CN108949251A - 一种灶用醇基燃料及其制备方法 - Google Patents
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 239000000446 fuel Substances 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 60
- -1 ketone compounds Chemical class 0.000 claims abstract description 31
- 238000002485 combustion reaction Methods 0.000 claims abstract description 29
- 238000006555 catalytic reaction Methods 0.000 claims abstract description 24
- 239000000779 smoke Substances 0.000 claims abstract description 24
- 239000002671 adjuvant Substances 0.000 claims abstract description 23
- 150000001924 cycloalkanes Chemical class 0.000 claims abstract description 23
- 239000006184 cosolvent Substances 0.000 claims abstract description 19
- 235000019441 ethanol Nutrition 0.000 claims description 37
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 14
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 10
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 10
- BGTOWKSIORTVQH-UHFFFAOYSA-N cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 claims description 10
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims description 10
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims description 8
- 229910052684 Cerium Inorganic materials 0.000 claims description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 7
- 230000031709 bromination Effects 0.000 claims description 7
- 238000005893 bromination reaction Methods 0.000 claims description 7
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims description 7
- ASAMDJHOONJZTG-UHFFFAOYSA-K dysprosium(3+);triiodate Chemical compound [Dy+3].[O-]I(=O)=O.[O-]I(=O)=O.[O-]I(=O)=O ASAMDJHOONJZTG-UHFFFAOYSA-K 0.000 claims description 7
- 229910052700 potassium Inorganic materials 0.000 claims description 7
- 239000011591 potassium Substances 0.000 claims description 7
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical group [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- KRIOVPPHQSLHCZ-UHFFFAOYSA-N propiophenone Chemical compound CCC(=O)C1=CC=CC=C1 KRIOVPPHQSLHCZ-UHFFFAOYSA-N 0.000 claims description 5
- 150000002576 ketones Chemical class 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- DMEGYFMYUHOHGS-UHFFFAOYSA-N cycloheptane Chemical compound C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 claims 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 3
- 230000000903 blocking effect Effects 0.000 abstract description 2
- 230000009967 tasteless effect Effects 0.000 abstract description 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 8
- 239000002904 solvent Substances 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002283 diesel fuel Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 239000002551 biofuel Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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Abstract
本发明涉及一种灶用醇基燃料及其制备方法，属于醇基燃料技术领域，包括有甲醇55～57质量份，酮类化合物20～22质量份，环烷烃11～13质量份，共溶剂7～9质量份，消烟助燃剂0.5～0.7质量份，催化助燃剂2.3～2.5质量份。该灶用醇基燃料中的甲醇、酮类化合物、环烷烃、共溶剂在消烟助燃剂和催化助燃剂的共同作用下，燃烧时无烟、无味，燃烧时的热值高，可达到6370卡/克；燃烧时不会产生堵塞，燃烧效率能够达到95％以上。
Description
技术领域
本发明涉及醇基燃料技术领域，尤其涉及一种灶用醇基燃料及其制备方法。
背景技术
醇基燃料就是以醇类(如甲醇、乙醇、丁醇等)物质为主体配置的燃料。生物燃料燃烧值比液化气、柴油低但是价格比较有优势，可作为石油液化气及燃料柴油的替代燃料，它低价、安全、方便具有无残渣残液、不黑锅底，具有清洁卫生、安全、廉价、原料易购、使用方便等特点，成本仅为石油液化气或柴油批发价格的三分之一左右，利润空间巨大，具备极高的投资价值。
目前，醇基燃料以甲醇为主，主要用于酒店餐饮行业，但存在热值低的缺点，其热值仅在4500卡/克左右，且还具有能耗高、易挥发、燃烧效率较低等缺陷。
发明内容
本发明针对现有技术存在的不足，提供了一种灶用醇基燃料及其制备方法，具体技术方案如下：
一种灶用醇基燃料及其制备方法，包括以下组分的重量份：
甲醇：55～57质量份，
酮类化合物：20～22质量份，
环烷烃：11～13质量份，
共溶剂：7～9质量份，
消烟助燃剂：0.5～0.7质量份，
催化助燃剂：2.3～2.5质量份。
作为上述技术方案的改进，所述酮类化合物为丙酮、丁酮、环己酮、环戊酮、苯乙酮、苯丙酮中的一种或数种。
作为上述技术方案的改进，所述环烷烃为环戊烷、环己烷、环庚烷、环辛烃中的一种或数种。
作为上述技术方案的改进，所述共溶剂为乙醇、丙醇、丁醇、戊醇、己醇、二乙二醇、丙三醇中的一种或数种。
作为上述技术方案的改进，所述消烟助燃剂为二茂铁。
作为上述技术方案的改进，所述催化助燃剂是溴化铈、碘化镝、硼氢化钾按照质量比100∶(50～60)∶(1～2)的比例混合制成。
作为上述技术方案的改进，所述灶用醇基燃料的制备方法：按照配方量称取甲醇、酮类化合物、环烷烃、共溶剂、消烟助燃剂、催化助燃剂，然后将消烟助燃剂、催化助燃剂、共溶剂通过搅拌混合制成助燃溶液，然后将助燃溶液与甲醇、酮类化合物、环烷烃通过搅拌混合即得所述灶用醇基燃料。
本发明的有益效果：本发明所述灶用醇基燃料中的甲醇、酮类化合物、环烷烃、共溶剂在消烟助燃剂和催化助燃剂的共同作用下，燃烧时无烟、无味，燃烧时的热值高，可达到6370卡/克；燃烧时不会产生堵塞，燃烧效率能够达到95％以上。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白，以下结合实施例，对本发明进行进一步详细说明。应当理解，此处所描述的具体实施例仅仅用以解释本发明，并不用于限定本发明。
实施例1
一种灶用醇基燃料包括以下组分：
甲醇：55kg，
酮类化合物：22kg，
环烷烃：11kg，
共溶剂：9kg，
消烟助燃剂：0.5kg，
催化助燃剂：2.5kg。
其中，所述酮类化合物为丙酮、丁酮、环己酮、环戊酮、苯乙酮、苯丙酮中的一种或数种。所述环烷烃为环戊烷、环己烷、环庚烷、环辛烃中的一种或数种。所述共溶剂为乙醇、丙醇、丁醇、戊醇、己醇、二乙二醇、丙三醇中的一种或数种。所述消烟助燃剂为二茂铁。所述催化助燃剂是溴化铈、碘化镝、硼氢化钾按照质量比100∶50∶1的比例混合制成。
所述灶用醇基燃料的制备方法为：按照配方量称取甲醇、酮类化合物、环烷烃、共溶剂、消烟助燃剂、催化助燃剂，然后将消烟助燃剂、催化助燃剂、共溶剂通过搅拌混合制成助燃溶液，然后将助燃溶液与甲醇、酮类化合物、环烷烃通过搅拌混合即得所述灶用醇基燃料。
实施例2
一种灶用醇基燃料包括以下组分：
甲醇：56kg，
酮类化合物：21kg，
环烷烃：12kg，
共溶剂：8kg，
消烟助燃剂：0.6kg，
催化助燃剂：2.4kg。
其中，所述酮类化合物为丙酮、丁酮、环己酮、环戊酮、苯乙酮、苯丙酮中的一种或数种。所述环烷烃为环戊烷、环己烷、环庚烷、环辛烃中的一种或数种。所述共溶剂为乙醇、丙醇、丁醇、戊醇、己醇、二乙二醇、丙三醇中的一种或数种。所述消烟助燃剂为二茂铁。所述催化助燃剂是溴化铈、碘化镝、硼氢化钾按照质量比100∶57∶1.6的比例混合制成。
所述灶用醇基燃料的制备方法为：按照配方量称取甲醇、酮类化合物、环烷烃、共溶剂、消烟助燃剂、催化助燃剂，然后将消烟助燃剂、催化助燃剂、共溶剂通过搅拌混合制成助燃溶液，然后将助燃溶液与甲醇、酮类化合物、环烷烃通过搅拌混合即得所述灶用醇基燃料。
实施例3
一种灶用醇基燃料包括以下组分：
甲醇：57kg，
酮类化合物：20kg，
环烷烃：13kg，
共溶剂：7kg，
消烟助燃剂：0.7kg，
催化助燃剂：2.3kg。
其中，所述酮类化合物为丙酮、丁酮、环己酮、环戊酮、苯乙酮、苯丙酮中的一种或数种。所述环烷烃为环戊烷、环己烷、环庚烷、环辛烃中的一种或数种。所述共溶剂为乙醇、丙醇、丁醇、戊醇、己醇、二乙二醇、丙三醇中的一种或数种。所述消烟助燃剂为二茂铁。所述催化助燃剂是溴化铈、碘化镝、硼氢化钾按照质量比100∶60∶2的比例混合制成。
所述灶用醇基燃料的制备方法为：按照配方量称取甲醇、酮类化合物、环烷烃、共溶剂、消烟助燃剂、催化助燃剂，然后将消烟助燃剂、催化助燃剂、共溶剂通过搅拌混合制成助燃溶液，然后将助燃溶液与甲醇、酮类化合物、环烷烃通过搅拌混合即得所述灶用醇基燃料。
在上述实施例中，二茂铁作为消烟助燃剂，具有消烟、助燃的效果。催化助燃剂中溴化铈、碘化镝、硼氢化钾按照配方量均能够溶于共溶剂中，这使得成品中不存在沉淀。在催化助燃剂中，溴化铈与碘化镝在燃烧后会被氧化成相应的氧化物，再加上硼氢化钾的配合，可促进所述灶用醇基燃料在燃烧的过程中会裂解产生部分氢气，从而使得燃烧的热值能够提高，最终提高醇基燃料利用率。
本发明所述灶用醇基燃料热值高，其热值大于或等于5350卡/克；燃烧效率能够达到95％以上。
以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等，均应包含在本发明的保护范围之内。
Claims (7)
1.一种灶用醇基燃料，其特征在于包括以下组分的重量份：
甲醇：55～57质量份，
酮类化合物：20～22质量份，
环烷烃：11～13质量份，
共溶剂：7～9质量份，
消烟助燃剂：0.5～0.7质量份，
催化助燃剂：2.3～2.5质量份。
2.根据权利要求1所述的一种灶用醇基燃料，其特征在于：所述酮类化合物为丙酮、丁酮、环己酮、环戊酮、苯乙酮、苯丙酮中的一种或数种。
3.根据权利要求1所述的一种灶用醇基燃料，其特征在于：所述环烷烃为环戊烷、环己烷、环庚烷、环辛烃中的一种或数种。
4.根据权利要求1所述的一种灶用醇基燃料及其制备方法，其特征在于：所述共溶剂为乙醇、丙醇、丁醇、戊醇、己醇、二乙二醇、丙三醇中的一种或数种。
5.根据权利要求1所述的一种灶用醇基燃料，其特征在于：所述消烟助燃剂为二茂铁。
6.根据权利要求1所述的一种灶用醇基燃料及其制备方法，其特征在于：所述催化助燃剂是溴化铈、碘化镝、硼氢化钾按照质量比100∶(50～60)∶(1～2)的比例混合制成。
7.根据权利要求1～6任一项所述的一种灶用醇基燃料的制备方法，其特征在于：按照配方量称取甲醇、酮类化合物、环烷烃、共溶剂、消烟助燃剂、催化助燃剂，然后将消烟助燃剂、催化助燃剂、共溶剂通过搅拌混合制成助燃溶液，然后将助燃溶液与甲醇、酮类化合物、环烷烃通过搅拌混合即得所述灶用醇基燃料。
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