CN108899394A - A kind of technique for enhancing single polycrystalline silicon battery plate surface passivation and improving open-circuit voltage - Google Patents

A kind of technique for enhancing single polycrystalline silicon battery plate surface passivation and improving open-circuit voltage Download PDF

Info

Publication number
CN108899394A
CN108899394A CN201810691296.4A CN201810691296A CN108899394A CN 108899394 A CN108899394 A CN 108899394A CN 201810691296 A CN201810691296 A CN 201810691296A CN 108899394 A CN108899394 A CN 108899394A
Authority
CN
China
Prior art keywords
silicon
silicon wafer
circuit voltage
layer
chip surface
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810691296.4A
Other languages
Chinese (zh)
Inventor
景彦姣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oriental Sunrise (luoyang) New Energy Co Ltd
Original Assignee
Oriental Sunrise (luoyang) New Energy Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oriental Sunrise (luoyang) New Energy Co Ltd filed Critical Oriental Sunrise (luoyang) New Energy Co Ltd
Priority to CN201810691296.4A priority Critical patent/CN108899394A/en
Publication of CN108899394A publication Critical patent/CN108899394A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1804Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof comprising only elements of Group IV of the Periodic System
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0236Special surface textures
    • H01L31/02363Special surface textures of the semiconductor body itself, e.g. textured active layers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

A kind of technique for enhancing single polycrystalline silicon battery plate surface passivation and improving open-circuit voltage, process flow steps are:Making herbs into wool → diffusion → etching → oxidation → PECVD → silk-screen printing → sintering → sorting → test;The present invention proposes a kind of technique for enhancing single polycrystalline silicon battery plate surface passivation effect and improving open-circuit voltage, at high temperature, it is passed through oxygen into Quartz stove tube and forms one layer of silicon dioxide layer with certain thickness, compactness and uniformity in silicon chip surface, this layer of oxide layer has good passivation to silicon chip surface, barrier metal ion is spread into silicon, limit the movement of charged carriers, the open-circuit voltage of silicon wafer improves 2~5mv, transfer efficiency is improved into 0.03-0.05%, improves the yield rate of single polycrystalline cell piece;Oxidation operation is mature simple, is easy to implement, can use existing diffusion furnace and be directly realized by, do not need the new equipment of extra purchase, single polycrystalline is general.

Description

A kind of technique for enhancing single polycrystalline silicon battery plate surface passivation and improving open-circuit voltage
Technical field:
The present invention relates to single polysilicon solar cell field more particularly to a kind of enhancing single polycrystalline silicon battery plate surface are blunt Change the technique for improving open-circuit voltage.
Background technique
Photovoltaic cell technology is constantly brought forth new ideas, and high efficiency technical has tended to maturation and met enterprise's volume production needs, and single polycrystalline efficiency is not Disconnected to be refreshed, how that the manufacturing process of cell piece is more optimized, developing higher transfer efficiency has been that each photovoltaic enterprise finishes The raw target pursued, in the case where cost is without what difference, the higher transfer efficiency of same silicon wafer just represents higher Interests return, therefore strong company constantly by the process route in laboratory by equipment improvement or technological innovation by its Successful utilization obtains higher transfer efficiency into actual production process;The transfer efficiency for how improving silicon wafer, becomes Insoluble technical problem for a long time.
In view of the foregoing, a kind of work for enhancing single polycrystalline silicon battery plate surface passivation and improving open-circuit voltage is now developed Skill.
Summary of the invention
Purpose of the invention is to overcome the shortcomings in the prior art, provides a kind of enhancing single polycrystalline silicon battery plate surface Passivation improves the technique of open-circuit voltage, improves the yield rate of single polycrystalline cell piece;Oxidation operation is mature simple, is easy to implement, It can use existing diffusion furnace to be directly realized by, do not need the new equipment of extra purchase, single polycrystalline is general.
The present invention to achieve the goals above, adopts the following technical scheme that:A kind of enhancing single polycrystalline silicon battery plate surface is blunt Change the technique for improving open-circuit voltage, process flow steps are:Making herbs into wool → diffusion → etching → oxidation → PECVD → silk-screen printing → Sintering → sorting → test.
The first step:Making herbs into wool:Monocrystalline forms a layer texture structure in silicon wafer using sodium hydroxide, additive, is formed and falls into light Effect increases the absorption of light, reduces surface reflectivity;Polycrystalline forms a layer texture structure in silicon wafer using nitric acid, hydrofluoric acid, It is formed and falls into luminous effect, increase the absorption of light, reduce surface reflectivity, additive is water, isopropanol, sodium hydroxide, surface-active The mixture of agent;
Second step:Diffusion:Silicon chip surface after making herbs into wool manufactures a PN junction;P-type wafer is put into the quartz of diffusion furnace In container, phosphorus oxychloride is brought into quartz container using nitrogen at a high temperature of 800~900 DEG C, passes through phosphorus oxychloride and silicon wafer Reacted to obtain phosphorus atoms, by certain time, phosphorus atoms enter the superficial layer of silicon wafer from surrounding, and by silicon atom it Between gap spread to silicon wafer internal penetration, form N-type semiconductor, the interface of N-type semiconductor and P-type semiconductor is PN Knot;
Third step:Etching:PN junction using nitric acid and hydrofluoric acid by diffusing procedure in silicon wafer surrounding and bottom removes, and makes silicon The insulation of piece upper and lower surface, while removing the one layer of phosphorosilicate glass formed after diffusing procedure knot in silicon chip surface, the phosphorosilicate glass The transfer efficiency of cell piece can be reduced in layer containing many impurity;
4th step:Oxidation:Silicon wafer after etching is placed in oxygen in diffusion furnace tube, is passed through at high temperature, oxygen is in silicon Piece surface occurs chemical reaction and forms silicon dioxide layer;Temperature in diffusion furnace tube is:700~1200 DEG C, oxygen flow 1000 ~2000sccm, 10000~20000sccm of nitrogen flow, time 1000s~2000s;
5th step:PECVD:So that the silicon wafer after oxidation is warming up to specified temperature using radio frequency glow discharge, then passes to Reaction gas SiH4 and NH3 form silicon nitride film in silicon chip surface;The silicon nitride film can increase sunlight short-wave band light Absorption, reduce surface reflectivity, improve short circuit current to improving transfer efficiency;
6th step:Silk-screen printing:Positive and negative two electrodes are made on silicon chip surface after PECVD, it will PN junction under light illumination The electric current of generation exports;The process is printed by cell backside silver paste, the printing of cell backside aluminium paste and cell front side silver paste print three Part forms;Slurry is penetrated using halftone visuals mesh, applies pressure at the slurry position of halftone with scraper, while towards net The version other end is mobile, and slurry is expressed on silicon wafer from the mesh of visuals by scraper on the move, is formed in silicon chip surface Figure;
7th step:Silicon wafer after silk-screen printing is sintered, by the organic compound combustion in the slurry of silicon chip surface figure Fall, make back side aluminium paste, silver paste in conjunction with silicon crystal, front side silver paste forms silver-colored silicon alloy and alusil alloy, shape in conjunction with silicon crystal At the Ohmic contact of upper/lower electrode, two key parameters of open-circuit voltage and fill factor of cell piece are improved, resistance is made it have Characteristic, to improve the transfer efficiency of cell piece;
8th step:Sorting:Color classification will be carried out according to color standard film by sintered silicon wafer, according to color from being deep to Shallowly, the silicon wafer of same color carries out unified testing package;
9th step:Test:By the silicon wafer after sorting be put into test equipment test, after test, according to the open-circuit voltage of silicon wafer, Silicon wafer is carried out stepping placement according to efficiency by the parameters such as short circuit current, transfer efficiency.
The beneficial effects of the invention are as follows:The present invention proposes that a kind of single polycrystalline silicon battery plate surface passivation effect of enhancing improves and opens The technique of road voltage is passed through oxygen into Quartz stove tube in silicon chip surface and forms one layer with certain thickness, densification at high temperature The silicon dioxide layer of property and uniformity, this layer of oxide layer have a good passivation to silicon chip surface, barrier metal ion to It is spread in silicon, limits the movement of charged carriers, the open-circuit voltage of silicon wafer improves 2~5mv, transfer efficiency is improved 0.03- 0.05%, improve the yield rate of single polycrystalline cell piece;Oxidation operation is mature simple, is easy to implement, can use existing expansion Scattered furnace is directly realized by, and does not need the new equipment of extra purchase, and single polycrystalline is general.
Detailed description of the invention
The present invention will be further explained below with reference to the attached drawings:
Fig. 1 is process flow diagram.
Specific embodiment
Below with reference to embodiment, invention is further described in detail with specific embodiment:
Embodiment 1
The first step:Making herbs into wool:Monocrystalline forms a layer texture structure in silicon wafer using sodium hydroxide, additive, is formed and falls into light Effect increases the absorption of light, reduces surface reflectivity;Polycrystalline forms a layer texture structure in silicon wafer using nitric acid, hydrofluoric acid, It is formed and falls into luminous effect, increase the absorption of light, reduce surface reflectivity, additive is water, isopropanol, sodium hydroxide, surface-active The mixture of agent;
Second step:Diffusion:Silicon chip surface after making herbs into wool manufactures a PN junction;P-type wafer is put into the quartz of diffusion furnace In container, phosphorus oxychloride is brought into quartz container using nitrogen at a high temperature of 850 DEG C, is carried out by phosphorus oxychloride and silicon wafer anti- Phosphorus atoms should be obtained, by certain time, phosphorus atoms enter the superficial layer of silicon wafer from surrounding, and pass through the sky between silicon atom Gap is spread to silicon wafer internal penetration, forms N-type semiconductor, and the interface of N-type semiconductor and P-type semiconductor is PN junction;
Third step:Etching:PN junction using nitric acid and hydrofluoric acid by diffusing procedure in silicon wafer surrounding and bottom removes, and makes silicon The insulation of piece upper and lower surface, while removing the one layer of phosphorosilicate glass formed after diffusing procedure knot in silicon chip surface, the phosphorosilicate glass The transfer efficiency of cell piece can be reduced in layer containing many impurity;
4th step:Oxidation:Silicon wafer after etching is placed in oxygen in diffusion furnace tube, is passed through at high temperature, oxygen is in silicon Piece surface occurs chemical reaction and forms silicon dioxide layer;Temperature in diffusion furnace tube is:1000 DEG C, oxygen flow 1500sccm, Nitrogen flow 20000sccm, time 2000s;
5th step:PECVD:So that the silicon wafer after oxidation is warming up to specified temperature using radio frequency glow discharge, then passes to Reaction gas SiH4 and NH3 form silicon nitride film in silicon chip surface;The silicon nitride film can increase sunlight short-wave band light Absorption, reduce surface reflectivity, improve short circuit current to improving transfer efficiency;
6th step:Silk-screen printing:Positive and negative two electrodes are made on silicon chip surface after PECVD, it will PN junction under light illumination The electric current of generation exports;The process is printed by cell backside silver paste, the printing of cell backside aluminium paste and cell front side silver paste print three Part forms;Slurry is penetrated using halftone visuals mesh, applies pressure at the slurry position of halftone with scraper, while towards net The version other end is mobile, and slurry is expressed on silicon wafer from the mesh of visuals by scraper on the move, is formed in silicon chip surface Figure;
7th step:Silicon wafer after silk-screen printing is sintered, by the organic compound combustion in the slurry of silicon chip surface figure Fall, make back side aluminium paste, silver paste in conjunction with silicon crystal, front side silver paste forms silver-colored silicon alloy and alusil alloy, shape in conjunction with silicon crystal At the Ohmic contact of upper/lower electrode, two key parameters of open-circuit voltage and fill factor of cell piece are improved, resistance is made it have Characteristic, to improve the transfer efficiency of cell piece;
8th step:Sorting:Color classification will be carried out according to color standard film by sintered silicon wafer, according to color from being deep to Shallowly, the silicon wafer of same color carries out unified testing package;
9th step:Test:By the silicon wafer after sorting be put into test equipment test, after test, according to the open-circuit voltage of silicon wafer, Silicon wafer is carried out stepping placement according to efficiency by the parameters such as short circuit current, transfer efficiency.

Claims (2)

1. a kind of technique for enhancing single polycrystalline silicon battery plate surface passivation and improving open-circuit voltage, it is characterised in that:Process flow step Suddenly it is:Making herbs into wool → diffusion → etching → oxidation → PECVD → silk-screen printing → sintering → sorting → test.
2. a kind of technique for enhancing single polycrystalline silicon battery plate surface passivation and improving open-circuit voltage according to claim 1, It is characterized in that:
The first step:Making herbs into wool:Monocrystalline forms a layer texture structure in silicon wafer using sodium hydroxide, additive, is formed and falls into luminous effect, Increase the absorption of light, reduces surface reflectivity;Polycrystalline forms a layer texture structure in silicon wafer using nitric acid, hydrofluoric acid, is formed Luminous effect is fallen into, the absorption of light is increased, reduces surface reflectivity, additive is water, isopropanol, sodium hydroxide, surfactant Mixture;
Second step:Diffusion:Silicon chip surface after making herbs into wool manufactures a PN junction;P-type wafer is put into the quartz container of diffusion furnace It is interior, phosphorus oxychloride is brought into quartz container using nitrogen at a high temperature of 800~900 DEG C, is carried out by phosphorus oxychloride and silicon wafer Reaction obtains phosphorus atoms, and by certain time, phosphorus atoms enter the superficial layer of silicon wafer from surrounding, and by between silicon atom Gap is spread to silicon wafer internal penetration, forms N-type semiconductor, and the interface of N-type semiconductor and P-type semiconductor is PN junction;
Third step:Etching:PN junction using nitric acid and hydrofluoric acid by diffusing procedure in silicon wafer surrounding and bottom removes, and makes on silicon wafer Lower surface insulation, while the one layer of phosphorosilicate glass formed after diffusing procedure knot in silicon chip surface is removed, in the phosphorosilicate glass layer The transfer efficiency of cell piece can be reduced containing many impurity;
4th step:Oxidation:Silicon wafer after etching is placed in oxygen in diffusion furnace tube, is passed through at high temperature, oxygen is in silicon wafer table Face occurs chemical reaction and forms silicon dioxide layer;Temperature in diffusion furnace tube is:700~1200 DEG C, oxygen flow 1000~ 2000sccm, 10000~20000sccm of nitrogen flow, time 1000s~2000s;
5th step:PECVD:So that the silicon wafer after oxidation is warming up to specified temperature using radio frequency glow discharge, then passes to reaction Gas SiH4 and NH3 form silicon nitride film in silicon chip surface;The silicon nitride film can increase the suction of sunlight short-wave band light It receives, reduces surface reflectivity, improve short circuit current to improve transfer efficiency;
6th step:Silk-screen printing:Positive and negative two electrodes are made on silicon chip surface after PECVD, PN junction will be generated under light illumination Electric current export;The process is printed by cell backside silver paste, three parts are printed in the printing of cell backside aluminium paste and cell front side silver paste Composition;Slurry is penetrated using halftone visuals mesh, applies pressure at the slurry position of halftone with scraper, while another towards halftone One end is mobile, and slurry is expressed on silicon wafer from the mesh of visuals by scraper on the move, forms figure in silicon chip surface;
7th step:Silicon wafer after silk-screen printing is sintered, the organic compound combustion in the slurry of silicon chip surface figure is fallen, is made Back side aluminium paste, silver paste are in conjunction with silicon crystal, and front side silver paste is in conjunction with silicon crystal, the silver-colored silicon alloy of formation and alusil alloy, in formation The Ohmic contact of lower electrode improves two key parameters of open-circuit voltage and fill factor of cell piece, makes it have resistance characteristic, To improve the transfer efficiency of cell piece;
8th step:Sorting:Color classification will be carried out according to color standard film by sintered silicon wafer, it is shallow from being deep to according to color, The silicon wafer of same color carries out unified testing package;
9th step:Test:Silicon wafer after sorting is put into test equipment test, after test, according to the open-circuit voltage of silicon wafer, short circuit Silicon wafer is carried out stepping placement according to efficiency by the parameters such as electric current, transfer efficiency.
CN201810691296.4A 2018-06-28 2018-06-28 A kind of technique for enhancing single polycrystalline silicon battery plate surface passivation and improving open-circuit voltage Pending CN108899394A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810691296.4A CN108899394A (en) 2018-06-28 2018-06-28 A kind of technique for enhancing single polycrystalline silicon battery plate surface passivation and improving open-circuit voltage

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810691296.4A CN108899394A (en) 2018-06-28 2018-06-28 A kind of technique for enhancing single polycrystalline silicon battery plate surface passivation and improving open-circuit voltage

Publications (1)

Publication Number Publication Date
CN108899394A true CN108899394A (en) 2018-11-27

Family

ID=64347185

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810691296.4A Pending CN108899394A (en) 2018-06-28 2018-06-28 A kind of technique for enhancing single polycrystalline silicon battery plate surface passivation and improving open-circuit voltage

Country Status (1)

Country Link
CN (1) CN108899394A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109360802A (en) * 2018-12-13 2019-02-19 杭州海莱德智能科技有限公司 A kind of flush system disperser
CN112768566A (en) * 2021-02-01 2021-05-07 上海理工大学 Photocell preparation method based on molybdenum disulfide as carrier

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102629643A (en) * 2012-04-16 2012-08-08 中利腾晖光伏科技有限公司 Manufacturing method of high-square-resistance solar cell
US20130089943A1 (en) * 2011-10-06 2013-04-11 National Taiwan University Method of manufacturing a solar cell
CN103094419A (en) * 2013-01-24 2013-05-08 山东力诺太阳能电力股份有限公司 Preparation method of high-efficiency solar cell
CN103413841A (en) * 2013-08-28 2013-11-27 中电投西安太阳能电力有限公司 Solar cell surface passive layer structure and preparing method thereof
WO2016142434A1 (en) * 2015-03-09 2016-09-15 Heraeus Deutschland GmbH & Co. KG Conductive polymer/si interfaces at the back side of solar cells
CN107293613A (en) * 2017-05-10 2017-10-24 东方环晟光伏(江苏)有限公司 Realize the method that thermal oxide passivation layer cell piece makes

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130089943A1 (en) * 2011-10-06 2013-04-11 National Taiwan University Method of manufacturing a solar cell
CN102629643A (en) * 2012-04-16 2012-08-08 中利腾晖光伏科技有限公司 Manufacturing method of high-square-resistance solar cell
CN103094419A (en) * 2013-01-24 2013-05-08 山东力诺太阳能电力股份有限公司 Preparation method of high-efficiency solar cell
CN103413841A (en) * 2013-08-28 2013-11-27 中电投西安太阳能电力有限公司 Solar cell surface passive layer structure and preparing method thereof
WO2016142434A1 (en) * 2015-03-09 2016-09-15 Heraeus Deutschland GmbH & Co. KG Conductive polymer/si interfaces at the back side of solar cells
CN107293613A (en) * 2017-05-10 2017-10-24 东方环晟光伏(江苏)有限公司 Realize the method that thermal oxide passivation layer cell piece makes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109360802A (en) * 2018-12-13 2019-02-19 杭州海莱德智能科技有限公司 A kind of flush system disperser
CN112768566A (en) * 2021-02-01 2021-05-07 上海理工大学 Photocell preparation method based on molybdenum disulfide as carrier

Similar Documents

Publication Publication Date Title
CN106992229A (en) A kind of PERC cell backsides passivation technology
CN105355693B (en) A kind of PERC solar-energy photo-voltaic cells for improving photoelectric transformation efficiency
CN101414647A (en) Diffusion method for high-efficiency solar battery local depth junction
CN101179100A (en) Manufacturing method of large area low bending flexure ultra-thin type double face lighting solar cell
CN101369612A (en) Production method for implementing selective emitter solar battery
CN206864484U (en) One kind passivation contact solar cell
CN109346536A (en) A kind of contact passivation crystal silicon solar energy battery structure and preparation method
CN105576083A (en) N-type double-side solar cell based on APCVD technology and preparation method thereof
CN106711239A (en) Preparation method of PERC solar battery and PERC solar battery
CN109802008B (en) Manufacturing method of efficient low-cost N-type back-junction PERT double-sided battery
CN213519984U (en) Solar cell
CN112968074A (en) Preparation method of selective passivation contact battery
CN108666377A (en) A kind of p-type back contacts solar cell and preparation method thereof
CN110137305A (en) A kind of preparation method of p-type polysilicon selective emitter double-side cell
CN108899394A (en) A kind of technique for enhancing single polycrystalline silicon battery plate surface passivation and improving open-circuit voltage
CN111816714A (en) Laser boron-doped back-passivated solar cell and preparation method thereof
CN206040655U (en) Many main grids solar cell and subassembly and system
CN102306664B (en) Solar battery with black silicon structure on emitter and preparation method of solar battery
CN114744054A (en) TOPCon battery and preparation method thereof
CN102637776B (en) N type solar cell and manufacturing method thereof
CN110767772A (en) Preparation method of local contact passivation solar cell
CN102983225A (en) Manufacturing process of local back surface field
CN102024869B (en) Method for manufacturing solar cell
CN110534614A (en) A kind of preparation method of P-type crystal silicon battery
CN208538871U (en) A kind of p-type back contacts solar cell

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20181127