CN108837680A - A kind of preparation method of turpentine oil deodorant - Google Patents

A kind of preparation method of turpentine oil deodorant Download PDF

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Publication number
CN108837680A
CN108837680A CN201810488661.1A CN201810488661A CN108837680A CN 108837680 A CN108837680 A CN 108837680A CN 201810488661 A CN201810488661 A CN 201810488661A CN 108837680 A CN108837680 A CN 108837680A
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China
Prior art keywords
parts
turpentine oil
water
preparation
added
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CN201810488661.1A
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Chinese (zh)
Inventor
戴舒涵
戴思捷
戴艳庭
沈存亮
朱嘉艺
张智新
赵孝阳
戴舒雅
韩信诚
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Jiangsu Fine Shield Energy Saving Technology Co Ltd
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Jiangsu Fine Shield Energy Saving Technology Co Ltd
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Priority to CN201810488661.1A priority Critical patent/CN108837680A/en
Publication of CN108837680A publication Critical patent/CN108837680A/en
Withdrawn legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A61L9/014—Deodorant compositions containing sorbent material, e.g. activated carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/52—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/54—Nitrogen compounds
    • B01D53/58—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77—Liquid phase processes
    • B01D53/78—Liquid phase processes with gas-liquid contact
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20—Method-related aspects
    • A61L2209/21—Use of chemical compounds for treating air or the like
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20—Method-related aspects
    • A61L2209/22—Treatment by sorption, e.g. absorption, adsorption, chemisorption, scrubbing, wet cleaning
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/306—Organic sulfur compounds, e.g. mercaptans

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biomedical Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Zoology (AREA)
  • Botany (AREA)
  • Materials Engineering (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention discloses a kind of preparation method of turpentine oil deodorant, selection rosin is raw material, extracted to obtain turpentine oil, is mixed with inorganic porous material, dispersing agent, bleeding agent, carbomer, sodium alginate.The deodorant is to the main odorous substance H in household refuse landfill sites2S、NH3、C3H8The removal ability of S is stronger, and deodorizing effect is obvious.

Description

A kind of preparation method of turpentine oil deodorant
Technical field
The invention belongs to technical field of waste treatment, and in particular to a kind of preparation method of turpentine oil deodorant.
Background technique
As China's urban population is increasing, the quickening of urbanization process, domestic waste also rapid growth.And I The sense organ for the foul smell stimulation people that the domestic waste of state generates during transporting, stack in refuse landfill, endangers people Body is healthy, contains hydrogen sulfide, ammonia, mercaptan, organic sulfur, organic amine and some inorganic matters in domestic waste foul smell mostly Matter.In order to eliminate harm of the odorant pollutant to human health, research deodorization technology has huge realistic meaning.
Currently, the deodorant being widely used has physical deodorization agent, chemical deodorizing agent, biological deodorant, plant extraction liquid to remove Smelly dose etc..Wherein the cardinal principle of physical deodorization is absorption, covers, and neutralization reaction etc., feature mainly occur for chemical deodorizing It is to react relatively rapidly, but effect is not lasting, is also easy to produce secondary pollution, and complex process.The great advantage of microbial deodorant Secondary pollution will not be generated by being that effect is lasting, and low in cost, process range is wide and nontoxic, but cannot be generated and be removed at once when use Smelly effect.And plant extraction liquid is the plant deodorant formed after emulsifying with water after the volatile oil extracted in trees flowers and plants, Its mechanism of action is then based on physical and chemical reaction, but unlike physical chemistry deodorant, and plant deodorant is to acid, alkali Property and neutral gas can play a role, and can be completely degraded under the premise of eliminating stench, noxious material can be made to be transformed into nothing Noxious material will not generate environment and poison pollution.
Summary of the invention
The object of the present invention is to provide a kind of preparation method of turpentine oil deodorant, gained deodorant deodorizing effect is obvious.
A kind of preparation method of turpentine oil deodorant, includes the following steps：
Step 1, scrape is added in the water of 3-5 times of weight, extracting through microwave heating, collects extracting solution；
Step 2, using petroleum ether extraction extracting solution, water is removed into oil reservoir drying in upper layer, vacuum distillation removal petroleum ether obtains turpentine Oil；
Step 3, in parts by weight, 1-3 parts of turpentine oil, 0.5-1 parts of dispersing agent, 3-5 parts of porous material are added to 5-10 parts of solvent In, after mixing evenly, bleeding agent 0.5-1 parts, 2-3 parts of carbomer, 1-2 parts of sodium alginate is added, after mixing, stands, i.e., It can.
Further, water is gone using anhydrous sodium sulfate drying in step 2.
Further, the dispersing agent is the mixture of neopelex and Tween 80, dodecyl benzene sulfonic acid The weight ratio of sodium and Tween 80 is 2：3.
Further, the porous material is selected from attapulgite, diatomite, bentonite or superfine silica gel powder.
Further, the solvent is the mixture of polyethylene glycol, second alcohol and water, the weight of polyethylene glycol, second alcohol and water Than for 1-2：5-10：20-30.
Further, the polyethylene glycol is polyethylene glycol-800 or cetomacrogol 1000.
Further, step 1 is in water also added with 5-10wt.% potassium sulfate.
Garbage deodorant is made using natural extracting solution turpentine oil cooperation inorganic porous material in the present invention, fills out to house refuse Bury the main odorous substance H in field2S、NH3、C3H8The removal ability of S is stronger, and deodorizing effect is obvious.
Specific embodiment
Embodiment 1
A kind of preparation method of turpentine oil deodorant, includes the following steps：
Step 1, scrape is added in the water of 3 times of weight, extracting through microwave heating, collects extracting solution；
Step 2, using petroleum ether extraction extracting solution, water, vacuum distillation removal stone are removed into oil reservoir anhydrous sodium sulfate drying in upper layer Oily ether, obtains turpentine oil；
Step 3, in parts by weight, 1 part of turpentine oil, 0.5 part of dispersing agent, 3 parts of porous material are added in 5 parts of solvent, stirring is equal After even, 0.5 part of bleeding agent, 2 parts of carbomer, 1 part of sodium alginate is added, after mixing, stands.
Wherein, the dispersing agent is the mixture of neopelex and Tween 80, neopelex and The weight ratio of Tween 80 is 2：3.
The porous material is attapulgite, diatomite, bentonitic mixture, attapulgite, diatomite, bentonitic Amount ratio is 1：2：1.
The solvent is the mixture of polyethylene glycol-800, second alcohol and water, polyethylene glycol, second alcohol and water weight ratio be 1： 5：20.
Step 1 is in water also added with 5wt.% potassium sulfate.
Gained deodorant is pressed 1：It after 500 are diluted with water, is uniformly sprayed in the plastic barrel equipped with rubbish, fountain height is After 500mL/kg, residence time 20min, H is measured2S、NH3、C3H8The removal rate of S is respectively 73.5%, 71.4%, 75.6%.
Embodiment 2
A kind of preparation method of turpentine oil deodorant, includes the following steps：
Step 1, scrape is added in the water of 4 times of weight, extracting through microwave heating, collects extracting solution；
Step 2, using petroleum ether extraction extracting solution, water, vacuum distillation removal stone are removed into oil reservoir anhydrous sodium sulfate drying in upper layer Oily ether, obtains turpentine oil；
Step 3, in parts by weight, 2 parts of turpentine oil, 0.7 part of dispersing agent, 4 parts of porous material are added in 7 parts of solvent, stirring is equal After even, 0.8 part of bleeding agent, 2.5 parts of carbomer, 1.2 parts of sodium alginate is added, after mixing, stands.
Wherein, the dispersing agent is the mixture of neopelex and Tween 80, neopelex and The weight ratio of Tween 80 is 2：3.
The porous material is attapulgite, diatomite, bentonitic mixture, attapulgite, diatomite, bentonitic Amount ratio is 1：2：1.
The solvent is the mixture of polyethylene glycol-800, second alcohol and water, polyethylene glycol, second alcohol and water weight ratio be 2： 7：22.
Step 1 is in water also added with 6wt.% potassium sulfate.
Gained deodorant is pressed 1：It after 500 are diluted with water, is uniformly sprayed in the plastic barrel equipped with rubbish, fountain height is After 500mL/kg, residence time 20min, H is measured2S、NH3、C3H8The removal rate of S is respectively 74.2%, 72.8%, 73.5%.
Embodiment 3
A kind of preparation method of turpentine oil deodorant, includes the following steps：
Step 1, scrape is added in the water of 3 times of weight, extracting through microwave heating, collects extracting solution；
Step 2, using petroleum ether extraction extracting solution, water, vacuum distillation removal stone are removed into oil reservoir anhydrous sodium sulfate drying in upper layer Oily ether, obtains turpentine oil；
Step 3, in parts by weight, 2 parts of turpentine oil, 0.5 part of dispersing agent, 4 parts of porous material are added in 8 parts of solvent, stirring is equal After even, 0.7 part of bleeding agent, 2.5 parts of carbomer, 1.5 parts of sodium alginate is added, after mixing, stands.
Wherein, the dispersing agent is the mixture of neopelex and Tween 80, neopelex and The weight ratio of Tween 80 is 2：3.
The porous material is attapulgite, diatomite, bentonitic mixture, attapulgite, diatomite, bentonitic Amount ratio is 1：2：1.
The solvent is the mixture of polyethylene glycol-800, second alcohol and water, polyethylene glycol, second alcohol and water weight ratio be 2： 8：24.
Step 1 is in water also added with 7wt.% potassium sulfate.
Gained deodorant is pressed 1：It after 500 are diluted with water, is uniformly sprayed in the plastic barrel equipped with rubbish, fountain height is After 500mL/kg, residence time 20min, H is measured2S、NH3、C3H8The removal rate of S is respectively 72.7%, 73.2%, 76.1%.
Embodiment 4
A kind of preparation method of turpentine oil deodorant, includes the following steps：
Step 1, scrape is added in the water of 5 times of weight, extracting through microwave heating, collects extracting solution；
Step 2, using petroleum ether extraction extracting solution, water, vacuum distillation removal stone are removed into oil reservoir anhydrous sodium sulfate drying in upper layer Oily ether, obtains turpentine oil；
Step 3, in parts by weight, 3 parts of turpentine oil, 1 part of dispersing agent, 5 parts of porous material are added in 10 parts of solvent, is stirred evenly Afterwards, 1 part of bleeding agent, 3 parts of carbomer, 2 parts of sodium alginate is added, after mixing, stands.
Wherein, the dispersing agent is the mixture of neopelex and Tween 80, neopelex and The weight ratio of Tween 80 is 2：3.
The porous material is attapulgite, diatomite, bentonitic mixture, attapulgite, diatomite, bentonitic Amount ratio is 2：1：1.
The solvent is the mixture of polyethylene glycol-800, second alcohol and water, polyethylene glycol, second alcohol and water weight ratio be 1： 10：30.
Step 1 is in water also added with 5-10wt.% potassium sulfate.
Gained deodorant is pressed 1：It after 500 are diluted with water, is uniformly sprayed in the plastic barrel equipped with rubbish, fountain height is After 500mL/kg, residence time 20min, H is measured2S、NH3、C3H8The removal rate of S is respectively 74.3%, 72.5%, 73.4%.

Claims (7)

1. a kind of preparation method of turpentine oil deodorant, it is characterised in that：Include the following steps：
Step 1, scrape is added in the water of 3-5 times of weight, extracting through microwave heating, collects extracting solution；
Step 2, using petroleum ether extraction extracting solution, water is removed into oil reservoir drying in upper layer, vacuum distillation removal petroleum ether obtains turpentine Oil；
Step 3, in parts by weight, 1-3 parts of turpentine oil, 0.5-1 parts of dispersing agent, 3-5 parts of porous material are added to 5-10 parts of solvent In, after mixing evenly, bleeding agent 0.5-1 parts, 2-3 parts of carbomer, 1-2 parts of sodium alginate is added, after mixing, stands, i.e., It can.
2. the preparation method of turpentine oil deodorant according to claim 1, it is characterised in that：Anhydrous sulphur is used in step 2 Water is removed in sour sodium drying.
3. the preparation method of turpentine oil deodorant according to claim 1, it is characterised in that：The dispersing agent is dodecane The weight ratio of the mixture of base benzene sulfonic acid sodium salt and Tween 80, neopelex and Tween 80 is 2：3.
4. the preparation method of turpentine oil deodorant according to claim 1, it is characterised in that：The porous material is selected from recessed Convex stick soil, diatomite, bentonite or superfine silica gel powder.
5. the preparation method of turpentine oil deodorant according to claim 1, it is characterised in that：The solvent is poly- second two The mixture of alcohol, second alcohol and water, polyethylene glycol, second alcohol and water weight ratio be 1-2：5-10：20-30.
6. the preparation method of turpentine oil deodorant according to claim 5, it is characterised in that：The polyethylene glycol is poly- second Glycol 800 or cetomacrogol 1000.
7. the preparation method of turpentine oil deodorant according to claim 1, it is characterised in that：Step 1 in water also added with 5-10wt.% potassium sulfate.
CN201810488661.1A 2018-05-21 2018-05-21 A kind of preparation method of turpentine oil deodorant Withdrawn CN108837680A (en)

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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810488661.1A CN108837680A (en) 2018-05-21 2018-05-21 A kind of preparation method of turpentine oil deodorant

Publications (1)

Publication Number Publication Date
CN108837680A true CN108837680A (en) 2018-11-20

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CN201810488661.1A Withdrawn CN108837680A (en) 2018-05-21 2018-05-21 A kind of preparation method of turpentine oil deodorant

Country Status (1)

Country Link
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117323807A (en) * 2023-12-01 2024-01-02 吉林大学 Deodorant containing microgel and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117323807A (en) * 2023-12-01 2024-01-02 吉林大学 Deodorant containing microgel and preparation method thereof
CN117323807B (en) * 2023-12-01 2024-01-23 吉林大学 Deodorant containing microgel and preparation method thereof

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Application publication date: 20181120