CN108841420A - A kind of Microbial fuel synergy cleaning solution and preparation method thereof - Google Patents

A kind of Microbial fuel synergy cleaning solution and preparation method thereof Download PDF

Info

Publication number
CN108841420A
CN108841420A CN201810575458.8A CN201810575458A CN108841420A CN 108841420 A CN108841420 A CN 108841420A CN 201810575458 A CN201810575458 A CN 201810575458A CN 108841420 A CN108841420 A CN 108841420A
Authority
CN
China
Prior art keywords
microbial fuel
cleaning solution
synergy
raw material
dimethoxymethane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810575458.8A
Other languages
Chinese (zh)
Inventor
沈井然
魏正冠
沈楠
魏晨
祝康祥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Science and Technology Co Ltd
Original Assignee
Jiangsu Science and Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Science and Technology Co Ltd filed Critical Jiangsu Science and Technology Co Ltd
Priority to CN201810575458.8A priority Critical patent/CN108841420A/en
Publication of CN108841420A publication Critical patent/CN108841420A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/18—Use of additives to fuels or fires for particular purposes use of detergents or dispersants for purposes not provided for in groups C10L10/02 - C10L10/16
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

A kind of Microbial fuel synergy cleaning solution, selects a variety of oxidizing combustibles and is aided with multi-functional composite additive and be formulated for primary raw material；The raw material weight proportioning of soup processed：Microbial fuel 50~85, dimethoxymethane 10~30, dimethyl carbonate 10~30, multi-functional composite additive 5~10.Compared with regular gasoline is used alone, CO discharge amount declines 30~50, HC discharge amount and declines 30~50, NO for the use of Microbial fuel synergy cleaning solutionxDischarge amount decline 10~20, exhaust gas purifying liquid is free of benzene, not olefin-containing, not sulfur-bearing, itself is oxygen-containing, using especially advantageous under the anaerobic environments such as plateau.

Description

A kind of Microbial fuel synergy cleaning solution and preparation method thereof
Technical field
The present invention is to be related to a kind of novel Microbial fuel synergy cleaning solution and preparation method.
Background technique
In modern civilization, automobile has become the indispensable transport facility of the mankind.But in automobile industry height While speed development, auto output and ownership are continuously increased, automobile also brings atmosphere pollution, i.e. automobile exhaust pollution.Section Learn analysis shows, containing hundreds of different compound in vehicle exhaust, wherein main pollutant has solid aerosol, one Carbonoxide, carbon dioxide, hydrocarbon, oxynitrides, lead and oxygen sulfur compound etc..
Automobile engine is energy conversion device and power occurring source.During fuel combustion is converted into power, with sky Gas is oxidant, in addition to CO after fuel combustion2And H2Outside O, there are also CO, uncombusted hydrocarbon (HC) and high-temp combustions When the NO that generatesxEqual pernicious gases.The main source of atmosphere pollution is the discharge of motor-vehicle tail-gas, short time in China city Automobile quantity steeply rises, and is the one of the major reasons for causing national extensive haze weather to occur.Confirmed PM2.5, The main source that PM10 is generated is that daily power generation, industrial production, motor vehicle exhaust emission etc. are discharged residual by burning in the process Stay object.
The novel Microbial fuel synergy cleaning solution of the applicant's research with a variety of oxidizing combustibles and is aided with multi-functional multiple Additive is closed to be formulated for primary raw material.Using the relevant technical indicator of country, controlled by strict measurement, through multiple working procedure It deploys.It is noted that the main material " Microbial fuel " of synergy cleaning solution is the product of an environment-friendly engineering, it is tight Industrial water after heavily contaminated is obtained by special fermentation process.Raw material is trade effluent, product " microorganism combustion Material ", then use and administer in the product of tail gas pollution.This is a spotlight of this product.
To meet in the market to the material requisite during environmental protection, my company has specially developed cleaning solution, is used for vapour The purification of oil machine vehicle emission.Existing treating vehicle exhaust can be summarized as emission controls by improving combustion and external purification two major classes.But vapour The improvement of tail gas pollution is a great system engineering, it is necessary to outside the emission controls by improving combustion and machine of existing treating vehicle exhaust This link of fuel optimization is added in purification.So-called fuel optimization, it is not simply modify and using clear to fuel oil Clean fuel, but new theory and technology are used, fuel oil is transformed.Under the premise of not needing to change vehicle, make existing The discharge amount of pollutant in tail gas is greatly lowered in vehicle operation.
Novel exhaust gas purifying liquid can greatly reduce the discharge amount of vehicle exhaust.CO discharge amount declines 30~50, HC discharge 30~50, NO of amount declinexDischarge amount decline 10~20.Exhaust gas purifying liquid is free of benzene, not olefin-containing, not sulfur-bearing, unregulated exhaust Object is also better than Fuel Petroleum.
Tail gas cleaning solution is deployed by a variety of oxygen-enriched substances and micro functional additive.With tail gas cleaning solution come Optimize fuel oil, so that the harmful substance sharp fall after burning, to reach the target for administering automobile exhaust pollution, this is one A good selection.
(1) density:It to be controlled.It is significant to the metering of oil used in fuel, while being estimated that the dosage of each raw material, Or it can be seen that the quality problems when batch raw material.
(2) moisture content:It is not only to guarantee the fuel important finger that evaporation gasifies and burns rapidly in engine chamber Mark.Importantly, moisture content height can accelerate to corrosion of metal.First is that moisture content can directly cause the chemistry of metal and electrochemistry rotten Erosion；Second is that certain acidic materials are soluble in water in fuel, accelerate corrosion of metal process.
(3) flash-point (silent):The flash-point of tail gas cleaning solution is the index for controlling tail gas cleaning solution vapo(u)rability, is also to ensure that The index of tail gas cleaning solution safety.For conventional fuel, its low vapo(u)rability of flash-point is good.But the flash-point of conventional fuel is not yet Preferably too low, flash-point is low, and vapo(u)rability is strong, the combustion process in cylinder can be made excessively fierce, so that the working condition of engine is lost It controls, is unstable, and the safety of fuel during transportation is reduced.Flash-point is high, will cause vehicle sparking in winter not Spirit.Therefore the flash-point of tail gas cleaning solution must be moderate.
(4) copper strip test:Test objective is that judge that tail gas cleaning solution has metal non-corrosive.Important item controlled. Also reflect the superiority and inferiority degree of product quality.
(5) sodium content:It is a project of keeping under strict control.Na salt corresponding with metal function generation, deposition can add in a device Fast mechanical abrasion.When containing in a small amount of moisture content in fuel, to the corrosion that aluminium and aluminium alloy have Strong strong, it can be with aluminium and aluminium alloy The aluminum oxide film film reaction on surface generates NaAlO2, newly exposed metallic aluminium is then easy and the moisture content effect in fuel, generation glue The Al (OH) of shape3Precipitating influences engine very big.
Al2O3+2NaOH——→2NaAlO2+H2O
(6) sulfur content:Sulphur-containing substance in tail gas cleaning solution is mainly brought by functional additive, based on organic sulfur. But it was found that can then reflect the quality problems of the functional additive used when sulfur content is abnormal.Sulfur content is low, possible function Property additive effective content it is insufficient；Sulfur content is high, then the quality of possible functional additive is problematic.
The organic sewage that Microbial fuel refers in particular to as high concentration, by obtained after special biochemical treatment it is a kind of environmental protection, Clean green energy resource.With the surge and sustained economic development of big city population, trade effluent and sanitary sewage is caused to discharge Amount increasingly increases, these organic sewages have the feature of high toxicity, high pollution, high organic matter.And it is complex in composition, amount it is huge. The Microbial fuel obtained after special biochemical treatment, essence are a kind of mixing fusels, can become a kind of good alcohol fuel, Because the amount of its organic sewage is huge, this good Microbial fuel is also a kind of very important alternative energy source.Develop this Alternative energy source is the Major Strategic for ensureing national energy security, mitigating petroleum import pressure, alleviating resource and environmental constraints Behave.The development of this novel Microbial fuel synergy cleaning solution, first is that in order to solve the problems, such as resource scarcity；Second is that in order to Mitigate pollution of the automotive emission to atmosphere；Third is that be high-quality using being obtained after biochemical treatment organic sewage on a large scale Alcohol fuel seeks optimal outlet.
Summary of the invention
The object of the present invention is to propose that formula of liquid and preparation method are cleaned in a kind of novel Microbial fuel synergy.
Technical solution of the present invention：A kind of Microbial fuel synergy cleaning solution selects a variety of oxidizing combustibles and is aided with more function Energy compound additive is formulated for primary raw material；The raw material weight proportioning of soup processed：Microbial fuel 50~85, dimethoxymethane 10~30, dimethyl carbonate 10~30, multi-functional composite additive 5~10.
Optimization formula 1 of the invention, raw material are formulated by the mixing of following weight proportion:Microbial fuel 60, two Methoxyl group methane 25, dimethyl carbonate 12, multi-functional composite additive 3.
Optimization formula 2 of the invention, raw material are formulated by the mixing of following weight proportion:Microbial fuel 70, two Methoxyl group methane 15, dimethyl carbonate 11, multi-functional composite additive 4.
Optimization formula 3 of the invention, raw material are formulated by the mixing of following weight proportion:Microbial fuel 75, two Methoxyl group methane 10, dimethyl carbonate 11, multi-functional composite additive 4.
In multi-functional composite additive of the invention, other auxiliary agents, including catalyst, corrosion inhibiter can be added, agent is melted in increasing Deng.
A kind of novel Microbial fuel synergy cleaning liquid and preparation method thereof, feature are stirring multi-functional composite additive In Microbial fuel under state plus after metering, dimethoxymethane and dimethyl carbonate are added after 30min, continues to stir Stop stirring after 30min, obtains the compounded Microbial fuel synergy cleaning solution of white to light yellow transparent liquid after filtering.
It is mainly studied in following several respects for Microbial fuel synergy cleaning solution applicant：
(1) several inherent quality standards of Microbial fuel synergy cleaning solution, mainly by several primary raw materials allotment and At.Such as density, moisture content, flash-point (silent), evaporation residue.
(2) to the research of additive.Certain performances of Microbial fuel synergy cleaning solution, being can be functional by being added Additive and improved.What is more concentrated is copper corrosion etc..
(3) several external quality standards of Microbial fuel synergy cleaning solution, are that can pass through technology controlling and process if appearance Come what is realized.
(4) to the research of Microbial fuel synergy cleaning solution application aspect.
For the multi-functional composite additive of Microbial fuel synergy cleaning solution, formula is：Dimethyl carbonate 40~80, Ethyl alcohol 10~40, butanol 10~40, glycerol 5~30, Methanol/Vegetable Oil acid soap 2~20, stearate 0.5~5, BTA0.1~3, TTA0.1~3, T5010.1~3, T502A0.1~3, M0.1~3, octylated diphenylamine 0.5~5.The a variety of materials are passed through It heats and is sufficiently stirred, obtain the compounded compound additive of pale yellow transparent after filtering.
Beneficial effect：The present invention is a kind of new vehicle environmental supplies, dedicated for the purification of gasoline locomotive emission. Exhaust gas purifying liquid is promoted the use of, the discharge amount of vehicle exhaust can be greatly reduced.Normal use accounts for fuel oil weight (gasoline or bavin Oil, especially gasoline) 20%, can be dissolved each other with national standard oil with arbitrary proportion, it is not stratified, non-discolouring.Microbial fuel synergy is clear The use of clean liquid can bring good environmental benefit and economic benefit.Compared with regular gasoline is used alone, the decline of CO discharge amount 30~50, HC discharge amount decline 30~50, NOxDischarge amount decline 10~20, Unregulated emissions are also better than Fuel Petroleum. The discharge amount of PM2.5 and PM10 can also decline 40~60.Exhaust gas purifying liquid is free of benzene, not olefin-containing, not sulfur-bearing, itself is oxygen-containing, Using especially advantageous under the anaerobic environments such as plateau.
Specific embodiment
It is further described below with reference to embodiment invention.
Implement:It is to be deployed by a variety of oxygen-enriched substances and micro functional additive.By multi-functional composite additive In Microbial fuel under stirring plus after metering, dimethoxymethane and dimethyl carbonate are added after 30min, continues to stir Stop stirring after mixing 30min, obtains white to the compounded Microbial fuel synergy of light yellow transparent liquid after filtering and clean Liquid.Also other auxiliary agents, including catalyst, corrosion inhibiter can be added in above-mentioned ingredient, agent etc. is melted in increasing.
Embodiment 1, raw material are formulated by the mixing of following weight proportion:Microbial fuel 60, dimethoxymethane 25, dimethyl carbonate 12, multi-functional composite additive 3.
Embodiment 2, raw material are formulated by the mixing of following weight proportion:Microbial fuel 70, dimethoxymethane 15, dimethyl carbonate 11, multi-functional composite additive 4.
Embodiment 3, raw material are formulated by the mixing of following weight proportion:Microbial fuel 75, dimethoxymethane 10, dimethyl carbonate 11, multi-functional composite additive 4.
Liquid product conventional detection data are cleaned in Microbial fuel synergy:

Claims (6)

1. a kind of Microbial fuel synergy cleaning solution, it is characterized in that selecting a variety of oxidizing combustibles and being aided with multi-functional composite additive It is formulated for primary raw material；The raw material weight proportioning of soup processed：Microbial fuel 50 ~ 85, dimethoxymethane 10 ~ 30, carbonic acid two Methyl esters 10 ~ 30, multi-functional composite additive 5 ~ 10.
2. Microbial fuel synergy cleaning solution according to claim 1, it is characterised in that its raw material presses following weight proportion Mixed preparing forms：Microbial fuel 60, dimethoxymethane 25, dimethyl carbonate 12, multi-functional composite additive 3.
3. Microbial fuel synergy cleaning solution according to claim 1, it is characterised in that its raw material presses following weight proportion Mixed preparing forms：Microbial fuel 70, dimethoxymethane 15, dimethyl carbonate 11, multi-functional composite additive 4.
4. Microbial fuel synergy cleaning solution according to claim 1, it is characterised in that its raw material presses following weight proportion Mixed preparing forms：Microbial fuel 75, dimethoxymethane 10, dimethyl carbonate 11, multi-functional composite additive 4.
5. Microbial fuel synergy cleaning solution according to claim 1, it is characterized in that other are added in the synergy cleaning solution Agent is melted in auxiliary agent, including catalyst, corrosion inhibiter, increasing.
6. the preparation method of Microbial fuel synergy cleaning solution described in one of -5 according to claim 1, feature will be multi-functional In Microbial fuel of the compound additive under stirring plus after metering, dimethoxymethane and carbonic acid two are added after 30min Methyl esters continues to stop stirring after stirring 30min, obtains white to the compounded microorganism of light yellow transparent liquid after filtering and fires Expect synergy cleaning solution.
CN201810575458.8A 2018-06-06 2018-06-06 A kind of Microbial fuel synergy cleaning solution and preparation method thereof Pending CN108841420A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810575458.8A CN108841420A (en) 2018-06-06 2018-06-06 A kind of Microbial fuel synergy cleaning solution and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810575458.8A CN108841420A (en) 2018-06-06 2018-06-06 A kind of Microbial fuel synergy cleaning solution and preparation method thereof

Publications (1)

Publication Number Publication Date
CN108841420A true CN108841420A (en) 2018-11-20

Family

ID=64210487

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810575458.8A Pending CN108841420A (en) 2018-06-06 2018-06-06 A kind of Microbial fuel synergy cleaning solution and preparation method thereof

Country Status (1)

Country Link
CN (1) CN108841420A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110408472A (en) * 2019-08-07 2019-11-05 深圳市车安达汽保设备有限公司 The formula and its manufacture craft of deodorization and sterilization purification cleaning solution
CN111944569A (en) * 2020-08-02 2020-11-17 南京沿江资源生态科学研究院有限公司 Oxygen-enriched additive for diesel locomotive fuel by using recovered alcohol as raw material and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110408472A (en) * 2019-08-07 2019-11-05 深圳市车安达汽保设备有限公司 The formula and its manufacture craft of deodorization and sterilization purification cleaning solution
CN111944569A (en) * 2020-08-02 2020-11-17 南京沿江资源生态科学研究院有限公司 Oxygen-enriched additive for diesel locomotive fuel by using recovered alcohol as raw material and preparation method thereof

Similar Documents

Publication Publication Date Title
CN108165326A (en) A kind of boiler methanol-based fuel
CN100510030C (en) Cleaning type combustion assistant for coal and oil
CN108841420A (en) A kind of Microbial fuel synergy cleaning solution and preparation method thereof
CN104178231B (en) High-flash-point alcohol ether diesel oil
CN101215484A (en) Methanol gasoline additive
CN1184146A (en) Fuel additive
CN112354343A (en) Ammonia-free organic liquid denitration agent and preparation method thereof
CN108822904A (en) A kind of Microbial fuel synergy cleaning solution compound additive formula and preparation method
CN103361134B (en) Additive for reducing PM2.5 emission of diesel engines and application of additive
CN102899099A (en) Alcohol ether gasoline for new energy vehicles
CN112646625A (en) Sludge briquette composition and preparation method thereof
CN105038873A (en) Alcohol-base diesel oil additive and preparation method of alcohol-base diesel oil
CN111394149B (en) High-efficiency dry-method coal-saving combined auxiliary agent for cement kiln and application thereof
CN101768478B (en) Vehicle low-carbon biodiesel
CN107892961B (en) Preparation method of environment-friendly gasoline additive
CN1257906A (en) Car tail gas purificant and its preparing process
CN104974804A (en) Preparation methods of alcohol base liquid fuel and alcohol base liquid fuel additive
CN106118796B (en) A method of preparing coal-based alcohol ether fuel adjunct using chemical byproduct
CN114011234B (en) Dry desulfurization method for treating low-temperature flue gas
CN107723040A (en) A kind of high efficiency composition combustion adjuvant and preparation method thereof
CN104789282B (en) Gasoline energy-saving cleaning liquid and preparation method thereof
CN109022065A (en) A kind of gasoline compounding agent
CN1912077A (en) Gasification combustion improver and its manufacturing method
CN116445191B (en) Preparation method of renewable alternative fuel
CN106118797B (en) A kind of coal-based alcohol ether fuel adjunct and its application based on chemical byproduct

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20181120