CN108849962A - A kind of insecticide composition containing double third ring worm esters and Buprofezin - Google Patents
A kind of insecticide composition containing double third ring worm esters and Buprofezin Download PDFInfo
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- CN108849962A CN108849962A CN201810925831.8A CN201810925831A CN108849962A CN 108849962 A CN108849962 A CN 108849962A CN 201810925831 A CN201810925831 A CN 201810925831A CN 108849962 A CN108849962 A CN 108849962A
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- buprofezin
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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Abstract
The present invention relates to a kind of compounded pesticides and its application, specifically a kind of insecticide compounded using double third ring worm esters and Buprofezin as main active and its application belong to technical field of pesticide compounding.The weight fraction ratio of double third ring worm esters and Buprofezin is 10: 1~1: 20, the compounded pesticides have synergistic effect obvious, quick-acting is good, duration length, low toxicity, low-residual, it is esy to use, safe and reliable the advantages that, can effectively delay the drug resistance of pest to generate, have larger application value in agricultural production.
Description
Technical field
The present invention relates to a kind of compounded pesticides and its application, specifically one kind is with double third ring worm esters and Buprofezin
The insecticide of main active compounding and its application, belong to technical field of pesticide compounding, are mainly used in same on crops
Wing mesh control of insect.
Background technique
Double third ring worm esters are the novel botanical pesticide of Japan's exploitation, English name afidopyropen, molecular formula
C33H39NO9.Double third ring worm esters have unique structure and completely new mechanism of action, multiple by interference insect vanilloid receptor channel
It closes the regulation of object and plays a role, so that the feeding of interference insect and other behaviors, it is hungry dead to eventually lead to pest.With it is existing
Insecticide no interactions resistance, can be used for foliar spray and soil treatment, to the aphid on melon dish, fruit tree, grain work and flowers, powder
Lice, plant hopper, leafhopper and coccid all have very high virulence.
Buprofezin is insect growth regulator, IGR insecticides, English name Buprofezin, molecular formula C16H23N3SO.It is main to use
In the control of insect of the crops such as rice, fruit tree, tea tree, vegetables, there is lasting effect to coleoptera, part Homoptera and Acarina
Larvicidal activity.Cicadellidae on rice, Delphacidae can be effectively prevented:Cicadellidae on potato;Citrus, cotton and vegetables
On Aleyrodidae;The pests such as a red-spotted lizard section, Diaspididae and Pseudococcidae on citrus.
In actual production, chemical pesticide is the principal security for guaranteeing crops high and stable yields, the mini pest on crops
Such as aleyrodid, aphid, coccid, plant hopper due to reproduction speed it is fast, drug resistance is more prone to produce to pesticide, is especially made for a long time
With single chemical insecticide.How to delay pest resistance to insecticide generation is one of problem of researcher, and reasonable chemistry kills
Worm agent compounding has many advantages, such as that synergy is obvious, reduces dosage, reducing pesticide residue, expansion prevention spectrum, to delaying the anti-medicine of pest
Property has good effect.
In joint toxicity measuring research indoors, inventor matches after finding double third ring worm esters and buprofezin compound in certain
Than having significant synergies in range, while in the application of crop field, the various pests of crops are all had outstanding
Control efficiency, while having no the report for being used to prevent and treat the document of agricultural pests in relation to double third ring worm esters and buprofezin compound agent.
Summary of the invention
That the object of the present invention is to provide a kind of quick-acting is good, the lasting period is long, high-efficiency low-toxicity, can effectively prevent crops
The insecticide composition containing double third ring worm esters and Buprofezin of pest.
The technical solution provided of the invention is:A kind of insecticide composition containing double third ring worm esters and Buprofezin,
It is characterized in comprising the double third ring worm esters of the first effective component and the second effective component Buprofezin and common auxiliary element, double third ring worms
The weight fraction ratio of ester and Buprofezin is 10: 1~1: 20.
Further, the weight fraction ratio of double third ring worm esters and Buprofezin is 3: 1~1: 5, preferably 1: 3.
Further, the weight of double third ring worm esters and Buprofezin and total weight percentage composition is 2%- in the composition
90%, it is preferably 10%-48%, remaining is the auxiliary agent allowed on pesticide.
Further, the dosage form which can prepare is suspending agent, missible oil, aqueous emulsion, microemulsion, wettable
One of pulvis, water dispersible granules.
Further, which is suitable for the homoptera pest prevention and treatment on crops.
Further, the pest includes aleyrodid, planthopper, aphid, leafhopper, wood louse, coccid etc..
Compared with the prior art, the advantages of the present invention are as follows:
The insecticidal mechanism of effective component is different in the present invention, reasonable mixture ratio of components, and insecticidal effect is not each component activity letter
Single addition, but have significant synergies, the dosage of each single dose is reduced, drug cost is reduced, reduces environment
Pollution, while greatly pest resistance to insecticide can be delayed to generate, it is worth promoting the use of in agricultural production.
Specific embodiment
The following provides a specific embodiment of the present invention, for technical scheme of the present invention is further explained, but this hair
It is bright to be not limited to these embodiments, it is only for preferably to explain true spirit, be not construed as making the present invention
With the limitation of range.
1, formula and FORMULATION PROCESS EXAMPLES
Embodiment one:20% pair of the third ring worm ester buprofezin suspension agent
Double third ring worm ester raw medicines (folding hundred) 10%, Buprofezin raw medicine (folding hundred) 10%, alkyl phenol polyoxyethylene ether 5.5%,
Lauryl sodium sulfate 4%, silicone compound 0.15%, propylene glycol 3%, polyvinyl alcohol 0.3%, preservative sodium benzoate
0.5%, deionized water adds to 100%, weighs each component in proportion and is sanded, obtains 20% pair of the third ring worm ester thiazine after filtering
Ketone suspending agent.
Embodiment two:48% pair of the third ring worm ester wettable powder with buprofezin
Double third ring worm ester raw medicines (folding hundred) 12%, Buprofezin raw medicine (folding hundred) 36%, alkyl phenol polyoxyethylene ether 3%, ten
Sodium dialkyl sulfate 4%, white carbon black 10%, add kaolin to complement to 100%, in proportion after weighing each component co-grinding to obtain the final product
To 48% pair of the third ring worm ester wettable powder with buprofezin.
Embodiment three:16% pair of the third ring worm ester Buprofezin missible oil
Double third ring worm ester raw medicines (folding hundred) 12%, Buprofezin raw medicine (folding hundred) 4%, 10% fatty alcohol polyoxyethylene ether, 5%
Alkylbenzene sulfonate, heavy aromatic solvent oil complement to 100%, in proportion after weighing each component after mixing stirring and processing filtering
Can be made into 16% pair of the third ring worm ester Buprofezin missible oil can be added suitable dimethylbenzene according to actual needs.
Example IV:28.8% pair of the third ring worm ester Buprofezin microemulsion
Double third ring worm ester raw medicines (folding hundred) 24%, Buprofezin raw medicine (folding hundred) 4.8%, fatty alcohol polyoxyethylene ether 3%, 3-
Stirring and processing filtering can make after octylpyrrolidone 5%, propylene glycol 3%, silicone oil 0.2%, deionized water supply 100% mixing
Obtain 28.8% pair of the third ring worm ester Buprofezin microemulsion.
Embodiment five:35.2% pair of the third ring worm ester wettable powder with buprofezin
Double third ring worm ester raw medicines (folding hundred) 32%, Buprofezin raw medicine (folding hundred) 3.2%, alkyl phenol polyoxyethylene ether 3%, ten
Sodium dialkyl sulfate 4%, white carbon black 10%, add kaolin to complement to 100%, after weighing each component co-grinding in proportion
35.2% pair of the third ring worm ester wettable powder with buprofezin is made.
Embodiment six:32% pair of the third ring worm ester Buprofezin water dispersible granules
Double third ring worm ester raw medicines (folding hundred) 8%, Buprofezin raw medicine (folding hundred) 24%, polycarboxylate 5%, detergent alkylate sulphur
Sour sodium 2%, white carbon black 2%, light calcium complement to 100%, weigh each component co-grinding in proportion, and then plus water is mediated and is granulated simultaneously
It can be made into 32% pair of the third ring worm ester Buprofezin water dispersible granules after drying.
Embodiment seven:18% pair of the third ring worm ester thiazine ketone aqueous emulsion
Double third ring worm ester raw medicines (folding hundred) 3%, Buprofezin raw medicine (folding hundred) 15%, alkyl phosphoric acid esters 2%, EO-PO is embedding
Section copolymer 1 %, dimethylbenzene 20%, propylene glycol 5%, polyvinyl alcohol 0.1%, preservative sodium benzoate 0.5%, silicone antifoams agent
0.5%, deionized water complements to 100%, weighs alkyl phosphoric acid esters, EO-PO block copolymer, propylene glycol, poly- second in proportion
Enol, sodium benzoate are mixed to form water phase after silicone antifoams agent and with deionized water, and double third ring worm esters, Buprofezin raw medicine are dissolved in
Oily phase is formed in dimethylbenzene;It is mutually added to oily in water phase under high speed shear, that is, can be made into 18% pair of the third ring worm ester thiazine
Ketone aqueous emulsion.
Embodiment eight:44% pair of the third ring worm ester wettable powder with buprofezin
Double third ring worm ester raw medicines (folding hundred) 4%, Buprofezin raw medicine (folding hundred) 40%, alkyl phenol polyoxyethylene ether 3%, 12
Sodium alkyl sulfate 4%, white carbon black 10%, add kaolin to complement to 100%, can make after weighing each component co-grinding in proportion
At 44% pair of the third ring worm ester wettable powder with buprofezin.
Embodiment nine:33.6% pair of the third ring worm ester Buprofezin water dispersible granules
Double third ring worm ester raw medicines (folding hundred) 1.6%, Buprofezin raw medicine (folding hundred) 32%, polycarboxylate 5%, detergent alkylate
Sodium sulfonate 2%, white carbon black 2%, light calcium complement to 100%, weigh each component co-grinding in proportion, and then plus water is mediated and is granulated
And it can be made into 33.6% pair of the third ring worm ester Buprofezin water dispersible granules after drying.
Embodiment ten:14% pair of the third ring worm ester Buprofezin missible oil
Double third ring worm ester raw medicines (folding hundred) 8%, Buprofezin raw medicine (folding hundred) 6%, 10% fatty alcohol polyoxyethylene ether, 5%
Alkylbenzene sulfonate, heavy aromatic solvent oil complement to 100%, in proportion after weighing each component after mixing stirring and processing filtering
Can be made into 14% pair of the third ring worm ester Buprofezin missible oil can be added suitable dimethylbenzene according to actual needs.
Embodiment 11::18% pair of the third ring worm ester buprofezin suspension agent
Double third ring worm ester raw medicines (folding hundred) 6%, Buprofezin raw medicine (folding hundred) 12%, alkyl phenol polyoxyethylene ether 5.5%, ten
Sodium dialkyl sulfate 4%, silicone compound 0.15%, propylene glycol 3%, polyvinyl alcohol 0.3%, preservative sodium benzoate
0.5%, deionized water adds to 100%, weighs each component in proportion and is sanded, obtains 18% pair of the third ring worm ester thiazine after filtering
Ketone suspending agent.
Embodiment 12:10% pair of the third ring worm ester Buprofezin microemulsion
Double third ring worm ester raw medicines (folding hundred) 6%, Buprofezin raw medicine (folding hundred) 4%, fatty alcohol polyoxyethylene ether 3%, 3- are pungent
Stirring and processing filtering can be prepared by after base pyrrolidones 5%, propylene glycol 3%, silicone oil 0.2%, deionized water supply 100% mixing
10% pair of the third ring worm ester Buprofezin microemulsion.
Embodiment 13:16% pair of the third ring worm ester wettable powder with buprofezin
Double third ring worm ester raw medicines (folding hundred) 8%, Buprofezin raw medicine (folding hundred) 8%, alkyl phenol polyoxyethylene ether 3%, 12
Sodium alkyl sulfate 4%, white carbon black 10%, add kaolin to complement to 100%, obtain after weighing each component co-grinding in proportion
16% pair of the third ring worm ester wettable powder with buprofezin.
2, indoor biological activity assay and field efficacy verify embodiment
Test example one:The indoor toxicity test of double third ring worm esters and Buprofezin different ratio to brown paddy plant hopper
Test pest:Brown paddy plant hopper
Experimental design:Test worm is acquired from the middle rice field in Jiangxi Province Village, and the rice seedlings TN1 of indoor uncontaminated pesticide is continuous
As test worm sources after passage raising.Indoor joint toxicity measuring method reference《People's Republic of China (PRC) agricultural industry criteria NY/
T1154.11-2008》It carries out.Double third ring worm esters and Buprofezin raw medicine acetone solution, then with containing the water-soluble of 0.1% Tween 80
Liquid dilution, prepares single dose mother liquor, and devise 11 groups of proportions according to mixed purpose, each single dose and every group of proportion mixture are pressed respectively
5 series mass concentration (suitable lethasl concentration is configured to according to trial test result) are set for use according to the method for equal ratios.Selection
The rice seedling in tillering stage connect root dug clean, be cut into 10cm grow band root rice stem, by ready rice stem in prepared medical fluid
It impregnates 30s taking-up to dry, encases root moisturizing with absorbent cotton and be put into large size test tube, each test tube is put into 3 plants.Each test tube is used
Pest sucking device sucks brown paddy plant hopper nymph 20 of 3 ages, and nozzle is sealed with gauze, 4 repetitions of each processing, not contain pair of medicament
Answer solvent processing as a control group.Test tube is put into 25 DEG C, in the growth cabinet of relative humidity 80%.It is observed and recorded after 48h
The test worm survival condition respectively handled touches reactionless for dead worm, the calculating death rate, corrected mortality and CTC with writing brush type brush.
Using the logarithm of drug concentration (mg/L) as independent variable x, the probit value with corrected mortality is y, establishes poison respectively
Power regression equation, it is for statistical analysis with DPS 7.05, count the LC of each medicament50.Calculate the co-toxicity coefficient of compound drug mixture
(CTC)。
Calculation formula is as follows:
Survey toxicity index (ATI)=(standard agent LC50/ reagent agent) × 100
Percentage composition+B the medicament toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent
Co-toxicity coefficient (CTC)=ATI/TTI × 100
According to the criteria for classifying of co-toxicity coefficient (CTC), CTC < 80 is antagonism, and 80 < CTC < 120 are summation action,
CTC > 120 is synergistic effect.
Test result:
The indoor toxicity test of 1 pair of the third ring worm ester of table and Buprofezin different ratio to Brown Planthopper
Data can be seen that two medicaments have better effects to brown paddy plant hopper from table 1, and the CTC of all proportions is all larger than
80, wherein in addition to the proportion of double third ring worm esters and Buprofezin be 40: 1,20: 1 and 1: 40 CTC less than 120 other than, remaining is matched
The CTC of ratio is all larger than 120, and double third ring worm esters and Buprofezin show good synergistic effect between 10: 1-1: 20 proportion
Rather than it is simply added effect, wherein CTC is maximum when the proportion of double third ring worm esters and Buprofezin is 1: 3.
We specify the synergy section of double third ring worm esters and Buprofezin on the basis of joint toxicity measuring result indoors,
Carry out field efficacy verifying again on this basis with the practical drug effect of each proportion of determination.
Test example two:The field control effectiveness test of double third ring worm esters and buprofezin composition to Brown Planthopper
Subjects:Brown paddy plant hopper
Test method:It tests and carries out in Ganzhou City of Jiangxi Province, test method is referring to National Standard of the People's Republic of China's agriculture
Medicine field trial criterion GB/T17980.4-2000 is executed, radix investigation before being administered, using parallel jump sampling method, with ceramic whiteware disk
It is placed in rice root, rice of firmly flapping shakes off plant hopper on ceramic whiteware disk, counts the plant hopper number on ceramic whiteware disk, each cell tune
Look at 20 points, 2 clumps of rice of every investigation.1d after application, 7d, 20d same method check the remnants of each cell borer population living and observe
Whether there is phytotoxicity, calculates Revision insect recluced rate and opposite control efficiency.Cell uses RANDOMIZED BLOCK DESIGN, and a cell is as one
It repeats, minizone sets protection row, and each chemicals treatment is repeated 4 times.Test medicine is embodiment two, comparison medicament is 12% pair third
Ring worm ester WP, 36% Buprofezin WP are provided by Jiangxi Zheng Bang biochemical industry Co., Ltd.
Drug effect calculation method:
Total borer population × 100 before Revision insect recluced rate (%)=(insect population-residual borer population living before medicine)/medicine
Preventive effect (%)=(treatment region Revision insect recluced rate-check plot Revision insect recluced rate)/(check plot 100- Revision insect recluced rate)
×100
Test result:
2 pairs of the third ring worm esters of table and buprofezin composition prevention and treatment each preventive effect of Brown Planthopper pharmacodynamic test result are average value,
Different letters indicate significant difference (lowercase p < 0.05, capitalization the p < 0.01) under duncan Multiple range test
The composition of embodiment two has good control efficiency, preparation dosage to Brown Planthopper as can be seen from Table 2
1d preventive effect shows good quick-acting up to 93.66% after medicine when being 15g/ mus;3d, 20d preventive effect reach 96.37% and after application
97.64%, show good lasting effect.It is significantly better than single dose processing, good synergistic effect is showed, reduces dosage, together
When increase preventive effect.
Test example three:The field control effectiveness test of double third ring worm esters and buprofezin composition to Trialeurodes vaporariorum Westwood
Subjects:Trialeurodes vaporariorum Westwood
Test method:The test is carried out in Shandong Shouguang City, is experimental field cucumber booth.Investigation method is referring to national standard
Pesticide field trial criterion GB/T17980.16-2000 is carried out:Each cell pinpoints 15 plants of cucumber of label, in every plant of cucumber label
5, portion blade, the front and back sides borer population of index blade is investigated in morning in the case where letting alone adult.Cell uses random district's groups
Design, each cell setting protection row, each processing are repeated 4 times.Radix is counted before medicine, 2d, 7d, 20d are similarly square after application
Method investigates the residual borer population of each cell, calculates preventive effect and sees whether phytotoxicity.Test medicine is embodiment six, comparison medicine
Agent is 8% couple third ring worm ester WG, 24% Buprofezin WG, is provided by Jiangxi Zheng Bang biochemical industry Co., Ltd.
Drug effect calculation method:
Total borer population × 100 before Revision insect recluced rate (%)=(insect population-residual borer population living before medicine)/medicine
Preventive effect (%)=(treatment region Revision insect recluced rate-check plot Revision insect recluced rate)/(check plot 100- Revision insect recluced rate)
×100
Test result:
3 pairs of the third ring worm esters of table and buprofezin composition prevention and treatment Trialeurodes vaporariorum Westwood effect each preventive effect of test result are average value, no
Significant difference (lowercase p < 0.05, capitalization the p < 0.01) under duncan Multiple range test is indicated with letter
The composition of embodiment six has outstanding preventive effect to Trialeurodes vaporariorum Westwood as can be seen from Table 3, and field rate is
10, good control effect is all had to trialeurodes vaporariorum when 15,20g/ mus, when wherein the composition dosage of embodiment six is 20g/ mus
2 after medicine, 7, the preventive effect of 20d be respectively 89.47%, 96.49% and 95.66%, good quick-acting and lasting effect is showed, with list
Agent is compared, and dosage is reduced, and increases control efficiency, and performance the composition has good synergistic effect.
Test example four:The field control effectiveness test of double third ring worm esters and buprofezin composition to citrus icerya purchasi
Subjects:Icerya purchasi
Test method:It tests and carries out in Guangxi Yongfu city, the testing site of selection is the sugar orange garden of 6 years age of trees, test side
Method is referring to national standard pesticide field trial criterion GB/T17980.12-2000.Radix investigation, each cell each tree before being administered
In all directions, four direction randomly selects 1 year or biennial young sprout, investigates the borer population on 20 branches altogether, and radix is answered before medicine
It is corrected with natural mortality rate (insect-taking carries out microscopy calculating and obtains outside enumeration district).5d, 10d, 20d are directly carried out after application
Microscopy records worm age and dead borer population, calculates Revision insect recluced rate and control efficiency.Cell uses RANDOMIZED BLOCK DESIGN, each cell
Setting protection row, a cell include 4 trees, and each chemicals treatment is repeated 4 times.Test medicine is embodiment one, comparison medicament
For 10% couple third ring worm ester SC, 10% Buprofezin SC, provided by Jiangxi Zheng Bang biochemical industry Co., Ltd.
Drug effect calculation method:
Total borer population × 100 before Revision insect recluced rate (%)=(insect population-residual borer population living before medicine)/medicine
Preventive effect (%)=(treatment region Revision insect recluced rate-check plot Revision insect recluced rate)/(check plot 100- Revision insect recluced rate)
×100
Test result:
4 pairs of the third ring worm esters of table and buprofezin composition are average to each preventive effect of the field control effectiveness test result of citrus icerya purchasi
Value, different letters indicate significant difference (lowercase p < 0.05, capitalization the p < 0.01) under duncan Multiple range test
Embodiment a pair of citrus icerya purchasi has preferable control efficiency, while the group of embodiment one as can be seen from Table 4
Close object 5 under diluting 1000-3000 times of concentration, 10, the preventive effect of 20d is superior to two single dose singles when preventive effect, composition
Dilute 5 under 3000 times of dosages, 10, the preventive effect of 20d be respectively 82.47%, 93.41% and 96.43%, compared with single dose, increase
Control efficiency, reduces dosage, and performance the composition has good synergistic effect, illustrate pair third ring worm ester and Buprofezin
There is apparent synergistic effect after compounding according to a certain percentage, rather than simple summation action, have in agricultural production compared with
Big application value.
Claims (7)
1. a kind of insecticide composition containing double third ring worm esters and Buprofezin, it is characterised in that:It is double comprising the first effective component
The weight fraction ratio of third ring worm ester and the second effective component Buprofezin, double third ring worm esters and Buprofezin is 10: 1~1: 20.
2. a kind of insecticide composition containing double third ring worm esters and Buprofezin according to claim 1, it is characterised in that:
The weight fraction ratio of double third ring worm esters and Buprofezin is 3: 1~1: 5.
3. a kind of insecticide composition containing double third ring worm esters and Buprofezin according to claim 1, it is characterised in that:
The weight of double third ring worm esters and Buprofezin and in the composition total weight percentage composition are 2%-90%, remaining is allows on pesticide
Auxiliary agent.
4. a kind of insecticide composition containing double third ring worm esters and Buprofezin according to claim 3, it is characterised in that:
The weight of double third ring worm esters and Buprofezin and in the composition total weight percentage composition are 10%-48%.
5. a kind of insecticide composition containing double third ring worm esters and Buprofezin according to claim 1, feature exist
In:The dosage form of composition is one of suspending agent, missible oil, aqueous emulsion, microemulsion, wettable powder, water dispersible granules.
6. a kind of insecticide composition containing double third ring worm esters and Buprofezin according to any one of claim 1 to 5,
It is characterized in that:Suitable for the homoptera pest prevention and treatment on crops.
7. a kind of insecticide composition containing double third ring worm esters and Buprofezin according to claim 6, it is characterised in that:
The homoptera pest includes aleyrodid, planthopper, aphid, leafhopper, wood louse, coccid.
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CN115968900A (en) * | 2019-06-25 | 2023-04-18 | 江苏龙灯化学有限公司 | Insecticidal composition |
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