CN108914637A - 一种全棉织物印花糊料 - Google Patents

一种全棉织物印花糊料 Download PDF

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CN108914637A
CN108914637A CN201810626702.9A CN201810626702A CN108914637A CN 108914637 A CN108914637 A CN 108914637A CN 201810626702 A CN201810626702 A CN 201810626702A CN 108914637 A CN108914637 A CN 108914637A
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carboxymethyl starch
cotton fabric
sodium hydroxide
sodium
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严洪华
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Qin Li Printing Industry (taicang) Co Ltd
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Qin Li Printing Industry (taicang) Co Ltd
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    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48—Derivatives of carbohydrates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
    • D06P1/5228—Polyalkenyl alcohols, e.g. PVA
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
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    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
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    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
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Abstract

本发明公开了一种全棉织物印花糊料，按质量配比如下：羧甲基淀粉75份，海藻酸钠13份，纳米二氧化硅8份，蛋白浆料4份；所述羧甲基淀粉是将玉米淀粉和马铃薯淀粉与氢氧化钠、氯乙酸充分混合后，使用螺杆挤压机挤压，在挤压机的后半程向物料喷洒甲醛，最后干燥制得，所述玉米淀粉、马铃薯淀粉、氢氧化钠、氯乙酸的质量比为46：48：19：8；所述羧甲基淀粉与硅粉混合后加入去离子水中，并添加氢氧化钠和甲醇，进行水解后干燥提纯获得羧甲基淀粉与纳米二氧化硅的混合物；所述蛋白浆料由大豆蛋白加入浓度为0.25%的氢氧化钠溶液中，48℃下匀速搅拌20分钟后滤去沉淀物后获得。具有性能好、生产成本低的有益效果。

Description

一种全棉织物印花糊料
技术领域
本发明属于纺织工程技术领域，尤其涉及一种全棉织物印花糊料。
背景技术
在活性染料印花中糊料一般用做增稠剂来调节色浆的流变性能。海藻酸钠因其不与活性染料反应、得色量高、色谱齐全、易从织物上洗去、织物手感柔软等优点，一直是活性染料印花糊料的首选。但它价格较贵，印花成本相对较高，因此寻找一种成本低廉能够印制精细花型的糊料已经成为当务之急。淀粉是一种可再生资源，它储备丰富，容易获取，但其分子上存在活泼羟基，易与染料反应，在活性染料印花糊料的应用上受到限制。
因此，亟需新的技术来改进现有技术的不足。
发明内容
发明目的：本发明的目的是：克服上述技术的缺点，提供了一种性能好、生产成本低的全棉织物印花糊料。
技术方案：一种全棉织物印花糊料，其特征在于，按质量配比如下：羧甲基淀粉75份，海藻酸钠13份，纳米二氧化硅8份，蛋白浆料4份；所述羧甲基淀粉是将玉米淀粉和马铃薯淀粉与氢氧化钠、氯乙酸充分混合后，使用螺杆挤压机挤压，在挤压机的后半程向物料喷洒甲醛，最后干燥制得，所述玉米淀粉、马铃薯淀粉、氢氧化钠、氯乙酸的质量比为46：48：19：8；所述羧甲基淀粉与硅粉混合后加入去离子水中，并添加氢氧化钠和甲醇，进行水解后干燥提纯获得羧甲基淀粉与纳米二氧化硅的混合物；所述蛋白浆料由大豆蛋白加入浓度为0.25%的氢氧化钠溶液中，48℃下匀速搅拌20分钟后滤去沉淀物后获得。
其中，还包括5质量份的苯甲酸钠。
其中，还包括6质量份的硫代硫酸钠。
其中，还包括 3质量份的聚乙烯醇。
本发明带来的有益效果是：本发明主要以羧甲基淀粉为主，海藻酸钠为辅，纳米二氧化硅作为助剂，糊料各方面性能都能满足活性印染需求，其海藻酸钠用量较低，具有性能好、生产成本低的有益效果。
具体实施方式
下面对本发明的技术方案做进一步说明。
一种全棉织物印花糊料，其特征在于，按质量配比如下：羧甲基淀粉75份，海藻酸钠13份，纳米二氧化硅8份，蛋白浆料4份；所述羧甲基淀粉是将玉米淀粉和马铃薯淀粉与氢氧化钠、氯乙酸充分混合后，使用螺杆挤压机挤压，在挤压机的后半程向物料喷洒甲醛，最后干燥制得，所述玉米淀粉、马铃薯淀粉、氢氧化钠、氯乙酸的质量比为46：48：19：8；所述羧甲基淀粉与硅粉混合后加入去离子水中，并添加氢氧化钠和甲醇，进行水解后干燥提纯获得羧甲基淀粉与纳米二氧化硅的混合物；所述蛋白浆料由大豆蛋白加入浓度为0.25%的氢氧化钠溶液中，48℃下匀速搅拌20分钟后滤去沉淀物后获得。
其中，还包括5质量份的苯甲酸钠。
其中，还包括6质量份的硫代硫酸钠。
其中，还包括 3质量份的聚乙烯醇。
本发明不局限于上述实施例所述的具体技术方案，除上述实施例外，本发明还可以有其他实施方式。对于本领域的技术人员来说，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等形成的技术方案，均应包含在本发明的保护范围之内。

Claims (4)

1.一种全棉织物印花糊料，其特征在于，按质量配比如下：羧甲基淀粉75份，海藻酸钠13份，纳米二氧化硅8份，蛋白浆料4份；所述羧甲基淀粉是将玉米淀粉和马铃薯淀粉与氢氧化钠、氯乙酸充分混合后，使用螺杆挤压机挤压，在挤压机的后半程向物料喷洒甲醛，最后干燥制得，所述玉米淀粉、马铃薯淀粉、氢氧化钠、氯乙酸的质量比为46：48：19：8；所述羧甲基淀粉与硅粉混合后加入去离子水中，并添加氢氧化钠和甲醇，进行水解后干燥提纯获得羧甲基淀粉与纳米二氧化硅的混合物；所述蛋白浆料由大豆蛋白加入浓度为0.25%的氢氧化钠溶液中，48℃下匀速搅拌20分钟后滤去沉淀物后获得。
2.根据权利要求1所述的一种全棉织物印花糊料，其特征在于，还包括5质量份的苯甲酸钠。
3.根据权利要求1所述的一种全棉织物印花糊料，其特征在于，还包括6质量份的硫代硫酸钠。
4.根据权利要求1所述的一种全棉织物印花糊料，其特征在于，还包括 3质量份的聚乙烯醇。
CN201810626702.9A 2018-06-19 2018-06-19 一种全棉织物印花糊料 Pending CN108914637A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115961486A (zh) * 2022-12-12 2023-04-14 福建省新宏港纺织科技有限公司 一种活性印花色浆制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103911887A (zh) * 2014-04-17 2014-07-09 苏州润弘贸易有限公司 一种适用于全棉织物的活性印花糊料
CN103911882A (zh) * 2014-04-17 2014-07-09 苏州润弘贸易有限公司 一种全棉织物活性印花糊料制备方法
CN103911883A (zh) * 2014-04-17 2014-07-09 苏州润弘贸易有限公司 一种活性印花糊料

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103911887A (zh) * 2014-04-17 2014-07-09 苏州润弘贸易有限公司 一种适用于全棉织物的活性印花糊料
CN103911882A (zh) * 2014-04-17 2014-07-09 苏州润弘贸易有限公司 一种全棉织物活性印花糊料制备方法
CN103911883A (zh) * 2014-04-17 2014-07-09 苏州润弘贸易有限公司 一种活性印花糊料

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115961486A (zh) * 2022-12-12 2023-04-14 福建省新宏港纺织科技有限公司 一种活性印花色浆制备方法

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