CN108842445B - 防泼水涤棉磨毛织物的制备方法 - Google Patents

防泼水涤棉磨毛织物的制备方法 Download PDF

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CN108842445B
CN108842445B CN201810890718.0A CN201810890718A CN108842445B CN 108842445 B CN108842445 B CN 108842445B CN 201810890718 A CN201810890718 A CN 201810890718A CN 108842445 B CN108842445 B CN 108842445B
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polyester
cloth
fabric
cotton
rinsing
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CN108842445A (zh
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白莉
王义栋
任晓晖
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Shishi Zhanyao Textile Technology Co ltd
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Abstract

本发明公开了一种防泼水涤棉磨毛织物的制备方法，属于面料领域。本发明的防泼水涤棉磨毛织物的制备方法，包括如下步骤：织造坯布、冷堆、漂洗、碳磨、回煮、染色、皂洗、防水处理、柔软处理及一次烘干处理和二次烘干。本发明制得的防泼水涤棉磨毛织物，其纤维强度高，防水性能优异，具有很强的色牢度，使用寿命长。

Description

防泼水涤棉磨毛织物的制备方法
技术领域
本发明属于面料技术领域，具体涉及一种防泼水涤棉磨毛织物的制备方法。
背景技术
近年来，科学技术更新速度越来越快，人们的生活水平越来越高，现代社会的人们越来越追求时尚，尤其是00后，在现代网络发达的环境中，追求个性张扬，对随身用品都有比较高的追求。越来越多的人喜欢多性能且具有美观性的纺织品，而常见的起毛织物其防水性能不佳，且起毛后容易成球状，影响织物美观性，使用寿命不长。
因此，需要一种制备工艺简便单，防水性佳、起毛效果好、纤维强度高、色牢度强、且含氟量符合欧盟“REACH”法案的涤棉磨毛织物。
发明内容
本发明的目的在于克服现有技术的不足，提供一种制备工艺流程简单，制得的涤棉磨毛织物具有高效防水性，且起毛效果好，纤维强度高，色牢度强。
本发明采用如下技术方案：
防泼水涤棉磨毛织物的制备方法，包括如下步骤：
步骤一、织造坯布：
将涤棉混纺纱进行织造，得涤棉织物；
步骤二、冷堆：
将步骤一所得涤棉织物进行冷堆，得冷堆坯布；
步骤三、漂洗：
将步骤二所得冷堆坯布进行漂洗，得漂洗布；
步骤四、碳磨：
将步骤三所得漂洗布进行碳磨，得碳磨布；
步骤五、回煮：
将步骤四所得碳磨布进行回煮，得回煮布；
步骤六、染色：
将步骤五所得回煮布进行染色，得染色布；
步骤七、皂洗：
将步骤六所得染色布进行皂洗，得皂洗布；
步骤八、防水处理：
将步骤七所得皂洗布进行防水处理，得防水坯布；
步骤九、柔软处理及一次烘干处理：
将步骤八所得防水坯布进行坯布整理，然后对整理后的坯布进行柔软处理，得柔软坯布；最后进行一次烘干，得一次烘干坯布；
步骤十、二次烘干：
将步骤九所得一次烘干坯布进行二次烘干处理，冷却后得防泼水涤棉磨毛织物。
进一步的，步骤二所述冷堆温度为30～35℃，冷堆时间为10～12h，其中，冷堆助剂包括按照水量计的如下组份：甲基丙烯酸缩水甘油酯4～7g/L，辛酸癸酸聚乙二醇甘油酯2～3g/L，醋酸2～3g/L。
进一步的，步骤三所述漂洗过程中，漂洗温度为50～65℃，漂洗时间为1～2h，漂洗时采用清水进行漂洗，所述冷堆坯布沿着同个方向搅动，搅动速率为100～150r/min。
进一步的，步骤四所述碳磨过程中，采用6～8根碳磨棍和1～2根砂磨棍，车速为28～30m/min，所述碳磨过程中，所述碳磨棍和所述砂磨棍外表面均涂覆起毛剂，所述起毛剂包括按照质量份数计的如下组份：磷酸单乙酯8～12份，聚乙烯醇3～4份，八甲基环四硅氧烷6～8份，去离子水30～35份。
进一步的，步骤五所述回煮过程中，采用清水回煮，所述回煮的温度为50～60℃，所述回煮的时间为30～35min。
进一步的，步骤八所述防水处理过程如下：将所得皂洗布置于防水液中浸渍2～3s，然后进行浸轧，轧余率为4.3～4.5％，最后进行一次烘干；其中，所述防水液包括按照水量计的如下组份：交联剂8～10g/L，有机硅油20～24g/L，车速25～28m/min，所述一次烘干温度为160～180℃。
进一步的，所述交联剂包括按照质量份数计的如下组份：3-甲基丙烯酰氧丙基甲基二乙氧基硅烷6～8份，木质素磺酸钠5～7份，水20～30份；所述有机硅油为聚二甲基硅氧烷。
进一步的，步骤九所述柔软处理时，是采用柔软剂进行柔软处理，柔软剂采用东莞市嘉宏有机硅科技有限公司的纺织柔软剂，型号Goon1260。
所述一次烘干过程，所述一次烘干温度为190～200℃，车速为28～30m/min；步骤十所述二次烘干过程，所述二次烘干温度为110～130℃，车速为28～30m/min。
进一步的，所述涤棉混纺纱包括按照质量百分比计的65～70％的涤纶纱和30～35％的棉纱。
本发明与现有技术相比，具有以下有益效果：
第一、本发明的防泼水涤棉磨毛织物的制备方法，在冷堆过程中，采用自主研发的冷堆助剂，由甲基丙烯酸缩水甘油酯、辛酸癸酸聚乙二醇甘油酯和醋酸组成，甲基丙烯酸缩水甘油酯作为纤维处理剂，和辛酸癸酸聚乙二醇甘油酯和醋酸混合使用后，对织物纤维具有很强的渗透性，且会在织物纤维外表面形成一层透气保护膜，可以有效防止织物在后续处理过程中被损坏；
第二、通过6～8根碳磨棍和1～2根砂磨棍进行磨毛，配合自主研发的起毛剂可以得到很好的起毛效果，其中，聚乙烯醇作为乳化剂，聚乙烯醇同磷酸单乙酯和八甲基环四硅氧烷进行复配，制得的改性硅油乳液对织物进行起毛处理，具有起毛时间短的效果；
第三、为了使得织物具有防泼水效果，通过使用自主研发的防水液进行处理，通过3-甲基丙烯酰氧丙基甲基二乙氧基硅烷作为粘合剂，木质素磺酸钠作为表面活性剂两者混合使用后形成具有高透气性的的粘合剂，配合有机硅油对织物进行防水处理，经过烘干后，得到的涤棉磨毛织物不仅具有很强的防泼水效果，而且透气性强，不易脱毛，延长织物的使用寿命。
第四、通过本发明的方法制得的织物在具有高防水性能的同时，未检测出PFOA(全氟辛烷磺酸盐)和PFOA(全氟辛酸)，符合欧盟“REACH”法案的要求。
具体实施方式
本发明所使用的原料均为市售品，其中：
3-甲基丙烯酰氧丙基甲基二乙氧基硅烷购自南京优普化工有限公司，型号65100-04-1；
柔软剂购自东莞市嘉宏有机硅科技有限公司的纺织柔软剂，型号Goon1260，品牌嘉宏科技。
实施例1
防泼水涤棉磨毛织物的制备方法，包括如下步骤：
步骤一、织造坯布：
将涤棉混纺纱进行织造，得涤棉织物，其中，所述涤棉混纺纱包括按照质量百分比计的65％的涤纶纱和35％的棉纱。
步骤二、冷堆：
将步骤一所得涤棉织物进行冷堆，得冷堆坯布，所述冷堆温度为30℃，冷堆时间为10h，其中，冷堆助剂包括按照水量计的如下组份：甲基丙烯酸缩水甘油酯4g/L，辛酸癸酸聚乙二醇甘油酯2g/L，醋酸2g/L。
步骤三、漂洗：
将步骤二所得冷堆坯布进行漂洗，得漂洗布；所述漂洗过程中，漂洗温度为50℃，漂洗时间为1h，漂洗时采用清水进行漂洗，所述冷堆坯布沿着同个方向搅动，搅动速率为100r/min。
步骤四、碳磨：
将步骤三所得漂洗布进行碳磨，得碳磨布，所述碳磨过程中，采用6根碳磨棍和1根砂磨棍，车速为28m/min，所述碳磨过程中，所述碳磨棍和所述砂磨棍外表面均涂覆起毛剂，所述起毛剂包括按照质量份数计的如下组份：磷酸单乙酯8份，聚乙烯醇3份，八甲基环四硅氧烷6份，去离子水30份。
步骤五、回煮：
将步骤四所得碳磨布进行回煮，得回煮布；所述回煮过程中，采用清水回煮，所述回煮的温度为50℃，所述回煮的时间为30min。
步骤六、染色：
将步骤五所得回煮布进行染色，得染色布。
步骤七、皂洗：
将步骤六所得染色布进行皂洗，得皂洗布。
步骤八、防水处理：
将步骤七所得皂洗布进行防水处理，得防水坯布；所述防水处理过程如下：将所得皂洗布置于防水液中浸渍2s，然后进行浸轧，轧余率为4.3％，最后进行一次烘干；其中，所述防水液包括按照水量计的如下组份：交联剂8g/L，有机硅油20g/L，车速25m/min，所述一次烘干温度为160℃。
所述交联剂包括按照质量份数计的如下组份：3-甲基丙烯酰氧丙基甲基二乙氧基硅烷6份，木质素磺酸钠5份，水20份；所述有机硅油为聚二甲基硅氧烷。
步骤九、柔软处理及一次烘干处理：
将步骤八所得防水坯布进行坯布整理，然后对整理后的坯布进行柔软处理，得柔软坯布；最后进行一次烘干，得一次烘干坯布，所述一次烘干过程，所述一次烘干温度为190℃，车速为28m/min。
步骤十、二次烘干：
将步骤九所得一次烘干坯布进行二次烘干处理，冷却后得防泼水涤棉磨毛织物，所述二次烘干过程，所述二次烘干温度为110℃，车速为28m/min。
实施例2
防泼水涤棉磨毛织物的制备方法，包括如下步骤：
步骤一、织造坯布：
将涤棉混纺纱进行织造，得涤棉织物，所述涤棉混纺纱包括按照质量百分比计的70％的涤纶纱和30％的棉纱。
步骤二、冷堆：
将步骤一所得涤棉织物进行冷堆，得冷堆坯布，所述冷堆温度为33℃，冷堆时间为11h，其中，冷堆助剂包括按照水量计的如下组份：甲基丙烯酸缩水甘油酯5g/L，辛酸癸酸聚乙二醇甘油酯3g/L，醋酸3g/L。
步骤三、漂洗：
将步骤二所得冷堆坯布进行漂洗，得漂洗布；所述漂洗过程中，漂洗温度为60℃，漂洗时间为2h，漂洗时采用清水进行漂洗，所述冷堆坯布沿着同个方向搅动，搅动速率为130r/min。
步骤四、碳磨：
将步骤三所得漂洗布进行碳磨，得碳磨布，所述碳磨过程中，采用7根碳磨棍和2根砂磨棍，车速为30m/min，所述碳磨过程中，所述碳磨棍和所述砂磨棍外表面均涂覆起毛剂，所述起毛剂包括按照质量份数计的如下组份：磷酸单乙酯10份，聚乙烯醇4份，八甲基环四硅氧烷7份，去离子水33份。
步骤五、回煮：
将步骤四所得碳磨布进行回煮，得回煮布；所述回煮过程中，采用清水回煮，所述回煮的温度为55℃，所述回煮的时间为33min。
步骤六、染色：
将步骤五所得回煮布进行染色，得染色布。
步骤七、皂洗：
将步骤六所得染色布进行皂洗，得皂洗布。
步骤八、防水处理：
将步骤七所得皂洗布进行防水处理，得防水坯布；所述防水处理过程如下：将所得皂洗布置于防水液中浸渍2～3s，然后进行浸轧，轧余率为4.3～4.5％，最后进行一次烘干；其中，所述防水液包括按照水量计的如下组份：交联剂9g/L，有机硅油22g/L，车速26m/min，所述一次烘干温度为170℃。
所述交联剂包括按照质量份数计的如下组份：3-甲基丙烯酰氧丙基甲基二乙氧基硅烷7份，木质素磺酸钠6份，水25份；所述有机硅油为聚二甲基硅氧烷。
步骤九、柔软处理及一次烘干处理：
将步骤八所得防水坯布进行坯布整理，然后对整理后的坯布进行柔软处理，得柔软坯布；最后进行一次烘干，得一次烘干坯布，所述一次烘干过程，所述一次烘干温度为195℃，车速为30m/min。
步骤十、二次烘干：
将步骤九所得一次烘干坯布进行二次烘干处理，冷却后得防泼水涤棉磨毛织物，所述二次烘干过程，所述二次烘干温度为120℃，车速为30m/min。
实施例3
防泼水涤棉磨毛织物的制备方法，包括如下步骤：
步骤一、织造坯布：
将涤棉混纺纱进行织造，得涤棉织物，所述涤棉混纺纱包括按照质量百分比计的70％的涤纶纱和30％的棉纱。
步骤二、冷堆：
将步骤一所得涤棉织物进行冷堆，得冷堆坯布，所述冷堆温度为35℃，冷堆时间为12h，其中，冷堆助剂包括按照水量计的如下组份：甲基丙烯酸缩水甘油酯7g/L，辛酸癸酸聚乙二醇甘油酯3g/L，醋酸3g/L。
步骤三、漂洗：
将步骤二所得冷堆坯布进行漂洗，得漂洗布；所述漂洗过程中，漂洗温度为65℃，漂洗时间为2h，漂洗时采用清水进行漂洗，所述冷堆坯布沿着同个方向搅动，搅动速率为150r/min。
步骤四、碳磨：
将步骤三所得漂洗布进行碳磨，得碳磨布，所述碳磨过程中，采用8根碳磨棍和2根砂磨棍，车速为30m/min，所述碳磨过程中，所述碳磨棍和所述砂磨棍外表面均涂覆起毛剂，所述起毛剂包括按照质量份数计的如下组份：磷酸单乙酯12份，聚乙烯醇4份，八甲基环四硅氧烷8份，去离子水35份。
步骤五、回煮：
将步骤四所得碳磨布进行回煮，得回煮布；所述回煮过程中，采用清水回煮，所述回煮的温度为60℃，所述回煮的时间为35min。
步骤六、染色：
将步骤五所得回煮布进行染色，得染色布；所述回煮过程中，采用清水回煮，所述回煮的温度为60℃，所述回煮的时间为35min。
步骤七、皂洗：
将步骤六所得染色布进行皂洗，得皂洗布。
步骤八、防水处理：
将步骤七所得皂洗布进行防水处理，得防水坯布；所述防水处理过程如下：将所得皂洗布置于防水液中浸渍3s，然后进行浸轧，轧余率为4.5％，最后进行一次烘干；其中，所述防水剂包括按照水量计的如下组份：交联剂10g/L，有机硅油24g/L，车速28m/min，所述一次烘干温度为180℃。
所述交联剂包括按照质量份数计的如下组份：3-甲基丙烯酰氧丙基甲基二乙氧基硅烷8份，木质素磺酸钠7份，水30份；所述有机硅油为聚二甲基硅氧烷。
步骤九、柔软处理及一次烘干处理：
将步骤八所得防水坯布进行坯布整理，然后对整理后的坯布进行柔软处理，得柔软坯布；最后进行一次烘干，得一次烘干坯布，所述一次烘干过程，所述一次烘干温度为200℃，车速为30m/min。
步骤十、二次烘干：
将步骤九所得一次烘干坯布进行二次烘干处理，冷却后得防泼水涤棉磨毛织物，所述二次烘干过程，所述二次烘干温度为130℃，车速为30m/min。
将实施例1～3所得的防泼水涤棉磨毛织物进行性能检测，其中：
采用FZT 14023-2012涤(棉)纶防水透湿雨衣面料，选择的织物质量为130g/m3，并对其透气率、表面抗湿性-沾水等级、色牢度进行测试；
采用BS EN24920:1992喷淋法测试防水级别；
有机溶剂萃取和液相色谱质谱分析测试PFOA(全氟辛烷磺酸盐)和PFOA(全氟辛酸)的含量；
检测结果如下表1；
表1：实施例1～3制得的防泼水涤棉磨毛织物的检测结果：
Figure BDA0001756886960000081
从表1中可以看出，用本发明的制作方法制得的防泼水涤棉磨毛织物断裂强度达到径向610N，纬向480N，撕裂强度达到径向21N，纬向17N，断裂延伸率达到径向15％，纬向14％，织物纤维强度高，透气性达到1.2mm/s，具有较强的透气性能，且防水级别达到了4级，在完全不影响防水性能的同时，未检测出PFOA(全氟辛烷磺酸盐)和PFOA(全氟辛酸)，符合欧盟“REACH”法案的要求。不仅如此，织物耐水洗色牢度、耐汗渍色牢度和耐摩擦色牢度均达到了4级，具有很强的色牢度，使用寿命长。
以上所述是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也视为本发明的保护范围。

Claims (6)

1.防泼水涤棉磨毛织物的制备方法，其特征在于，包括如下步骤：
步骤一、织造坯布：
将涤棉混纺纱进行织造，得涤棉织物；
所述涤棉混纺纱为30英支涤棉混纺纱，所述涤棉混纺纱包括按照质量百分比计的65~70%的涤纶纱和30~35%的棉纱；
步骤二、冷堆：
将步骤一所得涤棉织物进行冷堆，得冷堆坯布；
所述冷堆温度为30~35℃，冷堆时间为10~12h，其中，冷堆助剂包括按照水量计的如下组份：甲基丙烯酸缩水甘油酯4~7g/L，辛酸癸酸聚乙二醇甘油酯2~3 g/L，醋酸2~3 g/L；
步骤三、漂洗：
将步骤二所得冷堆坯布进行漂洗，得漂洗布；
步骤四、碳磨：
将步骤三所得漂洗布进行碳磨，得碳磨布；
所述碳磨过程中，采用6~8根碳磨棍和1~2根砂磨棍，车速为28~30m/min，所述碳磨过程中，所述碳磨棍和所述砂磨棍外表面均涂覆起毛剂，所述起毛剂包括按照质量份数计的如下组份：磷酸单乙酯8~12份，聚乙烯醇3~4份，八甲基环四硅氧烷6~8份，去离子水30~35份；
步骤五、回煮：
将步骤四所得碳磨布进行回煮，得回煮布；
步骤六、染色：
将步骤五所得回煮布进行染色，得染色布；
步骤七、皂洗：
将步骤六所得染色布进行皂洗，得皂洗布；
步骤八、防水处理：
将步骤七所得皂洗布进行防水处理，得防水坯布；
步骤九、柔软处理及一次烘干处理：
将步骤八所得防水坯布进行坯布整理，然后对整理后的坯布进行柔软处理，得柔软坯布；最后进行一次烘干，得一次烘干坯布；
步骤十、二次烘干：
将步骤九所得一次烘干坯布进行二次烘干处理，冷却后得防泼水涤棉磨毛织物。
2.根据权利要求1所述的防泼水涤棉磨毛织物的制备方法，其特征在于，步骤三所述漂洗过程中，漂洗温度为50~65℃，漂洗时间为1~2h，漂洗时采用清水进行漂洗，所述冷堆坯布沿着同个方向搅动，搅动速率为100~150r/min。
3.根据权利要求1所述的防泼水涤棉磨毛织物的制备方法，其特征在于，步骤五所述回煮过程中，采用清水回煮，所述回煮的温度为50~60℃，所述回煮的时间为30~35min。
4.根据权利要求1所述的防泼水涤棉磨毛织物的制备方法，其特征在于，步骤八所述防水处理过程如下：将所得皂洗布置于防水液中浸渍2~3s，然后进行浸轧，轧余率为4.3~4.5%，最后进行一次烘干；其中，所述防水液包括按照水量计的如下组份：交联剂8~10g/L，有机硅油20~24g/L，车速25~28m/min，所述一次烘干温度为160~180℃。
5.根据权利要求4所述的防泼水涤棉磨毛织物的制备方法，其特征在于，所述交联剂包括按照质量份数计的如下组份：3-甲基丙烯酰氧丙基甲基二乙氧基硅烷6~8份，木质素磺酸钠5~7份，水20~30份；所述有机硅油为聚二甲基硅氧烷。
6.根据权利要求1所述的防泼水涤棉磨毛织物的制备方法，其特征在于，步骤九所述一次烘干过程，所述一次烘干温度为190~200℃，车速为28~30m/min；步骤十所述二次烘干过程，所述二次烘干温度为110~130℃，车速为28~30m/min。
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