CN109015395A - A kind of production method of list glaze layer aluminium sheet decoration painting - Google Patents

A kind of production method of list glaze layer aluminium sheet decoration painting Download PDF

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Publication number
CN109015395A
CN109015395A CN201811010858.0A CN201811010858A CN109015395A CN 109015395 A CN109015395 A CN 109015395A CN 201811010858 A CN201811010858 A CN 201811010858A CN 109015395 A CN109015395 A CN 109015395A
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Prior art keywords
aluminium sheet
glaze layer
parts
decoration painting
firing
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CN201811010858.0A
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Chinese (zh)
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CN109015395B (en
Inventor
张柳松
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Baofeng Bo porcelain cultural and Creative Co.,Ltd.
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张柳松
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24CABRASIVE OR RELATED BLASTING WITH PARTICULATE MATERIAL
    • B24C1/00Methods for use of abrasive blasting for producing particular effects; Use of auxiliary equipment in connection with such methods
    • B24C1/08Methods for use of abrasive blasting for producing particular effects; Use of auxiliary equipment in connection with such methods for polishing surfaces, e.g. smoothing a surface by making use of liquid-borne abrasives
    • B24C1/086Descaling; Removing coating films
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/24Pressing or stamping ornamental designs on surfaces
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/20Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23DENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D5/00Coating with enamels or vitreous layers
    • C23D5/06Coating with enamels or vitreous layers producing designs or letters
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2207/00Compositions specially applicable for the manufacture of vitreous enamels
    • C03C2207/08Compositions specially applicable for the manufacture of vitreous enamels for light metals

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

The present invention relates to a kind of production methods of single glaze layer aluminium sheet decoration painting, including choose aluminium sheet, prepare glaze layer, mixing, spraying glaze layer, high definition are printed, are directly fired, cooling.The method of the present invention reasonable, it is ingenious in design, it is shaped using the glazing of single glaze layer, is not necessarily to secondary glazing, save production cost, the production time is saved, glaze layer and aluminium sheet are tightly combined, and it is beautiful and generous to fire product, it is wrinkle resistant that plate draws surfacing, it is sturdy and durable, it can save for a long time, solve aluminium sheet present in existing aluminium sheet enamel picture manufacturing process and be difficult to combine closely with surface glaze layer;Some factories are combined using double glaze layers with aluminium sheet, there are glazed thickness it is blocked up cause weight increase influence transport, when aluminium sheet is fired, do not grasp the time, cool down suddenly after firing, be easy to cause surface of aluminum plate arching deformation, influences the technical problems such as product quality and enterprise's productivity effect, for the prior art, have good market prospects and development space.

Description

A kind of production method of list glaze layer aluminium sheet decoration painting
Technical field
The present invention relates to metallic enamel technical fields, and in particular to a kind of production method of list glaze layer aluminium sheet decoration painting.
Background technique
Enamel is unorganic glass enamel of the blackening on metal bottom base surface.Carrying out the enamel application of slip in metal surface can be to prevent Only metal rusting makes metal be unlikely to form oxide layer on surface when heated and can resist the erosion of various liquid.Enamel Product is not only safe and non-toxic, is easy to wash cleaning, can be widely used as ware used in daily life and washing is used Tool is and under given conditions, hardness height that the enamel application of slip is shown on metal body, high temperature resistant, wear-resisting and insulate The excellent performances such as effect, make enamelware have more extensive purposes.Enamel layer can also impart to product with beautiful appearance, Decorate people's lives.It can be seen that enamelware has had both the intensity of metal and the property of the magnificent appearance and resistance to chemical attack of enamel Energy.
It is mainly that iron plate enamel picture and aluminium sheet enamel are drawn that existing metallic enamel, which is drawn, and iron plate enamel is drawn due to quality weight, fortune Defeated inconvenience becomes the reason of limiting its development.Although aluminium sheet enamel picture is low in cost, quality is light and handy, and there is also following Problem: one, surface of aluminum plate has one layer of fine and close oxidation film, and without processing, aluminium sheet is difficult close with surface glaze layer In conjunction with;Two, ground glaze layer is first prepared using special process by some factories and aluminium sheet tentatively fires combinations, then again with surface glaze layer and The mode that ground glaze layer recombines still has glaze layer although operation can combine surface glaze layer with aluminium sheet in this way Thickness is blocked up to lead to problems such as weight increase influence transport;Three, when aluminium sheet is fired, the time is not grasped, is cooled down suddenly after firing, It is easy to cause surface of aluminum plate arching deformation, influences quality.
How a kind of method reasonable is designed, it is ingenious in design, it is shaped using the glazing of single glaze layer, on secondary Glaze saves production cost, saves the production time, and glaze layer and aluminium sheet are tightly combined, and firing product is beautiful and generous, and plate draws surfacing Wrinkle resistant, sturdy and durable, the production method for the single glaze layer aluminium sheet decoration painting that can be saved for a long time is current problem to be solved.
Summary of the invention
There is one layer of fine and close oxidation film to solve surface of aluminum plate present in existing aluminium sheet enamel picture manufacturing process, not In processed situation, aluminium sheet is difficult to combine closely with surface glaze layer;Some factories are combined using double glaze layers with aluminium sheet, are deposited Glazed thickness it is blocked up cause weight increase influence transport, aluminium sheet fire when, do not grasp the time, cool down suddenly after firing, hold Surface of aluminum plate arching deformation is easily led to, the technical problems such as product quality and enterprise's productivity effect are influenced, the present invention provides a kind of list The production method of glaze layer aluminium sheet decoration painting carrys out implementation method reasonable, ingenious in design, is shaped using the glazing of single glaze layer, Without secondary glazing, production cost is saved, saves the production time, glaze layer and aluminium sheet are tightly combined, and firing product is beautiful and generous, plate It is wrinkle resistant to draw surfacing, sturdy and durable, the purpose that can be saved for a long time.
Used technical solution is the present invention to solve above-mentioned technical problem: a kind of production of list glaze layer aluminium sheet decoration painting Method, comprising the following steps:
Step 1 chooses aluminium sheet, is derusted using physical method or chemical method to surface of aluminum plate, oil removal processing;
Step 2 prepares glaze layer, each component quality proportioning of the glaze layer are as follows: and 20-30 parts of metallic aluminium powder, titanium dioxide powder 5- 10 parts, 10-20 parts of Aluminum sol solution, 30-60 parts of aluminium silicate mineral powder, 20-30 parts of low temperature frit powder, potassium oxide 10- 30 parts, 60-70 parts of water;
Step 3 uniformly mixes each component described in step 2, stirs 30-60 minutes, stands 10-30 minutes;
Aluminium sheet is horizontally arranged on glazing production line conveyer belt by step 4, using reciprocal automatic spray gun to aluminium sheet process face into Row even application glaze layer;
Step 5 carries out the printing of high definition pattern to the aluminium sheet after spraying glaze layer using nano ceramics printer;
Step 6, the aluminium sheet level after high definition is printed, which is put into glass tempering furnace, carries out rolling firing, firing temperature 550-650 DEG C, firing time 5-20min cools to aluminium sheet using Dual-layer air grid after having fired;
Physical method used in the step 1 is that sandblasting dust removal machine carries out derusting by sandblasting to surface of aluminum plate.
The diamond dust mesh number that the sandblasting dust removal machine uses is 200-400 mesh.
Chemical method used in the step 1 is base extraction surface of aluminum plate.
Compared with prior art, the beneficial effects of the present invention are:
1) present invention carries out derusting by sandblasting to surface of aluminum plate using sandblasting dust removal machine, and the diamond dust mesh number of sandblasting dust removal machine is 200- 400 mesh, when diamond dust mesh number is 200-400 in experiment, diamond dust can effectively during high-velocity spray to surface of aluminum plate into Row surface derusting carries out place mat for subsequent surface of aluminum plate glazing layer;
It is 2) innovative in the present invention to be added to Aluminum sol solution, aluminium silicate mineral, low temperature frit powder and potassium oxide powder, Potassium oxide is reacted with water in the solution generates potassium hydroxide and a large amount of heat, and potassium hydroxide is again in the Aluminum sol solution of heat and aluminium Powder powder further reacts, and generates colloidal solution, and glaze layer is uniformly attached to surface of aluminum plate, glazing forming, nothing well Secondary glazing need to be carried out, production cost is saved, saves the production time;
3) when low temperature frit, i.e. preparation glaze, by the water-soluble material of sodium carbonate, potassium carbonate, borax, boric acid etc and quartz or Other silicates are mixed in a certain ratio, manufactured frit, and frit and photoghraphic coupler are put together melting in proportion, make photoghraphic coupler It is uniformly distributed, adds a certain amount of clay to be mixed and finely ground again after cooling, mixed well with water or other liquid as fritted glaze, can be made water-soluble Property substance become insoluble, increase stability, suspension and the tackness with carcass of glaze, reduce bubble, to prevent these raw materials It dissolves when preparing glaze slip in water, is easily absorbed by green body during glazing;
4) printing of high definition pattern, the printing of nano ceramics printer are carried out to the aluminium sheet for spraying single glaze layer using nano ceramics printer Clearly, error is small, and easily operated control guarantees the beautiful and generous of pattern;
5) the aluminium sheet level after printing high definition, which is put into glass tempering furnace, carries out rolling firing, 550-650 DEG C of firing temperature, burns Time 5-20min processed cools to aluminium sheet using Dual-layer air grid after having fired, using novel reciprocating glass tempering Furnace is fired, and firing temperature and firing time are easily controllable, and firing product is beautiful and generous, and etching surfacing is wrinkle resistant, firm resistance to With reducing subsequent board with enamel panel layer in the prior art and flatten process, saved cost of labor, improved the performance of enterprises.
Specific embodiment
Specific embodiments of the present invention will be described in further detail below.
Embodiment one,
A kind of production method of list glaze layer aluminium sheet decoration painting, comprising the following steps:
Step 1 chooses aluminium sheet, is derusted using physical method or chemical method to surface of aluminum plate, oil removal processing;
Step 2 prepares glaze layer, each component quality proportioning of the glaze layer are as follows: and 20 parts of metallic aluminium powder, 5 parts of titanium dioxide powder, 10 parts of Aluminum sol solution, 30 parts of aluminium silicate mineral powder, 20 parts of low temperature frit powder, 10 parts of potassium oxide, 60 parts of water;
Step 3 uniformly mixes each component described in step 2, stirs 30 minutes, stands 10-30 minutes;
Aluminium sheet is horizontally arranged on glazing production line conveyer belt by step 4, using reciprocal automatic spray gun to aluminium sheet process face into Row even application glaze layer;
Step 5 carries out the printing of high definition pattern to the aluminium sheet after spraying glaze layer using nano ceramics printer;
Step 6, the aluminium sheet level after high definition is printed, which is put into glass tempering furnace, carries out rolling firing, and 550 DEG C of firing temperature, Firing time 5min cools to aluminium sheet using Dual-layer air grid after having fired;
The above are basic embodiments of the invention, further can be improved, improved and limited on the basis of above: as described in Physical method used in step 1 is that sandblasting dust removal machine carries out derusting by sandblasting to surface of aluminum plate.
The above are basic embodiments of the invention, further can be improved, improved and limited on the basis of above: such as The diamond dust mesh number that the sandblasting dust removal machine uses is 200 mesh.
The above are basic embodiments of the invention, further can be improved, improved and limited on the basis of above: such as Chemical method used in the step 1 is base extraction surface of aluminum plate.
Embodiment two,
A kind of production method of list glaze layer aluminium sheet decoration painting, comprising the following steps:
Step 1 chooses aluminium sheet, is derusted using physical method or chemical method to surface of aluminum plate, oil removal processing;
Step 2 prepares glaze layer, each component quality proportioning of the glaze layer are as follows: and 25 parts of metallic aluminium powder, 8 parts of titanium dioxide powder, 15 parts of Aluminum sol solution, 45 parts of aluminium silicate mineral powder, 25 parts of low temperature frit powder, 15 parts of potassium oxide, 65 parts of water;
Step 3 uniformly mixes each component described in step 2, stirs 45 minutes, stands 25 minutes;
Aluminium sheet is horizontally arranged on glazing production line conveyer belt by step 4, using reciprocal automatic spray gun to aluminium sheet process face into Row even application glaze layer;
Step 5 carries out the printing of high definition pattern to the aluminium sheet after spraying glaze layer using nano ceramics printer;
Step 6, the aluminium sheet level after high definition is printed, which is put into glass tempering furnace, carries out rolling firing, and 600 DEG C of firing temperature, Firing time 10min cools to aluminium sheet using Dual-layer air grid after having fired;
The above are basic embodiments of the invention, further can be improved, improved and limited on the basis of above: as described in Physical method used in step 1 is that sandblasting dust removal machine carries out derusting by sandblasting to surface of aluminum plate.
The above are basic embodiments of the invention, further can be improved, improved and limited on the basis of above: such as The diamond dust mesh number that the sandblasting dust removal machine uses is 300 mesh.
The above are basic embodiments of the invention, further can be improved, improved and limited on the basis of above: such as Chemical method used in the step 1 is base extraction surface of aluminum plate.
Embodiment three,
A kind of production method of list glaze layer aluminium sheet decoration painting, comprising the following steps:
Step 1 chooses aluminium sheet, is derusted using physical method or chemical method to surface of aluminum plate, oil removal processing;
Step 2 prepares glaze layer, each component quality proportioning of the glaze layer are as follows: and 30 parts of metallic aluminium powder, 10 parts of titanium dioxide powder, 20 parts of Aluminum sol solution, 60 parts of aluminium silicate mineral powder, 30 parts of low temperature frit powder, 30 parts of potassium oxide, 70 parts of water;
Step 3 uniformly mixes each component described in step 2, stirs 60 minutes, stands 30 minutes;
Aluminium sheet is horizontally arranged on glazing production line conveyer belt by step 4, using reciprocal automatic spray gun to aluminium sheet process face into Row even application glaze layer;
Step 5 carries out the printing of high definition pattern to the aluminium sheet after spraying glaze layer using nano ceramics printer;
Step 6, the aluminium sheet level after high definition is printed, which is put into glass tempering furnace, carries out rolling firing, and 650 DEG C of firing temperature, Firing time 20min cools to aluminium sheet using Dual-layer air grid after having fired;
The above are basic embodiments of the invention, further can be improved, improved and limited on the basis of above: as described in Physical method used in step 1 is that sandblasting dust removal machine carries out derusting by sandblasting to surface of aluminum plate.
The above are basic embodiments of the invention, further can be improved, improved and limited on the basis of above: such as The diamond dust mesh number that the sandblasting dust removal machine uses is 400 mesh.
The above are basic embodiments of the invention, further can be improved, improved and limited on the basis of above: such as Chemical method used in the step 1 is base extraction surface of aluminum plate.
In practical operation, step 2 prepares the low temperature frit powder that uses of transition glaze layer, water, wherein low temperature frit powder End number can increase and decrease according to actual needs, the present invention in be not limited to mass fraction required by above-described embodiment;In step In rapid five, the aluminium sheet for having sprayed glaze layer is fired using glass tempering furnace roll mode, firing temperature and firing time by Depending on the aluminium plate thickness of selection, aluminium sheet is thinner, and the firing time is shorter, and aluminium sheet is thicker, and the firing time is longer.
In printing step, the printing dyestuff that the present invention uses is inorganic dyestuff, in printing and firing, will not generate Machine exhaust gas, it is environmentally friendly, it is environmentally protective, meet enterprise Green developing direction.
It is cooled using Dual-layer air grid to aluminium sheet after having fired, is burnt using novel reciprocating glass tempering furnace System, firing temperature and firing time are easily controllable, and firing product is beautiful and generous, and etching surfacing is wrinkle resistant, sturdy and durable, subtract Subsequent board with enamel panel layer in the prior art is lacked and has flattened process, has saved cost of labor, improved the performance of enterprises.
The method of the present invention reasonable, it is ingenious in design, it is shaped using the glazing of single glaze layer, is not necessarily to secondary glazing, saved Production cost saves the production time, and glaze layer and aluminium sheet are tightly combined, and firing product is beautiful and generous, and plate picture surfacing is wrinkle resistant, It is sturdy and durable, it can save for a long time, solving surface of aluminum plate present in existing aluminium sheet enamel picture manufacturing process has one layer of fine and close oxygen Change film, without processing, aluminium sheet is difficult to combine closely with surface glaze layer;Some factories are using double glaze layers and aluminium sheet knot Altogether, cause weight to increase to influence transport when aluminium sheet is fired and do not grasp the time, fire processus aboralis there are glazed thickness is blocked up So cooling, is easy to cause surface of aluminum plate arching deformation, the technical problems such as product quality and enterprise's productivity effect is influenced, to existing skill For art, have good market prospects and development space.
The preferred embodiments of the disclosure and embodiment are explained in detail above, but the present invention is not limited to The above-described embodiment and examples can also not depart from the present invention within the knowledge of those skilled in the art Various changes can be made under the premise of design.

Claims (4)

1. a kind of production method of list glaze layer aluminium sheet decoration painting, it is characterised in that: the following steps are included:
Step 1 chooses aluminium sheet, is derusted using physical method or chemical method to surface of aluminum plate, oil removal processing;
Step 2 prepares glaze layer, each component quality proportioning of the glaze layer are as follows: and 20-30 parts of metallic aluminium powder, titanium dioxide powder 5- 10 parts, 10-20 parts of Aluminum sol solution, 30-60 parts of aluminium silicate mineral powder, 20-30 parts of low temperature frit powder, potassium oxide 10- 30 parts, 60-70 parts of water;
Step 3 uniformly mixes each component described in step 2, stirs 30-60 minutes, stands 10-30 minutes;
Aluminium sheet is horizontally arranged on glazing production line conveyer belt by step 4, using reciprocal automatic spray gun to aluminium sheet process face into Row even application glaze layer;
Step 5 carries out the printing of high definition pattern to the aluminium sheet after spraying glaze layer using nano ceramics printer;
Step 6, the aluminium sheet level after high definition is printed, which is put into glass tempering furnace, carries out rolling firing, firing temperature 550-650 DEG C, firing time 5-20min cools to aluminium sheet using Dual-layer air grid after having fired.
2. a kind of production method of single glaze layer aluminium sheet decoration painting as described in claim 1, it is characterised in that: in the step 1 The physical method used is that sandblasting dust removal machine carries out derusting by sandblasting to surface of aluminum plate.
3. a kind of production method of single glaze layer aluminium sheet decoration painting as claimed in claim 2, it is characterised in that: the sandblasting removes The diamond dust mesh number that dirt machine uses is 200-400 mesh.
4. a kind of production method of single glaze layer aluminium sheet decoration painting as described in claim 1, it is characterised in that: in the step 1 The chemical method used is base extraction surface of aluminum plate.
CN201811010858.0A 2018-08-31 2018-08-31 Method for manufacturing single-glaze-layer aluminum plate decorative picture Active CN109015395B (en)

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CN109015395B CN109015395B (en) 2020-09-04

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110228321A (en) * 2019-06-06 2019-09-13 浙江开尔新材料股份有限公司 A kind of production method for making white pattern on background color enamel steel plate
CN112681652A (en) * 2020-12-24 2021-04-20 宝丰大博瓷画文化创意有限公司 Manufacturing method and application of eye-protecting ultrathin diamond-jade television background wall

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CN103467134A (en) * 2012-06-06 2013-12-25 湖南泰鑫瓷业有限公司 Preparation method of beige high brightness metal glaze
CN103992694A (en) * 2014-05-21 2014-08-20 佛山远牧数码科技有限公司 High-vanadium ceramic printing ink, and preparation and application methods thereof
CN104692833A (en) * 2015-02-27 2015-06-10 唐山中陶卫浴制造有限公司 High-hardness wollastonite glaze slip and preparation method thereof
CN105218165A (en) * 2015-10-19 2016-01-06 福建省德化县华茂陶瓷有限公司 Dazzling iron rust glaze and by its dazzling iron rust glaze ceramic prepared and preparation method
CN105272366A (en) * 2015-10-15 2016-01-27 蒙娜丽莎集团股份有限公司 Preparation method of color-sprayed ceramic plate decorative painting
CN106396394A (en) * 2016-08-29 2017-02-15 佛山市高明区诚睿基科技有限公司 Ecological ceramic tile and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103467134A (en) * 2012-06-06 2013-12-25 湖南泰鑫瓷业有限公司 Preparation method of beige high brightness metal glaze
CN103992694A (en) * 2014-05-21 2014-08-20 佛山远牧数码科技有限公司 High-vanadium ceramic printing ink, and preparation and application methods thereof
CN104692833A (en) * 2015-02-27 2015-06-10 唐山中陶卫浴制造有限公司 High-hardness wollastonite glaze slip and preparation method thereof
CN105272366A (en) * 2015-10-15 2016-01-27 蒙娜丽莎集团股份有限公司 Preparation method of color-sprayed ceramic plate decorative painting
CN105218165A (en) * 2015-10-19 2016-01-06 福建省德化县华茂陶瓷有限公司 Dazzling iron rust glaze and by its dazzling iron rust glaze ceramic prepared and preparation method
CN106396394A (en) * 2016-08-29 2017-02-15 佛山市高明区诚睿基科技有限公司 Ecological ceramic tile and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110228321A (en) * 2019-06-06 2019-09-13 浙江开尔新材料股份有限公司 A kind of production method for making white pattern on background color enamel steel plate
CN112681652A (en) * 2020-12-24 2021-04-20 宝丰大博瓷画文化创意有限公司 Manufacturing method and application of eye-protecting ultrathin diamond-jade television background wall

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Effective date of registration: 20211216

Address after: 467400 4th floor, Baofeng County, Pingdingshan City, Henan Province

Patentee after: Baofeng Bo porcelain cultural and Creative Co.,Ltd.

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Patentee before: Zhang Liusong

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