CN108929771A - A kind of extracting method and its application of Tea Saponin - Google Patents
A kind of extracting method and its application of Tea Saponin Download PDFInfo
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- CN108929771A CN108929771A CN201810777863.8A CN201810777863A CN108929771A CN 108929771 A CN108929771 A CN 108929771A CN 201810777863 A CN201810777863 A CN 201810777863A CN 108929771 A CN108929771 A CN 108929771A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/06—Production of fats or fatty oils from raw materials by pressing
- C11B1/08—Production of fats or fatty oils from raw materials by pressing by hot pressing
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H1/00—Processes for the preparation of sugar derivatives
- C07H1/06—Separation; Purification
- C07H1/08—Separation; Purification from natural products
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H15/00—Compounds containing hydrocarbon or substituted hydrocarbon radicals directly attached to hetero atoms of saccharide radicals
- C07H15/20—Carbocyclic rings
- C07H15/24—Condensed ring systems having three or more rings
- C07H15/256—Polyterpene radicals
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- C07J—STEROIDS
- C07J63/00—Steroids in which the cyclopenta(a)hydrophenanthrene skeleton has been modified by expansion of only one ring by one or two atoms
- C07J63/008—Expansion of ring D by one atom, e.g. D homo steroids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/02—Pretreatment
- C11B1/04—Pretreatment of vegetable raw material
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Abstract
The invention discloses a kind of extracting method of Tea Saponin and its applications, are related to Tea Saponin application field；Fresh camellia oleifera fruit is picked, is covered with preservative film, is put into saturated vapour pressure and handles, then it shells, by separation of hull from kernel after shelling, the tea seed kernel after separation is impregnated with inorganic agent, then it stir-fries, it is being impregnated after stir-frying, is then taking oil meal and tea-seed oil with cold pressing legal system, the oil meal produced, which is put into leaching liquor, to be impregnated, centrifugal filtration after immersion, recycling leaching liquor is concentrated under reduced pressure, Tea Saponin is made, Tea Saponin is applied to daily necessities facial cleanser；The Tea Saponin content of extraction is high, impurity is few and soluble easily in water, and extracting method is simple, easy to operate; high production efficiency applies it in facial cleanser, and the facial cleanser of preparation does not stimulate mildly; it is suitble to all skin quality to use, while deoiling decontamination, protection skin preserves from.
Description
Technical field:
The present invention relates to Tea Saponin application fields, and in particular to a kind of extracting method and its application of Tea Saponin.
Background technique:
Tea Saponin is a kind of sugared formula compound extracted from the seed of plant of theaceae, it belongs to saponin class, is a kind of day
Right nonionic surface active agent.Through detecting, Tea Saponin has the function of good emulsification, dispersion, foaming, wet etc., and has
There are anti-inflammatory, analgesia, the pharmacological actions such as impermeabilisation.Tea Saponin as pesticide wetting agent can be improved wettable powder wet performance and
Suspensibility (>=75%) is added in pesticide and uses as a kind of natural nonionic surface active agent, hence it is evident that improves pesticide
The physicochemical property of medical fluid improves medicament effective accumulated amount on target, is allowed to facilitate giving full play to for pesticide efficacy, therefore, make
It can be improved with effect.It is that wetting speed is fast as pesticide wetting agent outstanding advantages, dispersion performance is strong, pH5.5-6.5, neutral
Meta-acid will not cause pesticide to decompose, and be conducive to the storage of pesticide.These are all that synthetic surfactant can not be by comparison
's.Tea Saponin is widely used in the wetting agent of the pesticides such as paclobutrazol, Mobucin, aliette, tricyclazole.
As the improvement of people's living standards, continuous pursuit of the people to beauty, cosmetics have become the articles for daily use of people,
Beauty is brought.Currently, cosmetic product go out to the greatest extent it is not poor, it is effective, do not have effect, mix the genuine with the fictitious, price has height
Have low, difference is also very big, and technical breakthrough, the breakthrough especially in using effect is that manufacturer and consumer are total to
With what is pursued.Current facial cleanser, it is mostly too many containing chemical synthesis ingredient, occurred after leading to many skin allergy person uses
It is quick, even if chemical class facial cleanser is used for a long time there is no the skin of allergy, to the also irritant harm of face.
Summary of the invention:
Technical problem to be solved by the present invention lies in provide the extracting method and its application of a kind of Tea Saponin, the tea of extraction
Saponin content is high, impurity is few and soluble easily in water, and extracting method is simple, easy to operate, and high production efficiency applies it to facial cleanser
In, the facial cleanser of preparation does not stimulate mildly, and all skin quality is suitble to use, and while deoiling decontamination, protection skin preserves from.
The following technical solution is employed for the technical problems to be solved by the invention to realize:
A kind of extracting method of Tea Saponin, comprising the following steps:
(1) fresh camellia oleifera fruit is picked, one layer of preservative film is coated on camellia oleifera fruit surface, camellia oleifera fruit is put into 70 DEG C of vapor
60-90min is handled in saturated vapour pressure, naturally dry after cooling removes preservative film, and the tea seed after drying is sent into hulling machine
In shell, then camellia seed kernel and shell are separated with winnowing machine, collect camellia seed kernel；
(2) camellia seed kernel is immersed in inorganic agent in 35-45 DEG C of immersion 3-4h, cleans 3-5 with deionized water after immersion
It is secondary, it is put into curer and is dried at 55-65 DEG C, the camellia seed kernel after drying is put into pot with being stirred by slow fire, in stir-frying process
The middle salt that camellia seed kernel quality 0.05% is added, stir-fry 3-5min, and after natural cooling, camellia seed kernel is crushed, crosses 10 meshes,
It is placed again into inorganic agent in 35-45 DEG C of immersion 120-150min, is cleaned 3-5 times after immersion with deionized water, be put into curer
In 55-65 DEG C dry, be sent into squeezer in carry out cold press obtain oil meal and thick tea-seed oil；
(3) oil meal obtained above is crushed, crosses 30 meshes, the ultrasound extraction 150- at 45-55 DEG C is added in leaching liquor
180min, ultrasonic frequency 20KHz, power 90W, centrifugal filtration after extraction are concentrated under reduced pressure recycling leaching liquor, tea soap are made
Element.
The inorganic agent is made of the raw material of following parts by weight: 12-16 parts of potassium sorbate, 8-10 parts of cornstarch, paddy ammonia
6-8 parts sour, 18-22 parts of loquat dew, 14-16 parts of sodium acetate, 22-26 parts of green tea, 3-5 parts of niacin, tert-butylhydroquinone 9-
12 parts, 15-20 parts of dehydroacetic acid, 300-350 parts of deionized water.
The inorganic agent the preparation method comprises the following steps:
(1) green tea is added to the water, is put into 3-5 DEG C of environment and handles 20-30min, after being warming up to room temperature, filtered, it is dry,
It is added in the ethyl alcohol of 12-15 times of green tea weight, in 82-85 DEG C of reflux 40-50min, recycling ethyl alcohol is concentrated under reduced pressure in centrifugal filtration,
Green-tea extract is made；
(2) green-tea extract and other raw materials are mixed, stirs 20- under 80-90 DEG C, 200-300r/min revolving speed
30min；
(3) above-mentioned mixed solution is put into reaction kettle, with ultraviolet light irradiation after 60-80 DEG C of processing 2-2.5h, cooling
Inorganic agent is made in 5-8min.
The leaching liquor the preparation method comprises the following steps: by ethyl alcohol, n-butanol mix, stirred under 60-80r/min revolving speed, and add
Enter the mono- 2- ethylhexyl of 2- ethylhexyl phosphoric acid to be uniformly mixed, continues to stir 10min, mixed liquor is heated to 50-55 after stirring
DEG C, 10min is stood, the microwave treatment 2min under 800W power is put into micro-wave oven, leaching liquor, ethyl alcohol, n-butanol and 2- is made
The volume ratio of the mono- 2- ethylhexyl of ethylhexyl phosphoric acid is 5:2:1.
Application of the extracting method of the Tea Saponin in daily necessities.
It is preferred, application of the Tea Saponin in facial cleanser, the facial cleanser by following parts by weight raw material group
At: 80-100 parts of Tea Saponin, 25-35 parts of methyl glycol fatty acid ester, 15-25 parts of Aloe Vera Gel, 30-40 parts of strawberry juice, honey 10-15
Part, 7-9 parts of pearl powder, 18-22 parts of deionized water.
The facial cleanser the preparation method comprises the following steps: honey and strawberry juice are uniformly mixed, stirred under 200-250r/min revolving speed
5min is mixed, Aloe Vera Gel stirring 10min is added, revolving speed is reduced to 120-150r/min, deionized water is added, stir 3min, then
Tea Saponin, methyl glycol fatty acid ester and pearl powder is added, stirs 30min, is made.
The present invention provides a kind of extracting method of Tea Saponin and its applications, it has the advantage that:
(1) fresh camellia oleifera fruit is covered with preservative film, is put into 70 DEG C of saturated vapour pressures and handles, camellia oleifera fruit can be accelerated
Curing keeps the nutriment in camellia oleifera fruit more abundant, while can reduce the fatty acid saturation degree of tea-seed oil in camellia oleifera fruit, will
Tea seed kernel is immersed in inorganic agent and handles, and can soften tea seed kernel, while the nutritional ingredient for retaining tea seed kernel is not destroyed, softening
Afterwards by stir-frying, tea seed oil component is precipitated in advance, is progressively disengaged inside tea seed kernel with other ingredients such as protein, Tea Saponins,
It crushes after stir-frying, impregnates again, be detached from other ingredients such as oil component and protein, Tea Saponin thoroughly, be conducive to postorder low temperature
The purity and yield of tea-seed oil are improved during cold pressing process, while concentrates on Tea Saponin in oil meal, are conducive to tea in oil meal
The direct extraction of saponin.
(2) inorganic agent selects special formulation, is not only safe from harm, but also can promote the precipitation of oil, makes to tea seed kernel
Oil and Tea Saponin separation avoid directly extracting Tea Saponin incorporation tea-seed oil impurity with tea seed kernel.
(3) leaching liquor can propose Tea Saponin from oil meal, and be easy to back after extraction to Tea Saponin structure without destruction
It receives.
(4) Tea Saponin is applied to prepare facial cleanser, the facial cleanser of preparation does not stimulate mildly, does not need addition chemical synthesis
Reagent is suitble to all skin quality to use, and while deoiling decontamination, protection skin preserves from, wherein Tea Saponin plays cleaning mesh
, it avoids conventional facial cleanser from playing cleaning purpose using surfactant, skin is had damage.
Specific embodiment:
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below
Specific embodiment is closed, the present invention is further explained.
Embodiment 1:
A kind of extracting method of Tea Saponin, comprising the following steps:
(1) fresh camellia oleifera fruit is picked, one layer of preservative film is coated on camellia oleifera fruit surface, camellia oleifera fruit is put into 70 DEG C of vapor
60min is handled in saturated vapour pressure, naturally dry after cooling removes preservative film, and the tea seed after drying is sent into hulling machine
It shells, then is separated camellia seed kernel and shell with winnowing machine, collect camellia seed kernel；
(2) camellia seed kernel is immersed in inorganic agent in 35 DEG C of immersion 3h, is cleaned 3 times, is put into deionized water after immersion
It is dried in curer at 55 DEG C, the camellia seed kernel after drying is put into pot with being stirred by slow fire, oil tea is added during stir-frying
The salt of seed benevolence quality 0.05%, stir-fry 3min, and after natural cooling, camellia seed kernel is crushed, 10 meshes is crossed, is placed again into processing
It in 35 DEG C of immersion 120min in agent, is cleaned 3 times after immersion with deionized water, is put into curer and is dried at 55 DEG C, be sent into squeezing
Cold press is carried out in machine obtains oil meal and thick tea-seed oil；
(3) oil meal obtained above is crushed, crosses 30 meshes, the ultrasound extraction 150min at 45 DEG C is added in leaching liquor,
Ultrasonic frequency is 20KHz, power 90W, centrifugal filtration after extraction, reduced pressure recycling leaching liquor, obtained Tea Saponin.
The inorganic agent is made of the raw material of following parts by weight: 12 parts of potassium sorbate, 8 parts of cornstarch, 6 parts of glutamic acid,
18 parts of loquat dew, 14 parts of sodium acetate, 22 parts of green tea, 3 parts of niacin, 9 parts of tert-butylhydroquinone, 15 parts of dehydroacetic acid, go from
300 parts of sub- water.
The inorganic agent the preparation method comprises the following steps:
(1) green tea is added to the water, is put into 3 DEG C of environment and handles 20min, after being warming up to room temperature, filtered, it is dry, it is added
In the ethyl alcohol that 12 times of green tea weight, in 82 DEG C of reflux 40min, recycling ethyl alcohol is concentrated under reduced pressure in centrifugal filtration, and green tea is made and extracts
Object；
(2) green-tea extract and other raw materials are mixed, stirs 20min under 80 DEG C, 200r/min revolving speed；
(3) above-mentioned mixed solution is put into reaction kettle, with ultraviolet light irradiation 5min, system after 60 DEG C of processing 2h, cooling
Obtain inorganic agent.
Embodiment 2:
A kind of extracting method of Tea Saponin, comprising the following steps:
(1) fresh camellia oleifera fruit is picked, one layer of preservative film is coated on camellia oleifera fruit surface, camellia oleifera fruit is put into 70 DEG C of vapor
90min is handled in saturated vapour pressure, naturally dry after cooling removes preservative film, and the tea seed after drying is sent into hulling machine
It shells, then is separated camellia seed kernel and shell with winnowing machine, collect camellia seed kernel；
(2) camellia seed kernel is immersed in inorganic agent in 45 DEG C of immersion 4h, is cleaned 5 times, is put into deionized water after immersion
It is dried in curer at 65 DEG C, the camellia seed kernel after drying is put into pot with being stirred by slow fire, oil tea is added during stir-frying
The salt of seed benevolence quality 0.05%, stir-fry 5min, and after natural cooling, camellia seed kernel is crushed, 10 meshes is crossed, is placed again into processing
It in 45 DEG C of immersion 150min in agent, is cleaned 5 times after immersion with deionized water, is put into curer and is dried at 65 DEG C, be sent into squeezing
Cold press is carried out in machine obtains oil meal and thick tea-seed oil；
(3) oil meal obtained above is crushed, crosses 30 meshes, the ultrasound extraction 180min at 55 DEG C is added in leaching liquor,
Ultrasonic frequency is 20KHz, power 90W, centrifugal filtration after extraction, reduced pressure recycling leaching liquor, obtained Tea Saponin.
The inorganic agent is made of the raw material of following parts by weight: 16 parts of potassium sorbate, 10 parts of cornstarch, 8 parts of glutamic acid,
22 parts of loquat dew, 16 parts of sodium acetate, 26 parts of green tea, 5 parts of niacin, 12 parts of tert-butylhydroquinone, 20 parts of dehydroacetic acid, go from
350 parts of sub- water.
The inorganic agent the preparation method comprises the following steps:
(1) green tea is added to the water, is put into 5 DEG C of environment and handles 30min, after being warming up to room temperature, filtered, it is dry, it is added
In the ethyl alcohol that 15 times of green tea weight, in 85 DEG C of reflux 50min, recycling ethyl alcohol is concentrated under reduced pressure in centrifugal filtration, and green tea is made and extracts
Object；
(2) green-tea extract and other raw materials are mixed, stirs 30min under 90 DEG C, 300r/min revolving speed；
(3) above-mentioned mixed solution is put into reaction kettle, in 80 DEG C of processing 2.5h, it is cooling after with ultraviolet light irradiation 8min,
Inorganic agent is made.
The leaching liquor the preparation method comprises the following steps: by ethyl alcohol, n-butanol mix, stirred under 80r/min revolving speed, and 2- is added
The mono- 2- ethylhexyl of ethylhexyl phosphoric acid is uniformly mixed, and continues to stir 10min, mixed liquor is heated to 55 DEG C after stirring, stand
10min is put into micro-wave oven the microwave treatment 2min under 800W power, and leaching liquor, ethyl alcohol, n-butanol and 2- ethylhexyl is made
The volume ratio of the mono- 2- ethylhexyl of phosphoric acid is 5:2:1.
Embodiment 3:
A kind of extracting method of Tea Saponin, comprising the following steps:
(1) fresh camellia oleifera fruit is picked, one layer of preservative film is coated on camellia oleifera fruit surface, camellia oleifera fruit is put into 70 DEG C of vapor
70min is handled in saturated vapour pressure, naturally dry after cooling removes preservative film, and the tea seed after drying is sent into hulling machine
It shells, then is separated camellia seed kernel and shell with winnowing machine, collect camellia seed kernel；
(2) camellia seed kernel is immersed in inorganic agent in 40 DEG C of immersion 3h, is cleaned 4 times, is put into deionized water after immersion
It is dried in curer at 60 DEG C, the camellia seed kernel after drying is put into pot with being stirred by slow fire, oil tea is added during stir-frying
The salt of seed benevolence quality 0.05%, stir-fry 4min, and after natural cooling, camellia seed kernel is crushed, 10 meshes is crossed, is placed again into processing
It in 40 DEG C of immersion 130min in agent, is cleaned 4 times after immersion with deionized water, is put into curer and is dried at 60 DEG C, be sent into squeezing
Cold press is carried out in machine obtains oil meal and thick tea-seed oil；
(3) oil meal obtained above is crushed, crosses 30 meshes, the ultrasound extraction 160min at 50 DEG C is added in leaching liquor,
Ultrasonic frequency is 20KHz, power 90W, centrifugal filtration after extraction, reduced pressure recycling leaching liquor, obtained Tea Saponin.
The inorganic agent is made of the raw material of following parts by weight: 14 parts of potassium sorbate, 9 parts of cornstarch, 7 parts of glutamic acid,
20 parts of loquat dew, 15 parts of sodium acetate, 23 parts of green tea, 4 parts of niacin, 10 parts of tert-butylhydroquinone, 18 parts of dehydroacetic acid, go from
320 parts of sub- water.
The inorganic agent the preparation method comprises the following steps:
(1) green tea is added to the water, is put into 4 DEG C of environment and handles 25min, after being warming up to room temperature, filtered, it is dry, it is added
In the ethyl alcohol that 13 times of green tea weight, in 83 DEG C of reflux 45min, recycling ethyl alcohol is concentrated under reduced pressure in centrifugal filtration, and green tea is made and extracts
Object；
(2) green-tea extract and other raw materials are mixed, stirs 25min under 85 DEG C, 250r/min revolving speed；
(3) above-mentioned mixed solution is put into reaction kettle, with ultraviolet light irradiation 6min, system after 70 DEG C of processing 2h, cooling
Obtain inorganic agent.
The leaching liquor the preparation method comprises the following steps: by ethyl alcohol, n-butanol mix, stirred under 60r/min revolving speed, and 2- is added
The mono- 2- ethylhexyl of ethylhexyl phosphoric acid is uniformly mixed, and continues to stir 10min, mixed liquor is heated to 50 DEG C after stirring, stand
10min is put into micro-wave oven the microwave treatment 2min under 800W power, and leaching liquor, ethyl alcohol, n-butanol and 2- ethylhexyl is made
The volume ratio of the mono- 2- ethylhexyl of phosphoric acid is 5:2:1.
Application of the extracting method of the Tea Saponin in facial cleanser, the facial cleanser by following parts by weight raw material group
At: 80 parts of Tea Saponin, 15 parts of Aloe Vera Gel, 30 parts of strawberry juice, 10 parts of honey, 7 parts of pearl powder, is gone 25 parts of methyl glycol fatty acid ester
18 parts of ionized water.
The facial cleanser the preparation method comprises the following steps: honey and strawberry juice are uniformly mixed, stirred under 200r/min revolving speed
5min adds Aloe Vera Gel stirring 10min, reduces revolving speed to 120r/min, deionized water is added, stirs 3min, adds tea
Saponin, methyl glycol fatty acid ester and pearl powder stir 30min, are made.
Embodiment 4:
A kind of extracting method of Tea Saponin, comprising the following steps:
(1) fresh camellia oleifera fruit is picked, one layer of preservative film is coated on camellia oleifera fruit surface, camellia oleifera fruit is put into 70 DEG C of vapor
80min is handled in saturated vapour pressure, naturally dry after cooling removes preservative film, and the tea seed after drying is sent into hulling machine
It shells, then is separated camellia seed kernel and shell with winnowing machine, collect camellia seed kernel；
(2) camellia seed kernel is immersed in inorganic agent in 38 DEG C of immersion 3h, is cleaned 5 times, is put into deionized water after immersion
It is dried in curer at 60 DEG C, the camellia seed kernel after drying is put into pot with being stirred by slow fire, oil tea is added during stir-frying
The salt of seed benevolence quality 0.05%, stir-fry 4min, and after natural cooling, camellia seed kernel is crushed, 10 meshes is crossed, is placed again into processing
It in 40 DEG C of immersion 140min in agent, is cleaned 4 times after immersion with deionized water, is put into curer and is dried at 60 DEG C, be sent into squeezing
Cold press is carried out in machine obtains oil meal and thick tea-seed oil；
(3) oil meal obtained above is crushed, crosses 30 meshes, the ultrasound extraction 170min at 45 DEG C is added in leaching liquor,
Ultrasonic frequency is 20KHz, power 90W, centrifugal filtration after extraction, reduced pressure recycling leaching liquor, obtained Tea Saponin.
The inorganic agent is made of the raw material of following parts by weight: 13 parts of potassium sorbate, 9 parts of cornstarch, 7 parts of glutamic acid,
18 parts of loquat dew, 16 parts of sodium acetate, 22 parts of green tea, 4 parts of niacin, 11 parts of tert-butylhydroquinone, 15 parts of dehydroacetic acid, go from
350 parts of sub- water.
The inorganic agent the preparation method comprises the following steps:
(1) green tea is added to the water, is put into 4 DEG C of environment and handles 25min, after being warming up to room temperature, filtered, it is dry, it is added
In the ethyl alcohol that 14 times of green tea weight, in 83 DEG C of reflux 45min, recycling ethyl alcohol is concentrated under reduced pressure in centrifugal filtration, and green tea is made and extracts
Object；
(2) green-tea extract and other raw materials are mixed, stirs 20min under 85 DEG C, 250r/min revolving speed；
(3) above-mentioned mixed solution is put into reaction kettle, with ultraviolet light irradiation 5min, system after 80 DEG C of processing 2h, cooling
Obtain inorganic agent.
The leaching liquor the preparation method comprises the following steps: by ethyl alcohol, n-butanol mix, stirred under 70r/min revolving speed, and 2- is added
The mono- 2- ethylhexyl of ethylhexyl phosphoric acid is uniformly mixed, and continues to stir 10min, mixed liquor is heated to 50 DEG C after stirring, stand
10min is put into micro-wave oven the microwave treatment 2min under 800W power, and leaching liquor, ethyl alcohol, n-butanol and 2- ethylhexyl is made
The volume ratio of the mono- 2- ethylhexyl of phosphoric acid is 5:2:1.
Application of the extracting method of the Tea Saponin in facial cleanser, the facial cleanser by following parts by weight raw material group
At: 100 parts of Tea Saponin, 25 parts of Aloe Vera Gel, 40 parts of strawberry juice, 15 parts of honey, 9 parts of pearl powder, is gone 35 parts of methyl glycol fatty acid ester
22 parts of ionized water.
The facial cleanser the preparation method comprises the following steps: honey and strawberry juice are uniformly mixed, stirred under 250r/min revolving speed
5min adds Aloe Vera Gel stirring 10min, reduces revolving speed to 150r/min, deionized water is added, stirs 3min, adds tea
Saponin, methyl glycol fatty acid ester and pearl powder stir 30min, are made.
Comparative example:
After taking a certain amount of choline chloride to mix with glycerol according to 1:2 molar ratio, in 80 DEG C, under the conditions of 500rpm/min
After agitating and heating 1h, homogeneous and transparent eutectic reagent is formed；By leached tea oil slag in 65 DEG C of vacuum ovens after drying, in
Medicine disintegrator smashes it through 60 meshes and is further ground into cell grade micropowders, take 5.0kg tea seed cell grade micropowders with
After -0.25 sodium sulfate salt solution double-aqueous phase system of 45% ethyl alcohol is by the mass volume ratio mixing of 1:10, in 400W ultrasonic power,
Centrifugation obtains supernatant after microwave-ultrasound 40min under the conditions of the microwave power of 200W and 35 DEG C, and residue uses ethyl alcohol-salt double again
Water phase merges supernatant after extracting 3 times, enters after 25% choline chloride-glycerol eutectic reagent into supernatant after vortex 20s
Centrifugation, system split-phase obtain preliminary purification after being 1.15-1.25g/mL to density after the contracting of decompression inspissation after taking out upper phase
Tea Saponin extract；The Tea Saponin extract of preliminary purification is transferred in supercritical CO 2 extraction device, in pressure 25MPa, is extracted
Temperature is 45 DEG C, and 35% -80% ethyl alcohol of water is entrainer, the flow of fluid be 26L/h under the conditions of to Tea Saponin extract into
After the purifying extraction of one step, the Tea Saponin of natural 94% purity of chemical product had both been obtained after the solvent in removing extract.
Purity detecting is carried out to Tea Saponin prepared by the above various embodiments and comparative example, as a result as follows:
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (7)
1. a kind of extracting method of Tea Saponin, which comprises the following steps:
(1) fresh camellia oleifera fruit is picked, one layer of preservative film is coated on camellia oleifera fruit surface, camellia oleifera fruit is put into 70 DEG C of steam-ladens
Handle 60-90min in vapour pressure, it is cooling after naturally dry, remove preservative film, the tea seed after drying be sent into hulling machine into
Row shelling, then separated camellia seed kernel and shell with winnowing machine, collect camellia seed kernel；
(2) camellia seed kernel is immersed in inorganic agent in 35-45 DEG C of immersion 3-4h, is cleaned 3-5 times, is put with deionized water after immersion
Enter in curer and dried at 55-65 DEG C, the camellia seed kernel after drying is put into pot with being stirred by slow fire, is added during stir-frying
The salt of camellia seed kernel quality 0.05%, stir-fry 3-5min, and after natural cooling, camellia seed kernel is crushed, 10 meshes is crossed, puts again
Enter in inorganic agent in 35-45 DEG C of immersion 120-150min, is cleaned 3-5 times, be put into curer in 55- with deionized water after immersion
65 DEG C of drying are sent into progress cold press in squeezer and obtain oil meal and thick tea-seed oil；
(3) oil meal obtained above is crushed, crosses 30 meshes, the ultrasound extraction 150- at 45-55 DEG C is added in leaching liquor
180min, ultrasonic frequency 20KHz, power 90W, centrifugal filtration after extraction are concentrated under reduced pressure recycling leaching liquor, tea soap are made
Element.
2. the extracting method of Tea Saponin according to claim 1, which is characterized in that the inorganic agent is by following parts by weight
Raw material composition: 12-16 parts of potassium sorbate, 8-10 parts of cornstarch, 6-8 parts of glutamic acid, 18-22 parts of loquat dew, sodium acetate 14-16
Part, 22-26 parts of green tea, 3-5 parts of niacin, 9-12 parts of tert-butylhydroquinone, 15-20 parts of dehydroacetic acid, deionized water 300-
350 parts.
3. the extracting method of Tea Saponin according to claim 2, which is characterized in that the inorganic agent the preparation method comprises the following steps:
(1) green tea is added to the water, is put into 3-5 DEG C of environment and handles 20-30min, after being warming up to room temperature, filtered, it is dry, it is added
In the ethyl alcohol of 12-15 times of green tea weight, in 82-85 DEG C of reflux 40-50min, centrifugal filtration is concentrated under reduced pressure recycling ethyl alcohol, is made
Green-tea extract；
(2) green-tea extract and other raw materials are mixed, stirs 20-30min under 80-90 DEG C, 200-300r/min revolving speed；
(3) above-mentioned mixed solution is put into reaction kettle, with ultraviolet light irradiation 5- after 60-80 DEG C of processing 2-2.5h, cooling
Inorganic agent is made in 8min.
4. the extracting method of Tea Saponin according to claim 1, which is characterized in that the leaching liquor the preparation method comprises the following steps:
Ethyl alcohol, n-butanol are mixed, stirred under 60-80r/min revolving speed, and it is mixed that the mono- 2- ethylhexyl of 2- ethylhexyl phosphoric acid is added
It closes uniformly, continues to stir 10min, mixed liquor is heated to 50-55 DEG C after stirring, stand 10min, be put into micro-wave oven in 800W
Leaching liquor, the volume of ethyl alcohol, n-butanol and the mono- 2- ethylhexyl of 2- ethylhexyl phosphoric acid is made in microwave treatment 2min under power
Than for 5:2:1.
5. application of the extracting method of Tea Saponin according to claim 1-4 in daily necessities.
6. application of the extracting method of Tea Saponin according to claim 5 in daily necessities, which is characterized in that the tea
Application of the saponin in facial cleanser, the facial cleanser are made of the raw material of following parts by weight: 80-100 parts of Tea Saponin, propylene glycol rouge
25-35 parts of fat acid esters, 15-25 parts of Aloe Vera Gel, 30-40 parts of strawberry juice, 10-15 parts of honey, 7-9 parts of pearl powder, deionized water 18-
22 parts.
7. application of the extracting method of Tea Saponin according to claim 6 in daily necessities, which is characterized in that described to wash one's face
Milk the preparation method comprises the following steps: honey and strawberry juice are uniformly mixed, stir 5min under 200-250r/min revolving speed, add aloe
Glue stirs 10min, reduces revolving speed to 120-150r/min, deionized water is added, stirs 3min, adds Tea Saponin, propylene glycol
Aliphatic ester and pearl powder stir 30min, are made.
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