2014-03-12 济南开发区星火科学技术研究院 Environment-friendly composite fuel oil additive and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109022016A (en) * 2018-08-31 2018-12-18 洛阳华燃石化科技有限公司 A kind of composite fuel oil prepared using waste tire cracked oil

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