CN114075472B - Efficient energy-saving automobile steering system oil - Google Patents
Efficient energy-saving automobile steering system oil Download PDFInfo
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- CN114075472B CN114075472B CN202010833192.XA CN202010833192A CN114075472B CN 114075472 B CN114075472 B CN 114075472B CN 202010833192 A CN202010833192 A CN 202010833192A CN 114075472 B CN114075472 B CN 114075472B
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/142—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings polycarboxylic
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/086—Imides
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
- C10M2219/068—Thiocarbamate metal salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/043—Ammonium or amine salts thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
Abstract
The invention relates to the technical field of automobiles, in particular to high-efficiency energy-saving automobile steering system oil which comprises the following components in percentage by weight: 0.1 to 10 percent of antioxidant, 0.5 to 10 percent of dispersant, 0.1 to 0.5 percent of extreme pressure antiwear agent, 3 to 10 percent of rubber improver, 0.01 to 0.2 percent of antifoaming agent, 0.1 to 1 percent of friction improver and the balance of coal-made base oil. The automobile steering system oil composition selects coal base oil, optimizes and combines an antioxidant, a dispersing agent, an extreme pressure antiwear agent, a rubber improver, an antifoaming agent and a friction improver, plays a role in transmitting steering force and buffering in an automobile steering system, has the characteristics of high efficiency and energy saving, can obviously reduce the labor intensity of a driver for steering, and improves the maneuverability and the stability of the automobile steering system.
Description
Technical Field
The invention relates to the technical field of automobiles, in particular to efficient and energy-saving automobile steering system oil.
Background
The steering system of the automobile is an important device for controlling the driving route and direction of the automobile, and directly influences the maneuverability and stability of the automobile. For an automobile steering system, besides the requirements of safe and reliable operation, light operation, good maneuverability, high efficiency and energy conservation, the automobile steering system also needs to be capable of providing the best road feel under various working conditions (such as straight running, normal steering, fast steering, pivot steering and the like) according to different running speeds and road conditions.
A steering system for an automobile generally includes: steering gear, steering oil pump, oilcan, oil pipe and coupling. The energy required by the steering gear comes from a steering oil pump, and the steering oil pump transmits steering force through steering system oil, so that the performance of the steering system oil directly determines the performance of the steering gear. If the working pressure and flow provided by the steering oil pump are too low, the steering oil pump feels heavy or cannot move; when the working pressure and the flow provided by the steering oil pump are too high (the valve is blocked), the high-pressure oil can pierce the low-pressure seal, so that the steering engine leaks oil; therefore, the steering system of the automobile requires that the used steering system oil has excellent viscosity-temperature performance, extreme pressure abrasion resistance, rubber compatibility and proper friction performance under various working conditions and environments. If the steering system oil contains air or foam, the phenomena of noise and poor power assisting effect can be generated, so the steering system oil also needs to have good anti-foam performance, and simultaneously has good oxidation resistance and oil sludge dispersion performance to meet the requirement of long oil change period.
In view of the above, there is a need to develop an oil product having excellent viscosity-temperature properties, oxidation resistance, sludge dispersibility, extreme pressure antiwear properties, rubber compatibility, anti-foaming properties, friction properties, and being highly efficient and energy-saving for use in an automobile steering system.
Disclosure of Invention
The invention aims to provide the automobile steering system oil which has excellent viscosity-temperature performance, oxidation resistance, oil sludge dispersion performance, extreme pressure abrasion resistance, rubber compatibility, anti-foaming performance, friction performance, high efficiency and energy conservation.
Specifically, the invention provides the following technical scheme.
The automobile steering system oil comprises the following components in percentage by weight:
preferably, the automobile steering system oil comprises the following components in percentage by weight:
preferably, the antioxidant is one or a mixture of more than two of octyl diphenylamine, thiocarbamate and tolyltriazole;
further preferably tolyltriazole, which has the characteristics of excellent high-temperature thermal stability and good compounding effect with various additives, and also has certain metal corrosion resistance.
Preferably, the dispersant is one or a mixture of more than two of boronized succinimide, bis-succinimide and polyisobutylene succinate;
more preferably polyisobutylene succinate, which does not contain metal elements, is an ashless type additive, and has excellent dispersing properties at both low and high temperatures.
Preferably, the extreme pressure antiwear agent is one or a mixture of more than two of calcium borate, butyl isooctyl dodecyl phosphate and butyl triphenyl thiophosphate;
further preferably butyl triphenyl phosphorothioate, which has excellent thermal stability and wear resistance and is non-corrosive to yellow metals.
Preferably, the rubber improver is one or a mixture of more than two of 2, 2-ethyl hexyl sebacate, dioctyl adipate and 2, 2-ethyl phthalate;
the 2, 2-ethyl phthalate is further preferable, the 2, 2-ethyl phthalate can improve the compatibility of a steering system with rubber, especially the steering system oil blended by coal base oil, the coal base oil can shrink a rubber sealing element to cause oil leakage, and after the 2, 2-ethyl phthalate is added, the shrinkage effect of the coal base oil on the rubber sealing element can be obviously improved, the steering system sealing element is ensured to deform little, and the oil leakage is avoided.
Preferably, the anti-foaming agent is one or a mixture of more than two of polysiloxane, polymethylsilicone oil and octyl acrylate;
further preferably octyl acrylate, and the octyl acrylate has excellent anti-foaming performance and air release performance, quick defoaming and lasting foam inhibition.
Preferably, the friction modifier is one or a mixture of more than two of vulcanized vegetable oil, nitrogen borate ester and dialkyl molybdenum dithiocarbamate;
and the preferable molybdenum dialkyl dithiocarbamate is further molybdenum dialkyl dithiocarbamate, and the molybdenum dialkyl dithiocarbamate can effectively reduce friction between steering system oil and the surface of equipment, so that the automobile steering system is more efficient and energy-saving, and has certain oxidation resistance.
As a preferred combination, the specific choices of the components are:
alternatively, the first and second electrodes may be,
alternatively, the first and second electrodes may be,
the preferable scheme comprises the following components in parts by weight:
the rubber modifier is 2, 2-ethyl phthalate, the antifoaming agent is octyl acrylate, and the friction modifier is dialkyl molybdenum dithiocarbamate.
As a preferred example, the composition comprises the following components in percentage by weight:
or the automobile steering system oil comprises the following components in percentage by weight:
or the automobile steering system oil comprises the following components in percentage by weight:
the invention also provides a preparation method of the automobile steering system oil, which comprises the following steps: adding an antioxidant, a dispersant, an extreme pressure antiwear agent, a rubber improver, an anti-foaming agent and a friction improver into the coal-based base oil in sequence, and stirring for 4.5-5.5 hours at 55-65 ℃ to obtain the lubricant.
The invention has the following beneficial effects:
the invention provides a steering system oil product which is efficient and energy-saving and improves the maneuverability and the stability of an automobile steering system under various road working conditions. The steering system oil composition has stable performance and reliable quality, has excellent viscosity-temperature performance, oxidation resistance, oil sludge dispersion performance, extreme pressure abrasion resistance, rubber compatibility, foam resistance and friction performance, can obviously reduce the labor intensity of a driver for steering, improves the maneuverability and stability of an automobile steering system, is efficient and energy-saving, and is particularly suitable for lubricating, sealing and transmitting work of the automobile steering system.
Detailed Description
The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention. The examples do not show the specific techniques or conditions, according to the technical or conditions described in the literature in the field, or according to the product specifications. The reagents or instruments used are conventional products available from normal commercial vendors, not indicated by the manufacturer.
In each embodiment of the invention, the coal-based base oil is purchased from Shanxi Lu' an group; the tolyltriazole and the dialkyl molybdenum dithiocarbamate are purchased from Van der Bit company; polyisobutylene succinate and octyl acrylate were purchased from luoborun corporation; butyl triphenyl phosphorothioate available from basf; 2, 2-ethyl phthalate was purchased from petrochemical technology development, inc. of Changling, hunan. The other reagents are all conventional and commercially available.
Example 1
The composition of the automobile steering system oil composition comprises the following components:
sequentially adding the tolyltriazole, the polyisobutylene succinate, the butyl triphenyl thiophosphate, the 2, 2-ethyl phthalate, the octyl acrylate and the dialkyl molybdenum dithiocarbamate into the coal base oil according to the dosage, and mixing and stirring for 5 hours at 60 ℃ to obtain the composition.
Example 2
The composition of the automobile steering system oil composition of the embodiment is as follows:
the octyl diphenylamine, the boronized succinimide, the calcium borate, the 2, 2-ethyl hexyl sebacate, the polysiloxane and the vulcanized vegetable oil are sequentially added into the coal-made base oil according to the dosage, and are mixed and stirred for 5.5 hours at the temperature of 55 ℃ to obtain the composition.
Example 3
The composition of the automobile steering system oil composition of the embodiment is as follows:
and sequentially adding the thiocarbamate, the bis-succinimide, the butylisooctyl dodecylamine phosphate, the dioctyl adipate, the polymethylsilicone oil and the nitrogen borate into the coal base oil according to the dosage, and mixing and stirring for 4.5 hours at 65 ℃ to obtain the composition.
Comparative example 1
The difference is that the antioxidant is 2, 6-di-tert-butyl-p-cresol, as compared with example 1.
Comparative example 2
The difference compared to example 1 is that the friction modifier is a phosphonate.
The performances of the automobile steering system oil compositions provided in examples 1 to 3 and comparative examples 1 to 2 are compared in the following table, wherein the test items and methods are shown in table 1, and the test results are shown in table 2.
TABLE 1
TABLE 2 Performance data for an energy efficient automotive steering system oil composition
As shown by the pour point and the kinematic viscosity data at the temperature of minus 20 ℃, the invention has good fluidity in a low-temperature environment.
It is seen from the seal suitability index data that the present invention has good compatibility with rubber.
The oxidation stability data show that the antioxidant oil composition has good oxidation resistance, can effectively inhibit the generation of oil sludge, and prolongs the oil change period of the steering system oil.
The foaming data shows that the foam-resistant coating has excellent foam resistance, can quickly defoam and inhibit foam for a long time.
The wear-resisting extreme pressure wear-resisting agent has excellent extreme pressure wear-resisting performance as shown by the wear-resisting spot diameter and the vane pump test data.
As seen from the friction characteristic data, the present invention has excellent friction characteristics.
The pump efficiency improvement rate data shows that the invention has the characteristics of high efficiency and energy saving.
Meanwhile, in embodiments 1 to 3, the composition provided in embodiment 1 has the best comprehensive performance, which indicates that tolyltriazole, polyisobutylene succinate, butyl triphenyl thiophosphate, 2-ethyl phthalate, octyl acrylate, dialkyl molybdenum dithiocarbamate and coal-made base oil are used in combination, so that the composition has very excellent viscosity-temperature performance, oxidation resistance, oil sludge dispersion performance, extreme pressure abrasion resistance, rubber compatibility, anti-foaming performance and friction performance, can remarkably reduce the labor intensity of a driver for steering, improves the maneuverability and stability of an automobile steering system, is efficient and energy-saving, and is particularly suitable for lubricating sealing and transferring work of the automobile steering system.
Although the invention has been described in detail hereinabove by way of general description, specific embodiments and experiments, it will be apparent to those skilled in the art that modifications and improvements can be made thereto without departing from the scope of the invention. Accordingly, such modifications and improvements are intended to be within the scope of the invention as claimed.
Claims (3)
1. The automobile steering system oil is characterized by comprising the following components in percentage by weight:
5 to 6 percent of antioxidant;
6 to 7 percent of dispersant;
extreme pressure antiwear agent 0.25-0.35%;
6 to 7 percent of rubber improver;
0.1 to 0.13 percent of antifoaming agent;
0.6 to 0.7 percent of friction modifier;
the balance of coal-made base oil;
the rubber modifier is 2, 2-ethyl phthalate, the antifoaming agent is octyl acrylate, and the friction modifier is dialkyl molybdenum dithiocarbamate.
2. The automobile steering system oil according to claim 1, wherein the coal-based base oil has a kinematic viscosity of 44 to 48mm at 40 ℃ 2 /s。
3. The automobile steering system oil according to claim 1, characterized by comprising the following components in percentage by weight:
5.5 percent of tolyltriazole;
6.5 percent of polyisobutylene succinate;
butyl triphenyl thiophosphate 0.3%;
6.5 percent of 2, 2-ethyl phthalate;
0.12 percent of octyl acrylate;
0.65% of molybdenum dialkyl dithiocarbamate;
the balance of the coal-made base oil.
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CN115058278B (en) * | 2022-07-05 | 2023-07-21 | 郑州市欧普士科技有限公司 | Gearbox oil and preparation method and application thereof |
CN116083136A (en) * | 2023-02-08 | 2023-05-09 | 徐工集团工程机械股份有限公司 | Lubricating oil composition and method for producing the same |
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US7214648B2 (en) * | 1997-08-27 | 2007-05-08 | Ashland Licensing And Intellectual Property, Llc | Lubricant and additive formulation |
US5916852A (en) * | 1997-09-02 | 1999-06-29 | Exxon Chemical Patents Inc. | Power transmission fluids with improved friction break-in |
KR20000026786A (en) * | 1998-10-19 | 2000-05-15 | 정몽규 | Operating oil for steering apparatus of automobile |
US20070213235A1 (en) * | 2002-07-29 | 2007-09-13 | Saini Mandeep S | Lubricant and additive formulation |
JP4677359B2 (en) * | 2005-03-23 | 2011-04-27 | アフトン・ケミカル・コーポレーション | Lubricating composition |
US8022024B2 (en) * | 2007-06-28 | 2011-09-20 | Chevron U.S.A. Inc. | Functional fluid compositions |
CN102337172B (en) * | 2010-07-27 | 2013-10-30 | 中国石油化工股份有限公司 | Directional power-assisted oil composition and its application |
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