CN108968059A - A kind of spider silk composite nutrient-fluid - Google Patents
A kind of spider silk composite nutrient-fluid Download PDFInfo
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- CN108968059A CN108968059A CN201811137701.4A CN201811137701A CN108968059A CN 108968059 A CN108968059 A CN 108968059A CN 201811137701 A CN201811137701 A CN 201811137701A CN 108968059 A CN108968059 A CN 108968059A
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Classifications
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
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- Life Sciences & Earth Sciences (AREA)
- Mycology (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Cosmetics (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
Abstract
The invention belongs to health food preparation technical fields, are related to a kind of spider silk composite nutrient-fluid；The weight proportion of its each raw material component is amino acid solution: low tart apple juice: gumbo juice: honey=20:10:5:2；It is spare that spider silk is first hydrolyzed into obtained amino acid solution in the case where mass fraction is 98% concentrated sulfuric acid environment by the mass ratio of 1:3-4 with pure water, again by apple skin with sodium bicarbonate aqueous solution soaking to after light yellow, it is spare with juice extractor squeeze juice, then by gumbo, squeeze juice is spare after hot-water soak cold water is cooling, finally amino acid solution, cider, gumbo juice and honey are uniformly mixed, spider silk composite nutrient-fluid is made after distillation and concentration；The product preparation process is simple, and step is scientific and reasonable, and nutritive value is high, can be used in supplementing human body protein, and strengthen immunity is quick, and effect is good, convenient, is particularly suitable for being badly in need of the crowd of supplement protein, eat environmental-friendly.
Description
Technical field:
The invention belongs to health food preparation technical fields, and it is main former for being related to one kind with spider silk, apple skin and gumbo
The health care non-staple food of material, and in particular to a kind of spider silk composite nutrient-fluid, nutritive value is high, good health care effect.
Background technique:
Concern of the spider silk by various circles of society in recent years, research and utilization to spider silk have become hot topic；Spider
The main component of the spider's thread is protein, glycine, alanine, glutamic acid and leucine rich in etc.；Spider silk is one
High toughness and elastic splendid fiber are planted, the traction fiber in spider silk has silk and general synthesis in terms of mechanical property
The incomparable outstanding advantage of fiber；Spider silk phsyical density is 1.34g/cm3, spider mercerising close with silk and wool
Cunning is glittering, UV resistant performance is strong, and compared with high temperature resistant and low temperature；Heat analysis shows that spider silk is steady in 200 DEG C or less performance heat
Qualitative good, 300 DEG C or more ability xanthochromias, subzero 40 DEG C whens, are still flexible, and spider silk has that intensity is high, elasticity is good, initial modulus
Greatly, the characteristics such as work to break height are a kind of natural materials that performance is very excellent, and therefore, spider silk fiber is (anti-in national defence, military affairs
Play clothing), building and the fields such as medicines and health protection there is broad prospect of application.
Spider silk has special dissolution characteristics, and the orange-yellow chance alkali shown by it is deepened, and meets acid and fades, it is insoluble in dilute
Acid, diluted alkaline, are only soluble in the concentrated sulfuric acid, potassium bromide, formic acid etc., and resistant to most of hydrolysising protease；Spider silk is in water
In have sizable swellability, longitudinally have apparent contraction；When heated, spider silk can be slightly soluble in ethyl alcohol；Due to spider silk
Building material be almost protein, so it is biosoluble, and can biodegrade and recycling.
In medical health field；Spider silk has hemostasis, the effect of the wart that disappears, cures mainly haematemesis, metal-inflicted wound bleeding, wart,
Blood tumor, hemorrhoid complicated by anal fistula；It is recorded according to " prescriptions worth thousand gold ", spider silk, which includes, " to be controlled proliferative sore, and control all sores for many years: in spider film patch sore, counting easy
It, is recovered only." effect, recording spider silk according to " moving back the refined news of vegetarian to record " " can control sudden and violent haematemesis: cobweb, nine sons are twisted into, under thin rice gruel
Drink." recorded according to Holy Benevolent Prescriptions: " sore is treated, only metal-inflicted wound blood goes out.Stir-bake to yellowish is ground, and wine clothes control haematemesis."
Currently, in the prior art, the Chinese patent of Publication No. CN108452374A discloses a kind of spider silk combination
Object and preparation method thereof, includes the following steps: the preparation of a, spidroin solution, the preparation of b, graphene oxide dispersion,
C, spidroin solution and graphene oxide dispersion is compound, obtains composite solution, d, by composite solution through electrostatic spinning
It spins obtained spinning film and obtains the artificial skin being made of spider silk fibroin and graphene oxide through vacuum freeze drying,
The artificial skin that this technology is related to can be used for various wound repairs, and good biocompatibility, wound repair ability is strong, it is alternative from
Body skin-grafting；The Chinese patent of Publication No. CN108244657A discloses a kind of method for hydrolysis of spider silk.This method includes such as
Lower step: being soaked in the sulfuric acid solution that mass percentage concentration is 80%~90% for spider silk, stirs 20~40min, slowly adds
Enter water mixing, calcium carbonate is added after the water bath is in 100~180min of heating water bath under the conditions of 80~90 DEG C, and side edged stirs
It mixes, until pH value is 5~7, after hydrolyzate is cooled to room temperature, water repeatedly washs precipitating, collects eluent, eluent is through dense
Contracting, filtering is to get spider silk hydrolyzate, and the acid hydrolysis yield of the spider silk hydrolyzate of the method for the present invention preparation is high, the third ammonia
Acid, serine equal size are higher, can be used as health food or cosmetics nutritional supplements are used.
Rich in protein in spider silk, nutritive value is high, has the effect of hemostasis, the wart that disappears；However in existing skill
There is no being used to spider silk supplement human body protein in art, even if having there is the skill that protein in spider silk is hydrolyzed into amino acid
Art, but it is not used for nutraceutical product really, make the nutritive value of spider silk be difficult to play.
Summary of the invention:
It is an object of the invention to overcome spider silk nutritive value in the prior art it is ignored, using difficult disadvantage, seek
It designs a kind of using spider silk, apple skin and gumbo as the spider silk composite nutrient-fluid of primary raw material.
To achieve the goals above, the weight proportion of each raw material component is in spider silk composite nutrient-fluid of the present invention
Amino acid solution: low tart apple juice: gumbo juice: honey=20:10:5:2；Wherein amino acid solution by spider silk with it is pure
Water is hydrolyzed in the case where mass fraction is 98% concentrated sulfuric acid environment by the mass ratio of 1:3-4 and is made.
The specific step of preparation process of spider silk composite nutrient-fluid of the present invention are as follows:
(1) spider silk pre-processes: taking natural spider silk to be cleaned up with pure water, is put into 90-100 DEG C of baking after dripping moisture removal
10-15 minutes are toasted in case to drying, and are the concentrated sulfuric acid aqueous solution of 93-98% according to 1:10-15 by spider silk and mass fraction
Weight ratio mixed in reaction pot, pure water is added dropwise into the reaction pot in 0-10 DEG C of cold bath and stirs, prevents pure
Water purification discharges a large amount of heat after mixing with the concentrated sulfuric acid make solution bumping, and the mass ratio of the pure water inventory of spider silk and dropwise addition is
1:3-4, pure water stop cold bath after being at the uniform velocity added dropwise within 1-1.5 hour, heat reaction pot temperature control using heater
65-70 DEG C the reaction was continued 4-5 hours, and the concentrated sulfuric acid aqueous solution that mole is above-mentioned addition is added into reaction pot after reaction
Middle 1.1-1.2 times of sulfuric acid mole of barium carbonate powder, barium carbonate powder constant-speed material-adding in 0.5-0.8 hours, which adds, to be finished and adds
Lasting stirring, is filtered after pH value of solution in reaction pot reaches 5.3-5.8 during adding, and is collected filter residue and is used to prepare barium sulfate, receives
Taking filtrate is amino acid solution, and wherein the mass fraction of amino acid is 11-14%；
(2) low tart apple skin juice preparation: apple is stripped into the apple skin with a thickness of 1-2mm with peeling machine, then will be fresh
Apple skin is uniformly mixed with the sodium bicarbonate aqueous solution that weight percent concentration is 2-3% according to the weight ratio of 1:8-10 rapidly, and
Impregnating 10-15 minutes in sodium bicarbonate aqueous solution makes its lighter yellow, then pulls apple skin juice extractor squeeze juice out
Afterwards, 2-3 hour filtering is stood, stereoplasm object is discarded, filtrate is taken to be low tart apple skin juice and be sealed；
(3) gumbo juice prepare: take fresh gumbo with 95-100 DEG C hot-water soak 2-3 minutes, 0-5 DEG C of cold water is put into after taking-up
It is quickly cooled down within middle immersion 2-3 minutes, uses juice extractor squeeze juice after dripping moisture removal, juice is poured into Buchner funnel and use is matched
The Suction filtration device of set filters 20-30 minutes, takes smoke filtrate up to gumbo juice；
(4) spider silk composite nutrient-fluid prepare: first by amino acid solution, low tart apple juice, gumbo juice and honey according to
Mixing crude liquid is mixed evenly to obtain in the weight ratio of 20:10:5:2, then steams mixing 100-120 DEG C of stirring of crude liquid heated for controlling temperature
Concentration is evaporated, when the volume concentration of filtrate is to former filtrate volume 2/3-1/2, stops distilling spider silk composite nutrient-fluid is made,
The mass fraction of middle amino acid is 10-12%, can be used in keeping fit and healthy, strengthen immunity.
The spider of spider silk of the present invention includes: Araneus diadematus, Araneus ventricosus and network bride spider.
Compared with prior art, the present invention the preparation process of related spider silk composite nutrient-fluid is simple, step science
Rationally, nutritive value is high, can be used in supplementing human body protein, and quick, effect is good, convenient, is particularly suitable for being badly in need of supplement
The crowd of protein eats environmental-friendly.
Specific embodiment:
Below by embodiment, the technical scheme of the present invention will be further described.
Embodiment 1
The weight proportion of each raw material component is amino acid solution in the spider silk composite nutrient-fluid that the present embodiment is related to: low
Tart apple juice: gumbo juice: honey=20:10:5:2；Wherein amino acid solution is pressed the quality of 1:3-4 by spider silk and pure water
It is made than being hydrolyzed in the case where mass fraction is 98% concentrated sulfuric acid environment.
The spider for the spider silk that the present embodiment is related to includes: Araneus diadematus, Araneus ventricosus and network bride spider.
The specific step of preparation process for the spider silk composite nutrient-fluid that the present embodiment is related to are as follows:
(1) spider silk pre-processes: taking natural spider silk to be cleaned up with pure water, is put into 90-100 DEG C of baking after dripping moisture removal
10-15 minutes are toasted in case to drying, and are the concentrated sulfuric acid aqueous solution of 93-98% according to 1:10-15 by spider silk and mass fraction
Weight ratio mixed in reaction pot, pure water is added dropwise into the reaction pot in 0-10 DEG C of cold bath and stirs, prevents pure
Water purification discharges a large amount of heat after mixing with the concentrated sulfuric acid make solution bumping, and the mass ratio of the pure water inventory of spider silk and dropwise addition is
1:3-4, pure water stop cold bath after being at the uniform velocity added dropwise within 1-1.5 hour, heat reaction pot temperature control using heater
65-70 DEG C the reaction was continued 4-5 hours, and the concentrated sulfuric acid aqueous solution that mole is above-mentioned addition is added into reaction pot after reaction
Middle 1.1-1.2 times of sulfuric acid mole of barium carbonate powder, barium carbonate powder constant-speed material-adding in 0.5-0.8 hours, which adds, to be finished and adds
Lasting stirring, is filtered after pH value of solution in reaction pot reaches 5.3-5.8 during adding, and is collected filter residue and is used to prepare barium sulfate, receives
Taking filtrate is amino acid solution, and wherein the mass fraction of amino acid is 11-14%；
(2) low tart apple skin juice preparation: apple is stripped into the apple skin with a thickness of 1-2mm with peeling machine, then will be fresh
Apple skin is uniformly mixed with the sodium bicarbonate aqueous solution that weight percent concentration is 2-3% according to the weight ratio of 1:8-10 rapidly, and
Impregnating 10-15 minutes in sodium bicarbonate aqueous solution makes its lighter yellow, then pulls apple skin juice extractor squeeze juice out
Afterwards, 2-3 hour filtering is stood, stereoplasm object is discarded, filtrate is taken to be low tart apple skin juice and be sealed；
(3) gumbo juice prepare: take fresh gumbo with 95-100 DEG C hot-water soak 2-3 minutes, 0-5 DEG C of cold water is put into after taking-up
It is quickly cooled down within middle immersion 2-3 minutes, uses juice extractor squeeze juice after dripping moisture removal, juice is poured into Buchner funnel and use is matched
The Suction filtration device of set filters 20-30 minutes, takes smoke filtrate up to gumbo juice；
(4) spider silk composite nutrient-fluid prepare: first by amino acid solution, low tart apple juice, gumbo juice and honey according to
Mixing crude liquid is mixed evenly to obtain in the weight ratio of 20:10:5:2, then steams mixing 100-120 DEG C of stirring of crude liquid heated for controlling temperature
Concentration is evaporated, when the volume concentration of filtrate is to former filtrate volume 2/3-1/2, stops distilling spider silk composite nutrient-fluid is made,
The mass fraction of middle amino acid is 10-12%, can be used in keeping fit and healthy, strengthen immunity.
The spider silk composite nutrient-fluid amino acid content that the present embodiment is related to is abundant, for human body missing protein and is immunized
The low crowd of power, daily secondary, each 5-10g are taken after mixing it with water with 100 milliliters of 30-40 DEG C of warm water, adhere to taking 5-7 days, people
Body protein content can restore normal level, and immunity improves 30% or more, works well, without side-effects.
Embodiment 2
Each raw material component includes: spider silk mixed liquor, low tart apple in the spider silk composite nutrient-fluid that the present embodiment is related to
Juice, gumbo juice and honey；Wherein the weight proportion of spider silk mixed liquor, low tart apple juice, gumbo juice and honey is 10:10:5:
2, spider silk mixed liquor is mixed for 60% ethanol water according to the weight ratio of 1:5-8 by spider silk powder with weight percent concentration
Dissolution filter is made afterwards.
The specific step of preparation process for the spider silk composite nutrient-fluid that the present embodiment is related to are as follows:
(1) spider silk pre-processes: taking natural spider silk to be cleaned up with pure water, is then placed in 30-40 DEG C of warm water
It impregnates 20-30 minutes, pulls out to be put into 90-100 DEG C of baking oven after dripping moisture removal and toast 10-15 minutes, put after spider silk drying
Enter in iron pan and stir-fried 3-8 minutes with high fire, cooling be put into mortar is taken out after spider silk colour changed into yellow and is ground into end, crosses 300 mesh
Spider silk powder is made in sieve；
(2) prepared by spider silk mixed liquor: being 60-65% by spider silk powder made from step (1) and weight percent concentration
Ethanol water is mixed according to the weight ratio of 1:5-8, is stirred 3-5 minutes, is then allowed to stand under 10-20 DEG C of temperature control of closed environment
1-2 hours, filtrate was collected in filtering, discarded solid, gained filtrate is spider silk mixed liquor；
(3) low tart apple skin juice preparation: apple is stripped into the fresh apple skin with a thickness of 1-2mm with peeling machine, then will be new
Fresh apple skin is uniformly mixed with the sodium bicarbonate aqueous solution that weight percent concentration is 2-3% according to the weight ratio of 1:8-10 rapidly,
And impregnated 10-15 minutes in sodium bicarbonate aqueous solution and make its lighter yellow, then pull apple skin juice extractor extracting juice out
After liquid, 2-3 hour filtering is stood, stereoplasm object is discarded, filtrate is taken to be low tart apple skin juice and be sealed；
(4) gumbo juice prepare: take fresh gumbo with 95-100 DEG C hot-water soak 2-3 minutes, 0-5 DEG C of cold water is put into after taking-up
It is quickly cooled down within middle immersion 2-3 minutes, uses juice extractor squeeze juice after dripping moisture removal, juice is poured into Buchner funnel and use is matched
The Suction filtration device of set filters 20-30 minutes, takes smoke filtrate up to gumbo juice；
(5) spider silk composite nutrient-fluid prepare: first by spider silk mixed liquor, low tart apple juice, gumbo juice and honey according to
The weight ratio of 10:10:5:2 is mixed evenly to obtain mixing crude liquid, and it is dense then will to mix the 80-90 DEG C of distillation of crude liquid heated for controlling temperature
Contracting, collects the ethyl alcohol distilled out and utilizes again, when the volume concentration of filtrate is to former filtrate volume 2/3-1/2, stops distillation system
The weight percent concentration that spider silk must be contained is the concentrate of 3-5%, as spider silk composite nutrient-fluid, spider silk compound nutritional
The ethanol content of liquid is lower than 0.5%.
The spider silk composite nutrient-fluid that the present embodiment is related to is daily secondary, each 3-5g, with 100 milliliters 30-40 DEG C
Warm water is taken after mixing it with water；Adhere to taking for a long time, rheumatic arthralgia can be prevented, has therapeutic effect to pulled muscle, clinical effective rate reaches
70% or more；This product also has hemostasia effect to nosebleed person, has nosebleed symptom to adhere to taking above-mentioned dosage 20-30 days,
Treated effect can reach 65% or more.
Claims (2)
1. a kind of spider silk composite nutrient-fluid, it is characterised in that: the weight proportion of each raw material component is amino acid solution: low acid
Cider: gumbo juice: honey=20:10:5:2；Wherein amino acid solution is pressed the mass ratio of 1:3-4 by spider silk and pure water
It hydrolyzes and is made in the case where mass fraction is 98% concentrated sulfuric acid environment.
2. spider silk composite nutrient-fluid according to claim 1, it is characterised in that: specific preparation process are as follows:
(1) spider silk pre-processes: taking natural spider silk to be cleaned up with pure water, is put into 90-100 DEG C of baking oven after dripping moisture removal
Baking 10-15 minute to drying, by spider silk and mass fraction for 93-98% concentrated sulfuric acid aqueous solution according to 1:10-15 weight
Amount ratio mixes in reaction pot, and pure water is added dropwise into the reaction pot in 0-10 DEG C of cold bath and stirs, prevents pure water
A large amount of heat is discharged after mixing with the concentrated sulfuric acid makes solution bumping, and the mass ratio of the pure water inventory of spider silk and dropwise addition is 1:3-
4, pure water stops cold bath after being at the uniform velocity added dropwise within 1-1.5 hour, heats reaction pot temperature control 65-70 using heater
DEG C the reaction was continued 4-5 hours, and it is sulphur in the concentrated sulfuric acid aqueous solution of above-mentioned addition that mole is added into reaction pot after reaction
The barium carbonate powder of 1.1-1.2 times of sour mole, barium carbonate powder constant-speed material-adding in 0.5-0.8 hours, which adds, to be finished and added
It persistently stirs in journey, is filtered after pH value of solution in reaction pot reaches 5.3-5.8, collect filter residue and be used to prepare barium sulfate, collect filter
Liquid is amino acid solution, and wherein the mass fraction of amino acid is 11-14%；
(2) low tart apple skin juice preparation: stripping the apple skin with a thickness of 1-2mm with peeling machine for apple, then by fresh apple
Skin is uniformly mixed with the sodium bicarbonate aqueous solution that weight percent concentration is 2-3% according to the weight ratio of 1:8-10 rapidly, and small
Impregnating 10-15 minutes in aqueous soda solution makes its lighter yellow, quiet after then pulling apple skin juice extractor squeeze juice out
2-3 hour filtering is set, stereoplasm object is discarded, filtrate is taken to be low tart apple skin juice and be sealed；
(3) gumbo juice prepare: take fresh gumbo with 95-100 DEG C hot-water soak 2-3 minutes, be put into 0-5 DEG C of cold water and soak after taking-up
It is quickly cooled down within bubble 2-3 minutes, uses juice extractor squeeze juice after dripping moisture removal, juice is poured into Buchner funnel and using matched
Suction filtration device filters 20-30 minutes, takes smoke filtrate up to gumbo juice；
(4) prepared by spider silk composite nutrient-fluid: first by amino acid solution, low tart apple juice, gumbo juice and honey according to 20:
Mixing crude liquid is mixed evenly to obtain in the weight ratio of 10:5:2, then will the 100-120 DEG C of stirring distillation of mixing crude liquid heated for controlling temperature
Concentration stops distilling spider silk composite nutrient-fluid is made when the volume concentration of filtrate is to former filtrate volume 2/3-1/2, wherein
The mass fraction of amino acid is 10-12%, can be used in keeping fit and healthy, strengthen immunity.
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