CN108948885A - A kind of preparation method of high rigidity purification air wall paper-based membrane - Google Patents
A kind of preparation method of high rigidity purification air wall paper-based membrane Download PDFInfo
- Publication number
- CN108948885A CN108948885A CN201810650287.0A CN201810650287A CN108948885A CN 108948885 A CN108948885 A CN 108948885A CN 201810650287 A CN201810650287 A CN 201810650287A CN 108948885 A CN108948885 A CN 108948885A
- Authority
- CN
- China
- Prior art keywords
- parts
- temperature
- high rigidity
- wall paper
- purification air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The invention belongs to decorative materials technology, especially a kind of preparation method of high rigidity purification air wall paper-based membrane, the specific method is as follows: (1) weighing raw material by weight；(2) it by spinach, Chinese rose petal and Chinese wistaria petal co-grinding, ferments, takes out, be added in deionized water and stir evenly, be boiled by slow fire, take out, ferment, take out, filtering takes filtrate, obtains fermentation liquid；(3) D-sorbite, magnesium stearate and yam flour are put into fermentation liquid, mild fire is heated and is stirred continuously, styrene-acrylic emulsion and acrylate and vinyl acetate emulsion is added, mild fire is heated and is stirred continuously, room temperature natural cooling, modified mountain flour is added and nano-titanium dioxide is mixed evenly, is ultrasonically treated, obtains high rigidity purification air wall paper-based membrane；Not only there is stronger hardness, the ability that wallpaper basement membrane solidifies dusting metope can be effectively improved, and have the ability of stronger absorption VOC, can effectively purify air.
Description
Technical field
The invention belongs to decorative materials technology, especially a kind of preparation side of high rigidity purification air wall paper-based membrane
Method.
Background technique
Wallpaper basement membrane is a kind of special alkali resistant, moisture-proof, mould proof metope processing material, can effectively prevent construction metope
Moisture and alkaline matter extravasation, prevent getting damp for wall decorative material such as wallpaper, decorative panel, mouldy and turning black and changing color phenomenon hair
It is raw；Before wallpaper, as soon as needing first to brush a layer wallpaper basement membrane, done on metope etc. when basement membrane brush will form one layer later
Fine and close protective film, its effect is exactly that metope is isolated, and wallpaper and metope is allowed to keep apart, and not allow wallpaper to directly touch wall
Face effectively extends the service life of wallpaper, while providing convenience for the replacement of the later period of wallpaper；But wallpaper basement membrane on the market is made
With single, Wall paper adhesive cannot be inhibited to generate mildew, without lasting bacteriostasis, the metope for dusting will cause wallpaper large area
It falls off, some harmful organic gas can be discharged, polluted the environment, bring harm to human health；Therefore, it is badly in need of invention
A kind of wallpaper basement membrane makes up the defect of prior art basement membrane wallpaper.
Summary of the invention
In view of the above-mentioned problems, the present invention is intended to provide a kind of preparation method of high rigidity purification air wall paper-based membrane.
The invention is realized by the following technical scheme:
A kind of preparation method of high rigidity purification air wall paper-based membrane, the specific method is as follows:
(1) raw material is weighed by weight, modified 3.4 ~ 3.6 parts of mountain flour, 0.52 ~ 0.56 part of nano-titanium dioxide, styrene-acrylic emulsion 26 ~
28 parts, 20 ~ 22 parts of acrylate and vinyl acetate emulsion, 1.1 ~ 1.3 parts of D-sorbite, 3.1 ~ 3.3 parts of magnesium stearate, 2.2 ~ 2.4 parts of yam flour, spinach
7.2 ~ 7.8 parts, 5.2 ~ 5.4 parts of Chinese rose petal, 5.9 ~ 6.3 parts of Chinese wistaria petal, 90 ~ 100 parts of deionized water；
(2) by spinach, Chinese rose petal and Chinese wistaria petal co-grinding, be placed in ferment at constant temperature 48 under conditions of temperature is 44 ~ 46 DEG C ~
58h takes out, and is added in deionized water and stirs evenly, is boiled by slow fire, and takes out, constant temperature in the fermenting case that merging temperature is 29 ~ 31 DEG C
Ferment 32 ~ 38h, takes out, and filtering takes filtrate, obtains fermentation liquid；
(3) D-sorbite, magnesium stearate and yam flour are put into fermentation liquid, it is 64 ~ 68 DEG C simultaneously continuous that mild fire, which is heated to temperature,
Stirring, is added styrene-acrylic emulsion and acrylate and vinyl acetate emulsion, and mild fire is heated to temperature and is 86 ~ 90 DEG C and is stirred continuously that room temperature natural cooling adds
Enter modified mountain flour and nano-titanium dioxide is mixed evenly, be ultrasonically treated 45 ~ 49min, obtains high rigidity purification air wall paper base
Film.
As invention further embodiment: the modification mountain flour is prepared according to the following steps:
A. by the medical stone of 15.4 ~ 16.8 parts by weight, the hornblend of the vermiculite of 12.1 ~ 13.3 parts by weight and 6.2 ~ 6.8 parts by weight
It crushes respectively, is immersed in the acetum that mass fraction is 9.4% ~ 10.2% and impregnates 52 ~ 68min, filtrate is pulled out, and temperature is placed in
Constant temperature steam handles 23 ~ 27min under conditions of being 121 ~ 135 DEG C, takes out, permanent in the rotary frying pan that merging temperature is 57 ~ 61 DEG C
Warm 16 ~ 18min of frying takes out, obtains mixing stone grain；
B. stone grain will be mixed and 24 ~ 26 parts by weight, mass fraction is the liquor potassic permanganate that 8.3% ~ 8.7%, temperature is 38 ~ 40 DEG C
28 ~ 32min, clear water washing is mixed with the blender that revolving speed is 140 ~ 160r/min in mixing, and drying is ground to 160 ~ 180
Mesh, 15 ~ 17min of magnetization treatment under conditions of magnetic field strength is 2460 ~ 2500G, obtains modified mountain flour.
As invention further embodiment: the partial size of the nano-titanium dioxide is 40 ~ 50nm.
As invention further embodiment: the yam flour is prepared according to the following steps: Chinese yam is cleaned, and is crushed
Mashing, merging temperature are toasted 13 ~ 15min for constant temperature in 62 ~ 64 DEG C of baking box, are taken out, and are added 0.7 ~ 0.8 times of Chinese yam weight
Amount, the ethanol solution that mass fraction is 39% ~ 41% stir 23 ~ 25min, vacuum with the blender that revolving speed is 440 ~ 480r/min
Freeze-drying, obtains yam flour.
As invention further embodiment: ultrasonic treatment described in step (3) is 341 ~ 349W, frequency 212 in power
28 ~ 30min is ultrasonically treated under conditions of ~ 218kHz, it is ultrasonic under conditions of power is 173 ~ 181W, frequency is 113 ~ 117kHz
Handle 17 ~ 19min.
Beneficial effects of the present invention: a kind of preparation method of high rigidity purification air wall paper-based membrane provided by the invention adds
Enter modified mountain flour and the effect of nano-titanium dioxide coordinated, can effectively enhance the structural stability of wallpaper basement membrane, effectively promotees
Into fast filming, enhance its viscosity, rate of drying is fast, and penetrating power is strong, and big at film hardness, effectively enhancing solidifies dusting metope
Ability, effectively avoids the generation of differentiation metope picking and shedding phenomenon, and can effectively adsorb volatile organic compounds, subtracts
The content of volatile organic compounds, avoids threatening to human health in few air；Yam flour, spinach, China rose is added
Valve and the effect of Chinese wistaria petal coordinated, environmentally protective, promotion is with fresh air, effectively removes penetrating odor, and can be effective
Press down mycostatic growth, enhance the waterproof and dampproof ability of metope, so that the mildew of wallpaper effectively be inhibited to rot and blister, reduces wall
The use cost of paper improves the decorative effect of wallpaper；The method of the present invention is easily operated, has wallpaper basement membrane stronger
Hardness can effectively improve the ability that wallpaper basement membrane solidifies dusting metope, and the ability with stronger absorption VOC, can have
Effect purification air, it is environmentally protective.
Specific embodiment
Illustrate the present invention with specific embodiment below, but is not limitation of the present invention.
Embodiment 1
In the embodiment of the present invention, a kind of preparation method of high rigidity purification air wall paper-based membrane, the specific method is as follows:
(1) raw material, modified 3.4 parts of mountain flour, 0.52 part of nano-titanium dioxide, 26 parts of styrene-acrylic emulsion, the third cream of vinegar are weighed by weight
20 parts of liquid, 1.1 parts of D-sorbite, 3.1 parts of magnesium stearate, 2.2 parts of yam flour, 7.2 parts of spinach, 5.2 parts of Chinese rose petal, wistaria flower
5.9 parts of valve, 90 parts of deionized water；
(2) by spinach, Chinese rose petal and Chinese wistaria petal co-grinding, being placed in temperature is ferment at constant temperature 48h under conditions of 44 DEG C, is taken
Out, it is added in deionized water and stirs evenly, be boiled by slow fire, take out, ferment at constant temperature 32h in the fermenting case that merging temperature is 29 DEG C,
It takes out, filtering takes filtrate, obtains fermentation liquid；
(3) D-sorbite, magnesium stearate and yam flour are put into fermentation liquid, mild fire is heated to temperature and is 64 DEG C and constantly stirs
It mixes, styrene-acrylic emulsion and acrylate and vinyl acetate emulsion is added, mild fire is heated to temperature and is 86 DEG C and is stirred continuously that room temperature natural cooling, addition changes
Property mountain flour and nano-titanium dioxide be mixed evenly, be ultrasonically treated 45min, obtain high rigidity purification air wall paper-based membrane.
As invention further embodiment: the modification mountain flour is prepared according to the following steps:
A. the hornblend of the medical stone of 15.4 parts by weight, the vermiculite of 12.1 parts by weight and 6.2 parts by weight is crushed respectively, is immersed in
52min is impregnated in the acetum that mass fraction is 9.4%, filtrate is pulled out, and merging temperature is constant temperature steam under conditions of 121 DEG C
23min is handled, is taken out, constant temperature frying 16min in the rotary frying pan that merging temperature is 57 DEG C takes out, obtains mixing stone grain；
B. mixing stone grain is mixed with 24 parts by weight, mass fraction 8.3%, the liquor potassic permanganate that temperature is 38 DEG C, uses revolving speed
28min, clear water washing is mixed for the blender of 140r/min, drying is ground to 160 mesh, is 2460G's in magnetic field strength
Under the conditions of magnetization treatment 15min, obtain modified mountain flour.
As invention further embodiment: the partial size of the nano-titanium dioxide is 40nm.
As invention further embodiment: the yam flour is prepared according to the following steps: Chinese yam is cleaned, and is crushed
Mashing, merging temperature are toasted 13min for constant temperature in 62 DEG C of baking box, are taken out, and 0.7 times of Chinese yam weight amount, mass fraction is added
For 39% ethanol solution, 23min is stirred with the blender that revolving speed is 440r/min, vacuum freeze drying obtains yam flour.
As invention further embodiment: ultrasonic treatment described in step (3), power be 341W, frequency 212kHz
Under conditions of be ultrasonically treated 28min, be ultrasonically treated 17min under conditions of power is 173W, frequency is 113kHz.
Embodiment 2
In the embodiment of the present invention, a kind of preparation method of high rigidity purification air wall paper-based membrane, the specific method is as follows:
(1) raw material, modified 3.5 parts of mountain flour, 0.54 part of nano-titanium dioxide, 27 parts of styrene-acrylic emulsion, the third cream of vinegar are weighed by weight
21 parts of liquid, 1.2 parts of D-sorbite, 3.2 parts of magnesium stearate, 2.3 parts of yam flour, 7.5 parts of spinach, 5.3 parts of Chinese rose petal, wistaria flower
6.1 parts of valve, 95 parts of deionized water；
(2) by spinach, Chinese rose petal and Chinese wistaria petal co-grinding, being placed in temperature is ferment at constant temperature 53h under conditions of 45 DEG C, is taken
Out, it is added in deionized water and stirs evenly, be boiled by slow fire, take out, ferment at constant temperature 35h in the fermenting case that merging temperature is 30 DEG C,
It takes out, filtering takes filtrate, obtains fermentation liquid；
(3) D-sorbite, magnesium stearate and yam flour are put into fermentation liquid, mild fire is heated to temperature and is 66 DEG C and constantly stirs
It mixes, styrene-acrylic emulsion and acrylate and vinyl acetate emulsion is added, mild fire is heated to temperature and is 88 DEG C and is stirred continuously that room temperature natural cooling, addition changes
Property mountain flour and nano-titanium dioxide be mixed evenly, be ultrasonically treated 47min, obtain high rigidity purification air wall paper-based membrane.
As invention further embodiment: the modification mountain flour is prepared according to the following steps:
A. the hornblend of the medical stone of 16.1 parts by weight, the vermiculite of 12.7 parts by weight and 6.5 parts by weight is crushed respectively, is immersed in
60min is impregnated in the acetum that mass fraction is 9.8%, filtrate is pulled out, and merging temperature is constant temperature steam under conditions of 128 DEG C
25min is handled, is taken out, constant temperature frying 17min in the rotary frying pan that merging temperature is 59 DEG C takes out, obtains mixing stone grain；
B. mixing stone grain is mixed with 25 parts by weight, mass fraction 8.5%, the liquor potassic permanganate that temperature is 39 DEG C, uses revolving speed
30min, clear water washing is mixed for the blender of 150r/min, drying is ground to 170 mesh, is 2480G's in magnetic field strength
Under the conditions of magnetization treatment 16min, obtain modified mountain flour.
As invention further embodiment: the partial size of the nano-titanium dioxide is 45nm.
As invention further embodiment: the yam flour is prepared according to the following steps: Chinese yam is cleaned, and is crushed
Mashing, merging temperature are toasted 14min for constant temperature in 63 DEG C of baking box, are taken out, and 0.75 times of Chinese yam weight amount, mass fraction is added
For 40% ethanol solution, 24min is stirred with the blender that revolving speed is 460r/min, vacuum freeze drying obtains yam flour.
As invention further embodiment: ultrasonic treatment described in step (3), power be 345W, frequency 215kHz
Under conditions of be ultrasonically treated 29min, be ultrasonically treated 18min under conditions of power is 177W, frequency is 115kHz.
Embodiment 3
In the embodiment of the present invention, a kind of preparation method of high rigidity purification air wall paper-based membrane, the specific method is as follows:
(1) raw material, modified 3.6 parts of mountain flour, 0.56 part of nano-titanium dioxide, 28 parts of styrene-acrylic emulsion, the third cream of vinegar are weighed by weight
22 parts of liquid, 1.3 parts of D-sorbite, 3.3 parts of magnesium stearate, 2.4 parts of yam flour, 7.8 parts of spinach, 5.4 parts of Chinese rose petal, wistaria flower
6.3 parts of valve, 100 parts of deionized water；
(2) by spinach, Chinese rose petal and Chinese wistaria petal co-grinding, being placed in temperature is ferment at constant temperature 58h under conditions of 46 DEG C, is taken
Out, it is added in deionized water and stirs evenly, be boiled by slow fire, take out, ferment at constant temperature 38h in the fermenting case that merging temperature is 31 DEG C,
It takes out, filtering takes filtrate, obtains fermentation liquid；
(3) D-sorbite, magnesium stearate and yam flour are put into fermentation liquid, mild fire is heated to temperature and is 68 DEG C and constantly stirs
It mixes, styrene-acrylic emulsion and acrylate and vinyl acetate emulsion is added, mild fire is heated to temperature and is 90 DEG C and is stirred continuously that room temperature natural cooling, addition changes
Property mountain flour and nano-titanium dioxide be mixed evenly, be ultrasonically treated 49min, obtain high rigidity purification air wall paper-based membrane.
As invention further embodiment: the modification mountain flour is prepared according to the following steps:
A. the hornblend of the medical stone of 16.8 parts by weight, the vermiculite of 13.3 parts by weight and 6.8 parts by weight is crushed respectively, is immersed in
68min is impregnated in the acetum that mass fraction is 10.2%, filtrate is pulled out, and merging temperature is constant temperature steam under conditions of 135 DEG C
27min is handled, is taken out, constant temperature frying 18min in the rotary frying pan that merging temperature is 61 DEG C takes out, obtains mixing stone grain；
B. mixing stone grain is mixed with 26 parts by weight, mass fraction 8.7%, the liquor potassic permanganate that temperature is 40 DEG C, uses revolving speed
32min, clear water washing is mixed for the blender of 160r/min, drying is ground to 180 mesh, is 2500G's in magnetic field strength
Under the conditions of magnetization treatment 17min, obtain modified mountain flour.
As invention further embodiment: the partial size of the nano-titanium dioxide is 50nm.
As invention further embodiment: the yam flour is prepared according to the following steps: Chinese yam is cleaned, and is crushed
Mashing, merging temperature are toasted 15min for constant temperature in 64 DEG C of baking box, are taken out, and 0.8 times of Chinese yam weight amount, mass fraction is added
For 41% ethanol solution, 25min is stirred with the blender that revolving speed is 480r/min, vacuum freeze drying obtains yam flour.
As invention further embodiment: ultrasonic treatment described in step (3), power be 349W, frequency 218kHz
Under conditions of be ultrasonically treated 30min, under conditions of power is 181W, frequency is 117kHz be ultrasonically treated 17 ~ 19min.
Comparative example 1
A kind of preparation method of high rigidity purification air wall paper-based membrane, the difference from embodiment 1 is that, by the modification mountain flour
It is replaced with tourmaline powder, other conditions are all the same.
Comparative example 2
A kind of preparation method of high rigidity purification air wall paper-based membrane, the difference from embodiment 1 is that, it is not added in the raw material
Enter nano-titanium dioxide and yam flour, other conditions are all the same.
Comparative example 3
A kind of preparation method of high rigidity purification air wall paper-based membrane, the difference from embodiment 1 is that, it is not added in the raw material
It is all the same to enter spinach, Chinese rose petal and Chinese wistaria petal, other conditions.
Comparative example 4
A kind of preparation method of high rigidity purification air wall paper-based membrane, the difference from embodiment 1 is that, step (3) is without super
Sonication, other conditions are all the same.
The high rigidity that the preparation method of the preparation method for using embodiment and comparative example is prepared purifies air wallpaper
Basement membrane carry out performance detection, detection wallpaper basement membrane at film hardness (by the wallpaper basement membrane prepared uniformly brush 10cm ×
It on 20cm putty plate, hangs 30min and brushes again the 2nd time, place hard according to 2006 test film of GB/T6739-after 12h is fully cured
Degree) and VOC adsorption capacity (on organic glass case inner side brush wallpaper basement membrane template, 12h to parching completely for placement, with formaldehyde, first
Benzene, ammonium hydroxide and acetone are that 9:4:3:1 is made into mixed solvent according to mass ratio, are sprayed into the organic glass case of sealing, are mixed with watering can
The initial concentration for closing organic matter is 7000mg/m3, portable V OC tester test VOC content is used after 12h to adsorb as VOC
Ability), as a result such as table 1
The wallpaper basement membrane performance comparing result of 1 embodiment and comparative example of table
As it can be seen from table 1 the wallpaper basement membrane that the present invention is prepared not only has stronger hardness, wallpaper can be effectively improved
Basement membrane solidifies the ability of dusting metope, and has the ability of stronger absorption VOC, can effectively purify air.
Claims (5)
1. a kind of preparation method of high rigidity purification air wall paper-based membrane, which is characterized in that the specific method is as follows:
(1) raw material is weighed by weight, modified 3.4 ~ 3.6 parts of mountain flour, 0.52 ~ 0.56 part of nano-titanium dioxide, styrene-acrylic emulsion 26 ~
28 parts, 20 ~ 22 parts of acrylate and vinyl acetate emulsion, 1.1 ~ 1.3 parts of D-sorbite, 3.1 ~ 3.3 parts of magnesium stearate, 2.2 ~ 2.4 parts of yam flour, spinach
7.2 ~ 7.8 parts, 5.2 ~ 5.4 parts of Chinese rose petal, 5.9 ~ 6.3 parts of Chinese wistaria petal, 90 ~ 100 parts of deionized water；
(2) by spinach, Chinese rose petal and Chinese wistaria petal co-grinding, be placed in ferment at constant temperature 48 under conditions of temperature is 44 ~ 46 DEG C ~
58h takes out, and is added in deionized water and stirs evenly, is boiled by slow fire, and takes out, constant temperature in the fermenting case that merging temperature is 29 ~ 31 DEG C
Ferment 32 ~ 38h, takes out, and filtering takes filtrate, obtains fermentation liquid；
(3) D-sorbite, magnesium stearate and yam flour are put into fermentation liquid, it is 64 ~ 68 DEG C simultaneously continuous that mild fire, which is heated to temperature,
Stirring, is added styrene-acrylic emulsion and acrylate and vinyl acetate emulsion, and mild fire is heated to temperature and is 86 ~ 90 DEG C and is stirred continuously that room temperature natural cooling adds
Enter modified mountain flour and nano-titanium dioxide is mixed evenly, be ultrasonically treated 45 ~ 49min, obtains high rigidity purification air wall paper base
Film.
2. the preparation method of high rigidity purification air wall paper-based membrane according to claim 1, which is characterized in that described changes
Property mountain flour, is prepared according to the following steps:
A. by the medical stone of 15.4 ~ 16.8 parts by weight, the hornblend of the vermiculite of 12.1 ~ 13.3 parts by weight and 6.2 ~ 6.8 parts by weight
It crushes respectively, is immersed in the acetum that mass fraction is 9.4% ~ 10.2% and impregnates 52 ~ 68min, filtrate is pulled out, and temperature is placed in
Constant temperature steam handles 23 ~ 27min under conditions of being 121 ~ 135 DEG C, takes out, permanent in the rotary frying pan that merging temperature is 57 ~ 61 DEG C
Warm 16 ~ 18min of frying takes out, obtains mixing stone grain；
B. stone grain will be mixed and 24 ~ 26 parts by weight, mass fraction is the liquor potassic permanganate that 8.3% ~ 8.7%, temperature is 38 ~ 40 DEG C
28 ~ 32min, clear water washing is mixed with the blender that revolving speed is 140 ~ 160r/min in mixing, and drying is ground to 160 ~ 180
Mesh, 15 ~ 17min of magnetization treatment under conditions of magnetic field strength is 2460 ~ 2500G, obtains modified mountain flour.
3. the preparation method of high rigidity purification air wall paper-based membrane according to claim 1, which is characterized in that described receives
The partial size of rice titanium dioxide is 40 ~ 50nm.
4. the preparation method of high rigidity purification air wall paper-based membrane according to claim 1, which is characterized in that the mountain
Medicinal powder is prepared according to the following steps: Chinese yam being cleaned, crushes mashing, constant temperature dries in the baking box that merging temperature is 62 ~ 64 DEG C
Roasting 13 ~ 15min, takes out, and 0.7 ~ 0.8 times of Chinese yam weight amount is added, the ethanol solution that mass fraction is 39% ~ 41%, is with revolving speed
The blender of 440 ~ 480r/min stirs 23 ~ 25min, and vacuum freeze drying obtains yam flour.
5. the preparation method of high rigidity purification air wall paper-based membrane according to claim 1, which is characterized in that step (3)
The ultrasonic treatment is ultrasonically treated 28 ~ 30min, in function under conditions of power is 341 ~ 349W, frequency is 212 ~ 218kHz
17 ~ 19min is ultrasonically treated under conditions of rate is 173 ~ 181W, frequency is 113 ~ 117kHz.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810650287.0A CN108948885A (en) | 2018-06-22 | 2018-06-22 | A kind of preparation method of high rigidity purification air wall paper-based membrane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810650287.0A CN108948885A (en) | 2018-06-22 | 2018-06-22 | A kind of preparation method of high rigidity purification air wall paper-based membrane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108948885A true CN108948885A (en) | 2018-12-07 |
Family
ID=64491926
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810650287.0A Pending CN108948885A (en) | 2018-06-22 | 2018-06-22 | A kind of preparation method of high rigidity purification air wall paper-based membrane |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108948885A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101690888A (en) * | 2009-10-16 | 2010-04-07 | 清华大学 | Method for preparing chemical absorbent with porous mineral |
| CN106046906A (en) * | 2016-08-16 | 2016-10-26 | 张静 | Preparation method of environmentally friendly interior wall waterproof putty powder |
| CN107216752A (en) * | 2016-06-13 | 2017-09-29 | 嘉力丰科技股份有限公司 | Wallpaper basement membrane and preparation method thereof |
-
2018
- 2018-06-22 CN CN201810650287.0A patent/CN108948885A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101690888A (en) * | 2009-10-16 | 2010-04-07 | 清华大学 | Method for preparing chemical absorbent with porous mineral |
| CN107216752A (en) * | 2016-06-13 | 2017-09-29 | 嘉力丰科技股份有限公司 | Wallpaper basement membrane and preparation method thereof |
| CN106046906A (en) * | 2016-08-16 | 2016-10-26 | 张静 | Preparation method of environmentally friendly interior wall waterproof putty powder |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105754396B (en) | Powder of lacquer putty for use on and preparation method thereof | |
| CN102337193B (en) | Method for preparing starter for improving content of health flavor components of white spirit | |
| CN106318826A (en) | Preparation method for phellinus linteus healthcare wine | |
| CN108864670A (en) | A kind of preparation method of degradable food package film | |
| CN108948885A (en) | A kind of preparation method of high rigidity purification air wall paper-based membrane | |
| CN106635829B (en) | A kind of preparation method of Phellinus granular bacteria strain | |
| CN106665667A (en) | Preparation method of natural composite leather anti-bacterial and mildew-proof agent | |
| CN105477540A (en) | Turmeric red-yeast preparation method and turmeric red-yeast product | |
| CN104004663B (en) | The preparation method of nematode-destroying fungus biology lyophilized formulations | |
| CN108029799A (en) | A kind of jasmine tea preparation method of bulk bacteria floating | |
| CN107201072A (en) | A kind of powder of lacquer putty for use on and preparation method thereof | |
| CN208684967U (en) | Negative pressure freeze-day with constant temperature equipment | |
| CN107363948A (en) | The preparation method of purple willow fungusproof anti-corrosion agent is lost in a kind of anti-current | |
| CN107186848A (en) | A kind of processing method for lifting rattan anticorrosive mildewproof performance | |
| CN105532754B (en) | A kind of infested natural plants combined extracts to go mouldy of prevention grain | |
| CN104059843B (en) | A kind of preparation method of Semen Vitis viniferae fermentation rice wine | |
| CN105860636B (en) | Powder of lacquer putty for use on and preparation method thereof | |
| CN106916694A (en) | A kind of production technology of aromatic fruity white wine | |
| KR20130129524A (en) | Fomentation medium having herb and bath tube system | |
| CN1337164A (en) | Microbial bactericide and its prepn. | |
| CN105533571A (en) | Vegetable pickling method for restraining generation of nitrite and pellicle in pickling process | |
| CN108913467A (en) | A kind of preparation method of acorn wine | |
| CN109943204A (en) | A kind of preparation method of woodwork antibiosis anti-cracking water paint | |
| CN110050938A (en) | A kind of tea fresh keeping pulvis and its application method | |
| CN108967522A (en) | A kind of preparation method of passion fruit antistaling agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181207 |
|
| RJ01 | Rejection of invention patent application after publication |