CN108793764A - The surface treatment method and glassware of glassware - Google Patents
The surface treatment method and glassware of glassware Download PDFInfo
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- CN108793764A CN108793764A CN201810710630.6A CN201810710630A CN108793764A CN 108793764 A CN108793764 A CN 108793764A CN 201810710630 A CN201810710630 A CN 201810710630A CN 108793764 A CN108793764 A CN 108793764A
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- glassware
- surface treatment
- treatment method
- texture
- glass
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/72—Decorative coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/112—Deposition methods from solutions or suspensions by spraying
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/118—Deposition methods from solutions or suspensions by roller-coating
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
The invention belongs to glass surface treatment technical fields, are related to a kind of surface treatment method and glassware of glassware.The surface treatment method of the glassware of the present invention, including surface cleaning, colouring and drying；Wherein, used raw material includes mill base and texture slurry during colouring, and the texture slurry includes following components by weight percentage：Isopropanol 20%~30%, propylene glycol methyl ether acetate 50%~70% and nano silicon dioxide 10%~20%.The environmental-protecting performance of the present invention greatly promotes, it is nontoxic and pollution-free, the environmental-friendly artistic glassware of production has special decorative effect, it is strong to decorate texture, it is rich in color and lively, to glass material without limitation, the production of a large amount can be realized at a lower cost, can realize big batch metaplasia production truly.
Description
Technical field
The invention belongs to glass surface treatment technical fields, in particular to a kind of surface treatment side of glassware
Method and glassware.
Background technology
It is wide as spare part since glass has higher intensity, hardness and wearability, and the features such as corrosion resistance is good
General building, daily, medical, chemical, electronics, the instrument of being applied to is at field.With the development and improvement of living standard of society, people
It is higher and higher to the moulding of glass and the requirement of decorative effect, it is environmentally friendly, energy saving, efficient, have texture be glass production industry hair
The fresh target of exhibition.But prior art to product do appearance or surface treatment when, often use lacquer spraying technique, be to pass through spray gun
By means of air pressure, paint solution is dispersed into uniform and fine droplet, applies a kind of method on the surface for imposing on coated article.
Spray painting is one kind of artificial lacquer, is made of nitrocellulose, resin, pigment, solvent etc., water-fast, resistance to machine oil, is done
Soon；It can be used for painting automobile, aircraft, woodenware, leather etc..However, the substance is toxic, there are certain influence, different brands to body
Spray painting due to component content difference toxicity it is also different；When in use it should be particularly noted that safety, avoids sucking and skin contact.
If painted in the case that unshielded, benzene concentration is quite high in air of workplace, very harmful to spray painting worker.Long Term Contact
Benzene can cause slow poisoning, and Neuroleptic Leukocytopenia, blood platelet is caused to reduce, and hemopoietic function of bone marrow occurs the diseases such as obstacle and generates.Separately
Outside, harm of the paint to human body, can also not only be absorbed by lung sucks by skin；Human skin is straight
It connects and is contacted with paint, the fat in skin can be dissolved, cause chapped skin, also into human body while inflammation.When therefore painting
Protection configuration must be got ready, while limiting the working time (preferably not more than 30 minutes), and job site to have it is good
Ventilation condition；Otherwise it will affect human health, it is heavy then leukaemia can be suffered from.
Not only environmental-protecting performance is poor for existing lacquer spraying technique, have an impact to health, there are security risk and to environment, set
It is standby more demanding, and treated that product also lacks texture and three-dimensional sense, and without color change and level, dull coloring is not rich
Richness simplifies product stream in low gradeization；The surface color having simultaneously is insecure, is easy to fade, wrinkle, influences product matter
Amount uses limitation there are larger, cannot meet consumer demand.
In consideration of it, special propose the present invention.
Invention content
The first object of the present invention is to provide a kind of surface treatment method of glassware, and environmental-protecting performance greatly promotes,
Pollution-free, the environmental-friendly artistic glassware of production has special decorative effect, and decoration texture is strong, rich in color and lively,
And the production of a large amount can be realized at a lower cost, it can realize big batch metaplasia production truly.
The second object of the present invention is to provide a kind of glassware, glassware of the glassware by the present invention
It being made after surface treatment method processing, the glassware good environmental protection, existing preferable water resistance has good gas permeability again,
Decoration texture is strong, and color change is various, abundant and lively, and product is made to have more aesthetic feeling.
To achieve the above object, the technical solution adopted by the present invention is：
According to an aspect of the present invention, the present invention provides a kind of surface treatment method of glassware, including surface is clear
Clean, colouring and drying；
Wherein, used raw material includes mill base and texture slurry, texture slurry percentage by weight during colouring
Than including following components：
Isopropanol 20%~30%, propylene glycol methyl ether acetate 50%~70% and nano silicon dioxide 10%~20%.
As further preferred technical solution, the texture slurry includes following components by weight percentage：Isopropanol
22%~28%, propylene glycol methyl ether acetate 54%~68% and nano silicon dioxide 10%~18%.
As further preferred technical solution, the texture slurry includes following components by weight percentage：Isopropanol
24%~28%, propylene glycol methyl ether acetate 56%~64% and nano silicon dioxide 12%~16%.
As further preferred technical solution, the weight ratio of the mill base and the texture slurry is (12~2)：(88~
98), preferably (10~3)：(90~97), further preferably (8~4)：(92~96).
As further preferred technical solution, to the glass after surface cleaning by the way of spraying, roller coating or showering
Glass product is painted, it is preferred to use the mode of spraying.
As further preferred technical solution, the coating thickness of spraying is 1~6 μm, preferably 2~4 μm.
As further preferred technical solution, the step of surface cleaning, includes：First use glass cleaner to glass
Surface is washed, and is then cleaned with clear water, then is dried.
As further preferred technical solution, the drying is that baking chains, and the baking link preferably uses infrared ray
The mode of baking.
As further preferred technical solution, the time of infrared ray baking is 8~15min, and temperature is 160~180 DEG C；
Preferably, the time of infrared ray baking is 9~14min, and temperature is 165~175 DEG C.
According to another aspect of the present invention, the present invention also provides a kind of glasswares, by above-mentioned glassware
It is made after surface treatment method processing.
Compared with prior art, the beneficial effects of the present invention are：
1, the surface treatment method of the glassware of offer of the invention, by way of surface cleaning, colouring and drying
The surface treatment to glassware can be completed, technological process is simple, is conveniently operated, to environment, place, equipment etc. without special limit
System, practicability and adaptable is a kind of environmentally friendly, energy saving, efficient, inexpensive processing method.Especially the present invention is painting
In the process, mill base and texture slurry comprising isopropanol, propylene glycol methyl ether acetate and nano silicon dioxide are used cooperatively, pole
The texture of the big glass that enhances that treated, and the bright sense of various surface tactile sensations such as cloudy surface, crystal can be converted etc., while color
Coloured silk can also convert various such as monochromatic, monochromatic gradual change, multi-color gradual change, can be arranged in pairs or groups with the individual character of more options, texture is strong, rich
It is rich and lively, so that product is had more aesthetic feeling, makes us fresh and new.
2, texture slurry of the invention is feature of environmental protection slurry, nontoxic and pollution-free, avoids spray painting and is produced in use
Raw volatile organic toxic gas can generate health and surrounding enviroment certain harm；The slurry also has simultaneously
Preferable water resistance, solvent resistance and good gas permeability etc..Pass through isopropanol, propylene glycol methyl ether acetate and nanometer titanium dioxide
The coordinated of silicon acts on, and can enhance the texture of product, shows special decorative effect, and with preferable adhesive force and
Stability.
3, materials safety good environmental protection of the present invention, while technological process is simple, low for equipment requirements, investment
It is at low cost, therefore the production of a large amount can be realized at a lower cost, it can realize big batch metaplasia truly
Production, application easy to spread.
4, the present invention for glass material without limitation, it is more adaptable.The glass obtained after method processing through the invention
Glass product has good environmental protection, and decoration texture is strong, and color change is various, can be monochromatic, monochromatic gradual change or multi-color gradual change,
It is abundant and lively, product quality stablize, more aesthetic feeling the features such as.
Specific implementation mode
Embodiment of the present invention is described in detail below in conjunction with embodiments and examples, but this field skill
Art personnel will be understood that following embodiments and embodiment are merely to illustrate the present invention, and be not construed as the model of the limitation present invention
It encloses.Based on the embodiments of the present invention, obtained by those of ordinary skill in the art without making creative efforts
Every other embodiment, shall fall within the protection scope of the present invention.The person that is not specified actual conditions, builds according to normal condition or manufacturer
The condition of view carries out.Reagents or instruments used without specified manufacturer is the conventional production that can be obtained by commercially available purchase
Product.
In a first aspect, a kind of surface treatment method of glassware is provided at least one embodiment, including surface is clear
Clean, colouring and drying；
Wherein, used raw material includes mill base and texture slurry, texture slurry percentage by weight during colouring
Than including following components：
Isopropanol 20%~30%, propylene glycol methyl ether acetate 50%~70% and nano silicon dioxide 10%~20%.
The surface treatment to glassware can be completed in the present invention by way of surface cleaning, colouring and drying.This hair
The coordinated of the operation slurry of the bright production technology and independent research by independent research acts on, and simplifies surface treatment work
Skill saves production time and cost, and technological process is simple, easy to operate, easy to implement, and processing raw material sources are wide, economical easy
It obtains, be nontoxic, environment-friendly type raw material, alleviate existing technique and the problem of endangering will produce to health and environment.The present invention
To environment, place, equipment etc. without specifically limited, used raw material dosage is few, and safety and environmental protection performance is good, low for equipment requirements,
Cost of investment is low, practicability and adaptable, is a kind of environmentally friendly, energy saving, efficient, inexpensive and good treatment effect surface treatment
Method can realize the production of a large amount at a lower cost, can realize big batch metaplasia production truly, be easy to
It promotes and applies.Further speaking：
The present invention by mill base and includes isopropanol, propylene glycol methyl ether acetate and nano silicon dioxide during colouring
Texture slurry be used cooperatively, the texture for the glass that greatly enhances that treated, to glass article surface texture without limitation, and
Can convert bright sense of various surface tactile sensations such as cloudy surface, crystal etc., at the same color can also convert it is various, it is such as monochromatic, monochromatic gradually
Change, multi-color gradual change etc. can be arranged in pairs or groups with the individual character of more options, and texture is strong, abundant and lively, and product is made to have more aesthetic feeling, can be with
Meet the esthetic requirement of different people.And used texture slurry is feature of environmental protection slurry, nontoxic and pollution-free, environmental-friendly, nothing
Pernicious gas volatilizees, and improves atmospheric environment, avoids volatile organic toxic gas caused by spray painting in use,
Health and surrounding enviroment can be led to the problem of endanger, also alleviate existing lacquer spraying technique glassware have it is very strong
The problem of plastic cement sense.
It is acted on by the coordinated of isopropanol, propylene glycol methyl ether acetate and nano silicon dioxide, product can be enhanced
Texture, show special decorative effect, and there is preferable adhesive force and stability.In addition, as above-mentioned isopropanol, the third two
When alcohol methyl ether acetate and nano silicon dioxide are grouped as and are matched using above-mentioned group, influence each other between each component, it is mutually auxiliary
It coordinates, synergistic effect more preferably, can more embody above-mentioned texture slurry environmental protection, the valence that economic, personalized and decoration texture is strong
Value.
In addition, the present invention to the glass material type used in operating process without limitation, appointed using commonly used in the art
What glass material.The method of the present invention in turn avoids while improving the appearance characteristics of glassware to glass material
The limitation of type, it is more adaptable, wider application can be obtained.
It should be noted that the present invention does not have the source of isopropanol, propylene glycol methyl ether acetate and nano silicon dioxide
There is special limitation, using each raw material well-known to those skilled in the art；Its commercial goods such as may be used, it can also
It is voluntarily prepared using preparation method well known to those skilled in the art.
Type also not special limitation for the source of used mill base, mill base is commercially available
The product arrived.
In the present invention, isopropanol and propylene glycol methyl ether acetate be added can the transparent feel of reinforcing glass product, brightness,
Glass can be made limpid as crystal, nano silicon dioxide be added can reinforcing glass product the performances such as wearability, extend
The service life of product.In percentage by weight, the typical but non-limiting content of isopropanol can be 20%, 21%,
22%, 23%, 24%, 25%, 26%, 27%, 28%, 29% or 30%；Propylene glycol methyl ether acetate is typical but non-limiting
Content can be 50%, 52%, 54%, 55%, 56%, 58%, 60%, 62%, 64%, 65%, 66%, 68% or
70%；The typical but non-limiting content of nano silicon dioxide can be 10%, 11%, 12%, 13%, 14%, 15%,
16%, 17%, 18%, 19% or 20%.
In a preferred embodiment, the texture slurry includes following components by weight percentage：Isopropanol
22%~28%, propylene glycol methyl ether acetate 54%~68% and nano silicon dioxide 10%~18%；
Preferably, the texture slurry includes following components by weight percentage：Isopropanol 24%~28%, propylene glycol first
Ether acetate 56%~64% and nano silicon dioxide 12%~16%.
By rationally adjusting the proportioning between each component, the coordinated effect between each component is given full play to, is improved
Texture effect, enhances the aesthetics of glassware, also can further improve the performances such as adhesive force, stability.
In a preferred embodiment, the weight ratio of the mill base and the texture slurry is (12~2)：(88~
98), preferably (10~3)：(90~97), further preferably (8~4)：(92~96).
The ratio of mill base of the present invention and texture slurry can allocate according to the actual needs, recall color sense in principle
It is adapted with texture.Typical but unrestricted, the weight ratio of mill base and texture slurry can be 12：88,10：90,8：92,
6：94,5：95 or 4：96 etc..
Mill base of the present invention is the conventional mill base of commercially available this field, such as can be oil pastes, and color includes
A kind of compounding of the color such as black, grey, coffee color, red, green, yellow or multiple color.It can be according to different people's
Demand, selectivity add different types of mill base, and there is no special restriction on this by the present invention.
Conventional mixing complex process, the conventional skill of this field can be used in the preparation method of texture slurry of the present invention
Art means, it is specific as follows：
Isopropanol, propylene glycol methyl ether acetate and nano silicon dioxide are weighed according to formula rate, are mixed evenly
?.
In a preferred embodiment, to the glass after surface cleaning by the way of spraying, roller coating or showering
Glass product is painted, it is preferred to use the mode of spraying.
Preferably, spraying carries out at normal temperatures and pressures, and the air pressure of spraying and flow can adjust as desired；
Preferably, the air pressure of spraying is 100~300kPa；
And/or the flow of spraying is 20~60CC/min, preferably 30~50CC/min；Flow be generally small flow or
Middle flow, generally can be according to the different adjustment for carrying out flow of size, the required texture effect of product etc.；
And/or the temperature of spraying is 15~35 DEG C.The painting of the glassware obtained under spraying conditions within the above range
Film thickness is evenly, wrinkle resistant, not seediness, no tangerine peel.
It is understood that the present invention is not particularly limited the specific application mode during colouring, this can be used
Commonly used equipment carries out conventional operation in field.It is preferred that being painted by the way of spraying, such as can be that will get ready
Glass be put into spray-painting production line, ready mill base and texture slurry are sprayed on glass surface at normal temperatures and pressures, it is right
Glass surface after cleaning is painted, wherein air pressure and flow can be adjusted according to actual demand.
In a preferred embodiment, the coating thickness of spraying is 1~6 μm, preferably 2~4 μm；Typical but non-limit
System, such as can be 1 μm, 2 μm, 3 μm, 4 μm, 5 μm or 6 μm.
Invention provides for the coating thickness of spraying, preferably at 2 μm or so.The thickness of film is too thin, can make glass system
The clear sense of product is poor, and the thickness of film is too thick, will appear tangerine peel.
In a preferred embodiment, the step of surface cleaning includes：First use glass cleaner to glass
Surface is washed, and is then cleaned with clear water, then is dried.
It needing to illustrate, glass cleaner of the present invention is the glass cleaner of commercially available this field routine,
Such as can be aqueous cleaning agent or white point oil etc., there is no special restriction on this by the present invention, as long as can be by the dirt on glass
Etc. cleaning up.
In the present invention, first glass substrate surface to be painted is cleaned, removes glass surface dirt；It first uses general
Logical glass cleaner carries out first time washing to glass, then carries out second cleaning to glass with deionized water, then into
Row drying, it is spare.Dry temperature, time etc. are not particularly limited, carried out using the routine operation of this field.Example
The temperature that such as can be drying is 100~120 DEG C；The dry time is 5~10min.
Before spraying, glass is cleaned and is dried, is more advantageous to the progress of spraying, the glassware color after spraying
Evenly, wrinkle resistant, not seediness, bubble-free.
In a preferred embodiment, the drying is that baking chains, and the baking link preferably uses infrared ray
The mode of baking.
Preferably, the time of infrared ray baking is 8~15min, and temperature is 160~180 DEG C；；It is typical but unrestricted, when
Between for example can be 8min, 9min, 10min, 11min, 12min, 13min, 14min or 15min, temperature for example can be 160
DEG C, 162 DEG C, 165 DEG C, 166 DEG C, 170 DEG C, 172 DEG C, 175 DEG C or 180 DEG C.
Preferably, the time of infrared ray baking is 9~14min, and temperature is 165~175 DEG C；
It is highly preferred that the time of infrared ray baking is 10min, temperature is 170 DEG C.
The glass surface after colouring is dried by the way of infrared ray baking, it is efficient, the time is short, effect is good；
It can ensure that the ingredient in slurry is fully diffused into glass surface, improve treatment effect.The temperature of baking be not easy it is too high or too low,
Temperature is too low to be not achieved treatment effect, is also easy to fall off, and temperature is excessively high, will appear cracking.
The above-mentioned surface treatment method of the present invention cannot be only used for various glass (including tempered glass, common float glass
Deng) processing on surface, it may also be used for the surface treatment of other inorganic material, treatment effect are good, at low cost, applied widely.
Second aspect provides a kind of glassware at least one embodiment, by the surface of above-mentioned glassware
It is made after processing method processing.
The glassware obtained after method processing through the invention has good environmental protection, and decoration texture is strong, has
The features such as clear sense as crystal, color change is various, abundant and lively, product quality stabilization, more aesthetic feeling.
With reference to specific embodiment and comparative example, the invention will be further described.
Embodiment 1
A kind of surface treatment method of glassware, includes the following steps：Surface cleaning, colouring and drying；
Wherein, used raw material includes mill base and texture slurry during colouring, and texture slurry wraps by weight percentage
Include following components：
Isopropanol 24%, propylene glycol methyl ether acetate 58% and nano silicon dioxide 18%.
Embodiment 2
A kind of surface treatment method of glassware, includes the following steps：Surface cleaning, colouring and drying；
Wherein, used raw material includes mill base and texture slurry during colouring, and texture slurry wraps by weight percentage
Include following components：
Isopropanol 24%, propylene glycol methyl ether acetate 64% and nano silicon dioxide 12%.
Embodiment 3
A kind of surface treatment method of glassware, includes the following steps：Surface cleaning, colouring and drying；
Wherein, used raw material includes mill base and texture slurry during colouring, and texture slurry wraps by weight percentage
Include following components：
Isopropanol 28%, propylene glycol methyl ether acetate 56% and nano silicon dioxide 16%.
Embodiment 4
A kind of surface treatment method of glassware, includes the following steps：
Surface cleaning：First time washing first is carried out to glass using common glass cleaner, then with deionized water pair
Glass carries out second and cleans, and is then dried, spare；
Colouring：Using ready mill base and texture slurry by surface cleaning, treated that glass surface carries out room temperature
It is sprayed under normal pressure, the coating thickness of spraying is 6 μm；
Wherein, the weight ratio of mill base and texture slurry is 10：90, texture slurry includes following components by weight percentage：
Isopropanol 26%, propylene glycol methyl ether acetate 60% and nano silicon dioxide 14%；
It is dry：Baking link is carried out by the way of infrared ray baking, the time of infrared ray baking is 10min, and temperature is
170℃；Then cooled to room temperature.
Embodiment 5
A kind of surface treatment method of glassware, includes the following steps：
Surface cleaning：First time washing first is carried out to glass using common glass cleaner, then with deionized water pair
Glass carries out second and cleans, and is then dried, spare；
Colouring：Using ready mill base and texture slurry by surface cleaning, treated that glass surface carries out room temperature
It is sprayed under normal pressure, the coating thickness of spraying is 5 μm；
Wherein, the weight ratio of mill base and texture slurry is 8：92, texture slurry includes following components by weight percentage：It is different
Propyl alcohol 30%, propylene glycol methyl ether acetate 55% and nano silicon dioxide 15%；
It is dry：Baking link is carried out by the way of infrared ray baking, the time of infrared ray baking is 12min, and temperature is
175℃。
Embodiment 6
A kind of surface treatment method of glassware, includes the following steps：
Surface cleaning：First time washing first is carried out to glass using common glass cleaner, then with deionized water pair
Glass carries out second and cleans, and is then dried, spare；
Colouring：Using ready mill base and texture slurry by surface cleaning, treated that glass surface carries out room temperature
It is sprayed under normal pressure, the coating thickness of spraying is 4 μm；
Wherein, the weight ratio of mill base and texture slurry is 5：95, texture slurry includes following components by weight percentage：It is different
Propyl alcohol 22%, propylene glycol methyl ether acetate 67% and nano silicon dioxide 11%；
It is dry：Baking link is carried out by the way of infrared ray baking, the time of infrared ray baking is 8min, and temperature is
180℃。
Embodiment 7
A kind of surface treatment method of glassware, includes the following steps：
Surface cleaning：First time washing first is carried out to glass using common glass cleaner, then with deionized water pair
Glass carries out second and cleans, and is then dried, spare；
Colouring：Using ready mill base and texture slurry by surface cleaning, treated that glass surface carries out room temperature
It is sprayed under normal pressure, the coating thickness of spraying is 2 μm；
Wherein, the weight ratio of mill base and texture slurry is 10：90, texture slurry includes following components by weight percentage：
Isopropanol 25%, propylene glycol methyl ether acetate 58% and nano silicon dioxide 17%；
It is dry：Baking link is carried out by the way of infrared ray baking, the time of infrared ray baking is 15min, and temperature is
160℃。
Comparative example 1
A kind of surface treatment method of glassware, includes the following steps：Surface cleaning, colouring and drying；
Wherein, used raw material includes mill base and texture slurry during colouring, and texture slurry wraps by weight percentage
Include following components：
Isopropanol 10%, propylene glycol methyl ether acetate 70% and nano silicon dioxide 20%.
As different from Example 1, in this comparative example the content of isopropanol not in content range provided by the present invention.
Comparative example 2
A kind of surface treatment method of glassware, includes the following steps：Surface cleaning, colouring and drying；
Wherein, used raw material includes mill base and texture slurry during colouring, and texture slurry wraps by weight percentage
Include following components：
Isopropanol 8%, propylene glycol methyl ether acetate 85% and nano silicon dioxide 7%.
As different from Example 1, in this comparative example the content of each raw material not in content range provided by the present invention
It is interior.
Comparative example 3-4
A kind of surface treatment method of glassware, with embodiment 4 difference lies in：
The coating thickness of spraying is respectively 0.5 μm and 12 μm.
Comparative example 5-6
A kind of surface treatment method of glassware, with embodiment 4 difference lies in：
The time of infrared ray baking is 10min, and temperature is respectively 150 DEG C and 200 DEG C.
Comparative example 7
A kind of surface treatment method of glassware, using existing lacquer spraying technique, including：
Surface cleaning, spray painting, drying and cooling, wherein it includes wrinkle finish, crackle paint etc. that spray painting, which is pressure spray process novelty finish,.
Performance test
Surface property test is carried out to glassware made from above-described embodiment and comparative example, test result is as shown in table 1.
1 the performance test results of table
Wherein, the test method of gloss is to carry out surface test with glossometer under 60 degree of illumination angles.The survey of adhesion power
Method for testing is the glass sample that will be handled well, and with 3M adhesive tape peel tests, film layer is not damaged；Or after even tearing three times, film layer resistance
Value variation is no more than 10%；Very good is 100%, is well 95%, generally 92%, it is bad for less than or equal to 90%.
The surface treatment method of the present invention, can make the texture of glassware strong, color and luster is bright it can be seen from above
It is beautiful, new appearance is realized, and nontoxic, environmental protection, adhesion is excellent, stable and reliable product quality, improves the competing of product
Strive power.And change the proportioning of each raw material in slurry so that the proportioning of raw material not within the protection scope of the present invention, or changes red
The conditions such as outside line baking, make it not in particular range of the present invention, or use existing lacquer spraying technique, can not achieve above-mentioned
Effect, obtained glassware cannot be satisfied requirement.
Finally it should be noted that：The above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations；To the greatest extent
Present invention has been described in detail with reference to the aforementioned embodiments for pipe, it will be understood by those of ordinary skill in the art that：Its according to
So can with technical scheme described in the above embodiments is modified, either to which part or all technical features into
Row equivalent replacement；And these modifications or replacements, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution
The range of scheme.
Claims (10)
1. a kind of surface treatment method of glassware, which is characterized in that including surface cleaning, colouring and drying；
Wherein, used raw material includes mill base and texture slurry during colouring, and the texture slurry wraps by weight percentage
Include following components：
Isopropanol 20%~30%, propylene glycol methyl ether acetate 50%~70% and nano silicon dioxide 10%~20%.
2. the surface treatment method of glassware according to claim 1, which is characterized in that the texture slurry is by weight
Percentage includes following components：Isopropanol 22%~28%, propylene glycol methyl ether acetate 54%~68% and nano silicon dioxide
10%~18%.
3. the surface treatment method of glassware according to claim 1, which is characterized in that the texture slurry is by weight
Percentage includes following components：Isopropanol 24%~28%, propylene glycol methyl ether acetate 56%~64% and nano silicon dioxide
12%~16%.
4. the surface treatment method of glassware according to claim 1, which is characterized in that the mill base and the texture
The weight ratio of slurry is (12~2)：(88~98), preferably (10~3)：(90~97), further preferably (8~4)：(92
~96).
5. the surface treatment method of glassware according to claim 1, which is characterized in that using spraying, roller coating or leaching
The mode of painting paints to the glassware after surface cleaning, it is preferred to use the mode of spraying.
6. the surface treatment method of glassware according to claim 5, which is characterized in that the coating thickness of spraying is 1
~6 μm, preferably 2~4 μm.
7. according to the surface treatment method of claim 1~6 any one of them glassware, which is characterized in that the surface
The step of cleaning includes：First glass surface is washed using glass cleaner, is then cleaned with clear water, then is done
It is dry.
8. according to the surface treatment method of claim 1~6 any one of them glassware, which is characterized in that the drying
It is chained for baking, the baking link is preferably by the way of infrared ray baking.
9. the surface treatment method of glassware according to claim 8, which is characterized in that infrared ray baking time be
8~15min, temperature are 160~180 DEG C；
Preferably, the time of infrared ray baking is 9~14min, and temperature is 165~175 DEG C.
10. a kind of glassware, which is characterized in that pass through the surface treatment of claim 1~9 any one of them glassware
It is made after method processing.
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