CN108914548A - A kind of cloth and the preparation method and application thereof with superpower adsorptivity - Google Patents
A kind of cloth and the preparation method and application thereof with superpower adsorptivity Download PDFInfo
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- CN108914548A CN108914548A CN201810620504.1A CN201810620504A CN108914548A CN 108914548 A CN108914548 A CN 108914548A CN 201810620504 A CN201810620504 A CN 201810620504A CN 108914548 A CN108914548 A CN 108914548A
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- fibre
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- 239000004744 fabric Substances 0.000 title claims abstract description 91
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 239000000835 fiber Substances 0.000 claims abstract description 108
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 90
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000007788 liquid Substances 0.000 claims abstract description 54
- 238000006243 chemical reaction Methods 0.000 claims abstract description 51
- 239000006185 dispersion Substances 0.000 claims abstract description 51
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229920003043 Cellulose fiber Polymers 0.000 claims abstract description 21
- 238000005530 etching Methods 0.000 claims abstract description 17
- 229920000297 Rayon Polymers 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 5
- 229920000742 Cotton Polymers 0.000 claims description 4
- 229920000433 Lyocell Polymers 0.000 claims description 4
- 235000010469 Glycine max Nutrition 0.000 claims description 3
- 244000068988 Glycine max Species 0.000 claims description 3
- 229920002494 Zein Polymers 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 239000005019 zein Substances 0.000 claims description 3
- 229940093612 zein Drugs 0.000 claims description 3
- 230000003628 erosive effect Effects 0.000 claims 1
- 102000004169 proteins and genes Human genes 0.000 claims 1
- 108090000623 proteins and genes Proteins 0.000 claims 1
- 238000012360 testing method Methods 0.000 abstract description 12
- 235000015203 fruit juice Nutrition 0.000 abstract description 5
- 239000000243 solution Substances 0.000 description 61
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 26
- 238000003756 stirring Methods 0.000 description 21
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 18
- 238000000034 method Methods 0.000 description 17
- 239000000975 dye Substances 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 238000010792 warming Methods 0.000 description 9
- 238000002347 injection Methods 0.000 description 8
- 239000007924 injection Substances 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- 235000006408 oxalic acid Nutrition 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- -1 hydroxypropyl Chemical group 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- RFKJHQXSLBUONF-UHFFFAOYSA-N methyl blue free acid Chemical compound C1=CC(S(=O)(=O)O)=CC=C1NC1=CC=C(C(=C2C=CC(C=C2)=NC=2C=CC(=CC=2)S(O)(=O)=O)C=2C=CC(NC=3C=CC(=CC=3)S(O)(=O)=O)=CC=2)C=C1 RFKJHQXSLBUONF-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/328—Amines the amino group being bound to an acyclic or cycloaliphatic carbon atom
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention provides a kind of preparation methods of cloth with superpower adsorptivity, and cellulose fibre is soaked in sodium hydroxide solution first, carry out alkaline etching, obtain alkaline fiber dispersion liquid；Then the alkaline fiber dispersion liquid is mixed with poly-epoxychloropropane dimethylamine solution, is modified reaction, obtains modified fibre；The modified fibre is weaved, the cloth with superpower adsorptivity is obtained.Cloth provided by the present invention with superpower adsorptivity and general fibre cloth are dipped in ink solution, dye solution and fruit juice respectively and test adsorptivity, after taking-up, solution becomes to clarify, and the color of the cloth with superpower adsorptivity is obviously deeper than general fibre cloth.
Description
Technical field
The present invention relates to functional cloth technical field more particularly to a kind of cloth and preparation method thereof with superpower adsorptivity
With application.
Background technique
Currently, it is original that the functional cloth sold on the market such as face cleaning towel, makeup removing towel, wiper etc., which are usually directly with fiber,
Material, by weaving the cloth for obtaining different structure to be suitable for different fields.In application process, exist adsorptivity it is weak lack
Point not can effectively clear the substances to be removed such as dyestuff, cosmetics, the ink spot that face is smeared.
Summary of the invention
The purpose of the present invention is to provide a kind of cloth and the preparation method and application thereof with superpower adsorptivity, institute of the present invention
The cloth with superpower adsorptivity provided has excellent removal effect to cosmetics, ink, dyestuff, fruit juice etc..
In order to achieve the above-mentioned object of the invention, the present invention provides following technical scheme：
The present invention provides a kind of preparation methods of cloth with superpower adsorptivity, include the following steps：
(1) cellulose fibre is immersed in sodium hydroxide solution, carries out alkaline etching, obtains alkaline fiber dispersion liquid；
(2) the alkaline fiber dispersion liquid is mixed with poly-epoxychloropropane dimethylamine solution, is modified reaction, obtains
To modified fibre；
(3) modified fibre is weaved, obtains the cloth with superpower adsorptivity.
Preferably, the cellulose fibre is viscose rayon, azelon, soybean fiber, zein fiber, denier that is not fine
Dimension, tencel fiber or cotton fiber.
Preferably, the pH value of the sodium hydroxide solution is 8.5~10.5.
Preferably, the mass ratio of the cellulose fibre and sodium hydroxide solution is 30~35:100.
Preferably, the temperature of the alkaline etching is 55~70 DEG C, and the time of the alkaline etching is 5~10min.
Preferably, the concentration of the poly-epoxychloropropane dimethylamine solution is 10~20wt.%.
Preferably, the mass ratio of the poly-epoxychloropropane dimethylamine solution and cellulose fibre is 20~35:100.
Preferably, the modified-reaction includes first stage reaction and second stage reaction；The first stage reaction
Temperature is 65~75 DEG C, and the time of the first stage reaction is 10~15min；First stage after the reaction was completed, by described
The pH value of dispersion liquid obtained by one elementary reaction is adjusted to 9.5~11, carries out second stage reaction；The temperature of the second stage reaction
Degree is 65~75 DEG C, and the time of the second stage reaction is 15~20min.
The present invention also provides what preparation method described in a kind of any above-mentioned technical proposal obtained to have superpower adsorptivity
Cloth.
The present invention also provides the cloth with superpower adsorptivity described in above-mentioned technical proposal as face cleaning towel, makeup removing towel or
The application of wiper.
The present invention provides a kind of preparation methods of cloth with superpower adsorptivity, and cellulose fibre is immersed in hydrogen first
In sodium hydroxide solution, alkaline etching is carried out, alkaline dispersion is obtained；Then by the alkaline fiber dispersion liquid and Hydrin
Dimethylamine solution mixing, is modified reaction, obtains modified fibre；The modified fibre is weaved, obtains having superpower
The cloth of adsorptivity.The present invention first carries out alkaline etching to fiber, keeps fiber surface roughening, in favor of subsequent modified-reaction；With poly-
Epoxychloropropane dimethylamine is modifying agent, under alkaline condition, poly-epoxychloropropane dimethylamine ionization be quaternary ammonium salt sun from
Son and hydroxypropyl, the hydroxyl on hydroxypropyl are reacted with the hydroxyl on cellulose fibre, to keep cellulose fibre positively charged, are obtained
To modified fibre, so that modified fibre has stronger affinity and adsorptivity to external substance；It is made using the modified fibre
At cloth also there is superpower adsorptivity.The experimental results showed that by the cloth provided by the present invention with superpower adsorptivity and common fibre
Wei Bu is dipped in ink solution, dye solution and fruit juice respectively and tests adsorptivity, and after taking-up, solution becomes to clarify, and has super
The color of the cloth of strong adsorptivity is obviously deeper than general fibre cloth.
Detailed description of the invention
The prepared ink solution of Fig. 1 application examples 1；
The cloth with superpower adsorptivity and general fibre cloth of Fig. 2 application examples 1 are to ink solution adsorptivity test result figure；
Fig. 3 application examples 1 is using 4 pieces of cloth with superpower adsorptivity successively to the result of ink solution absorption；
The prepared dye solution of Fig. 4 application examples 2；
The cloth with superpower adsorptivity and general fibre cloth of Fig. 5 application examples 2 are to dye solution adsorptivity test result figure；
The cloth with superpower adsorptivity and general fibre cloth of Fig. 6 application examples 3 are to Finda fruit juice adsorptivity test result figure；
Lipstick print before being wiped in Fig. 7 application examples 4；
Removal test result figure of the cloth with superpower adsorptivity and general fibre cloth of Fig. 8 application examples 4 to lipstick.
Specific embodiment
The present invention provides a kind of preparation methods of cloth with superpower adsorptivity, include the following steps：
(1) cellulose fibre is immersed in sodium hydroxide solution, carries out alkaline etching, obtains alkaline fiber dispersion liquid；
(2) the alkaline fiber dispersion liquid is mixed with poly-epoxychloropropane dimethylamine solution, is modified reaction, obtains
To modified fibre；
(3) modified fibre is weaved, obtains the cloth with superpower adsorptivity.
The present invention mixes cellulose fibre with sodium hydroxide solution, carries out alkaline etching, obtains alkaline fiber dispersion liquid.
In the present invention, the cellulose fibre is preferably viscose rayon, azelon, soybean fiber, zein fiber, not
Denier that fiber, tencel fiber or cotton fiber.
The present invention is not particularly limited the diameter, specific gravity and length of the cellulose fibre, and those skilled in the art can
Selection as needed.
In the present invention, the pH value of the sodium hydroxide solution is preferably 8.5~10.5.
In the present invention, the mass ratio of the cellulose fibre and sodium hydroxide solution is preferably 30~35:100.
The present invention is not particularly limited the preparation method of the sodium hydroxide solution, can obtain the hydrogen-oxygen of required concentration
Change sodium solution.
The present invention is not particularly limited the order by merging of the cellulose fiber peacekeeping sodium hydroxide solution, of the invention real
It applies in example, temperature needed for sodium hydroxide solution is first preferably warming up to alkaline etching, then that cellulose fibre is dipped in sodium hydroxide is molten
In liquid.
In the present invention, the temperature of the alkaline etching is preferably 55~70 DEG C, and more preferably 58~62 DEG C；The alkaline etching when
Between preferably 5~10min, more preferably 7~9min；The time of the alkaline etching is preferably from meter when being warming up to alkaline etching required temperature
It rises.In the present invention, it can be coarse shape by the surface corrosion of cellulose fibre by alkaline etching, while play cleaning cellulose surface
Effect, in favor of subsequent modified-reaction.
In the present invention, the alkaline etching process preferably maintains stirring；The revolving speed of the stirring is preferably 50~60r/
min。
After obtaining alkaline fiber dispersion liquid, the present invention is by the alkaline fiber dispersion liquid and poly-epoxychloropropane dimethylamine
Solution mixing, is modified reaction, obtains modified fibre；
In the present invention, the concentration of the poly-epoxychloropropane dimethylamine solution is preferably 10~20wt.%, more preferably
For 15~18wt.%.
The present invention is not particularly limited the preparation method of the poly-epoxychloropropane dimethylamine solution, can obtain institute
Need the uniform solution of concentration.In embodiments of the present invention, preferably poly-epoxychloropropane dimethylamine is first soaked in water,
After dissolution, it is uniformly mixing to obtain the poly-epoxychloropropane dimethylamine solution of required concentration.
In the present invention, the mass ratio of the poly-epoxychloropropane dimethylamine solution and cellulose fibre be preferably 20~
35:100, more preferably 25~34:100.
The present invention is to the order by merging of the alkaline fiber dispersion liquid and poly-epoxychloropropane dimethylamine solution without spy
It is different to limit；In embodiments of the present invention, for ease of operation, preferably poly-epoxychloropropane dimethylamine solution is added to described
In alkaline fiber dispersion liquid.
In the present invention, the modified-reaction preferably includes first stage reaction and second stage reaction；First rank
The temperature of Duan Fanying is preferably 65~75 DEG C, and the time of the first stage reaction is preferably 10~15min；The first stage
The time of reaction is preferably from meter when being warming up to first stage reaction required temperature；First stage after the reaction was completed, preferably by institute
The pH value for stating first stage reaction gained dispersion liquid is adjusted to 9.5~11, carries out second stage reaction；The second stage reaction
Temperature be preferably 65~75 DEG C, the time of second stage reaction is preferably 15~20min；The second stage reaction
Time when the pH value of dispersion liquid is adjusted to 9.5~11 preferably from counting.In the present invention, solution when first stage reaction is completed
PH value is about 8~9, and the pH value that the first stage reacts gained dispersion liquid is adjusted to 9.5~11, under the stronger environment of alkalinity into
The reaction of row second stage, can make modified-reaction more abundant.
In the present invention, solution used in the adjusting pH value is preferably sodium hydroxide solution.The present invention is to the adjusting
The concentration of pH value sodium hydroxide solution is not particularly limited, and the pH value of dispersion liquid can be adjusted to required range.
In the present invention, the modified-reaction process is preferably carried out in stirring, and the revolving speed of the stirring is preferably 50
~60r/min.
After completing modified-reaction, the present invention preferably post-processes dispersion liquid obtained by modified-reaction, obtains modified fibre.
In the present invention, the post-processing preferably includes following steps：
Dispersion liquid obtained by modified-reaction is subjected to the first overflow rinsing；
The pH value of first overflow rinsing products therefrom is adjusted to 6.7~6.9, then carries out the second overflow rinsing；
Second overflow rinsing products therefrom is separated by solid-liquid separation, by obtained solid product through drying, obtains modified fibre.
In the present invention, it is preferably water that first overflow, which rinses washing lotion used,；The first overflow rinsing is floated when completing
The pH value for washing gained overflow water is preferably 7.5~8.5, and more preferably 7.5；In embodiments of the present invention, the first overflow drift
The waterflood injection rate washed is preferably 45~55kg/min, more preferably 50kg/min；The time of the first overflow rinsing is preferably 5
~8min.In the present invention, fiber can tentatively be cleaned using the first overflow rinsing.
In the present invention, adjusting regulator used in the pH value of the first overflow rinsing gained dispersion liquid is preferably aqueous acetic acid
Or oxalic acid aqueous solution；The present invention is not particularly limited the concentration of the aqueous acetic acid and oxalic acid aqueous solution, can be by first
The pH value of overflow rinsing gained dispersion liquid is adjusted to required range；In embodiments of the present invention, the aqueous acetic acid or
The concentration of oxalic acid aqueous solution is preferably 0.01~0.03g/mL.In the present invention, using the aqueous solution of above two weak acid to
The pH value of one overflow rinsing gained dispersion liquid is adjusted, in and while dispersion liquid, can to avoid in N-process to fibre
Dimension causes to corrode.
In the present invention, it is preferably water that second overflow, which rinses washing lotion used,；The second overflow rinsing is floated when completing
The pH value for washing gained overflow water is preferably 7.0~7.3, and more preferably 7.1；In embodiments of the present invention, the second overflow drift
The waterflood injection rate washed is preferably 45~55kg/min, more preferably 50kg/min；The time of the second overflow rinsing is preferably 5
~15min.In the present invention, fiber can further be cleaned using the second overflow rinsing.
The present invention is not particularly limited the mode of the separation of solid and liquid, and the solid-liquid separation method using this field routine is
It can.
The present invention is not particularly limited the mode of the drying, using the drying mode of this field routine；At this
In inventive embodiments, the drying preferably successively carries out centrifugation and forced air drying.
After obtaining modified fibre, the present invention weaves the modified fibre, obtains the cloth with superpower adsorptivity.
The present invention is not particularly limited the woven specific method, using conventional weaving process.In this hair
In bright embodiment, it is preferred to use modified fibre is fabricated to cloth by spun lacing method.
Preferably cloth is made by mixing into modified fibre and non-modified fiber by the present invention.
In the present invention, the non-modified fiber is preferably ES fiber, 8020 fiber of South Korea's Huvis or South Korea's Huvis
8040 fibers.In the present invention, the addition of ES fiber can increase the fastness and planarization of cloth cover, and the comfort of gained cloth
More preferably, it is more suitable for the purposes of skin, face wiping；8020 fiber of South Korea's Huvis or 8040 fiber of South Korea's Huvis add
Add, the use temperature of cloth can be improved, is more suitable for the purposes such as industrial electronic, electric appliance wiping and rag.
In the present invention, the mass ratio of the modified fibre and non-modified fiber is preferably 4~9:1, more preferably 6~8:
1。
The present invention also provides what preparation method described in a kind of any above-mentioned technical proposal obtained to have superpower adsorptivity
Cloth.
The present invention also provides the cloth with superpower adsorptivity described in above-mentioned technical proposal as face cleaning towel, makeup removing towel or
The application of wiper.
Cloth provided by the invention with superpower adsorptivity and the preparation method and application thereof is carried out below with reference to embodiment
Detailed description, but they cannot be interpreted as limiting the scope of the present invention.
Embodiment 1
(1) 100kg water is added and is warming up to 65 DEG C, sodium hydroxide solution is added and stirs evenly, it is 8.5 that adjustment, which obtains pH value,
Sodium hydroxide solution；
(2) viscose rayon of 30kg is dipped in sodium hydroxide solution obtained by 100kg step (1)；At 65 DEG C, with 50r/
The revolving speed of min stirs 5min, obtains alkaline fiber dispersion liquid；
(3) 1kg poly-epoxychloropropane dimethylamine is soaked in 5kg water, until completely dissolved, is stirred for uniformly preparing
At the poly-epoxychloropropane dimethylamine solution of 6kg；
(4) stirring for maintaining alkaline fiber dispersion liquid, 6kg poly-epoxychloropropane dimethylamine solution is added to alkali
Property fiber dispersion in, be warming up to 75 DEG C, continue to stir 10min (i.e. progress first stage reaction)；Then molten with sodium hydroxide
The pH value that first stage reacts gained dispersion liquid is adjusted to 9.5 by liquid, maintains 75 DEG C, is continued to be stirred to react 15min and (is carried out the
Two-stage reaction)；
(5) step (4) second stage is reacted into gained dispersion liquid and the first overflow drift is carried out with the waterflood injection rate of 50kg/min
5min is washed, the pH value of test gained overflow water is 8.0；Then the first overflow is floated with the oxalic acid aqueous solution that concentration is 0.03g/mL
The pH value for washing gained dispersion liquid is adjusted to 6.7；Then the dispersion liquid after adjusting pH value is carried out with the waterflood injection rate of 50kg/min
Second overflow rinses 15min, and the pH value of test gained overflow water is 7.1；
(6) the second overflow is rinsed the fiber in gained dispersion liquid to pull out, is then successively dried and dried, obtains viscose glue
Modified fibre；
It (7) is 100 according to mass ratio by Adhesive modifiers fiber obtained by step (6) and ES fiber:15 ratio mixing, then
Cloth is prepared into using water jet process, the process of the water jet process is specially：Fiber basis weight-shredding-mixing-preparing-intersection paving
Net-combing-lapping-drawing-off-spun lacing-drying, obtains the cloth with superpower adsorptivity.
Embodiment 2
(1) 100kg water is added and is warming up to 70 DEG C, sodium hydroxide solution is added and stirs evenly, adjustment obtains the hydrogen that pH value is 9
Sodium hydroxide solution；
(2) 30kg tencel fiber is dipped in sodium hydroxide solution obtained by 99kg step (1)；At 70 DEG C, with 50r/min's
Revolving speed stirs 7min, obtains alkaline fiber dispersion liquid；
(3) 1.5kg poly-epoxychloropropane dimethylamine is soaked in 7kg water, until completely dissolved, stirs evenly preparation
At the poly-epoxychloropropane dimethylamine solution of 8.5kg；
(4) alkali is added in 8.5kg poly-epoxychloropropane dimethylamine solution by the stirring for maintaining alkaline fiber dispersion liquid
Property fiber dispersion in, be warming up to 65 DEG C, continue to stir 15min (i.e. progress first stage reaction)；Then molten with sodium hydroxide
The pH value that first stage reacts gained dispersion liquid is adjusted to 10.5 by liquid, maintains 65 DEG C, continues to be stirred to react 15min (carrying out
Second stage reaction)；
(5) step (4) second stage is reacted into gained dispersion liquid and the first overflow drift is carried out with the waterflood injection rate of 50kg/min
8min is washed, the pH value of test gained overflow water is 8.0；Then the first overflow is floated with the oxalic acid aqueous solution that concentration is 0.03g/mL
The pH value for washing gained dispersion liquid is adjusted to 6.9；Second is carried out to the dispersion liquid after adjusting pH value with the waterflood injection rate of 50kg/min
Overflow rinses 15min, and the pH value of test gained overflow water is 7.2；
(6) the second overflow is rinsed the fiber in gained dispersion liquid to pull out, is then successively dried and dried, is modified
Fiber；
It (7) is 100 according to mass ratio by modified fibre obtained by step (6) and South Korea's dimension 8020 fiber of bodyguard:20 ratio is mixed
It closes, cloth is then prepared into using water jet process, the process of the water jet process is specially：Fiber basis weight-shredding-mixing-preparing-
Cross lapping-combing-lapping-drawing-off-spun lacing-drying, obtains the cloth with superpower adsorptivity.
Embodiment 3
(1) 100kg water is added and is warming up to 55 DEG C, sodium hydroxide solution is added and stirs evenly, it is 10.5 that adjustment, which obtains pH value,
Sodium hydroxide solution；
(2) 30kg cotton fiber is dipped in sodium hydroxide solution obtained by 97kg step (1)；At 55 DEG C, with turning for 55r/min
Speed stirring 10min, obtains alkaline fiber dispersion liquid；
(3) 2kg poly-epoxychloropropane dimethylamine is soaked in 8kg water, after to be dissolved, stir evenly and be configured to 10kg
Poly-epoxychloropropane dimethylamine solution；
(4) maintain alkaline fiber dispersion liquid stirring, by 10kg poly-epoxychloropropane dimethylamine solution be added to
In alkaline fiber dispersion liquid, 65 DEG C are warming up to, continues to stir 15min (i.e. progress first stage reaction)；Then sodium hydroxide is used
The pH value that first stage reacts gained dispersion liquid is adjusted to 11 by solution, maintains 65 DEG C, continues to be stirred to react 15min (carrying out
Second stage reaction)；
(5) step (4) second stage is reacted into gained dispersion liquid and the first overflow drift is carried out with the waterflood injection rate of 50kg/min
5min is washed, the pH value of test gained overflow water is 8.0；Then the first overflow is floated with the oxalic acid aqueous solution that concentration is 0.03g/mL
The pH value for washing gained dispersion liquid is adjusted to 6.8；Then the dispersion liquid after adjusting pH value is carried out with the waterflood injection rate of 50kg/min
Second overflow rinses 10min, and the pH value of test gained overflow water is 7.2；
(6) the second overflow is rinsed the fiber in gained dispersion liquid to pull out, is then successively dried and dried, is modified
Fiber；
It (7) is 100 according to mass ratio by modified fibre obtained by step (6) and South Korea's dimension 8040 fiber of bodyguard:18 ratio is mixed
It closes, cloth is then prepared into using water jet process, the process of the water jet process is specially：Fiber basis weight-shredding-mixing-preparing-
Cross lapping-combing-lapping-drawing-off-spun lacing-drying, obtains the cloth with superpower adsorptivity.
Application examples 1
1mL hero's black ink is mixed with 250mL clear water, obtains ink solution (as shown in Figure 1)；
By obtained by embodiment 1 with superpower adsorptivity cloth (rectangular) and general fibre cloth (fiber cloth not processed,
It is round) it is dipped in the ink solution simultaneously, after stirring 30s, while two kinds of cloth being taken out, is laid in desktop, observes two kinds of cloth
Color, as shown in Figure 2.
As shown in Figure 2, the color of the cloth of the 1 superpower adsorptivity of gained of embodiment is obviously deeper than general fibre cloth, illustrates to implement
Cloth with superpower adsorptivity obtained by example 1 has stronger adsorptivity to the dyestuff in ink.
Cloth obtained by 4 pieces of embodiments 1 with superpower adsorptivity is successively dipped in ink solution, 30s is impregnated, is put down after taking-up
It is laid on desktop, as a result as shown in Figure 3.From the figure 3, it may be seen that the color of 4 pieces of cloth successively reduces, and the color of ink solution is also significantly
Decline, solution become opposite and clarify.
Identical experiment is carried out to the cloth of 2~3 superpower adsorptivity of gained of embodiment, acquired results are similar.
Application examples 2
0.25g ink blue active dye is mixed with 250ml clear water, obtains dye solution (as shown in Figure 4)；
By obtained by embodiment 1 with superpower adsorptivity cloth (rectangular) and general fibre cloth (fiber cloth not processed,
It is round) it is dipped in the dye solution simultaneously, after stirring 30s, while two kinds of cloth being taken out, is laid in desktop, observes two kinds of cloth
Color, as shown in Figure 5.
As seen from contrast in Figure 5, the color of the cloth of the 1 superpower adsorptivity of gained of embodiment is obviously deeper than general fibre cloth, and contaminates
The color of material solution becomes to clarify, and illustrates that the cloth with superpower adsorptivity obtained by embodiment 1 has stronger adsorptivity to dyestuff.
Identical experiment is carried out to the cloth of 2~3 superpower adsorptivity of gained of embodiment, acquired results are similar.
Application examples 3
By obtained by embodiment 1 with superpower adsorptivity cloth (rectangular) and general fibre cloth (fiber cloth not dealt with,
It is round) it is dipped in from the Finda beverage (being held with white dixie cup) that market is bought simultaneously, after stirring 30s, while two kinds of cloth being taken
Out, it is laid in desktop, observes the color of two kinds of cloth, as shown in Figure 6.
The cloth of the 1 superpower adsorptivity of gained of embodiment shows the orange of Finda, it will be appreciated from fig. 6 that having obtained by embodiment 1 super
The color of the cloth of strong adsorptivity is obviously deeper than general fibre cloth, and the color of Finda becomes to clarify, and illustrates have obtained by embodiment 1
The cloth of superpower adsorptivity has stronger adsorptivity to Finda fruit juice.
Identical experiment is carried out to the cloth of 2~3 superpower adsorptivity of gained of embodiment, acquired results are similar.
Application examples 4
It draws twice lipstick using identical dynamics on arm using YSL lipstick to print, as shown in fig. 7, by 1 gained of embodiment
Cloth (rectangular) and general fibre cloth (fiber cloth not dealt with, round) with superpower adsorptivity are soaked with clear water respectively,
The lipstick print of left and right side in Fig. 7 is wiped respectively using identical dynamics, the result after wiping is as shown in Figure 8.
As shown in Figure 8, the place wiped using the cloth obtained by embodiment 1 with superpower adsorptivity, lipstick print are gone substantially
It removes, and the lipstick print of general fibre cloth wiping is used also to remain apparent trace, illustrate provided by the present invention with superpower
The cloth of adsorptivity has extremely strong removal ability to cosmetics.
Identical experiment is carried out to the cloth of 2~3 superpower adsorptivity of gained of embodiment, acquired results are similar.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (10)
1. a kind of preparation method of the cloth with superpower adsorptivity, includes the following steps：
(1) cellulose fibre is immersed in sodium hydroxide solution, carries out alkaline etching, obtains alkaline fiber dispersion liquid；
(2) the alkaline fiber dispersion liquid is mixed with poly-epoxychloropropane dimethylamine solution, is modified reaction, is changed
Property fiber；
(3) modified fibre is weaved, obtains the cloth with superpower adsorptivity.
2. preparation method according to claim 1, which is characterized in that the cellulose fibre is viscose rayon, protein fiber
Dimension, soybean fiber, zein fiber, not denier that fiber, tencel fiber or cotton fiber.
3. preparation method according to claim 1, which is characterized in that the pH value of the sodium hydroxide solution be 8.5~
10.5。
4. preparation method according to claim 3, which is characterized in that the matter of the cellulose fibre and sodium hydroxide solution
Amount is than being 30~35:100.
5. preparation method according to claim 1, which is characterized in that the temperature of the alkaline etching is 55~70 DEG C, the alkali
The time of erosion is 5~10min.
6. preparation method according to claim 1, which is characterized in that the poly-epoxychloropropane dimethylamine solution it is dense
Degree is 10~20wt.%.
7. preparation method according to claim 6, which is characterized in that the poly-epoxychloropropane dimethylamine solution and fibre
The mass ratio of cellulose fiber is 20~35:100.
8. preparation method according to claim 1, which is characterized in that the modified-reaction includes first stage reaction and the
Two-stage reaction；The temperature of first stage reaction is 65~75 DEG C, the time of the first stage reaction is 10~
15min；First stage is adjusted to 9.5~11 after the reaction was completed, by the pH value that the first stage reacts gained dispersion liquid, carries out
Second stage reaction；The temperature of second stage reaction is 65~75 DEG C, the time of the second stage reaction is 15~
20min。
9. the cloth with superpower adsorptivity that a kind of preparation method according to any one of claims 1 to 8 obtains.
10. application of the cloth as claimed in claim 9 with superpower adsorptivity as face cleaning towel, makeup removing towel or wiper.
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