CN105949922A - Wear resistant and anti-rust paint for building steel - Google Patents
Wear resistant and anti-rust paint for building steel Download PDFInfo
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- CN105949922A CN105949922A CN201610294760.7A CN201610294760A CN105949922A CN 105949922 A CN105949922 A CN 105949922A CN 201610294760 A CN201610294760 A CN 201610294760A CN 105949922 A CN105949922 A CN 105949922A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/08—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing fluorine
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/01—Magnetic additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a wear resistant and anti-rust paint for building steel. The raw materials include: modified acrylate, epoxy resin E-03, polyimide, gamma-aminopropyltriethoxysilane, polycarbonate diol, methyl triethoxysilane, dimethyldiethoxysilane, silica sol, isophorone diisocyanate, calcium carbonate whisker, glass hollow microsphere, nano silica, silicon carbide, bentonite, sericite powder, magnetic iron powder, iron phosphate, nano aluminium trioxide, a silane coupling agent KH-560, a curing agent, a leveling agent BYK-323, xylene, acetone and n-butanol. The paint provided by the invention has excellent wear resistance and anti-rust properties.
Description
Technical field
The present invention relates to paint field, particularly relate to a kind of structural steel wear resistant and rustproof paint.
Background technology
Antirust paint is a kind of chemistry protecting metal surfaces from air, acid & alkali liquid etc. or electrochemical corrosion
Coating.It is broadly divided into physical property and the big class of chemically antirust paint two.The former is by pigment and the suitable cooperation of paint vehicle,
Form fine and close paint film to stop the intrusion of corrosive substance, such as iron oxide red, aluminium powder, graphite antirust paint etc., after
Person presses down rust effect, such as Plumbum preparatium, zinc chromate anti-rust paint etc. by the chemistry of rust resisting pigment.For bridge, boats and ships, pipe
The metals such as road antirust.The antirust paint substantially oiliness used and aqueous two kinds.Oily antirust varniss makes material list
Face is greasy removes difficulty, is rarely employed.Oily antirust varniss is easy to use, cheap, but because of containing Asia
The noxious substance such as nitrate, chromate, relatively big to operator's harm, country has limited use, and this type of
Properties of product are single, it is impossible to meet the antirust requirement of magnetic alloy material.Metal selected by water-based metal antirust paint
Strongly chelating agen inositol hexaphosphate is main component, compounds in other several aqueous promoters and forms.Inositol six
Phosphate ester is the Nantural non-toxic Organic chemical products extracted from cereal crops, when it is antirust as magnetic material
When agent uses, can chelate rapidly with metal on surface, form one layer of fine and close unimolecule chelate protecting film,
Can effectively suppress corrosion of metal, after this product treatment, material surface keeps primary colors, it is not necessary to washing can be entered
Enter the next procedures such as application.
Antirust paint of the prior art relies primarily on the film on surface and carries out antirust, the anti-wear performance therefore smeared
Also being the key determining rustless property, the anti-wear performance of antirust paint of the prior art cannot meet actual production
Demand, therefore need invention badly and a kind of there is the antirust paint of excellent wear-resisting property to the need meeting in actual production
Ask.
Summary of the invention
For solving technical problem present in background technology, the present invention proposes a kind of structural steel wear resistant and rustproof paint,
There is the anti-wear performance of excellence, good antirust property.
A kind of structural steel wear resistant and rustproof paint that the present invention proposes, its raw material includes by weight: modified propylene
Acid esters 30-60 part, epoxy resin E-03 5-15 part, polyimides 2-8 part, gamma-aminopropyl-triethoxy
Silane 3-9 part, PCDL 1-5 part, MTES 2-5 part, dimethyl diethoxy
Base silane 3-6 part, Ludox 1-5 part, isophorone diisocyanate 2-4 part, calcium carbonate crystal whisker 1-5
Part, hollow glass bead 2-6 part, nano silicon 3-9 part, carborundum 1-5 part, bentonite 2-6
Part, sericite in powder 1-4 part, magnetic powder 2-5 part, iron phosphate 3-6 part, nanometer alchlor 1-8 part,
Silane coupler KH-560 2-6 part, firming agent 1-5 part, levelling agent BYK-323 3-9 part, dimethylbenzene 2-6
Part, acetone 1-4 part, n-butyl alcohol 2-6 part.
Preferably, the raw material of modification acrylate includes by weight: methyl methacrylate 2-8 part, third
Olefin(e) acid butyl ester 1-4 part, Kynoar 2-5 part, polyvinyl alcohol 1-4 part, benzoyl peroxide 2-6 part,
Deionized water 3-6 part.
Preferably, modification acrylate is prepared by following technique: by methyl methacrylate, acrylic acid
Butyl ester, Kynoar and benzoyl peroxide mix homogeneously, in room temperature ultrasonic disperse 25-45min, dissolve
After obtain material a；Then polyvinyl alcohol is dissolved in deionized water and obtains material b；By material a in room temperature nitrogen
Join in material b under gas shielded, then in 1980-2020r/min, then carry out heating in water bath and stir,
Temperature controls as 70-90 DEG C, and mixing speed is 400-500r/min, is then incubated 1-3h under nitrogen is protected,
Modification acrylate is obtained after natural cooling.
Preferably, the weight ratio of modification acrylate, epoxy resin E-03 and polyimides is 35-55:8-12:
3-7。
Preferably, gamma-aminopropyl-triethoxy-silane, PCDL, MTES, two
Methyldiethoxysilane, Ludox, isophorone diisocyanate and the weight of silane coupler KH-560
Ratio is 4-8:2-4:3-4:4-5:2-4:2.5-3.5:3-5.
Preferably, modification acrylate, epoxy resin E-03, polyimides, calcium carbonate crystal whisker, glass sky
Heart microballon, nano silicon, carborundum, bentonite, sericite in powder, magnetic powder, iron phosphate and receive
The weight ratio of rice alchlor is 35-55:8-12:3-7:2-4:3-5:4-8:2-4:3-5:2-3:
3-4:4-5:2-7.
Preferably, methyl methacrylate, butyl acrylate, Kynoar, polyvinyl alcohol, peroxidating
Benzoyl, deionized water, epoxy resin E-03, polyimides, gamma-aminopropyl-triethoxy-silane, poly-carbon
The weight ratio of acid esters glycol and MTES is 3-7:2-3:3-4:2-3:3-5:4-5:8-12:
3-7:4-8:2-4:3-4.
Preferably, its raw material includes by weight: modification acrylate 35-55 part, epoxy resin E-03 8-12
Part, polyimides 3-7 part, gamma-aminopropyl-triethoxy-silane 4-8 part, PCDL 2-4 part,
MTES 3-4 part, dimethyldiethoxysilane 4-5 part, Ludox 2-4 part, different Buddhist
That ketone diisocyanate 2.5-3.5 part, calcium carbonate crystal whisker 2-4 part, hollow glass bead 3-5 part, nanometer
Silicon dioxide 4-8 part, carborundum 2-4 part, bentonite 3-5 part, sericite in powder 2-3 part, magnetic powder
3-4 part, iron phosphate 4-5 part, nanometer alchlor 2-7 part, silane coupler KH-560 3-5 part, solid
Agent 2-4 part, levelling agent BYK-323 4-8 part, dimethylbenzene 3-5 part, acetone 2-3 part, n-butyl alcohol 3-5
Part.
Preferably, its raw material includes by weight: modification acrylate 45 parts, epoxy resin E-03 10 parts,
Polyimides 5 parts, gamma-aminopropyl-triethoxy-silane 6 parts, PCDL 3 parts, methyl three ethoxy
Base silane 3.5 parts, dimethyldiethoxysilane 4.5 parts, Ludox 3 parts, isophorone diisocyanate
Ester 3 parts, calcium carbonate crystal whisker 3 parts, hollow glass bead 4 parts, nano silicon 6 parts, carborundum 3
Part, bentonite 4 parts, sericite in powder 2.5 parts, magnetic powder 3.5 parts, iron phosphate 4.5 parts, nanometer three
Aluminium oxide 4.5 parts, silane coupler KH-560 4 parts, 3 parts of firming agent, levelling agent BYK-323 6 parts,
Dimethylbenzene 4 parts, 2.5 parts of acetone, n-butyl alcohol 4 parts.
A kind of structural steel wear resistant and rustproof paint of the present invention, its raw material includes modification acrylate, epoxy resin
E-03, polyimides, gamma-aminopropyl-triethoxy-silane, PCDL, MTES,
Dimethyldiethoxysilane, Ludox, isophorone diisocyanate, calcium carbonate crystal whisker, glass hollow
Microballon, nano silicon, carborundum, bentonite, sericite in powder, magnetic powder, iron phosphate, nanometer
Alchlor, silane coupler KH-560, firming agent, levelling agent BYK-323, dimethylbenzene, acetone and just
Butanol, wherein with modification acrylate as major ingredient, then auxiliary adds epoxy resin E-03 and polyimides is made
For the adjuvant of major ingredient, it is effectively increased the antirust of major ingredient and heat resistance；The gamma-aminopropyl-triethoxy added
Silane, PCDL, MTES, dimethyldiethoxysilane, Ludox and different
Isophorone diisocyanate cooperates, and utilizes Ludox wearability, and by gamma-aminopropyl-triethoxy silicon
Alkane, PCDL, MTES, dimethyldiethoxysilane and isophorone two are different
Cyanate is prepared for, containing Merlon segment polymer, under the effect of silane coupler KH-560, obtaining
The Merlon that wearability is strengthened, and coordinate with major ingredient modification acrylate so that the antirust paint tool of the present invention
There is the anti-wear performance of excellence；The calcium carbonate crystal whisker of interpolation, hollow glass bead, nano silicon, carbonization
Silicon, bentonite, sericite in powder, magnetic powder, iron phosphate and nanometer alchlor as filler and antirust agent,
It is effectively increased anti-wear performance and the rustless property of coating of the present invention.The structural steel antirust agent of the present invention has
There is the anti-wear performance of excellence, and then further ensure the rustless property of antirust agent.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail, it should be appreciated that embodiment is served only for
The bright present invention rather than be used for limiting the invention, any made on the basis of the present invention amendment,
Equivalents etc. are the most within the scope of the present invention.
In detailed description of the invention, the weight portion of modification acrylate can be 30 parts, 35 parts, 40 parts, 45
Part, 50 parts, 55 parts, 60 parts；The weight portion of epoxy resin E-03 can be 5 parts, 6 parts, 7 parts, 8
Part, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；The weight portion of polyimides is permissible
It it is 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The weight of gamma-aminopropyl-triethoxy-silane
Part can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight portion of PCDL can
Think 1 part, 2 parts, 3 parts, 4 parts, 5 parts；The weight portion of MTES can be 2 parts,
2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of dimethyldiethoxysilane is permissible
It it is 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5.5 parts, 6 parts；The weight portion of Ludox can be 1 part, 2
Part, 3 parts, 4 parts, 5 parts；The weight portion of isophorone diisocyanate can be 2 parts, 2.5 parts, 3 parts,
3.5 parts, 4 parts；The weight portion of calcium carbonate crystal whisker can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts；Glass
The weight portion of cenosphere can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The weight of nano silicon
Part can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight portion of carborundum can be 1
Part, 2 parts, 3 parts, 4 parts, 5 parts；Bentonitic weight portion can be 2 parts, 3 parts, 4 parts, 5 parts, 6
Part；The weight portion of sericite in powder can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；
The weight portion of magnetic powder can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Phosphorus
The weight portion of acid ferrum can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；Nanometer three
The weight portion of aluminium oxide can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5
Part, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The weight of silane coupler KH-560
Amount part can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；
The weight portion of firming agent can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts；The weight of levelling agent BYK-323
Part can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight portion of dimethylbenzene can be 2
Part, 3 parts, 4 parts, 5 parts, 6 parts；The weight portion of acetone can be 1 part, 1.5 parts, 2 parts, 2.5 parts,
3 parts, 3.5 parts, 4 parts；The weight portion of n-butyl alcohol can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts,
4.5 parts, 5 parts, 5.5 parts, 6 parts.
Embodiment 1
A kind of structural steel wear resistant and rustproof paint that the present invention proposes, its raw material includes by weight: modified propylene
Acid esters 45 parts, epoxy resin E-03 10 parts, polyimides 5 parts, gamma-aminopropyl-triethoxy-silane 6
Part, PCDL 3 parts, MTES 3.5 parts, dimethyldiethoxysilane 4.5
Part, Ludox 3 parts, isophorone diisocyanate 3 parts, calcium carbonate crystal whisker 3 parts, hollow glass bead 4
Part, nano silicon 6 parts, carborundum 3 parts, bentonite 4 parts, sericite in powder 2.5 parts, Armco magnetic iron
3.5 parts of powder, iron phosphate 4.5 parts, nanometer alchlor 4.5 parts, silane coupler KH-560 4 parts, solid
Agent 3 parts, levelling agent BYK-323 6 parts, dimethylbenzene 4 parts, 2.5 parts of acetone, n-butyl alcohol 4 parts.
Modification acrylate is prepared by following technique: by weight by 5 parts of methyl methacrylates, 2.5
Part butyl acrylate, 3.5 parts of Kynoar and 4 parts of benzoyl peroxide mix homogeneously, in ultrasonic point of room temperature
Dissipate 35min, after dissolving, obtain material a；Then 2.5 parts of polyvinyl alcohol are dissolved in 4.5 parts of deionized waters
To material b；Material a is joined in material b under nitrogen at room is protected, then in 2000r/min, connects
And carry out heating in water bath and stir, it is 80 DEG C that temperature controls, and mixing speed is 450r/min, then in nitrogen
It is incubated 2h under protection, after natural cooling, obtains modification acrylate.
Embodiment 2
A kind of structural steel wear resistant and rustproof paint that the present invention proposes, its raw material includes by weight: modified propylene
Acid esters 30 parts, epoxy resin E-03 15 parts, polyimides 2 parts, gamma-aminopropyl-triethoxy-silane 9
Part, PCDL 1 part, MTES 5 parts, dimethyldiethoxysilane 3 parts,
Ludox 5 parts, isophorone diisocyanate 2 parts, calcium carbonate crystal whisker 5 parts, hollow glass bead 2 parts,
Nano silicon 9 parts, carborundum 1 part, bentonite 6 parts, sericite in powder 1 part, magnetic powder 5 parts,
Iron phosphate 3 parts, nanometer alchlor 8 parts, silane coupler KH-560 2 parts, 5 parts of firming agent, levelling
Agent BYK-323 3 parts, dimethylbenzene 6 parts, 1 part of acetone, n-butyl alcohol 6 parts.
Modification acrylate is prepared by following technique: by weight by 2 parts of methyl methacrylates, 4 parts
Butyl acrylate, 2 parts of Kynoar and 6 parts of benzoyl peroxide mix homogeneously, in room temperature ultrasonic disperse
25min, obtains material a after dissolving；Then 4 parts of polyvinyl alcohol are dissolved in 3 parts of deionized waters and obtain material
b；Material a is joined in material b under nitrogen at room is protected, then in 2020r/min, then carries out
Heating in water bath also stirs, and it is 70 DEG C that temperature controls, and mixing speed is 500r/min, then under nitrogen is protected
Insulation 1h, obtains modification acrylate after natural cooling.
Embodiment 3
A kind of structural steel wear resistant and rustproof paint that the present invention proposes, its raw material includes by weight: modified propylene
Acid esters 60 parts, epoxy resin E-03 5 parts, polyimides 8 parts, gamma-aminopropyl-triethoxy-silane 3 parts,
PCDL 5 parts, MTES 2 parts, dimethyldiethoxysilane 6 parts, silicon are molten
1 part of glue, isophorone diisocyanate 4 parts, calcium carbonate crystal whisker 1 part, hollow glass bead 6 parts, receive
Rice silicon dioxide 3 parts, carborundum 5 parts, bentonite 2 parts, sericite in powder 4 parts, magnetic powder 2 parts,
Iron phosphate 6 parts, nanometer alchlor 1 part, silane coupler KH-560 6 parts, 1 part of firming agent, levelling
Agent BYK-323 9 parts, dimethylbenzene 2 parts, 4 parts of acetone, n-butyl alcohol 2 parts.
Modification acrylate is prepared by following technique: by weight by 8 parts of methyl methacrylates, 1 part
Butyl acrylate, 5 parts of Kynoar and 2 parts of benzoyl peroxide mix homogeneously, in room temperature ultrasonic disperse
45min, obtains material a after dissolving；Then 1 part of polyvinyl alcohol is dissolved in 6 parts of deionized waters and obtains material
b；Material a is joined in material b under nitrogen at room is protected, then in 1980r/min, then carries out
Heating in water bath also stirs, and it is 90 DEG C that temperature controls, and mixing speed is 400r/min, then under nitrogen is protected
Insulation 3h, obtains modification acrylate after natural cooling.
Embodiment 4
A kind of structural steel wear resistant and rustproof paint that the present invention proposes, its raw material includes by weight: modified propylene
Acid esters 35 parts, epoxy resin E-03 12 parts, polyimides 3 parts, gamma-aminopropyl-triethoxy-silane 8
Part, PCDL 2 parts, MTES 4 parts, dimethyldiethoxysilane 4 parts,
Ludox 4 parts, isophorone diisocyanate 2.5 parts, calcium carbonate crystal whisker 4 parts, hollow glass bead 3
Part, nano silicon 8 parts, carborundum 2 parts, bentonite 5 parts, sericite in powder 2 parts, magnetic powder 4
Part, iron phosphate 4 parts, nanometer alchlor 7 parts, silane coupler KH-560 3 parts, 4 parts of firming agent,
Levelling agent BYK-323 4 parts, dimethylbenzene 5 parts, 2 parts of acetone, n-butyl alcohol 5 parts.
Modification acrylate is prepared by following technique: by weight by 3 parts of methyl methacrylates, 3 parts
Butyl acrylate, 3 parts of Kynoar and 5 parts of benzoyl peroxide mix homogeneously, in room temperature ultrasonic disperse
28min, obtains material a after dissolving；Then 3 parts of polyvinyl alcohol are dissolved in 4 parts of deionized waters and obtain material
b；Material a is joined in material b under nitrogen at room is protected, then in 2015r/min, then carries out
Heating in water bath also stirs, and it is 75 DEG C that temperature controls, and mixing speed is 480r/min, then under nitrogen is protected
Insulation 1.5h, obtains modification acrylate after natural cooling.
Embodiment 5
A kind of structural steel wear resistant and rustproof paint that the present invention proposes, its raw material includes by weight: modified propylene
Acid esters 55 parts, epoxy resin E-03 8 parts, polyimides 7 parts, gamma-aminopropyl-triethoxy-silane 4 parts,
PCDL 4 parts, MTES 3 parts, dimethyldiethoxysilane 5 parts, silicon are molten
2 parts of glue, isophorone diisocyanate 3.5 parts, calcium carbonate crystal whisker 2 parts, hollow glass bead 5 parts,
Nano silicon 4 parts, carborundum 4 parts, bentonite 3 parts, sericite in powder 3 parts, magnetic powder 3 parts,
Iron phosphate 4 parts, nanometer alchlor 2 parts, silane coupler KH-560 5 parts, 2 parts of firming agent, levelling
Agent BYK-323 8 parts, dimethylbenzene 3 parts, 3 parts of acetone, n-butyl alcohol 3 parts.
Modification acrylate is prepared by following technique: by weight by 7 parts of methyl methacrylates, 2 parts
Butyl acrylate, 4 parts of Kynoar and 3 parts of benzoyl peroxide mix homogeneously, in room temperature ultrasonic disperse
42min, obtains material a after dissolving；Then 2 parts of polyvinyl alcohol are dissolved in 5 parts of deionized waters and obtain material
b；Material a is joined in material b under nitrogen at room is protected, then in 1985r/min, then carries out
Heating in water bath also stirs, and it is 85 DEG C that temperature controls, and mixing speed is 420r/min, then under nitrogen is protected
Insulation 2.5h, obtains modification acrylate after natural cooling.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention not office
Being limited to this, any those familiar with the art is in the technical scope that the invention discloses, according to this
The technical scheme of invention and inventive concept thereof in addition equivalent or change, all should contain the protection in the present invention
Within the scope of.
Claims (9)
1. a structural steel wear resistant and rustproof paint, it is characterised in that its raw material includes by weight: modified third
Olefin(e) acid ester 30-60 part, epoxy resin E-03 5-15 part, polyimides 2-8 part, γ-aminopropyl three ethoxy
Base silane 3-9 part, PCDL 1-5 part, MTES 2-5 part, dimethyl diethyl
TMOS 3-6 part, Ludox 1-5 part, isophorone diisocyanate 2-4 part, calcium carbonate crystal whisker 1-5
Part, hollow glass bead 2-6 part, nano silicon 3-9 part, carborundum 1-5 part, bentonite 2-6
Part, sericite in powder 1-4 part, magnetic powder 2-5 part, iron phosphate 3-6 part, nanometer alchlor 1-8 part,
Silane coupler KH-560 2-6 part, firming agent 1-5 part, levelling agent BYK-323 3-9 part, dimethylbenzene
2-6 part, acetone 1-4 part, n-butyl alcohol 2-6 part.
Structural steel wear resistant and rustproof paint the most according to claim 1, it is characterised in that modified acroleic acid
The raw material of ester includes by weight: methyl methacrylate 2-8 part, butyl acrylate 1-4 part, poly-inclined fluorine
Ethylene 2-5 part, polyvinyl alcohol 1-4 part, benzoyl peroxide 2-6 part, deionized water 3-6 part.
Structural steel wear resistant and rustproof paint the most according to claim 1 and 2, it is characterised in that modified third
Olefin(e) acid ester is prepared by following technique: by methyl methacrylate, butyl acrylate, Kynoar and
Benzoyl peroxide mix homogeneously, in room temperature ultrasonic disperse 25-45min, obtains material a after dissolving；Then
Polyvinyl alcohol is dissolved in deionized water and obtains material b；Material a is joined thing under nitrogen at room is protected
In material b, then in 1980-2020r/min, then carrying out heating in water bath and stir, temperature control is
70-90 DEG C, mixing speed is 400-500r/min, is then incubated 1-3h, natural cooling under nitrogen is protected
After obtain modification acrylate.
4. according to the structural steel wear resistant and rustproof paint described in any one of claim 1-3, it is characterised in that change
The weight ratio of property acrylate, epoxy resin E-03 and polyimides is 35-55:8-12:3-7.
5. according to the structural steel wear resistant and rustproof paint described in any one of claim 1-4, it is characterised in that γ
-aminopropyl triethoxysilane, PCDL, MTES, dimethyl diethoxy silicon
The weight ratio of alkane, Ludox, isophorone diisocyanate and silane coupler KH-560 is 4-8:2-4:
3-4:4-5:2-4:2.5-3.5:3-5.
6. according to the structural steel wear resistant and rustproof paint described in any one of claim 1-5, it is characterised in that change
Property acrylate, epoxy resin E-03, polyimides, calcium carbonate crystal whisker, hollow glass bead, nanometer two
Silicon oxide, carborundum, bentonite, sericite in powder, magnetic powder, iron phosphate and the weight of nanometer alchlor
Amount ratio is 35-55:8-12:3-7:2-4:3-5:4-8:2-4:3-5:2-3:3-4:4-5:2-7.
7. according to the structural steel wear resistant and rustproof paint described in any one of claim 1-6, it is characterised in that first
Base acrylic acid methyl ester., butyl acrylate, Kynoar, polyvinyl alcohol, benzoyl peroxide, deionization
Water, epoxy resin E-03, polyimides, gamma-aminopropyl-triethoxy-silane, PCDL and first
The weight ratio of ethyl triethoxy silicane alkane is 3-7:2-3:3-4:2-3:3-5:4-5:8-12:3-7:4-8:
2-4:3-4.
8. according to the structural steel wear resistant and rustproof paint described in any one of claim 1-7, it is characterised in that its
Raw material includes by weight: modification acrylate 35-55 part, epoxy resin E-03 8-12 part, polyamides Asia
Amine 3-7 part, gamma-aminopropyl-triethoxy-silane 4-8 part, PCDL 2-4 part, methyl three ethoxy
Base silane 3-4 part, dimethyldiethoxysilane 4-5 part, Ludox 2-4 part, isophorone two isocyanide
Acid esters 2.5-3.5 part, calcium carbonate crystal whisker 2-4 part, hollow glass bead 3-5 part, nano silicon 4-8
Part, carborundum 2-4 part, bentonite 3-5 part, sericite in powder 2-3 part, magnetic powder 3-4 part, phosphoric acid
Ferrum 4-5 part, nanometer alchlor 2-7 part, silane coupler KH-560 3-5 part, firming agent 2-4 part,
Levelling agent BYK-323 4-8 part, dimethylbenzene 3-5 part, acetone 2-3 part, n-butyl alcohol 3-5 part.
9. according to the structural steel wear resistant and rustproof paint described in any one of claim 1-8, it is characterised in that its
Raw material includes by weight: modification acrylate 45 parts, epoxy resin E-03 10 parts, polyimides 5 parts,
Gamma-aminopropyl-triethoxy-silane 6 parts, PCDL 3 parts, MTES 3.5 parts,
Dimethyldiethoxysilane 4.5 parts, Ludox 3 parts, isophorone diisocyanate 3 parts, calcium carbonate
Whisker 3 parts, hollow glass bead 4 parts, nano silicon 6 parts, carborundum 3 parts, bentonite 4 parts,
Sericite in powder 2.5 parts, magnetic powder 3.5 parts, iron phosphate 4.5 parts, nanometer alchlor 4.5 parts, silicon
Alkane coupling agent KH-560 4 parts, 3 parts of firming agent, levelling agent BYK-323 6 parts, dimethylbenzene 4 parts, acetone
2.5 parts, n-butyl alcohol 4 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201610294760.7A CN105949922A (en) | 2016-05-03 | 2016-05-03 | Wear resistant and anti-rust paint for building steel |
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| CN201610294760.7A CN105949922A (en) | 2016-05-03 | 2016-05-03 | Wear resistant and anti-rust paint for building steel |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106479326A (en) * | 2016-10-27 | 2017-03-08 | 岳西县宏胜铸造有限公司 | A kind of special antirusting paint of rice machine outer surface |
| CN106704720A (en) * | 2017-01-11 | 2017-05-24 | 江苏星源电站冶金设备制造有限公司 | Bi-metal composite abrasion-resistant pipe and preparation method thereof |
| CN108841286A (en) * | 2018-05-21 | 2018-11-20 | 三江学院 | A kind of wear resistant corrosion resistant coating material and preparation method thereof |
| CN108912927A (en) * | 2018-05-24 | 2018-11-30 | 合肥市闵葵电力工程有限公司 | A kind of power equipment anticorrosive paint and preparation method thereof |
| CN116445055A (en) * | 2023-04-21 | 2023-07-18 | 江苏中金玛泰医药包装有限公司 | Water-based corrosion-resistant composite coating of medicinal composite film and preparation method thereof |
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| CN103305101A (en) * | 2013-07-09 | 2013-09-18 | 湖南太子化工涂料有限公司 | Quick-drying anticorrosive and anti-rust primer and preparation method thereof |
| CN103627235A (en) * | 2013-11-08 | 2014-03-12 | 吴江邻苏精密机械有限公司 | Acrylic acid anti-rust coating |
| CN104610823A (en) * | 2015-01-21 | 2015-05-13 | 赖禄波 | Anti-rust coating |
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| CN103305101A (en) * | 2013-07-09 | 2013-09-18 | 湖南太子化工涂料有限公司 | Quick-drying anticorrosive and anti-rust primer and preparation method thereof |
| CN103627235A (en) * | 2013-11-08 | 2014-03-12 | 吴江邻苏精密机械有限公司 | Acrylic acid anti-rust coating |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106479326A (en) * | 2016-10-27 | 2017-03-08 | 岳西县宏胜铸造有限公司 | A kind of special antirusting paint of rice machine outer surface |
| CN106704720A (en) * | 2017-01-11 | 2017-05-24 | 江苏星源电站冶金设备制造有限公司 | Bi-metal composite abrasion-resistant pipe and preparation method thereof |
| CN106704720B (en) * | 2017-01-11 | 2019-09-13 | 江苏星源电站冶金设备制造有限公司 | Bimetal composite wear resistant tube and preparation method thereof |
| CN108841286A (en) * | 2018-05-21 | 2018-11-20 | 三江学院 | A kind of wear resistant corrosion resistant coating material and preparation method thereof |
| CN108912927A (en) * | 2018-05-24 | 2018-11-30 | 合肥市闵葵电力工程有限公司 | A kind of power equipment anticorrosive paint and preparation method thereof |
| CN116445055A (en) * | 2023-04-21 | 2023-07-18 | 江苏中金玛泰医药包装有限公司 | Water-based corrosion-resistant composite coating of medicinal composite film and preparation method thereof |
| CN116445055B (en) * | 2023-04-21 | 2023-10-20 | 江苏中金玛泰医药包装有限公司 | Water-based corrosion-resistant composite coating of medicinal composite film and preparation method thereof |
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Application publication date: 20160921 |