CN108841286A - A kind of wear resistant corrosion resistant coating material and preparation method thereof - Google Patents
A kind of wear resistant corrosion resistant coating material and preparation method thereof Download PDFInfo
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- CN108841286A CN108841286A CN201810493546.3A CN201810493546A CN108841286A CN 108841286 A CN108841286 A CN 108841286A CN 201810493546 A CN201810493546 A CN 201810493546A CN 108841286 A CN108841286 A CN 108841286A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The present invention discloses a kind of wear resistant corrosion resistant coating material, the component including following parts by weight:22-35 parts of epoxy resin, 6-12 parts of acrylic resin, 5-10 parts of ethyl orthosilicate, 6-11 parts of N- ethyl para toluene sulfonamide, 3-6 parts of nano magnesia, 5-11 parts of butyl maleate, 10-25 parts of isophorone diisocyanate, 2-5 parts of curing agent, 1-4 parts of aluminous cement.Wear resistant corrosion resistant coating material of the invention is to generate synergistic effect after mixing by epoxy resin, acrylic resin, ethyl orthosilicate, N- ethyl para toluene sulfonamide, nano magnesia, butyl maleate, isophorone diisocyanate, curing agent and aluminous cement to be made; the material is not likely to produce bubble; it is not easy to crack and fall off; and wear-resisting property and corrosion resistance effectively improve; it is widely portable to the every field of modern industry, for protecting workpiece not injured by high temperature, acid and alkali corrosion.
Description
Technical field
The present invention relates to a kind of coating materials, and in particular to a kind of wear resistant corrosion resistant coating material and its preparation
Method belongs to field of material technology.
Background technique
Coating is that obtained solid-state continuous film is once applied by coating, be in order to rise protection, insulation, decoration the effects of and
The plastic sheet being coated on the matrixes such as metal, fabric, plastics.Coated coating can be divided into gaseous state, liquid according to its state of matter
State and solid-state three types, the matrix sprayed as needed under normal conditions can determine the type and state of coating.
Modern industry, which usually requires workpiece, to work under the harsh operating condition such as high temperature, corrosion, therefore for workpiece
The requirement of material is also higher and higher, while implementing coating protection at the construction key position of workpiece, can be effectively protected workpiece, from
And save production cost.It is also easy to produce bubble, cracking is easy and falls off, wear-resisting property however, existing coating material still has
And the disadvantages of poor corrosion resistance.
Summary of the invention
Present invention aims at a kind of wear resistant corrosion resistant coating material in view of the deficiencies of the prior art, is provided, simultaneously
Preparation method is given, which, which has, is not likely to produce bubble, and not easy to crack and fall off, wear-resisting property and corrosion resistance are high
The advantages that.
In order to reach the goals above, the present invention provides a kind of wear resistant corrosion resistant coating material, the material include with
The component of lower parts by weight:22-35 parts of epoxy resin, 6-12 parts of acrylic resin, 5-10 parts of ethyl orthosilicate, N- ethyl is to first
6-11 parts of benzsulfamide, 3-6 parts of nano magnesia, 5-11 parts of butyl maleate, 10-25 parts of isophorone diisocyanate,
2-5 parts of curing agent, 1-4 parts of aluminous cement.
The technical solution of the present invention is further defined as coating material of the invention includes the component of following parts by weight:
25-32 parts of epoxy resin, 7-10 parts of acrylic resin, 6-9 parts of ethyl orthosilicate, 8-10 parts of N- ethyl para toluene sulfonamide is received
4-6 parts of magnesia of rice, 7-10 parts of butyl maleate, 14-22 parts of isophorone diisocyanate, 3-5 parts of curing agent, calcium aluminate
1-3 parts of cement.
Further, coating material of the invention includes the component of following parts by weight:30 parts of epoxy resin, acrylic acid tree
8 parts of rouge, 7 parts of ethyl orthosilicate, 9 parts of N- ethyl para toluene sulfonamide, 5 parts of nano magnesia, 9 parts of butyl maleate, different Buddhist
You have 20 parts of diisocyanate of ketone, 4 parts of curing agent, 2 parts of aluminous cement.
The present invention also provides a kind of preparation methods of wear resistant corrosion resistant coating material, include the following steps:
The first step weighs epoxy resin, acrylic resin, ethyl orthosilicate, N- ethyl according to above-mentioned formula to toluene sulphur
Amide, nano magnesia, butyl maleate, isophorone diisocyanate, curing agent and aluminous cement, it is spare;
Second step, extracting epoxy resin, acrylic resin, N- ethyl para toluene sulfonamide, butyl maleate and different Fo Er
After the mixing of ketone diisocyanate, it is stirred until homogeneous under the conditions of 55~85 DEG C of temperature, obtains mixture;
Third step adds ethyl orthosilicate, nano magnesia, curing agent and aluminous cement into mixture, 65~
Continue stirring to all raw materials under the conditions of 90 DEG C of temperature to be uniformly mixed, obtains coating material;
4th step, using ball mill to coating material carry out ball milling, make material refine and it is evenly dispersed, coating can be obtained
Finished material.
The beneficial effects of the invention are as follows:Wear resistant corrosion resistant coating material of the invention is by epoxy resin, propylene
Acid resin, ethyl orthosilicate, N- ethyl para toluene sulfonamide, nano magnesia, butyl maleate, isophorone diisocyanate
Synergistic effect is generated after ester, curing agent and aluminous cement mixing to be made, and enhances the wear-corrosion resistance of coating, the material
It is not likely to produce bubble, it is not easy to crack and fall off, and wear-resisting property and corrosion resistance effectively improve, and are broadly applicable
In the every field of modern industry, for protecting workpiece not injured by high temperature, acid and alkali corrosion.In addition, according to national standard GB23988-
The wearability of 2009 measurement coating of the present invention is 1358-1500L/ μm.
Specific embodiment
Technical solution of the present invention is described in detail below by embodiment, but protection scope of the present invention is not limited to
In the embodiment.
Material and reagent involved in following example are commercially available.
Epoxy resin is glycidyl ether type epoxy resin, glycidyl ester epoxy resin, glycidol amine epoxy
Resin, linear aliphatic epoxy resin, any one in alicyclic based epoxy resin.Such as bisphenol A epoxide resin.Solidification
Agent is curing agent commonly used in the art, such as polyamide.
Embodiment 1
A kind of wear resistant corrosion resistant coating material, the component including following parts by weight:22 parts of epoxy resin, acrylic acid
6 parts of resin, 5 parts of ethyl orthosilicate, 6 parts of N- ethyl para toluene sulfonamide is 3 parts of nano magnesia, 5 parts of butyl maleate, different
10 parts of isophorone diisocyanate, 2 parts of curing agent, 1 part of aluminous cement.
A kind of preparation method of wear resistant corrosion resistant coating material, includes the following steps:
The first step weighs 22 parts of epoxy resin according to weight, 6 parts of acrylic resins, 5 parts of ethyl orthosilicates, and 6 parts
N- ethyl para toluene sulfonamide, 3 parts of nano magnesias, 5 parts of butyl maleates, 10 parts of isophorone diisocyanate, 2 parts solid
Agent and 1 part of aluminous cement, it is spare;
Second step presses above-mentioned formula extracting epoxy resin, acrylic resin, N- ethyl para toluene sulfonamide, maleic acid only son
After ester and isophorone diisocyanate mixing, it is stirred until homogeneous under the conditions of 55 DEG C of temperature, obtains mixture;
Third step, by above-mentioned with adding ethyl orthosilicate, nano magnesia, curing agent and calcium aluminate water in the mixture of direction
Mud continues stirring to all raw materials under the conditions of 65 DEG C of temperature and is uniformly mixed, obtains coating material;
4th step carries out ball milling to coating material using ball mill, and coating material finished product can be obtained.
Embodiment 2
A kind of wear resistant corrosion resistant coating material, the component including following parts by weight:35 parts of epoxy resin, acrylic acid
12 parts of resin, 10 parts of ethyl orthosilicate, 11 parts of N- ethyl para toluene sulfonamide, 6 parts of nano magnesia, butyl maleate 11
Part, 25 parts of isophorone diisocyanate, 5 parts of curing agent, 4 parts of aluminous cement.
A kind of preparation method of wear resistant corrosion resistant coating material, includes the following steps:
The first step weighs 35 parts of epoxy resin according to weight, 12 parts of acrylic resins, 10 parts of ethyl orthosilicates,
11 parts of N- ethyl para toluene sulfonamides, 6 parts of nano magnesias, 11 parts of butyl maleates, 25 parts of isophorone diisocyanate,
5 parts of curing agent and 4 parts of aluminous cements, it is spare;
Second step presses above-mentioned formula extracting epoxy resin, acrylic resin, N- ethyl para toluene sulfonamide, maleic acid only son
After ester and isophorone diisocyanate mixing, it is stirred until homogeneous under the conditions of 85 DEG C of temperature, obtains mixture;
Third step, by above-mentioned with adding ethyl orthosilicate, nano magnesia, curing agent and calcium aluminate water in the mixture of direction
Mud continues stirring to all raw materials under the conditions of 90 DEG C of temperature and is uniformly mixed, obtains coating material;
4th step carries out ball milling to coating material using ball mill, and coating material finished product can be obtained.
Embodiment 3
A kind of wear resistant corrosion resistant coating material, the component including following parts by weight:30 parts of epoxy resin, acrylic acid
8 parts of resin, 7 parts of ethyl orthosilicate, 9 parts of N- ethyl para toluene sulfonamide is 5 parts of nano magnesia, 9 parts of butyl maleate, different
20 parts of isophorone diisocyanate, 4 parts of curing agent, 2 parts of aluminous cement.
A kind of preparation method of wear resistant corrosion resistant coating material, includes the following steps:
The first step weighs 30 parts of epoxy resin according to weight, 8 parts of acrylic resins, 7 parts of ethyl orthosilicates, and 9 parts
N- ethyl para toluene sulfonamide, 5 parts of nano magnesias, 9 parts of butyl maleates, 20 parts of isophorone diisocyanate, 4 parts solid
Agent and 2 parts of aluminous cements, it is spare;
Second step presses above-mentioned formula extracting epoxy resin, acrylic resin, N- ethyl para toluene sulfonamide, maleic acid only son
After ester and isophorone diisocyanate mixing, it is stirred until homogeneous under the conditions of 75 DEG C of temperature, obtains mixture;
Third step, by above-mentioned with adding ethyl orthosilicate, nano magnesia, curing agent and calcium aluminate water in the mixture of direction
Mud continues stirring to all raw materials under the conditions of 80 DEG C of temperature and is uniformly mixed, obtains coating material;
4th step carries out ball milling to coating material using ball mill, and coating material finished product can be obtained.
Embodiment 4
A kind of wear resistant corrosion resistant coating material, the component including following parts by weight:25 parts of epoxy resin, acrylic acid
7 parts of resin, 6 parts of ethyl orthosilicate, 8 parts of N- ethyl para toluene sulfonamide is 4 parts of nano magnesia, 7 parts of butyl maleate, different
14 parts of isophorone diisocyanate, 3 parts of curing agent, 1 part of aluminous cement.
A kind of preparation method of wear resistant corrosion resistant coating material, includes the following steps:
The first step weighs 25 parts of epoxy resin according to weight, 7 parts of acrylic resins, 6 parts of ethyl orthosilicates, and 8 parts
N- ethyl para toluene sulfonamide, 4 parts of nano magnesias, 7 parts of butyl maleates, 14 parts of isophorone diisocyanate, 3 parts solid
Agent and 1 part of aluminous cement, it is spare;
Second step presses above-mentioned formula extracting epoxy resin, acrylic resin, N- ethyl para toluene sulfonamide, maleic acid only son
After ester and isophorone diisocyanate mixing, it is stirred until homogeneous under the conditions of 60 DEG C of temperature, obtains mixture;
Third step, by above-mentioned with adding ethyl orthosilicate, nano magnesia, curing agent and calcium aluminate water in the mixture of direction
Mud continues stirring to all raw materials under the conditions of 72 DEG C of temperature and is uniformly mixed, obtains coating material;
4th step carries out ball milling to coating material using ball mill, and coating material finished product can be obtained.
Embodiment 5
A kind of wear resistant corrosion resistant coating material, the component including following parts by weight:32 parts of epoxy resin, acrylic acid
10 parts of resin, 9 parts of ethyl orthosilicate, 10 parts of N- ethyl para toluene sulfonamide, 6 parts of nano magnesia, 10 parts of butyl maleate,
22 parts of isophorone diisocyanate, 5 parts of curing agent, 3 parts of aluminous cement.
A kind of preparation method of wear resistant corrosion resistant coating material, includes the following steps:
The first step weighs 32 parts of epoxy resin according to weight, 10 parts of acrylic resins, 9 parts of ethyl orthosilicates, and 10
Part N- ethyl para toluene sulfonamide, 6 parts of nano magnesias, 10 parts of butyl maleates, 22 parts of isophorone diisocyanate, 5
Part curing agent and 3 parts of aluminous cements, it is spare;
Second step presses above-mentioned formula extracting epoxy resin, acrylic resin, N- ethyl para toluene sulfonamide, maleic acid only son
After ester and isophorone diisocyanate mixing, it is stirred until homogeneous under the conditions of 80 DEG C of temperature, obtains mixture;
Third step, by above-mentioned with adding ethyl orthosilicate, nano magnesia, curing agent and calcium aluminate water in the mixture of direction
Mud continues stirring to all raw materials under the conditions of 82 DEG C of temperature and is uniformly mixed, obtains coating material;
4th step carries out ball milling to coating material using ball mill, and coating material finished product can be obtained.
Embodiment 6
A kind of wear resistant corrosion resistant coating material, the component including following parts by weight:32 parts of epoxy resin, acrylic acid
7 parts of resin, 9 parts of ethyl orthosilicate, 7 parts of N- ethyl para toluene sulfonamide, 5.5 parts of nano magnesia, butyl maleate 6.2
Part, 22 parts of isophorone diisocyanate, 2.5 parts of curing agent, 3.4 parts of aluminous cement.
A kind of preparation method of wear resistant corrosion resistant coating material, includes the following steps:
The first step weighs 32 parts of epoxy resin according to weight, 7 parts of acrylic resins, 9 parts of ethyl orthosilicates, and 7 parts
N- ethyl para toluene sulfonamide, 5.5 parts of nano magnesias, 6.2 parts of butyl maleates, 22 parts of isophorone diisocyanate,
2.5 parts of curing agent and 3.4 parts of aluminous cements, it is spare;
Second step presses above-mentioned formula extracting epoxy resin, acrylic resin, N- ethyl para toluene sulfonamide, maleic acid only son
After ester and isophorone diisocyanate mixing, it is stirred until homogeneous under the conditions of 58 DEG C of temperature, obtains mixture;
Third step, by above-mentioned with adding ethyl orthosilicate, nano magnesia, curing agent and calcium aluminate water in the mixture of direction
Mud continues stirring to all raw materials under the conditions of 88 DEG C of temperature and is uniformly mixed, obtains coating material;
4th step carries out ball milling to coating material using ball mill, and coating material finished product can be obtained.
Embodiment 7
To embodiment 1-6 preparation wear resistant corrosion resistant coating material be tested for the property, obtain wear rate result with
And the corrosion resistance under acid-base condition, result are as shown in the table:
As seen from the above table, wear resistant corrosion resistant coating material abrasion resistance properties of the invention and acid-alkali-corrosive-resisting performance compared with
It is good.
As described above, must not be explained although the present invention has been indicated and described referring to specific preferred embodiment
For the limitation to invention itself.It without prejudice to the spirit and scope of the invention as defined in the appended claims, can be right
Various changes can be made in the form and details for it.
In addition to the implementation, the present invention can also have other embodiments.It is all to use equivalent substitution or equivalent transformation shape
At technical solution, fall within the scope of protection required by the present invention.
Claims (4)
1. a kind of wear resistant corrosion resistant coating material, which is characterized in that the material includes the component of following parts by weight:Epoxy
22-35 parts of resin, 6-12 parts of acrylic resin, 5-10 parts of ethyl orthosilicate, 6-11 parts of N- ethyl para toluene sulfonamide, nano oxygen
Magnesium 3-6 parts of change, 5-11 parts of butyl maleate, 10-25 parts of isophorone diisocyanate, 2-5 parts of curing agent, aluminous cement
1-4 parts.
2. a kind of wear resistant corrosion resistant coating material according to claim 1, which is characterized in that the material includes following heavy
Measure the component of number:25-32 parts of epoxy resin, 7-10 parts of acrylic resin, 6-9 parts of ethyl orthosilicate, N- ethyl is to toluene sulphur
8-10 parts of amide, 4-6 parts of nano magnesia, 7-10 parts of butyl maleate, 14-22 parts of isophorone diisocyanate, solidification
3-5 parts of agent, 1-3 parts of aluminous cement.
3. a kind of wear resistant corrosion resistant coating material according to claim 2, which is characterized in that the material includes following heavy
Measure the component of number:30 parts of epoxy resin, 8 parts of acrylic resin, 7 parts of ethyl orthosilicate, 9 parts of N- ethyl para toluene sulfonamide,
5 parts of nano magnesia, 9 parts of butyl maleate, 20 parts of isophorone diisocyanate, 4 parts of curing agent, 2 parts of aluminous cement.
4. a kind of any one of claims 1 to 3 preparation method of wear resistant corrosion resistant coating material, which is characterized in that
Include the following steps:
The first step, weighed according to above-mentioned formula epoxy resin, acrylic resin, ethyl orthosilicate, N- ethyl para toluene sulfonamide,
Nano magnesia, butyl maleate, isophorone diisocyanate, curing agent and aluminous cement, it is spare;
Second step, extracting epoxy resin, acrylic resin, N- ethyl para toluene sulfonamide, butyl maleate and isophorone two
After isocyanates mixing, it is stirred until homogeneous under the conditions of 55~85 DEG C of temperature, obtains mixture;
Third step adds ethyl orthosilicate, nano magnesia, curing agent and aluminous cement into mixture, at 65~90 DEG C
Continue stirring to all raw materials under the conditions of temperature to be uniformly mixed, obtains coating material;
4th step carries out ball milling to coating material using ball mill, and coating material finished product can be obtained.
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CN110343447A (en) * | 2019-07-25 | 2019-10-18 | 南京林业大学 | A kind of preparation method of high temperature corrosion-resisting modifying agent |
CN112226127A (en) * | 2020-10-17 | 2021-01-15 | 温州国微科技有限公司 | Vehicle tail lamp bracket and processing technology thereof |
WO2023219007A1 (en) * | 2022-05-09 | 2023-11-16 | 東レ株式会社 | Thermosetting resin composition, molded article, molding material for fiber-reinforced composite material, and fiber-reinforced composite material |
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CN101544505A (en) * | 2009-03-20 | 2009-09-30 | 高树森 | Nano Al2O3 and MgO composite ceramic bonded spinel-magnesia fireproof casting material and preparation method thereof |
CN102352168A (en) * | 2011-07-29 | 2012-02-15 | 中国兵器工业第五九研究所 | Anticorrosive wear-resistant paint for magnesium alloy and preparation method thereof |
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CN112226127B (en) * | 2020-10-17 | 2021-10-29 | 温州国微科技有限公司 | Vehicle tail lamp bracket and processing technology thereof |
WO2023219007A1 (en) * | 2022-05-09 | 2023-11-16 | 東レ株式会社 | Thermosetting resin composition, molded article, molding material for fiber-reinforced composite material, and fiber-reinforced composite material |
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Application publication date: 20181120 |