CN109006819A - A kind of bactericidal composition and application thereof containing zoxamide Yu biphenyl pyrrole bacterium amine - Google Patents
A kind of bactericidal composition and application thereof containing zoxamide Yu biphenyl pyrrole bacterium amine Download PDFInfo
- Publication number
- CN109006819A CN109006819A CN201811113334.4A CN201811113334A CN109006819A CN 109006819 A CN109006819 A CN 109006819A CN 201811113334 A CN201811113334 A CN 201811113334A CN 109006819 A CN109006819 A CN 109006819A
- Authority
- CN
- China
- Prior art keywords
- zoxamide
- bacterium amine
- pyrrole bacterium
- biphenyl pyrrole
- bactericidal composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group, wherein Cn means a carbon skeleton not containing a ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to technical field of pesticide, are related to a kind of bactericidal composition containing zoxamide Yu biphenyl pyrrole bacterium amine, further relate to the bactericidal composition for preventing and treating the purposes of corps diseases；The active constituent of bactericidal composition of the invention includes zoxamide and biphenyl pyrrole bacterium amine, and the weight ratio of the zoxamide and biphenyl pyrrole bacterium amine is 1:50~50:1；Bactericidal composition of the invention compares single active ingredient, the effect of prevention and treatment graw mold of tomato and speckled leaf blotch obviously increases, in other words, the tool of the two use in conjunction has an unexpected effect, rather than the preventive effect simple superposition of single-activity, preventive effect improve, and reduce dosage and times for spraying, and then production cost is saved, reduce the pollution to environment.
Description
Technical field
The present invention relates to a kind of bactericidal composition and application thereof containing zoxamide Yu biphenyl pyrrole bacterium amine, belongs to pesticide technology
Field.
Background technique
Zoxamide is a kind of efficient protective fungicide, has longer lasting period and good rain wash resistance
Can, belong to benzamides, is to be mainly used for preventing and treating oomycetes uniquely to the effective medicament of oomycetes in antimitotic class fungicide
Guiding principle disease such as epidemic disease and downy mildew etc..
Biphenyl pyrrole bacterium amine (Bixafen), chemical formula: C18H12Cl2F3N3O, chemical name: N- (3 ', 4 '-two -5- fluorine hexichol -
2- yl) -3- (difluoromethyl) -1- methylpyrazole -4- formamide, it is a kind of novel SDHI class fungicide, is opened by Beyer Co., Ltd
Hair, belongs to succinate dehydrogenase inhibitors, has the characteristics that broad-spectrum, protection and therapeutic activity have concurrently.The compound is to more
Kind germ has excellent activity, such as powdery mildew, rust, leaf spot and gray mold.
It combines different pesticide active ingredients, synergistic effect, which is significantly formulated, can greatly improve preventive effect, reduce medication
Amount and use cost reduce pesticide residue and environmental pollution.Currently, having no the relevant report of zoxamide Yu biphenyl pyrrole bacterium amine.
Summary of the invention
The purpose of the present invention is to provide a kind of bactericidal compositions applied widely, at low cost, effect is good.
It is another object of the present invention to be to provide a kind of bactericidal composition containing zoxamide and biphenyl pyrrole bacterium amine to be used for
The purposes of multiple kinds of crops disease is prevented and treated, such as is used for control rust, powdery mildew, leaf spot, brown spot, head blight, gray mold
Purposes on fungal disease.
To achieve the above object, the technical scheme adopted by the invention is that:
A kind of bactericidal composition containing zoxamide Yu biphenyl pyrrole bacterium amine, active constituent include zoxamide and biphenyl pyrrole bacterium
Amine, wherein the weight ratio of zoxamide and biphenyl pyrrole bacterium amine is 1:50~50:1.
Further, the weight ratio of the zoxamide and biphenyl pyrrole bacterium amine is 1:16~20:1.
Further, the weight ratio of the zoxamide and biphenyl pyrrole bacterium amine is 1:6~10:1.
In the bactericidal composition zoxamide and biphenyl pyrrole bacterium amine account for bactericidal composition weight percentage be 20%~
70%.
Further, zoxamide and biphenyl pyrrole bacterium amine account for bactericidal composition weight percentage in the bactericidal composition
It is 25%~50%.
Bactericidal composition of the invention can be prepared with conventional method, i.e., the raw medicine containing effective ingredient and suitably help
Agent can be processed into any dosage form agriculturally allowed.
Further, the dosage form preferably has suspending agent, wettable powder, water dispersible granules, missible oil, microemulsion, water
Emulsion, microcapsule suspending agent, suspension seed-coating agent.
Further, the auxiliary agent is to be beneficial to that effective component is stable in storage and use and known to drug effect plays
Substance, these known auxiliary agents are solvent, emulsifier, dispersing agent, wetting agent, defoaming agent, thickener, filler etc., can be used
Toluene, dimethylbenzene, loose base oil, soybean oil, agriculture breast 500, aliphatic acid polyethenoxy ether, lauryl sodium sulfate, secondary alkyl sulfuric acid
Sodium, sodium lignin sulfonate, ammonium sulfate, urea, silicone compound, C10-20Saturated fat acids compound, sodium benzoate, sorb
Sour potassium, sodium citrate, resorcinol, kaolin, bentonite, precipitated calcium carbonate, deionized water etc., the above auxiliary agent and other auxiliary materials
It can be applied alone or be used in combination.
Further, the active constituent zoxamide of the bactericidal composition and biphenyl pyrrole bacterium amine, can be administered simultaneously,
It can apply respectively or sequential application.
Of the invention can also apply containing zoxamide and biphenyl pyrrole bacterium amine with other active ingredient combinations, such as expanding
Big activity profile prevents from forming resistance.Other active constituents for example fungicide, bactericide, attractant, insecticide,
Acaricide, nematicide, growth regulator, herbicide, safener, fertilizer or semiochemical etc..
Compared with prior art, composition pesticide of the invention has the beneficial effect that
(1) present invention carries out use in conjunction by active constituent zoxamide and biphenyl pyrrole bacterium amine, compared to single-activity at
Point, the effect for preventing and treating graw mold of tomato and speckled leaf blotch obviously increases, and in other words, having for the two use in conjunction is expected not
The effect arrived, rather than the preventive effect simple superposition of single-activity.
(2) present invention carries out use in conjunction by active constituent zoxamide and biphenyl pyrrole bacterium amine, and it is general to have widened prevention and treatment, gram
The speed for taking or pathogen having been delayed to generate resistance.
(3) present invention carries out use in conjunction by active constituent zoxamide and biphenyl pyrrole bacterium amine, and preventive effect improves, reduces
Dosage and times for spraying, and then production cost is saved, reduce the pollution to environment.
Specific embodiment
To better describe the present invention, following exemplary embodiment is provided.Content mentioned by embodiment cannot recognize
To be limitation of the invention, the selection of material prescription can be according to the actual situation by other equivalent or replacing with similar purpose
It is replaced for feature.That is, being such as not particularly limited, each feature is a series of equivalent or similar characteristics a example, this
The protection scope of the technical solution of invention is subject to claim and is limited.
One, indoor biological activity assay
1. zoxamide is with biphenyl pyrrole bacterium amine combination preparation to the indoor biological activity assay of graw mold of tomato
Subjects: botrytis cinerea
Test method: mycelia growth inhibition assay is used, purified botrytis cinerea is first seeded in PDA culture medium
On, it sets and is cultivated in 25 DEG C of incubators to mycelia length to a certain extent, make bacteria cake from colony edge with the punch that diameter is 0.4cm
It is several, it is spare.Reagent agent has been configured to spare, 5 concentration gradients processing of each medicament setting, to spray equivalent clear water as sky
White control, 3 repetitions of each processing.While dissolving PDA culture medium, drawn from low concentration to high concentration with suction pipe respectively
The medical fluid of 1mL various concentration is put into the sterile graded tube of 25mL, when culture medium is cooled to 60 DEG C or so, pours into 9mL while hot and arrives
The scale test tube (be equivalent to liquor strength diluting 10 times) of dosing, shakes up rapidly and pours into the culture dish of diameter 9cm, be made
The uniform plate of thin and thick.After equal culture mediums solidification, bacteria cake mycelia is faced with transfer needle and is moved down on band medicine culture medium, every ware 1
A bacteria cake, every processing set 3 repetitions, then set and are inverted culture in 25 DEG C of constant incubators.After bacterium colony grows 72h, handed over cross
Fork method measures colony diameter, is averaged, relative inhibition is calculated by formula.Data are carried out returning after conversion to divide
Analysis, seeks virulence regression equation and EC50Value.Co-toxicity coefficient (CTC) is calculated with Sun Yunpei's Method again, test result such as table 1.
Co-toxicity coefficient classification: the mixture of CTC>120 have synergistic function, the mixture of CTC<80 have antagonism, 80≤
The mixture of CTC≤120 has summation action.
1 zoxamide of table and biphenyl pyrrole bacterium amine combination preparation are to graw mold of tomato biological activity determination
It was found from the measurement of the toxicity of upper table 1.Biphenyl pyrrole bacterium amine is than zoxamide to the inhibitory activity of graw mold of tomato
It is better, the weight ratio of the two has good inhibitory activity in the range of 1:50~50:1, to graw mold of tomato pathogen, performance
Synergistic function out, wherein when the weight ratio of the two is 4:5, the co-toxicity coefficient to graw mold of tomato pathogen is
191.00 synergistic most significant.
2. zoxamide and biphenyl pyrrole bacterium amine combination preparation are to speckled leaf blotch biological activity determination
Subjects: speckled leaf blotch bacterium
Test method: cutting out method measurement using basin, select susceptible wheat breed potting, standby to 2 leaves~3 leaf phases to seedling length
With.Zoxamide and biphenyl pyrrole bacterium amine raw medicine are scattered in chloroform and acetone respectively, then with 0.1% Tween-80 surfactant
Aqueous solution dilution.10ml medical fluid is uniformly sprayed on wheat seedling up to whole wettings by 4 basins of every processing, 10 plants of every basin, 4 repetitions,
It is spare to medical fluid naturally dry, and set containing only solvent and surfactant and make blank control without containing the processing for imitating ingredient.Medicine
Agent processing after for 24 hours, by fall ill wheat leaf blade on for 24 hours in generate Leaf blotch pathogeny be inoculated in processing 2~3 leaf phase pottings it is small
On wheat seeding, inoculation, which is placed under suitable condition, is cultivated.Wheat to be compareed sufficiently investigates all blades of every basin wheat seedling after the onset,
And the disease index and control efficiency of each processing are calculated, test result such as table 2:
Mode of application determines to use co-toxicity coefficient (CTC) method.The calculation formula of co-toxicity coefficient is as follows:
Toxicity index (TI)=standard agent EC50/ reagent agent EC50×100
Theoretical toxicity index (TTI)=standard agent toxicity index × standard agent in mixing assembles percentage+
Reagent agent toxicity index × reagent agent percentage in mixing assembles
Actual toxicity index (ATI)=standard single dose EC50Value/mixture EC50Value × 100
Co-toxicity coefficient (CTC)=survey toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient classification: the mixture of CTC>120 have synergistic function, the mixture of CTC<80 have antagonism, 80≤
The mixture of CTC≤120 has summation action.
2 zoxamide of table is with biphenyl pyrrole bacterium amine combination preparation to the indoor biological activity assay of speckled leaf blotch
Know that the weight ratio of zoxamide and biphenyl pyrrole bacterium amine is in 1:50~50:1 range from the measurement of the toxicity of upper table 2
It is interior, 120 are all larger than to the co-toxicity coefficient of speckled leaf blotch pathogen, synergistic function is obvious, wherein when the two mass fraction
When than for 5:6, co-toxicity coefficient 197.74 is synergistic most significant.
Two, example of formulations
Embodiment 1:48% zoxamide biphenyl pyrrole bacterium amine suspending agent (5:3)
Above-mentioned material is mixed in proportion, after being uniformly dispersed through high speed shear, being sanded in sand mill, 48% benzoyl can be made
Bacterium amine biphenyl pyrrole bacterium amine suspending agent.
Embodiment 2:36% zoxamide biphenyl pyrrole bacterium amine suspending agent (4:5)
Above-mentioned material is mixed in proportion, after being uniformly dispersed through high speed shear, being sanded in sand mill, can be prepared by 36% benzene
Acyl bacterium amine biphenyl pyrrole bacterium amine suspending agent.
Embodiment 3:27% zoxamide biphenyl pyrrole bacterium aqueous amine dispersible granule (7:2)
It is crushed with micro jet, through mediating, be then granulated, dried in addition fluidized-bed granulation dryer,
Through sampling analysis after screening, 27% zoxamide biphenyl pyrrole bacterium aqueous amine dispersible granule can be prepared by.
Embodiment 4:33% zoxamide biphenyl pyrrole bacterium amine wettable powder (5:6)
Above-mentioned material is mixed in proportion, after mechanical crushing again through air-flow crushing, after mixing, 33% benzoyl can be made
Bacterium amine biphenyl pyrrole bacterium amine wettable powder.
Embodiment 5:52% zoxamide biphenyl pyrrole bacterium aqueous amine emulsion (15:11)
Raw medicine, solvent, emulsifier are added together, make to be dissolved into homogeneous oil phase；Water-soluble component and water are mixed to prepare
Water phase；It is under high speed shear, oil is mutually mixed with water, it can be prepared by 52% zoxamide biphenyl pyrrole bacterium aqueous amine emulsion.
Embodiment 6:65% zoxamide biphenyl pyrrole bacterium amine microemulsion (7:6)
Raw medicine, solvent, emulsifier are added together, make to be dissolved into homogeneous oil phase；Water-soluble component and water are mixed to prepare
Water phase；Under high velocity agitation, oil is mutually mixed with water, it can be prepared by 60% zoxamide biphenyl pyrrole bacterium amine microemulsion.
Three, field trial
1. zoxamide and biphenyl pyrrole bacterium amine combination preparation are to graw mold of tomato pharmacodynamic test
Subjects: graw mold of tomato
Reagent agent: treatment agent is the composite preparation in invention formulation embodiment 1-4, and comparison medicament is 50% benzene
Acyl bacterium amine suspending agent and 40% biphenyl pyrrole bacterium amine suspending agent, using clear water as blank control.
Test method: experimental plot is divided into 16 cells, 25m2/ area.Spraying equipment produces Jacto board HD-300 using Singapore
Type knapsack hand sprayer, operating pressure 8cm2, injection diameter 1.33mm.It tests every processing to be repeated 4 times, different disposal cell
Random distribution, uniformly to squirt leave dual sides, spouting liquid 900L/hm when hydrojet2.Entire test sprays 2 times altogether, for the first time
Being administered to tomato, just fruiting period carries out, and is administered 1 time every 7d later.Entire field trial is completed in day-light greenhouse, is planted
Density in planting is 3500 plants/666.7m2.The application same day investigates the state of an illness radix of each cell, and 7d is once prevented after medicine every time later
Effect investigation.
Investigation method: the 5 grab sample investigation of every cell diagonal line, every is investigated 3 plants, and every plant of investigation upper, middle and lower portion is each
3 blades, every blade carry out severity Scaling by the percentage that lesion area accounts for entire leaf area, record investigation total leaf number,
The disease numbers of blade at different levels, indoor calculating disease index and control efficiency.
Graw mold of tomato blade grade scale (as unit of blade):
0 grade: disease-free spot；
1 grade: single blade has scab 3；
3 grades: single blade has scab 4~6；
5 grades: single blade has scab 7~10；
7 grades: single blade has scab 11~20, and part is intensive in blocks；
9 grades: single blade has scab, accounts for 1/4 or more leaf area.
Disease index and control efficiency is calculated as follows, and Multiple range test is carried out to each processing preventive effect.
Disease index=[Σ (diseased plant numbers at different levels × opposite value of series)/investigation total strain number × 9] × 100
Control efficiency %=(1-CK0×Pt1/CK1×Pt0)×100
Wherein: CK0Disease before blank district is administered is represented to refer to；CK1Disease refers to after representing blank district application；Pt0Represent medicine
Disease refers to before agent treatment region is administered；Pt1Disease refers to after representing chemicals treatment district application.
3 zoxamide of table and biphenyl pyrrole bacterium amine combination preparation are to graw mold of tomato field control effectiveness test
From the field test results of table 3 it is found that zoxamide and biphenyl pyrrole bacterium amine combination preparation to graw mold of tomato have compared with
Good prevention and treatment, zoxamide is compounded with biphenyl pyrrole bacterium amine or mixture, and component is reasonable, can reduce the amount of application of effective component, is trying
During testing, it is administered in region and phytotoxicity is not generated to crop.
2. zoxamide and biphenyl pyrrole bacterium amine composition preparation are to speckled leaf blotch field control effectiveness test:
Subjects: speckled leaf blotch
Test medicine: treatment agent is the composite preparation in invention formulation embodiment 1-4, and comparison medicament is 50% benzene
Acyl bacterium amine suspending agent and 40% biphenyl pyrrole bacterium amine suspending agent, using clear water as blank control.
Test method: experimental plot area is 20 square metres, and each test process setting is repeated 4 times, in speckled leaf blotch evil
Early period of origination carries out first time application, even spraying, is sprayed onto until blade drips, using clear water processing as blank control, the after 7 days
Secondary spray.The incidence of 7 days investigation water speckled leaf blotches before first time medicine and after second of medicine.Every experimental field uses five
Point sampling, every is investigated two plants, and every plant of all blades of investigation account for the percentage of entire leaf area with lesion area to be classified note
It carries.It calculates each processing disease index and control efficiency, test result see the table below 4:
4 zoxamide of table is with biphenyl pyrrole bacterium amine combination preparation to the field control effectiveness test of speckled leaf blotch
As can be seen from Table 4, zoxamide is with biphenyl pyrrole bacterium amine combination preparation to the control efficiency of speckled leaf blotch, hence it is evident that
It is synergistic obvious higher than single formulation, it is synergistic bright at first when zoxamide is 5:6 with biphenyl pyrrole bacterium amine mix ratio
Aobvious, preventive effect reaches 88.91%, during test, does not find there is adverse effect to crop.
Based on the above description of the preferred embodiments of the present invention, through the above description, related personnel completely can be with
Without departing from the scope of the technological thought of the present invention', various changes and amendments are carried out.The technical scope of this invention
It is not limited to the contents of the specification, it is necessary to determine the technical scope according to the scope of the claims.
Claims (10)
1. a kind of bactericidal composition containing zoxamide Yu biphenyl pyrrole bacterium amine, which is characterized in that the activity of the bactericidal composition
Ingredient includes zoxamide and biphenyl pyrrole bacterium amine, and the weight ratio of the zoxamide and biphenyl pyrrole bacterium amine is 1:50~50:1.
2. a kind of bactericidal composition containing zoxamide Yu biphenyl pyrrole bacterium amine according to claim 1, it is characterised in that: institute
The weight ratio for stating zoxamide and biphenyl pyrrole bacterium amine is 1:16~20:1.
3. a kind of bactericidal composition containing zoxamide Yu biphenyl pyrrole bacterium amine according to claim 1, it is characterised in that: institute
The weight ratio for stating zoxamide and biphenyl pyrrole bacterium amine is 1:6~10:1.
4. a kind of bactericidal composition containing zoxamide Yu biphenyl pyrrole bacterium amine according to claim 1, it is characterised in that: institute
Stating zoxamide and biphenyl pyrrole bacterium amine in bactericidal composition and accounting for bactericidal composition weight percentage is 20%~70%.
5. a kind of bactericidal composition containing zoxamide Yu biphenyl pyrrole bacterium amine according to claim 1, it is characterised in that: institute
Stating zoxamide and biphenyl pyrrole bacterium amine in bactericidal composition and accounting for bactericidal composition weight percentage is 25%~50%.
6. a kind of Bactericidal composite containing zoxamide Yu biphenyl pyrrole bacterium amine described in any one of -5 claims according to claim 1
Object, it is characterised in that: bactericidal composition active constituent zoxamide and biphenyl pyrrole bacterium amine are aided with auxiliary agent, are prepared into agricultural
Any dosage form of upper permission.
7. a kind of bactericidal composition containing zoxamide Yu biphenyl pyrrole bacterium amine according to claim 6, it is characterised in that: institute
Stating dosage form includes suspending agent, wettable powder, water dispersible granules, missible oil, microemulsion, aqueous emulsion, microcapsule suspending agent, suspended seed coating
Agent.
8. a kind of bactericidal composition containing zoxamide Yu biphenyl pyrrole bacterium amine according to claim 6, it is characterised in that: institute
Stating auxiliary agent is solvent, emulsifier, dispersing agent, wetting agent, defoaming agent, thickener, filler.
9. a kind of purposes of the bactericidal composition as described in any claim in claim 1-8, which is characterized in that described
Purposes is for preventing and treating corps diseases.
10. purposes according to claim 9, which is characterized in that the corps diseases are graw mold of tomato and wheat leaf
Pinta.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811113334.4A CN109006819A (en) | 2018-09-25 | 2018-09-25 | A kind of bactericidal composition and application thereof containing zoxamide Yu biphenyl pyrrole bacterium amine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811113334.4A CN109006819A (en) | 2018-09-25 | 2018-09-25 | A kind of bactericidal composition and application thereof containing zoxamide Yu biphenyl pyrrole bacterium amine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109006819A true CN109006819A (en) | 2018-12-18 |
Family
ID=64617707
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811113334.4A Pending CN109006819A (en) | 2018-09-25 | 2018-09-25 | A kind of bactericidal composition and application thereof containing zoxamide Yu biphenyl pyrrole bacterium amine |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109006819A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116439245A (en) * | 2023-04-14 | 2023-07-18 | 华南农业大学 | Bactericide with safety and low toxicity to aquatic organisms and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101647433A (en) * | 2009-07-21 | 2010-02-17 | 深圳诺普信农化股份有限公司 | Sterilization composition based on zoxamide |
| CN104170826A (en) * | 2013-05-21 | 2014-12-03 | 陕西美邦农药有限公司 | Bactericidal composition containing penflufen and amide |
| CN106857587A (en) * | 2017-04-19 | 2017-06-20 | 广东广康生化科技股份有限公司 | Microbicide compositions and its application comprising folpet and biphenyl pyrrole bacterium amine |
-
2018
- 2018-09-25 CN CN201811113334.4A patent/CN109006819A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101647433A (en) * | 2009-07-21 | 2010-02-17 | 深圳诺普信农化股份有限公司 | Sterilization composition based on zoxamide |
| CN104170826A (en) * | 2013-05-21 | 2014-12-03 | 陕西美邦农药有限公司 | Bactericidal composition containing penflufen and amide |
| CN106857587A (en) * | 2017-04-19 | 2017-06-20 | 广东广康生化科技股份有限公司 | Microbicide compositions and its application comprising folpet and biphenyl pyrrole bacterium amine |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116439245A (en) * | 2023-04-14 | 2023-07-18 | 华南农业大学 | Bactericide with safety and low toxicity to aquatic organisms and application thereof |
| CN116439245B (en) * | 2023-04-14 | 2024-01-02 | 华南农业大学 | Bactericide with safety and low toxicity to aquatic organisms and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106689145A (en) | Weeding composition containing pyroxasulfone and amide herbicides | |
| CN104542585A (en) | Fungicide composition and application thereof | |
| CN109006819A (en) | A kind of bactericidal composition and application thereof containing zoxamide Yu biphenyl pyrrole bacterium amine | |
| CN114208833B (en) | Pesticide composition containing fluroxypyr and diclosulam as well as preparation method and application thereof | |
| CN104542611A (en) | Bactericidal composition containing mandipropamid | |
| CN108849918A (en) | Bactericidal composition | |
| CN104488894B (en) | A kind of containing methylsulfonyl bacterium azoles and the complex composition of fluopicolide and antibacterial | |
| CN108207985A (en) | A kind of rice terrace ternary weeding composition | |
| CN108207974A (en) | Bactericidal composition and application containing folpet and isopropyl metsulfovax | |
| CN104026136B (en) | Agricultural fungicidal composition | |
| CN106665614A (en) | Weeding composition containing penoxsulam, bispyribac-sodium and mefenacet | |
| CN108967427A (en) | A kind of bactericidal composition and its application containing zoxamide and isopropyl metsulfovax | |
| CN105052997A (en) | Pesticide composition containing Dufulin and antibiotic bactericide, and bactericide thereof | |
| CN104012555A (en) | Agricultural sterilization composition | |
| CN105638686B (en) | A kind of combination sterilization composition containing tiger glue adipic acid copper | |
| CN109699655A (en) | A kind of composition pesticide of fluorine-containing thiazole pyrrole ethyl ketone and benziothiazolinone | |
| CN108353910A (en) | A kind of agriculture bactericidal composition containing ether azoles sulfanilamide (SN) ester type compound and prothioconazoles | |
| CN109953027A (en) | A kind of bactericidal composition of fluorine-containing phenylate amide and antibiotic in pyrimidine nucleoside class | |
| CN107318856B (en) | Sterilization composition containing dichloro-oxazole and oxine-copper | |
| CN109221121A (en) | A kind of bactericidal composition and application thereof containing zoxamide and fluopyram | |
| CN105794797A (en) | Sterilization composition containing flumorph, prothioconazole and penthiopyrad | |
| CN105284839A (en) | Mandipropamid and Zhongshengmycin-containing bacterial composition | |
| CN109006818A (en) | A kind of bactericidal composition and application thereof containing zoxamide Yu pyrrole metsulfovax | |
| CN104041523B (en) | A kind of bactericidal composition containing Boscalid | |
| CN106172453A (en) | A kind of bactericidal composition and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181218 |
|
| RJ01 | Rejection of invention patent application after publication |