CN108822931A - Low-temperature lifting oil for vehicles and preparation method thereof - Google Patents

Low-temperature lifting oil for vehicles and preparation method thereof Download PDF

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Publication number
CN108822931A
CN108822931A CN201810331066.7A CN201810331066A CN108822931A CN 108822931 A CN108822931 A CN 108822931A CN 201810331066 A CN201810331066 A CN 201810331066A CN 108822931 A CN108822931 A CN 108822931A
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oil
preparation
automobile
pour
foaming agent
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CN201810331066.7A
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CN108822931B (en
Inventor
郑洪源
何大礼
孟庆菊
赵云萍
吴章辉
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Dongfeng Trucks Co ltd
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Dongfeng Trucks Co ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/048Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02Pour-point; Viscosity index
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08Resistance to extreme temperature
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/08Hydraulic fluids, e.g. brake-fluids

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The low-temperature lifting oil for the vehicle comprises the following raw materials in percentage by mass: 0.4-1.5% of pour point depressant, 1.22001-3.00002% of auxiliary agent and the balance of blended base oil which is blended by 10# low-freezing white oil and 32# synthetic oil according to the mass ratio of 1: 1-3: 2, wherein in the preparation process, the 10# low-freezing white oil is heated to 60-80 ℃, then the 32# synthetic oil is added, the temperature is raised to 90-110 ℃, the mixture is mixed for 10-20 min, then the heat preservation dehydration treatment is carried out for 10-20 min, the temperature is reduced to 80-90 ℃, then the pour point depressant and the auxiliary agent are added, and the mixture is mixed for 60-90 min at 80-100 ℃. The design significantly improves the pour point, flash point, seal adaptability and demulsification performance of the lift oil.

Description

A kind of automobile-used low temperature lifting oil and preparation method thereof
Technical field
The invention belongs to hydraulic oil fields, and in particular to a kind of hydraulic oil for commercial-vehicle cab hoisting system and its Preparation method, suitable for improving condensation point, flash-point, sealing element adaptability and the demulsification performance of lifting oil.
Background technique
Driver's cabin support and floating and the transmitting of driver's cabin lifting strength, are all by hydraulic pressure system in vehicle travel process What the oil product in system carried out.And the environment of vehicle operation is complicated, needs oil product to have good weatherability, that is, adapt to It works under various temperature environments, in particular for the oil product of driver's cabin lifting, more to guarantee that driver's cabin is just at low ambient temperatures Often lifting speed.Currently, the domestic specialized oil product without driver's cabin lifting, can also refer to without standard, the big over-borrowing of main engine plants Use the low-viscosity oil of low temperature performance well as working media, such as shock absorber fluid, 10# aircraft fluid etc., especially with 10# aviation Hydraulic oil is most widely used.
Shock absorber fluid early stage mainly uses on automobile absorber, later due to not being suitble to oil product, just extends to and drives Room hoisting system is sailed, -30 DEG C of kinematic viscosity limit values specified in standard Q/DFCVCM4352-2005 are no more than 2000mm2/ s, relative to 10# aircraft fluid, its low temperature flow requirement is not harsh, so, it is lifted under pole cold air time It rises driver's cabin and just shows unable to do what one wishes, do not adapted to the needs that commercial vehicle develops in extremely cold area.
A kind of working solution of the 10# aircraft fluid as high-altitude vehicle hydraulic gear is applied to aviation field, and It is not the optimal selection of automobile-used oil product.Since surface temperature and engine operating temperature are all very high when vehicle summer uses, hair The surface temperature of motivation exhaust pipe is up to 400 DEG C, and the temperature of heat radiation to each road binders pipe of automobile is more than 100 DEG C, and its standard SH Flash-point limit value specified in 0358-1995 is no less than 92 DEG C, that is to say, that if 10# aviation liquid in summer use process Pressure oil leakage will cause spontaneous combustion, be absolutely unsafe.Secondly, anti-after moisture to being mixed into oil product in 10# hydraulic air oil standard Emulsifiability and the adaptability such as the swelling of sealing element are not required, and to the corrosion of the metal parts in hydraulic system requirement Also very low, and these are all the key that hydraulic system oil should have physical and chemical index.
Summary of the invention
To overcome existing hydraulic oil to be unable to satisfy commercial vehicle to condensation point, flash-point, sealing element adaptability and emulsion resistance etc. The problem of requirement of performance, the present invention provides it is a kind of can significantly improve lifting oil condensation point, flash-point, sealing element adaptability with And automobile-used low temperature lifting oil of demulsification performance and preparation method thereof.
In order to achieve the above object, technical scheme is as follows:
A kind of automobile-used low temperature lifting oil, raw material composition and mass percentage content are:Pour-point depressant 0.4%~1.5% helps Agent 1.22001%~3.00002%, remaining is blending base oil, wherein the blending base oil is by the low solidifying white oil of 10#, 32# Synthetic oil in mass ratio 1:1~3:2 concoct.
The auxiliary agent includes antioxidant, anti emulsifier, extreme pressure anti-wear additives, anti-foaming agent, the antioxidant, anti emulsifier, pole Press antiwear additive, the mass percentage content of anti-foaming agent is respectively 0.6%~2%:0.02%~0.1%:0.6%~0.9%: 0.00001%~0.00002%.
The pour-point depressant is poly alpha olefin, and pour point depression degree is not less than the kinematic viscosity at 15 °, 100 DEG C and is not more than 800mm2/ s。
The antioxidant is the high molecular weight phenolic antioxidant of sulfur-bearing ether, and the anti emulsifier is glycol-modified polyethers High-molecular compound, the extreme pressure anti-wear additives are sulphur phosphorous extreme pressure anti-wear additives, and the anti-foaming agent is by siliceous anti-foaming agent and non-silicon The composite anti-foam agent of anti-foaming agent composition.
A kind of preparation method of automobile-used low temperature lifting oil, successively includes the following steps:
The preparation of blending base oil:The low solidifying white oil of 10# is first heated to 60~80 DEG C, 32# synthetic oil is added, is warming up to 90~110 DEG C of 10~20min of mixing, then keep the temperature that 10~20min of dehydration, being cooled to 80~90 DEG C, to obtain blending basic Oil;
Lift the preparation of oil:Pour-point depressant and auxiliary agent are first added into blending base oil in required ratio, then at 80~100 DEG C 60~90min of lower mixing.
Compared with prior art, beneficial effects of the present invention are:
Blending base oil is by the low solidifying white oil of 10#, 32# synthetic oil in mass ratio 1 in a kind of automobile-used low temperature lifting oil of the present invention: 1~3:2 concoct, and the lifting oil that oil obtains based on the combination has low condensation point (- 60~-70 DEG C), high-flash (150~180 DEG C), high viscosity index (HVI) (130~140), the feature that sealing element adaptability is good, emulsion resistance is excellent, can not only expire The use environment of -60 DEG C of foot, to significantly improve the lifting speed of driver's cabin at low temperature, and can keep hydraulic system to exist Stability at a temperature of varying environment, while also can effectively prevent oil product spontaneous combustion at high temperature.Therefore, the present invention significantly improves Condensation point, flash-point, sealing element adaptability and the demulsification performance of oil are lifted, and effectively maintains hydraulic system in varying environment At a temperature of stability.
Specific embodiment
The present invention will be further described in detail with reference to the specific embodiments.
A kind of automobile-used low temperature lifting oil, raw material composition and mass percentage content are:Pour-point depressant 0.4%~1.5% helps Agent 1.22001%~3.00002%, remaining is blending base oil, wherein the blending base oil is by the low solidifying white oil of 10#, 32# Synthetic oil in mass ratio 1:1~3:2 concoct.
The auxiliary agent includes antioxidant, anti emulsifier, extreme pressure anti-wear additives, anti-foaming agent, the antioxidant, anti emulsifier, pole Press antiwear additive, the mass percentage content of anti-foaming agent is respectively 0.6%~2%:0.02%~0.1%:0.6%~0.9%: 0.00001%~0.00002%.
The pour-point depressant is poly alpha olefin, and pour point depression degree is not less than the kinematic viscosity at 15 °, 100 DEG C and is not more than 800mm2/ s。
The antioxidant is the high molecular weight phenolic antioxidant of sulfur-bearing ether, and the anti emulsifier is glycol-modified polyethers High-molecular compound, the extreme pressure anti-wear additives are sulphur phosphorous extreme pressure anti-wear additives, and the anti-foaming agent is by siliceous anti-foaming agent and non-silicon The composite anti-foam agent of anti-foaming agent composition.
A kind of preparation method of automobile-used low temperature lifting oil, successively includes the following steps:
The preparation of blending base oil:The low solidifying white oil of 10# is first heated to 60~80 DEG C, 32# synthetic oil is added, is warming up to 90~110 DEG C of 10~20min of mixing, then keep the temperature that 10~20min of dehydration, being cooled to 80~90 DEG C, to obtain blending basic Oil;
Lift the preparation of oil:Pour-point depressant and auxiliary agent are first added into blending base oil in required ratio, then at 80~100 DEG C 60~90min of lower mixing.
The principle of the present invention is described as follows:
Blending base oil:It is low using 10# of the present invention compared with individually using the low solidifying white oil of 10# or 32# synthetic oil Solidifying white oil, 32# synthetic oil in mass ratio 1:1~3:2 blendings, which are matched, can provide better cryogenic property, high viscosity index (HVI) and resist Oxidation susceptibility.
The preparation step of blending base oil:The low solidifying white oil of 10# is first heated to 60~80 DEG C in this step, makes base therein Plinth oil and additive sufficiently merge, and add 32# synthetic oil and are warming up to 90~110 DEG C, can make light crude oil volatilization in this way, go It is evaporated except the bubble of low temperature, and by the micro-moisture in oil, to be effectively improved the condensation point of lifting oil, flash-point Can, keep its sealing element adaptability and demulsification performance more stable.
Each component of the present invention is described as follows:
Embodiment 1:
A kind of automobile-used low temperature lifting oil, raw material composition and mass percentage content are:Pour-point depressant 1.0%, antioxidant 0.8%, anti emulsifier 0.04%, extreme pressure anti-wear additives 0.7%, anti-foaming agent 0.000015%, remaining is blending base oil, wherein The blending base oil is by the low solidifying white oil of 10#, 32# synthetic oil in mass ratio 3:2 concoct, and the pour-point depressant is poly- α-alkene Hydrocarbon, pour point depression degree are not less than the kinematic viscosity at 15 °, 100 DEG C and are not more than 800mm2/ s, the antioxidant are the height of sulfur-bearing ether Molecular weight phenolic antioxidant, the anti emulsifier are glycol-modified polyether high molecular compound, and the extreme pressure anti-wear additives are sulphur Phosphorous extreme pressure anti-wear additives, the anti-foaming agent are the composite anti-foam agent being made of siliceous anti-foaming agent and non-silicon anti-foaming agent.
A kind of preparation method of automobile-used low temperature lifting oil, successively includes the following steps:
The preparation of blending base oil:The low solidifying white oil of 10# is first heated to 80 DEG C, 32# synthetic oil is added, is warming up to 110 DEG C mixing 10min, then keeps the temperature dehydration 10min, is cooled to 90 DEG C and obtains blending base oil;
Lift the preparation of oil:Pour-point depressant and auxiliary agent are first added into blending base oil in required ratio, is mixed at 90 DEG C Close 80min.
Embodiment 2:
Difference from example 1 is that:
The raw material of the lifting oil forms and mass percentage content is:Pour-point depressant 1.5%, antioxidant 2%, anti emulsifier 0.1%, extreme pressure anti-wear additives 0.9%, anti-foaming agent 0.00002%, remaining is blending base oil, and the blending base oil is low by 10# Solidifying white oil, 32# synthetic oil in mass ratio 4:3 concoct.
The preparation method successively includes the following steps:
The preparation of blending base oil:The low solidifying white oil of 10# is first heated to 72 DEG C, 32# synthetic oil is added, is warming up to 100 DEG C mixing 12min, then keeps the temperature dehydration 20min, is cooled to 80 DEG C and obtains blending base oil;
Lift the preparation of oil:Pour-point depressant and auxiliary agent are first added into blending base oil in required ratio, is mixed at 100 DEG C Close 60min.
Embodiment 3:
Difference from example 1 is that:
The raw material of the lifting oil forms and mass percentage content is:Pour-point depressant 0.4%, antioxidant 0.6%, emulsion resistance Agent 0.02%, extreme pressure anti-wear additives 0.6%, anti-foaming agent 0.00001%, remaining is blending base oil, and the blending base oil is by 10# Low solidifying white oil, 32# synthetic oil in mass ratio 1:1 concocts.
The preparation method successively includes the following steps:
The preparation of blending base oil:The low solidifying white oil of 10# is first heated to 60 DEG C, 32# synthetic oil is added, is warming up to 90 DEG C 20min is mixed, dehydration 20min is then kept the temperature, is cooled to 90 DEG C and obtains blending base oil;
Lift the preparation of oil:Pour-point depressant and auxiliary agent are first added into blending base oil in required ratio, is mixed at 90 DEG C Close 90min.
To investigate inventive energy, the performance for the lifting oil that above-described embodiment is prepared is tested as follows, as a result It is shown in Table 1:
Result above can clearly show that the blending formula that the present invention uses, suitable in the condensation point of oil product, flash-point, sealing element There is following advantage in the service performances such as answering property and demulsification performance:
1, the lifting oil condensation point after reconciling declines 10~15 DEG C, hence it is evident that improves cryogenic property.
2, the lifting oil flash point after reconciling improves 30 DEG C or more, and safety and reliability improves.
3, the viscosity of the low solidifying white oil of 10# is lower, easily leads to the swelling of sealing element, and the viscosity of 32# synthetic oil is relatively high, It is excessive to will cause oil cylinder working-pressure, influences lifting efficiency, by the reconciliation of the two, so that hydraulic oil seal conformability index reduces 2~3 units, the lifting oil seal adaptability after reconciliation are good.
4, lifting oil of the present invention maintains the low solidifying preferable demulsification performance of white oil of 10#, and lifts the anti-cream of oil Change performance and is better than the synthesis of 32# oil.
5, lifting oil viscosity index of the present invention is than individually with the low solidifying white oil of 10# and individually with 32# synthetic oil work Based on oily hydraulic oil will be high, it is small that high viscosity index (VI) influences its viscosity by ambient temperature, and either high temperature is also It is that hydraulic system can be kept to stablize under low temperature environment well.

Claims (5)

1. a kind of automobile-used low temperature lifting oil, it is characterised in that:
The raw material of the lifting oil forms and its mass percentage content is:Pour-point depressant 0.4%~1.5%, auxiliary agent 1.22001%~ 3.00002%, remaining is blending base oil, wherein the blending base oil by the low solidifying white oil of 10#, 32# synthetic oil in mass ratio 1:1~3:2 concoct.
2. a kind of automobile-used low temperature lifting oil according to claim 1, it is characterised in that:The auxiliary agent includes antioxidant, resists Emulsifier, extreme pressure anti-wear additives, anti-foaming agent, the antioxidant, anti emulsifier, extreme pressure anti-wear additives, anti-foaming agent mass percent contain Amount is respectively 0.6%~2%:0.02%~0.1%:0.6%~0.9%:0.00001%~0.00002%.
3. a kind of automobile-used low temperature lifting oil according to claim 1 or 2, it is characterised in that:The pour-point depressant is poly- α-alkene Hydrocarbon, pour point depression degree are not less than the kinematic viscosity at 15 °, 100 DEG C and are not more than 800mm2/s。
4. a kind of automobile-used low temperature lifting oil according to claim 1 or 2, it is characterised in that:The antioxidant is Sulfide-containing Hindered The high molecular weight phenolic antioxidant of base, the anti emulsifier are glycol-modified polyether high molecular compound, the extreme-pressure anti-wear Agent is sulphur phosphorous extreme pressure anti-wear additives, and the anti-foaming agent is the composite anti-foam agent being made of siliceous anti-foaming agent and non-silicon anti-foaming agent.
5. a kind of preparation method of automobile-used low temperature lifting oil described in claim 1, it is characterised in that:
The preparation method successively includes the following steps:
The preparation of blending base oil:The low solidifying white oil of 10# is first heated to 60~80 DEG C, adds 32# synthetic oil, it is warming up to 90~ Then 110 DEG C of 10~20min of mixing keep the temperature 10~20min of dehydration, are cooled to 80~90 DEG C and obtain blending base oil;
Lift the preparation of oil:Pour-point depressant and auxiliary agent are first added into blending base oil in required ratio, is mixed at 80~100 DEG C Close 60~90min.
CN201810331066.7A 2018-04-13 2018-04-13 Low-temperature lifting oil for vehicles and preparation method thereof Active CN108822931B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001004240A1 (en) * 1999-07-13 2001-01-18 Canadian Oil Co Sweden Ab Hydraulic oil
US20050176597A1 (en) * 1999-01-19 2005-08-11 Cargill Incorporated, A Minnesota Corporation Oils with heterogenous chain lengths
CN105219492A (en) * 2015-09-16 2016-01-06 安徽贝利机械制造有限公司 A kind of rig lubricating oil and preparation method thereof
CN106479648A (en) * 2016-10-17 2017-03-08 中国石油化工股份有限公司 A kind of high viscosity synthetic hydraulic fluid compositionss and its application
CN104651026B (en) * 2015-02-02 2017-10-20 鞍山海华油脂化学有限公司 A kind of anti-coking type turbine oil and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050176597A1 (en) * 1999-01-19 2005-08-11 Cargill Incorporated, A Minnesota Corporation Oils with heterogenous chain lengths
WO2001004240A1 (en) * 1999-07-13 2001-01-18 Canadian Oil Co Sweden Ab Hydraulic oil
CN104651026B (en) * 2015-02-02 2017-10-20 鞍山海华油脂化学有限公司 A kind of anti-coking type turbine oil and preparation method thereof
CN105219492A (en) * 2015-09-16 2016-01-06 安徽贝利机械制造有限公司 A kind of rig lubricating oil and preparation method thereof
CN106479648A (en) * 2016-10-17 2017-03-08 中国石油化工股份有限公司 A kind of high viscosity synthetic hydraulic fluid compositionss and its application

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