CN104945976A - High-strength UV (Ultraviolet) curing coating for terrace - Google Patents
High-strength UV (Ultraviolet) curing coating for terrace Download PDFInfo
- Publication number
- CN104945976A CN104945976A CN201510339321.9A CN201510339321A CN104945976A CN 104945976 A CN104945976 A CN 104945976A CN 201510339321 A CN201510339321 A CN 201510339321A CN 104945976 A CN104945976 A CN 104945976A
- Authority
- CN
- China
- Prior art keywords
- parts
- coating material
- high intensity
- terrace
- material solidified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses a high-strength UV (Ultraviolet) curing coating for a terrace, and belongs to the field of coatings, in particular to the field of UV curing coatings. The high-strength UV curing coating for the terrace comprises the following raw materials: cyclohexyl methacrylate, methyl methacrylate, epoxy resin, tetraethoxysilane, isophorone diisocyanate, polyether glycol, a solvent, a wetting agent, a dispersing agent, a flatting agent, a photoinitiator and white carbon black. A curing product of the coating has good property; and a sample prepared by curing has excellent adhesion, scratch resistance, antifouling property and thermal conductivity.
Description
Technical field
The invention belongs to paint field, belong to the field of the water-borne coatings of ultraviolet light polymerization especially.
Background technology
Acrylic resin paint has developed into the class coating variety that type is maximum, over-all properties is the most complete.Acrylic resin paint has the advantages such as time of drying is short, snappiness good, look shallow is, excellent guarantor's light tint retention and outdoor weatherability, but the general sticking power of single component acrylic resin paint to special substrate is bad, limits its application to a certain extent.Epoxy resin is one of most important kind in coating resin, and the aromatic ring in molecular structure gives the good hardness of film and chemical-resistant, and ehter bond is convenient to the rotation of molecular chain, makes again film have certain snappiness.The many hydroxyls contained in epoxy resin structural and ehter bond, make film to metal, pottery, glass, concrete, the sticking power of timber isopolarity ground is good, but the epoxy resin of general high molecular weight and the consistency of acrylic resin bad, and need supporting epoxy hardener to use, limit the application of high molecular weight epoxy resin in single component acrylic resin.The present invention first synthesizes the acrylic resin of side chain with anhydride group, with epoxy resin, modification is carried out to it again, obtained epoxy modified acrylic resin, the single-component epoxy modified acrylic coating material prepared with it has excellent sticking power, good hardness and gloss.
Summary of the invention
Common terrace paint is generally difficult in high-performance situation the requirement reaching environmental protection, the object of the invention is obtained one cured epoxy acrylic coating under ultraviolet light, make it have excellent sticking power, good hardness and wear resistance, the good and environmental protection of use properties simultaneously.The present invention realizes above-mentioned purpose by following technical scheme:
A kind of terrace high intensity UV is coating material solidified, it is characterized in that being made up of by mass parts following raw material: isophorone diisocyanate 15-30 part, methacrylic acid cyclohexanol 40-75 part, methyl methacrylate 15-25 part, epoxy resin 9-17 part, tetraethoxy 20-30 part, polyether Glycols 5-15 part, solvent 15-25 part, wetting agent 0.5-1.5 part, dispersion agent 3-6 part, flow agent 2-5 part, light trigger 1-4 part, white carbon black 1-5 part.
As preferably, described solvent adopts one or more the aqueous solution of vinyl acetic monomer, ethanol, 1-Methoxy-2-propyl acetate.
Preferably, described solvent strength 10-15wt%.
As preferably, described wetting agent adopt aliphatic polymer in modification poly(silicon aether) and polyoxyethylene glycol one or more.
As preferably, described dispersion agent adopt glyceryl monostearate (GMS), polyoxyethylene glycol and Tristearoylglycerol (HTG) one or more.
As preferably, described flow agent adopt acrylic resin, urea-formaldehyde resin and terpolycyantoamino-formaldehyde resin one or more.
As preferably, described light trigger to adopt in benzoin dimethylether, 2-hydroxy-2-methyl-1-phenyl-acetone (UV-1173), 2,4,6-trimethylbenzoy-dipheny phosphine oxides (TPO) and methyl benzoylformate (MBF) one or more.
As preferably, described white carbon black is nano level.
White carbon black is the common name of fine powder or ultrafine particle shape anhydrous and aqueous silicon dioxide or silicates.White carbon black alleged is at ordinary times hydrated SiO 2, high-purity person SiO
2content reaches 99.8%, light weight, and primary particle particle diameter is generally less than 0.0003mm, and density is between 2.319 ~ 2.653t/m, and fusing point is 1750 DEG C.The chemical stability of white carbon black is good, not easily decomposes, does not burn, specific surface area is large, electrical insulating property is strong by high temperature, has very much higher permeability, water-absorbent, has good reinforcement and increases glutinous effect, good dispersiveness, suspension and thixotropy characteristic.White carbon black is the general name of white powder X-ray amorphous silicic acid and silicate product, mainly refers to precipitated silica, aerosil, superfine silicon dioxide gel and aerogel, also comprises Powdered synthetic aluminium silicate and Calucium Silicate powder etc.White carbon black is porous material, and it forms available SiO
2nH
2o represents, wherein nH
2o exists with the form of surface hydroxyl.Caustic alkali and hydrofluoric acid can be dissolved in, water insoluble, solvent and acid (except hydrofluoric acid).High temperature resistant, do not fire, tasteless, odorless, there is good electrical insulating property.White carbon black adds in coating and makes abrasion resistance bring up to more than 10,000 time by original more than 1,000 time, artificial acceleration weathering age and man-made radiation expose digestion time and bring up to 600 hours (without efflorescence by original 250 hours (efflorescence 1 grade, variable color 2 grades), paint film is without variable color, value of chromatism 4.8), in addition film and polycarbonate plate body bonding strength significantly improve, hardness of film significantly increases, and clean surfaces ability is also improved.
The invention has the beneficial effects as follows:
One, curing speed of the present invention is fast, can in ambient cure, and production efficiency is high, easily manufactured, cured product performance is good, and sample obtained after solidification has excellent sticking power, resistance to marring and didirtresistance;
Two, to adopt epoxy resin to obtain coating material solidified in the present invention, and it is high temperature resistant, resistant to chemical media, waterproof and oilproof performance significantly improve, and one-pass film-forming thickness is greater than 180 microns and does not ftracture, and sun-proof ability is strong;
Three, the present invention adopts nano-scale white carbon black can improve intensity, resistance to deterioration and improves the smooth finish of material surface and anticorrosive;
Four, easily manufactured, cost is low, product is practical, use is simple.
Embodiment
The present invention is set forth further below in conjunction with embodiment:
Embodiment one
A kind of terrace high intensity UV is coating material solidified, is made up of: isophorone diisocyanate 15 parts, methacrylic acid cyclohexanol 40 parts, methyl methacrylate 15 parts, epoxy resin 9 parts, tetraethoxy 20 parts, polyether Glycols 5 parts, solvent 15 parts, wetting agent 0.5 part, dispersion agent 3 parts, flow agent 2 parts, light trigger 1 part, white carbon black 1 part following raw material by mass parts.
Embodiment two
A kind of terrace high intensity UV is coating material solidified, is made up of: isophorone diisocyanate 17 parts, methacrylic acid cyclohexanol 45 parts, methyl methacrylate 17 parts, epoxy resin 11 parts, tetraethoxy 22 parts, polyether Glycols 7 parts, solvent 18 parts, wetting agent 1 part, dispersion agent 4 parts, flow agent 3 parts, light trigger 2 parts, white carbon black 2 parts following raw material by mass parts.
Embodiment three
A kind of terrace high intensity UV is coating material solidified, is made up of: isophorone diisocyanate 20 parts, methacrylic acid cyclohexanol 50 parts, methyl methacrylate 21 parts, epoxy resin 13 parts, tetraethoxy 25 parts, polyether Glycols 10 parts, solvent 20 parts, wetting agent 1.2 parts, dispersion agent 5 parts, flow agent 4 parts, light trigger 3 parts, white carbon black 4 parts following raw material by mass parts.
Embodiment four
A kind of terrace high intensity UV is coating material solidified, is made up of: isophorone diisocyanate 23 parts, methacrylic acid cyclohexanol 55 parts, methyl methacrylate 23 parts, epoxy resin 15 parts, tetraethoxy 27 parts, polyether Glycols 13 parts, solvent 22 parts, wetting agent 1.5 parts, dispersion agent 6 parts, flow agent 5 parts, light trigger 4 parts, white carbon black 5 parts following raw material by mass parts.
Embodiment five
A kind of terrace high intensity UV is coating material solidified, is made up of: isophorone diisocyanate 30 parts, methacrylic acid cyclohexanol 65 parts, methyl methacrylate 25 parts, epoxy resin 17 parts, tetraethoxy 30 parts, polyether Glycols 15 parts, solvent 25 parts, wetting agent 1.5 parts, dispersion agent 6 parts, flow agent 3 parts, light trigger 4 parts, white carbon black 5 parts following raw material by mass parts.
Embodiment six
A kind of terrace high intensity UV is coating material solidified, is made up of: isophorone diisocyanate 30 parts, methacrylic acid cyclohexanol 75 parts, methyl methacrylate 25 parts, epoxy resin 14 parts, tetraethoxy 24 parts, polyether Glycols 12 parts, solvent 19 parts, wetting agent 1.5 parts, dispersion agent 6 parts, flow agent 5 parts, light trigger 4 parts, white carbon black 3 parts following raw material by mass parts.
Although with reference to explanatory embodiment of the present invention, invention has been described here, above-described embodiment is only the present invention's preferably embodiment, embodiments of the present invention are not restricted to the described embodiments, should be appreciated that, those skilled in the art can design a lot of other amendment and embodiment, these amendments and embodiment will drop within spirit disclosed in the present application and spirit.
Claims (7)
1. a terrace high intensity UV is coating material solidified, it is characterized in that: be made up of by mass parts following raw material: isophorone diisocyanate 15-30 part, methacrylic acid cyclohexanol 40-75 part, methyl methacrylate 15-25 part, epoxy resin 9-17 part, tetraethoxy 20-30 part, polyether Glycols 5-15 part, solvent 15-25 part, wetting agent 0.5-1.5 part, dispersion agent 3-6 part, flow agent 2-5 part, light trigger 1-4 part, white carbon black 1-5 part.
2. terrace high intensity UV is coating material solidified according to claim 1, it is characterized in that: described solvent adopts concentration to be the vinyl acetic monomer of 10-15wt%, ethanol, one or more the aqueous solution of 1-Methoxy-2-propyl acetate.
3. terrace high intensity UV is coating material solidified according to claim 1, it is characterized in that: described wetting agent adopt aliphatic polymer in modification poly(silicon aether) and polyoxyethylene glycol one or more.
4. terrace high intensity UV is coating material solidified according to claim 1, it is characterized in that: described dispersion agent adopt glyceryl monostearate (GMS), polyoxyethylene glycol and Tristearoylglycerol (HTG) one or more.
5. terrace high intensity UV is coating material solidified according to claim 1, it is characterized in that: described flow agent adopt acrylic resin, urea-formaldehyde resin and terpolycyantoamino-formaldehyde resin one or more.
6. terrace high intensity UV is coating material solidified according to claim 1; it is characterized in that: described light trigger adopts benzoin dimethylether, 2-hydroxy-2-methyl-1-phenyl-acetone (UV-1173), 2; in 4,6-trimethylbenzoy-dipheny phosphine oxide (TPO) and methyl benzoylformate (MBF) one or more.
7. terrace high intensity UV is coating material solidified according to claim 1, it is characterized in that: described white carbon black is nano level.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510339321.9A CN104945976A (en) | 2015-06-18 | 2015-06-18 | High-strength UV (Ultraviolet) curing coating for terrace |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510339321.9A CN104945976A (en) | 2015-06-18 | 2015-06-18 | High-strength UV (Ultraviolet) curing coating for terrace |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104945976A true CN104945976A (en) | 2015-09-30 |
Family
ID=54161065
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510339321.9A Pending CN104945976A (en) | 2015-06-18 | 2015-06-18 | High-strength UV (Ultraviolet) curing coating for terrace |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104945976A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106517889A (en) * | 2016-11-08 | 2017-03-22 | 南京悠谷知识产权服务有限公司 | Insulating terrace coating material applicable to transformer substation and preparation method thereof |
| CN108841286A (en) * | 2018-05-21 | 2018-11-20 | 三江学院 | A kind of wear resistant corrosion resistant coating material and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020081391A1 (en) * | 2000-11-06 | 2002-06-27 | Beate Baumbach | Process for coating substrates |
| CN101307194A (en) * | 2008-06-27 | 2008-11-19 | 江苏科技大学 | Organic-inorganic hybridization ultraviolet cured paint for protecting metallic surface |
| CN202836829U (en) * | 2012-09-11 | 2013-03-27 | 天津东丽湖能源科技有限公司 | Heat meter box |
| CN103087294A (en) * | 2011-10-28 | 2013-05-08 | 安庆飞凯高分子材料有限公司 | Modified epoxy acrylic acid resin, preparation method and uses thereof |
| CN103408716A (en) * | 2013-05-02 | 2013-11-27 | 鑫洲科技有限公司 | (Methyl) acrylic modified polyurethane resin, and ultraviolet curable insulating coating containing same and nano-material |
-
2015
- 2015-06-18 CN CN201510339321.9A patent/CN104945976A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020081391A1 (en) * | 2000-11-06 | 2002-06-27 | Beate Baumbach | Process for coating substrates |
| CN101307194A (en) * | 2008-06-27 | 2008-11-19 | 江苏科技大学 | Organic-inorganic hybridization ultraviolet cured paint for protecting metallic surface |
| CN103087294A (en) * | 2011-10-28 | 2013-05-08 | 安庆飞凯高分子材料有限公司 | Modified epoxy acrylic acid resin, preparation method and uses thereof |
| CN202836829U (en) * | 2012-09-11 | 2013-03-27 | 天津东丽湖能源科技有限公司 | Heat meter box |
| CN103408716A (en) * | 2013-05-02 | 2013-11-27 | 鑫洲科技有限公司 | (Methyl) acrylic modified polyurethane resin, and ultraviolet curable insulating coating containing same and nano-material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106517889A (en) * | 2016-11-08 | 2017-03-22 | 南京悠谷知识产权服务有限公司 | Insulating terrace coating material applicable to transformer substation and preparation method thereof |
| CN108841286A (en) * | 2018-05-21 | 2018-11-20 | 三江学院 | A kind of wear resistant corrosion resistant coating material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104945983A (en) | UV-curable low-shrinkage environment-friendly coating | |
| CN102337068B (en) | Preparation method of water-based polyurethane acrylate (WPUA) silicon dioxide photocureable coating | |
| CN102653628B (en) | Preparation method and application of nano sol modified waterborne polyurethane emulsion | |
| CN103554343B (en) | Nano SiO2 hybridized acrylic acid ester soap-free emulsion and manufacturing method | |
| CN103113812A (en) | POSS (Polyhedral oligomeric silsesquioxane)-based nano material modified polyester powder coating and preparation method thereof | |
| CN102911584B (en) | A kind of anti-doodling and anti-affixing nano paint and preparation method thereof | |
| CN102775902B (en) | Finish paint for plastic | |
| CN107384195B (en) | A kind of weather-proof plucking decorative paint of organosilicon | |
| CN108178966A (en) | Super-hydrophobic anti-infrared insulating moulding coating of a kind of dark color and preparation method thereof | |
| CN102002289A (en) | Normal temperature curing fluorocarbon resin coating and preparation method thereof | |
| CN105237777A (en) | Preparation method of silicon modified waterborne epoxy resin | |
| CN105505093A (en) | Environment-friendly glass baking paint and preparation method thereof | |
| CN104945985A (en) | UV-curable environment-friendly coating | |
| CN104945974A (en) | UV-curable rust-proof environment-friendly coating | |
| CN112500747A (en) | Self-cleaning weather-resistant fluorocarbon aluminum veneer and preparation method thereof | |
| CN111732892A (en) | Household nano self-cleaning coating and preparation method thereof | |
| CN104945976A (en) | High-strength UV (Ultraviolet) curing coating for terrace | |
| CN1174059C (en) | Solvent type organic silicone modified acrylate coating material and its production method | |
| CN104945980A (en) | Photocurable coating with improved thermal conductivity | |
| CN108531047B (en) | Water-based epoxy resin fire-resistant paint, preparation method and application thereof | |
| CN114015296A (en) | Coating liquid for photovoltaic back plate and photovoltaic back plate | |
| CN102850828A (en) | Active nano silica composition and preparation method thereof | |
| CN104945984A (en) | UV-curable high-temperature-resistant environment-friendly coating | |
| CN104945981A (en) | Photo-curing anticorrosive paint for timber | |
| CN108559391B (en) | Polyaspartic acid ester finish paint and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150930 |