CN108887269A - A kind of bactericidal composition containing fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper - Google Patents
A kind of bactericidal composition containing fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper Download PDFInfo
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- CN108887269A CN108887269A CN201810944473.5A CN201810944473A CN108887269A CN 108887269 A CN108887269 A CN 108887269A CN 201810944473 A CN201810944473 A CN 201810944473A CN 108887269 A CN108887269 A CN 108887269A
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- Prior art keywords
- adipic acid
- acid copper
- fluorine azoles
- bacterium acyl
- azoles bacterium
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of microbicide compositions containing fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper, and containing fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper, the weight ratio of fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper is 1:60-60:1；The bactericidal composition can be used for the prevention and treatment of plurality of plant diseases, be preferred for the prevention and treatment of head blight, powdery mildew.
Description
Technical field
The invention belongs to pesticide fields, and in particular to a kind of Bactericidal composite of fluorine-containing azoles bacterium acyl azanol and tiger glue adipic acid copper
Object.
Background technique
Fluorine azoles bacterium acyl azanol belongs to succinate dehydrogenase inhibitors class fungicide, and the mode of action is by exhaling mitochondria
The Complex II (succinate dehydrogenase) for inhaling chain works, and the energetic supersession of cell is influenced, thus the spore of suppression target fungi
It sprouts, germ tube and mycelial growth show good protection and therapeutic effect.The fungicide has the characteristics that high-efficiency low-toxicity, right
A variety of pathogens such as Botrytis, Septoria, Cercospora leaf spot, Alternaria and Venturia have good activity.
Tiger glue adipic acid copper (copper (succinate+glutarate+adipate)), is a kind of high-efficiency low-toxicity broad spectrum activity
Fungicide, mechanism of action copper ion in pathogen film surface cation exchange, make the albumen on edge bacterium cell membrane
Matter solidification, while part copper ion penetrates into pathogen into the cell with certain enzymes ining conjunction with, and it is active to influence its.Tiger glue adipic acid copper is simultaneously
To the irritating effect of plant growth.
Chemical pesticide is used alone for a long time, is easy that disease is made to develop drug resistance, and causes dosage to increase, preventive effect is reduced, held
The problem of effect phase shortens, is unfavorable for environment sustainable development.Compound synergic effect is significantly formulated, and can be significantly improved anti-
Effect, substantially reduces the dosage of pesticide, can also expand fungicidal spectrum, improves germicidal efficiency.At present at home and abroad there is not yet fluorine azoles bacterium
Acyl azanol and tiger glue adipic acid copper compound relevant report.
Summary of the invention
It is an object of the invention to be directed to above-mentioned various problems, in order to widen service life, expand fungicidal spectrum, enhancing medicine
Effect reduces drug cost, to provide the bactericidal composition of a kind of fluorine-containing azoles bacterium acyl azanol and tiger glue adipic acid copper.
The present invention provides the following technical solutions：
A kind of microbicide compositions containing fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper, contain fluorine azoles bacterium acyl azanol and amber glue
The weight ratio of adipic acid copper, fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper is 1:60-60:1.
The weight ratio of microbicide compositions of the present invention, preferred fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper is 1:
30-60:1.More preferable 1:10-10:1
Bactericidal composition of the present invention can be prepared into the preparation received on pesticide, fluorine azoles bacterium acyl azanol and tiger glue adipic acid
The total weight of copper in the formulation accounts for the 1%-90% of the entire quality of the pharmaceutical preparations.
Bactericidal composition of the present invention, the total weight of preferred fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper in the formulation
Account for the 10%-65% of the entire quality of the pharmaceutical preparations.
The dosage form of bactericidal composition of the present invention is suspoemulsion, missible oil, suspending agent, water dispersible granules, granule, oil
Suspending agent, aqueous emulsion, wettable powder, microemulsion, microcapsule suspending agent etc..
Bactericidal composition of the present invention is used to prevent and treat the purposes of plurality of plant diseases.Bactericidal composite of the present invention
Object is preferred for the prevention and treatment of the diseases such as head blight, powdery mildew.
The reactive compound can be mixed preparation with customary adjuvant by known way by the preparation of the invention.Institute
The auxiliary material stated is selected from emulsifier, dispersing agent, wetting agent, disintegrating agent, binder, antifreeze, defoaming agent, thickener, filler, solvent
Deng one of or it is a variety of.
The dispersing agent is selected from polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulfuric acid of alkylphenol-polyethenoxy
Salt, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy are phonetic, aliphatic amine polyoxyethylene is phonetic, fatty
Sour polyoxyethylene ester, ester polyoxyethylene are one of phonetic or a variety of.
The wetting agent is selected from：Lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent
F, one of spaonin powder, silkworm excrement, spaonin powder or a variety of.
The disintegrating agent is selected from：One of bentonite, urea, ammonium sulfate, aluminium chloride are a variety of.
The binder is selected from：Arabic gum, white dextrin, methylcellulose, sodium acrylate, polyvinylpyrrolidone,
One of crosslinked polyvinylpyrrolidone, polyethylene glycol, polyvinyl alcohol are a variety of.
The antifreeze is selected from：One of ethylene glycol, propylene glycol, glycerine, polyethylene glycol are a variety of.
The defoaming agent is selected from：Silicone oil, silicone compound, C10-20 saturated fat acid compounds, C8-10 rouge
One of fat alcohol compound is a variety of.
The thickener is selected from：One of xanthan gum, polyvinyl alcohol, polyethylene glycol are a variety of.
The filler is selected from：Kaolin, diatomite, bentonite, attapulgite, white carbon black, starch, in precipitated calcium carbonate
It is one or more.
Compared with prior art, the present invention has the advantages that：
Bactericidal composition synergistic effect is obvious, and drug effect improves, and field rate decline reduces production and application cost, subtracts
Few pesticide residue and environmental pollution；
Bactericidal composition is made of the effective component of different role mechanism, and action site increases, and is conducive to overcome and delay
The generation of germ drug resistance.
Specific embodiment
Below with reference to embodiment, specific embodiments of the present invention will be described in detail, it is to be understood that guarantor of the invention
Shield range is not limited by the specific implementation.
1 fluorine azoles bacterium acyl azanol of embodiment and tiger glue adipic acid copper compound the indoor toxicity test to wheat scab
Subjects：Fusarium graminearum
Test method：Reference《Pesticide bioassay test rule》, reagent agent list is carried out using mycelial growth rate method
Agent and different ratio compounding agent are for statistical analysis with DPS data processing software to the indoor toxicity test of fusarium graminearum,
The EC50 of each medicament is calculated, then calculates co-toxicity coefficient (CTC) by Sun Yunpei's Method.Specific measurement result is shown in Table 1.
When CTC≤80, then composition shows as antagonism, and as 80 < CTC < 120, then composition shows as being added and make
With when CTC >=120, then composition shows as synergistic effect.
Survey toxicity index (ATI)=(standard agent EC50/ reagent agent EC50) × 100
Percentage composition+B the medicament toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent
Co-toxicity coefficient (CTC)=[mixture surveys toxicity index (ATI)/mixtures theoretical toxicity index (TTI)] × 100.
The toxicity test of 1 fluorine azoles bacterium acyl azanol of table and tiger glue adipic acid copper to fusarium graminearum
As seen from the above table, fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper compounding have synergistic effect to wheat scab, improve
To the control efficiency of wheat scab, preferably fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper weight proportion 1:30-60:1；More preferably
Fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper weight proportion 1:10-10:1.
Embodiment 2：Fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper compound the field efficacy to wheat powdery mildew
Test method：The preceding investigation wheat powdery mildew state of an illness is administered for the first time in state of an illness initial stage, and application in every 7 days is primary, is applied altogether
Medicine 2 times.Disease index is investigated respectively and calculates preventive effect within 14 days after second of application.
Test medicine
Medicament 1:38% fluorine azoles bacterium acyl azanol tiger glue adipic acid copper suspending agent (fluorine azoles bacterium acyl azanol：Tiger glue adipic acid copper=1:
1)；
Medicament 2:60% fluorine azoles bacterium acyl azanol tiger glue adipic acid copper wettable powder (fluorine azoles bacterium acyl azanol：Tiger glue adipic acid copper
=1:5)；
Medicament 3:66% fluorine azoles bacterium acyl azanol tiger glue adipic acid copper water dispersion granula (fluorine azoles bacterium acyl azanol：Tiger glue adipic acid copper
=1:10)；
Medicament 4:36% fluorine azoles bacterium acyl azanol tiger glue adipic acid copper microemulsion (fluorine azoles bacterium acyl azanol：Tiger glue adipic acid copper=5:
1)；
2 fluorine azoles bacterium acyl azanol of table and tiger glue adipic acid copper compound the field efficacy to wheat powdery mildew
| Test medicine | Extension rate | 14 days preventive effects (%) |
| Medicament 1 | 5000 | 92.83 |
| Medicament 2 | 8000 | 89.34 |
| Medicament 3 | 8500 | 86.18 |
| Medicament 4 | 5000 | 95.44 |
As seen from the above table, fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper, which are applied in combination, can significantly improve to wheat powdery mildew
Control efficiency, control efficiency is superior to the preventive effect of single dose, and preventive effect phase is long.To target crop without bad in test scope of medication
It influences.
Further narration is done to the present invention above in conjunction with embodiment, but present invention is not limited to the embodiments described above,
Within the knowledge of one of ordinary skill in the art, it can also make without departing from the purpose of the present invention
Various change.
Claims (8)
1. a kind of microbicide compositions containing fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper, it is characterised in that contain fluorine azoles bacterium acyl hydroxyl
The weight ratio of amine and tiger glue adipic acid copper, fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper is 1:60-60:1.
2. requiring the microbicide compositions according to right 1, it is characterised in that the weight of fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper
Amount is than being 1:30-60:1.
3. requiring the microbicide compositions according to right 1, it is characterised in that the weight of fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper
Amount is than being 1:10-10:1.
4. bactericidal composition according to claim 1 to 3, it is characterised in that can be prepared into the preparation received on pesticide, fluorine azoles
The total weight of bacterium acyl azanol and tiger glue adipic acid copper in the formulation accounts for the 1%-90% of the entire quality of the pharmaceutical preparations.
5. bactericidal composition described in -4 according to claim 1, it is characterised in that fluorine azoles bacterium acyl azanol and tiger glue adipic acid copper are being made
Total weight in agent accounts for the 10%-65% of the entire quality of the pharmaceutical preparations.
6. bactericidal composition according to claim 1, it is characterised in that the dosage form of the bactericidal composition is suspoemulsion, cream
Oil, suspending agent, water dispersible granules, granule, oil-suspending agent, aqueous emulsion, wettable powder, microemulsion, microcapsule suspending agent etc..
7. bactericidal composition described in -7 is used to prevent and treat the purposes of plurality of plant diseases according to claim 1.
8. purposes according to claim 8, it is characterised in that the disease is head blight, powdery mildew.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810944473.5A CN108887269B (en) | 2018-08-19 | 2018-08-19 | Sterilization composition containing fluconazole acyl hydroxylamine and copper succinate + glutarate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810944473.5A CN108887269B (en) | 2018-08-19 | 2018-08-19 | Sterilization composition containing fluconazole acyl hydroxylamine and copper succinate + glutarate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108887269A true CN108887269A (en) | 2018-11-27 |
| CN108887269B CN108887269B (en) | 2021-05-11 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810944473.5A Active CN108887269B (en) | 2018-08-19 | 2018-08-19 | Sterilization composition containing fluconazole acyl hydroxylamine and copper succinate + glutarate |
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| Country | Link |
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| CN (1) | CN108887269B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114223664A (en) * | 2021-12-31 | 2022-03-25 | 广东真格生物科技有限公司 | Composition containing fluxapyroxad and copper gluconate as well as preparation and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104351244A (en) * | 2014-11-06 | 2015-02-18 | 陕西上格之路生物科学有限公司 | Bactericidal composition containing oxalate diacetone ketone amine and amide bactericides |
| CN105165893A (en) * | 2015-10-27 | 2015-12-23 | 宁波三江益农作物保护有限公司 | Plant sterilization composite |
| CN107889832A (en) * | 2017-11-27 | 2018-04-10 | 联保作物科技有限公司 | Preparation containing the basic copper sulfate and complex composition of fluxapyroxad, agricultural bacteriocide and its application |
-
2018
- 2018-08-19 CN CN201810944473.5A patent/CN108887269B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104351244A (en) * | 2014-11-06 | 2015-02-18 | 陕西上格之路生物科学有限公司 | Bactericidal composition containing oxalate diacetone ketone amine and amide bactericides |
| CN105165893A (en) * | 2015-10-27 | 2015-12-23 | 宁波三江益农作物保护有限公司 | Plant sterilization composite |
| CN107889832A (en) * | 2017-11-27 | 2018-04-10 | 联保作物科技有限公司 | Preparation containing the basic copper sulfate and complex composition of fluxapyroxad, agricultural bacteriocide and its application |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114223664A (en) * | 2021-12-31 | 2022-03-25 | 广东真格生物科技有限公司 | Composition containing fluxapyroxad and copper gluconate as well as preparation and application thereof |
| CN114223664B (en) * | 2021-12-31 | 2023-09-15 | 广东真格生物科技有限公司 | Composition containing fluxapyroxad hydroxylamine and copper gluconate as well as preparation and application thereof |
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| Publication number | Publication date |
|---|---|
| CN108887269B (en) | 2021-05-11 |
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Effective date of registration: 20210422 Address after: 231323 economic development zone, Hangzhou town, Shucheng, Anhui, Lu'an Applicant after: ANHUI YINONG CHEMICAL Co.,Ltd. Address before: 231470 Anhui city of Anqing province Tongcheng city Du Zhen Yang Road North Applicant before: ANHUI JIALIAN BIOTECHNOLOGY Co.,Ltd. |
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