CN112646649A - Low-temperature-resistant long-life hydraulic transmission oil composition and preparation method and application thereof - Google Patents

Low-temperature-resistant long-life hydraulic transmission oil composition and preparation method and application thereof Download PDF

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Publication number
CN112646649A
CN112646649A CN201910959270.8A CN201910959270A CN112646649A CN 112646649 A CN112646649 A CN 112646649A CN 201910959270 A CN201910959270 A CN 201910959270A CN 112646649 A CN112646649 A CN 112646649A
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hydraulic transmission
base oil
oil composition
transmission oil
pour point
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Inventor
焦玉萍
陈惠卿
刘卜瑜
贾睿
汤涛
李永超
桂砚楠
张静如
李耿辉
龙茵
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China Petroleum and Chemical Corp
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/048Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/06Well-defined aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106Naphthenic fractions
    • C10M2203/1065Naphthenic fractions used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/0206Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084Acrylate; Methacrylate
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/062Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups bound to the aromatic ring
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention relates to the technical field of lubricating oil, in particular to a low-temperature-resistant long-life hydraulic transmission oil composition, and a preparation method and application thereof. The invention provides a low-temperature-resistant long-life hydraulic transmission oil composition, which comprises base oil, a complexing agent, a viscosity index improver, a pour point depressant, an antioxidant and an anti-foaming agent; the base oil includes polyalphaolefin base oil, naphthenic base oil and mineral base oil. The hydraulic transmission oil composition has excellent low-temperature performance, viscosity-temperature performance and oxidation resistance; the preparation method is simple, has the advantages of wide application range and the like, can be suitable for various hydraulic transmission equipment, and is used for severe working conditions with great environmental temperature difference change.

Description

Low-temperature-resistant long-life hydraulic transmission oil composition and preparation method and application thereof
Technical Field
The invention relates to the technical field of lubricating oil, in particular to a low-temperature-resistant long-life hydraulic transmission oil composition, and a preparation method and application thereof.
Background
The hydraulic transmission is transmission for transmitting power by means of kinetic energy of liquid, and is actually an energy conversion device using liquid as a working medium, and the energy conversion device has two forms of a coupler and a torque converter. The oil used as a hydraulic transmission medium, called hydraulic transmission oil, can be widely used for hydraulic torque converters and hydraulic couplers of industrial machinery, agricultural machinery and other equipment.
In recent years, hydraulic transmission technology at home and abroad has breakthrough progress in many aspects, and the novel hydraulic torque converter shows outstanding advantages in the application of large-scale wind driven generators. Under the condition that the performance requirements of common hydraulic couplers such as fans, pumps and the like are not changed, the hydraulic couplers are more compact in structure, smaller in size and lighter in weight, and therefore the hydraulic couplers have higher performance requirements on hydraulic transmission oil. In addition, the working condition of mechanical equipment in extremely cold regions puts severe requirements on the low-temperature performance and the service life of hydraulic transmission oil. Therefore, it is of great importance to develop hydraulic transmission oil having excellent low-temperature performance, viscosity-temperature performance and oxidation resistance.
Disclosure of Invention
In order to solve the technical problems in the prior art, the present invention aims to provide a hydraulic transmission oil composition having excellent low temperature performance, viscosity temperature performance and oxidation resistance.
In order to achieve the purpose, the technical scheme of the invention is as follows:
in order to improve the low-temperature performance, viscosity-temperature performance, oxidation resistance and other performances of the hydraulic transmission oil composition, the prior art mostly needs to add a large amount of or high-cost functional additives, but the excellent low-temperature performance and viscosity-temperature performance cannot be obtained, so that the use of the hydraulic transmission oil in a low-temperature environment is limited. The invention skillfully solves the problems by a specific compounding mode of the base oil. According to the invention, through a large amount of research and development and practice, the base oil formed by compounding the poly-alpha-olefin base oil, the naphthenic base oil and the mineral base oil is matched with a small amount of functional additives, so that the hydraulic transmission oil composition with excellent low-temperature performance and viscosity-temperature performance can be obtained, and meanwhile, the excellent oxidation resistance and extreme pressure wear resistance can be ensured.
Specifically, the technical scheme of the invention is as follows:
the invention provides a low-temperature-resistant long-life hydraulic transmission oil composition, which comprises base oil and a functional additive; the base oil includes polyalphaolefin base oil, naphthenic base oil and mineral base oil.
The invention further discovers that the reasonable control of the addition amount of the naphthenic base oil is more beneficial to improving the viscosity-temperature performance and the flash point performance of the hydraulic transmission oil composition.
Preferably, in the base oil, the content of the naphthenic base oil is 5-25% by mass. More preferably 5 to 20%.
Further, the low temperature resistance and viscosity temperature performance of the hydraulic transmission oil composition can be better ensured by selecting the naphthenic base oil and the polyalphaolefin base oil with low pour points.
Preferably, the polyalphaolefin base oil is one or a mixture of more of low pour point polyalphaolefin synthetic oils. More preferably a mixture of one or more selected from the group consisting of PAO2, PAO4 and PAO6 base oils.
Preferably, the naphthenic base oil is a low pour point naphthenic base oil with a pour point of no more than-50 ℃. More preferably one or a mixture of two selected from NS 3 and MAC 4005.
When NS 3 and MAC 4005 are selected as the naphthenic base oil, the content of the naphthenic base oil is preferably controlled to be 8-20% by mass; meanwhile, the mass ratio of the naphthenic base oil to the polyalphaolefin base oil is controlled to be (0.1-0.5): 1, the low temperature resistance, the viscosity temperature performance and the oxidation resistance of the hydraulic transmission oil composition can be ensured more favorably.
Preferably, the mineral base oil is a hydrorefined API group II base oil. More preferably one or a mixture of two selected from mineral oils II 2, II + 4.
The invention discovers that better hydraulic transmission oil composition performance can be obtained by compounding specific products in naphthenic base oil and poly-alpha olefin base oil with low pour point with specific products in mineral base oil, such as PAO6, NS 3 and mineral oil II 2; or PAO4, MAC 4005 and mineral oil II + 4; or PAO2, PAO6, MAC 4005 and mineral oil II + 4.
In the invention, the functional additive comprises one or more selected from a complexing agent, a viscosity index improver, a pour point depressant, an antioxidant and an antifoaming agent;
preferably, the hydraulic transmission oil composition comprises the following components in parts by weight:
Figure BDA0002228381270000031
more preferably, the hydraulic transmission oil composition comprises the following components in parts by weight:
Figure BDA0002228381270000032
as a preferred embodiment of the present invention, the hydraulic transmission oil composition comprises the following components in parts by weight:
Figure BDA0002228381270000033
Figure BDA0002228381270000041
as another preferred embodiment of the present invention, the hydraulic transmission oil composition comprises the following components in parts by weight:
Figure BDA0002228381270000042
as another preferred embodiment of the present invention, the hydraulic transmission oil composition comprises the following components in parts by weight:
Figure BDA0002228381270000043
in the hydraulic transmission oil composition, the complexing agent is a zinc-containing anti-wear hydraulic oil complexing agent; preferably Lz 5703.
The viscosity index improver is one or a mixture of more of polymethacrylate, ethylene propylene copolymer and polyisobutylene. Preferably polymethacrylates.
The pour point depressant is one or a mixture of two selected from polymethacrylate and alkyl naphthalene.
The antioxidant is one or more of phenolic antioxidant and amine antioxidant. Preferably one or more of dioctyl diphenylamine, styrenated diphenylamine and 2, 6-di-tert-butyl-dimethylamino-p-cresol.
The anti-foaming agent is a composite anti-foaming agent. The #1 composite antifoaming agent is preferred.
As a preferable aspect of the present invention, the hydraulic transmission oil composition includes the following components in parts by weight, based on 100 parts by weight in total:
Figure BDA0002228381270000051
in the formula, the polymethacrylate is used as a viscosity index improver and a pour point depressant.
As a preferable aspect of the present invention, the hydraulic transmission oil composition includes the following components in parts by weight, based on 100 parts by weight in total:
Figure BDA0002228381270000052
Figure BDA0002228381270000061
as a preferable aspect of the present invention, the hydraulic transmission oil composition includes the following components in parts by weight, based on 100 parts by weight in total:
Figure BDA0002228381270000062
in the formula, the polymethacrylate is used as a viscosity index improver and a pour point depressant.
The hydraulic transmission oil composition described above may be prepared by a method conventional in the art, for example: the components are mixed evenly according to the proportion.
The invention also provides a preparation method of the hydraulic transmission oil composition, which comprises the following steps: mixing base oil, a complexing agent, a viscosity index improver, a pour point depressant, an antioxidant and an antifoaming agent according to a mass ratio.
The invention also provides the application of the hydraulic transmission oil composition in a mechanical hydraulic torque converter or a coupler.
The invention has the beneficial effects that: the hydraulic transmission oil composition provided by the invention has the following advantages: according to the invention, the polyalphaolefin base oil, the naphthenic base oil and the mineral base oil are compounded, so that the low-temperature performance, the viscosity-temperature performance and the oxidation resistance of the hydraulic transmission oil composition are improved; functional additives such as a complexing agent, a viscosity index improver, a pour point depressant, an antioxidant, an anti-foaming agent and the like are further added to obtain the hydraulic transmission oil composition with excellent low-temperature performance, viscosity-temperature performance and oxidation resistance; the hydraulic transmission oil composition also has the advantages of simple preparation method, wide application range and the like, is suitable for various hydraulic transmission equipment, and is used for severe working conditions with great environmental temperature difference change.
Detailed Description
Preferred embodiments of the present invention will be described in detail with reference to the following examples. It is to be understood that the following examples are given for illustrative purposes only and are not intended to limit the scope of the present invention. Various modifications and alterations of this invention will become apparent to those skilled in the art without departing from the spirit and scope of this invention.
The experimental procedures used in the following examples are all conventional procedures unless otherwise specified.
Materials, reagents and the like used in the following examples are commercially available unless otherwise specified.
Example 1
The embodiment provides a hydraulic transmission oil composition, which consists of the following components in percentage by mass:
Figure BDA0002228381270000071
the preparation method of the hydraulic transmission oil composition comprises the following steps: mixing the above components at a certain ratio.
Example 2
The embodiment provides a hydraulic transmission oil composition, which consists of the following components in percentage by mass:
Figure BDA0002228381270000081
the preparation method of the hydraulic transmission oil composition comprises the following steps: mixing the above components at a certain ratio.
Example 3
The embodiment provides a hydraulic transmission oil composition, which consists of the following components in percentage by mass:
Figure BDA0002228381270000082
the preparation method of the hydraulic transmission oil composition comprises the following steps: mixing the above components at a certain ratio.
Comparative example 1
The comparative example provides a hydraulic transmission oil composition, which comprises the following components in percentage by mass:
Figure BDA0002228381270000091
comparative example 2
The comparative example provides a hydraulic transmission oil composition, which comprises the following components in percentage by mass:
Figure BDA0002228381270000092
experimental example 1
The hydraulic transmission oil compositions of examples 1 to 3 and comparative examples 1 to 2 were subjected to various performance evaluations, and the results are shown in table 1, and the results show that the hydraulic transmission oil compositions of examples 1 to 3 have more excellent low-temperature performance, viscosity-temperature performance, and oxidation resistance than comparative examples 1 to 2, and are applicable to severe conditions with greatly-varying environmental temperature differences.
TABLE 1 analysis of the properties of the fluid-power transmission oil composition
Figure BDA0002228381270000093
Figure BDA0002228381270000101
Although the invention has been described in detail hereinabove with respect to a general description and specific embodiments thereof, it will be apparent to those skilled in the art that modifications or improvements may be made thereto based on the invention. Accordingly, such modifications and improvements are intended to be within the scope of the invention as claimed.

Claims (10)

1. The hydraulic transmission oil composition with low temperature resistance and long service life is characterized by comprising base oil and functional additives; the base oil includes polyalphaolefin base oil, naphthenic base oil and mineral base oil.
2. The hydraulic transmission oil composition as defined in claim 1, wherein the content of the naphthenic base oil in the base oil is 5 to 25% by mass.
3. The hydraulic transmission oil composition as recited in claim 1 or 2, wherein the polyalphaolefin base stock is a mixture of one or more of low pour point polyalphaolefin synthetic oils;
preferably a mixture of one or more selected from PAO2, PAO4 and PAO6 base oils.
4. The hydraulic transmission oil composition as defined in any one of claims 1 to 3, wherein the cycloalkyl base oil is a low pour point cycloalkyl base oil having a pour point of not higher than-50 ℃;
preferably one or two of NS 3 and MAC 4005;
more preferably, the content of the naphthenic base oil is 8-20% by mass; the mass ratio of the naphthenic base oil to the poly-alpha-olefin base oil is (0.1-0.5): 1.
5. the hydraulic transmission oil composition as defined in any one of claims 1 to 4, wherein the mineral base oil is a hydrorefined APIII base oil;
preferably one or a mixture of two selected from mineral oils II 2, II + 4.
6. The hydraulic transmission oil composition as claimed in any one of claims 1 to 5, wherein the functional additive comprises one or more selected from a complexing agent, a viscosity index improver, a pour point depressant, an antioxidant and an anti-foaming agent;
preferably, the hydraulic transmission oil composition comprises the following components in parts by weight:
Figure FDA0002228381260000011
Figure FDA0002228381260000021
7. the hydraulic transmission oil composition as defined in any one of claims 1 to 6, comprising the following components in parts by weight:
Figure FDA0002228381260000022
8. the hydraulic transmission oil composition as claimed in any one of claims 1 to 7, wherein the complex agent is a zinc-containing anti-wear hydraulic oil complex agent; preferably Lz 5703;
and/or the viscosity index improver is one or a mixture of more of polymethacrylate, ethylene propylene copolymer and polyisobutylene; preferably polymethacrylates;
and/or the pour point depressant is one or a mixture of two selected from polymethacrylate and alkyl naphthalene;
and/or the antioxidant is one or a mixture of more of phenolic antioxidant and amine antioxidant; preferably one or more of dioctyl diphenylamine, styrenated diphenylamine and 2, 6-di-tert-butyl-dimethylamino-p-cresol;
and/or the antifoaming agent is a composite antifoaming agent.
9. The method for producing a hydraulic transmission oil composition according to any one of claims 1 to 8, comprising: mixing base oil, a complexing agent, a viscosity index improver, a pour point depressant, an antioxidant and an antifoaming agent according to a mass ratio.
10. Use of the hydraulic transmission oil composition according to any one of claims 1 to 8 in a mechanical torque converter or a coupling.
CN201910959270.8A 2019-10-10 2019-10-10 Low-temperature-resistant long-life hydraulic transmission oil composition and preparation method and application thereof Pending CN112646649A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115161097A (en) * 2022-07-04 2022-10-11 珠海美合科技股份有限公司 Preparation method of three-in-one bridge oil for electric automobile

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102757842A (en) * 2011-04-29 2012-10-31 中国石油化工股份有限公司 Ashless low-temperature hydraulic oil
CN103571589A (en) * 2012-07-31 2014-02-12 中国石油化工股份有限公司 Shock absorber oil composition
CN105969498A (en) * 2016-05-31 2016-09-28 广东哈弗石油能源有限公司 Environment-friendly energy-saving hydrodynamic drive oil composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102757842A (en) * 2011-04-29 2012-10-31 中国石油化工股份有限公司 Ashless low-temperature hydraulic oil
CN103571589A (en) * 2012-07-31 2014-02-12 中国石油化工股份有限公司 Shock absorber oil composition
CN105969498A (en) * 2016-05-31 2016-09-28 广东哈弗石油能源有限公司 Environment-friendly energy-saving hydrodynamic drive oil composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115161097A (en) * 2022-07-04 2022-10-11 珠海美合科技股份有限公司 Preparation method of three-in-one bridge oil for electric automobile

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Application publication date: 20210413