CN106319984B - A kind of aqueous matt canvas of Freehandhand-drawing and preparation method thereof - Google Patents

A kind of aqueous matt canvas of Freehandhand-drawing and preparation method thereof Download PDF

Info

Publication number
CN106319984B
CN106319984B CN201610757500.9A CN201610757500A CN106319984B CN 106319984 B CN106319984 B CN 106319984B CN 201610757500 A CN201610757500 A CN 201610757500A CN 106319984 B CN106319984 B CN 106319984B
Authority
CN
China
Prior art keywords
parts
calendering
baking oven
painting
canvas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201610757500.9A
Other languages
Chinese (zh)
Other versions
CN106319984A (en
Inventor
陈卫宏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Fenghuang painting material technology Co., Ltd
Original Assignee
WUXI PHOENIX DRAWING MATERIALS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WUXI PHOENIX DRAWING MATERIALS CO Ltd filed Critical WUXI PHOENIX DRAWING MATERIALS CO Ltd
Priority to CN201610757500.9A priority Critical patent/CN106319984B/en
Publication of CN106319984A publication Critical patent/CN106319984A/en
Application granted granted Critical
Publication of CN106319984B publication Critical patent/CN106319984B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0036—Polyester fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/042—Acrylic polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0094—Fibrous material being coated on one surface with at least one layer of an inorganic material and at least one layer of a macromolecular material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/04—Vegetal fibres
    • D06N2201/042—Cellulose fibres, e.g. cotton
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/14—Properties of the materials having chemical properties
    • D06N2209/141—Hydrophilic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1642—Hardnes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1671—Resistance to bacteria, mildew, mould, fungi

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

A kind of aqueous matt canvas of Freehandhand-drawing, preparation method include the following steps：(1) gel resin layer material is prepared；(2) base coating material is prepared；(3) topcoat material is prepared；(4) calendering processing first is carried out to fabric, then sprays gel resin layer, baking oven drying is carried out after painting；(5) spraying bottom coating on gel resin layer is dried using baking oven after painting, then carries out heating calendering；(6) finishing coat is sprayed on priming coat, is dried using baking oven after painting, and calendering processing is then carried out.The present invention has reformed traditional hand design canvas material and method for mounting, has opened up the frontier of weaven goods application.

Description

A kind of aqueous matt canvas of Freehandhand-drawing and preparation method thereof
Technical field
The present invention relates to canvas technical fields, more particularly, to a kind of matt canvas for Freehandhand-drawing.
Background technology
Existing Freehandhand-drawing painting canvas, water imbibition is poor, easily turns to be yellow, and is easy wrinkle, it is not easy to preserve, be also not suitable for outdoor suspension, quilt Drenching with rain to attend the meeting makes picture fade.For this reason, it is necessary to improve existing Freehandhand-drawing picture carrier.There is document report in chemical ＆ blended fabric, glass-fiber-fabric Or adhere to the faces PVC on cotton or prepare the production technology of painting canvas using the latex composite compounding of various polymer, or use terylene material Matter scrapes the production technology that PVC coatings prepare similar canvas material with knife.The major defect of this two methods is in base fabric After covering PVC film or imposing on polymer emulsion, effect is smooth, though air brushing painting canvas is can be used as, for Freehandhand-drawing painting canvas, it The skin texture of base fabric itself cannot be embodied, expression effect is greatly reduced.
Invention content
In view of the above-mentioned problems existing in the prior art, the applicant provides a kind of aqueous matt canvas of Freehandhand-drawing and its system Preparation Method.The present invention has reformed traditional hand design canvas material and method for mounting, has opened up the frontier of weaven goods application.
Technical scheme is as follows：
A kind of aqueous matt canvas of Freehandhand-drawing, preparation method include the following steps：
(1) gel resin layer material：By 1~3 part of trimethylolpropane trimethacrylate, 1~2 part of epoxy acrylate is anhydrous 2~3 parts of elder generations of ethyl alcohol uniformly mix, and then with 20~24 parts of acrylic ester adhesive, 20~22 parts of starch, 5~8 parts of alum goes It is stirred evenly after 10~14 parts of mixing of ionized water；
(2) base coating material：By 5~7 parts of silica, 30~32 parts of calcium carbonate, 10~15 parts of titanium dioxide, acrylate 20~23 parts of adhesive, 2~3 parts of brightener stir evenly after 20~25 parts of mixing of deionized water；
(3) topcoat material：By 10~12 parts of calcium carbonate, 20~23 parts of silica, 15~18 parts of deionized water, third 10~13 parts of olefin(e) acid ester adhesive stirs evenly after 4~5 parts of mixing of surfactant；
(4) calendering processing first is carried out to fabric, then sprays gel resin layer, baking oven drying is carried out after painting；
(5) spraying bottom coating on gel resin layer is dried using baking oven after painting, then carries out heating calendering；
(6) finishing coat is sprayed on priming coat, is dried using baking oven after painting, and calendering processing is then carried out；
The number of each raw material is parts by weight.The fabric uses polyester-cotton blend or cotton material.The gel resin layer Thickness be 50~80 μm.The thickness of the priming coat is 100~180 μm.The thickness of the finishing coat is 130~200 μm.
The temperature that three coatings carry out baking oven drying is 100~120 DEG C, fabric pass through the speed of baking oven be 5~ 6 ms/min.The heating temperature of step (5) the heating calendering is 110~120 DEG C, and calendering pressure is 40~45 tons.The step Suddenly the temperature of (6) calendering is 70~80 DEG C, and calendering pressure is 40~45 tons.
The present invention is beneficial to be had technical effect that：
The present invention is especially added with low polymer in coating, with low molecule material alum and brightener, makes painting canvas There is middle layer anti-oxidation efficacy, coating not to allow fugitive color.With low molecule materials silicon dioxide, make canvas coating that there is water suction Property, reach the soaking effect of quick-drying.The present invention is knitted using the novel of technique productions of three sprayings, two hot rollings, one of calendering The divine force that created the universe has the characteristics that Freehandhand-drawing painting canvas and performance；Painting canvas face can also be made smooth；Calendering finishing process is finally used, coating is made In low molecule material reach the maximum value of certain limit, painting canvas soft texture can be made.
Traditional painting canvas, can only draw oil painting, the acrylic painting in west etc., and the aqueous matt canvas of Freehandhand-drawing provided by the invention Soft texture, good water absorption is not fastidious to dilute consistency of pigment, and cloth cover is secured, it is not easy to and jaundice hair wrinkle is suitble to outdoor suspension, With folding crape, mould proof, Anti-moth-eating, anti-deformation, it is non-aging, be easy to mounting, be suitable for industrialized large-scaled production, color stable, have There is many advantages, such as unique texture appearance.
Specific implementation mode
With reference to embodiment, the present invention is specifically described.
Embodiment 1
A kind of aqueous matt canvas of Freehandhand-drawing, preparation method include the following steps：
(1) gel resin layer material：By 2 parts of trimethylolpropane trimethacrylate, 1.5 parts of epoxy acrylate, absolute ethyl alcohol 2.5 parts of elder generations uniformly mix, then with 22 parts of acrylic ester adhesive, 21 parts of starch, 6 parts of alum, after the mixing of 12 parts of deionized water It stirs evenly；
(2) base coating material：By 6 parts of silica, 31 parts of calcium carbonate, 12 parts of titanium dioxide, 21 parts of acrylic ester adhesive, 2.5 parts of brightener stirs evenly after 22 parts of mixing of deionized water；
(3) topcoat material：By 11 parts of calcium carbonate, 22 parts of silica, 17 parts of deionized water, acrylic ester adhesive 12 Part, it is stirred evenly after 4.5 parts of mixing of surfactant；
(4) calendering processing first is carried out to cotton fabric, then sprays gel resin layer, baking oven drying is carried out after painting, gel resin layer Thickness is 60 μm；The temperature of drying is 110 DEG C, and it is 5.5 ms/min that fabric, which passes through the speed of baking oven,；
(5) thickness of the spraying bottom coating on gel resin layer, priming coat is 150 μm；It is dried using baking oven after painting, the temperature of drying Degree is 120 DEG C, and it is 5 ms/min that fabric, which passes through the speed of baking oven,；Then heating calendering is carried out；Heat the heating temperature of calendering It it is 120 DEG C, calendering pressure is 40 tons；
(6) finishing coat is sprayed on priming coat, the thickness of finishing coat is 180 μm；It is dried using baking oven after painting, the temperature of drying Degree is 100 DEG C, and it is 6 ms/min that fabric, which passes through the speed of baking oven,；Then calendering processing is carried out；The temperature of calendering is 75 DEG C, is rolled Light pressure is 42 tons.
The number of each raw material is parts by weight.
Embodiment 2
A kind of aqueous matt canvas of Freehandhand-drawing, preparation method include the following steps：
(1) gel resin layer material：By 1~3 part of trimethylolpropane trimethacrylate, 1 part of epoxy acrylate, absolute ethyl alcohol 2 parts of elder generations uniformly mix, and then with 20 parts of acrylic ester adhesive, 20 parts of starch, 5 parts of alum stirs after the mixing of 10 parts of deionized water It mixes uniformly；
(2) base coating material：By 5 parts of silica, 30 parts of calcium carbonate, 10 parts of titanium dioxide, 20 parts of acrylic ester adhesive, 2 parts of brightener stirs evenly after 20 parts of mixing of deionized water；
(3) topcoat material：By 10 parts of calcium carbonate, 20 parts of silica, 15 parts of deionized water, acrylic ester adhesive 10 Part, it is stirred evenly after 4 parts of mixing of surfactant；
(4) calendering processing first is carried out to polyester-cotton blend fabric, then sprays gel resin layer, baking oven drying is carried out after painting, gel resin layer Thickness is 50 μm；The temperature of drying is 110 DEG C, and it is 6 ms/min that fabric, which passes through the speed of baking oven,；
(5) thickness of the spraying bottom coating on gel resin layer, priming coat is 100 μm；It is dried using baking oven after painting, the temperature of drying Degree is 100 DEG C, and it is 5 ms/min that fabric, which passes through the speed of baking oven,；Then heating calendering is carried out；Heat the heating temperature of calendering It it is 110 DEG C, calendering pressure is 45 tons；
(6) finishing coat is sprayed on priming coat, the thickness of finishing coat is 130 μm；It is dried using baking oven after painting, the temperature of drying Degree is 100 DEG C, and it is 5 ms/min that fabric, which passes through the speed of baking oven,；Then calendering processing is carried out；The temperature of calendering is 70 DEG C, is rolled Light pressure is 45 tons.
The number of each raw material is parts by weight.
Embodiment 3
A kind of aqueous matt canvas of Freehandhand-drawing, preparation method include the following steps：
(1) gel resin layer material：By 3 parts of trimethylolpropane trimethacrylate, 2 parts of epoxy acrylate, 3 parts of absolute ethyl alcohol First uniformly mixing, then with 24 parts of acrylic ester adhesive, 22 parts of starch, 8 parts of alum stirs after the mixing of 14 parts of deionized water Uniformly；
(2) base coating material：By 7 parts of silica, 32 parts of calcium carbonate, 15 parts of titanium dioxide, 23 parts of acrylic ester adhesive, 3 parts of brightener stirs evenly after 25 parts of mixing of deionized water；
(3) topcoat material：By 12 parts of calcium carbonate, 23 parts of silica, 18 parts of deionized water, acrylic ester adhesive 13 Part, it is stirred evenly after 5 parts of mixing of surfactant；
(4) calendering processing first is carried out to cotton fabric, then sprays gel resin layer, baking oven drying is carried out after painting, gel resin layer Thickness is 80 μm；The temperature of drying is 120 DEG C, and it is 5 ms/min that fabric, which passes through the speed of baking oven,；
(5) thickness of the spraying bottom coating on gel resin layer, priming coat is 180 μm；It is dried using baking oven after painting, the temperature of drying Degree is 120 DEG C, and it is 5 ms/min that fabric, which passes through the speed of baking oven,；Then heating calendering is carried out；Heat the heating temperature of calendering It it is 120 DEG C, calendering pressure is 40 tons；
(6) finishing coat is sprayed on priming coat, the thickness of finishing coat is 200 μm；It is dried using baking oven after painting, the temperature of drying Degree is 120 DEG C, and it is 6 ms/min that fabric, which passes through the speed of baking oven,；Then calendering processing is carried out；The temperature of calendering is 80 DEG C, is rolled Light pressure is 40 tons.
The number of each raw material is parts by weight.
Test case 1 carries out surface observation to painting canvas：
(1) visual effect：Painting canvas surface is clean and tidy, and longitude and latitude lines is clear, shows textural effect, and apparent colour is that white is sub- Light.Environment head-up painting canvas surface indoors, it is matt.
(2) sense of touch：Feel painting canvas longitude and latitude train of thought is clear, and painting canvas is flexible, and smoothness is moderate, there is certain resistance when streaking painting canvas Power, but it is not unsmooth, there is heavy feeling.
Test case 2 carries out physicochemical property detection to painting canvas：Detection method and the results are shown in Table 1.
Table 1
Test case 3, practical effect：
(1) this painting canvas is used as Freehandhand-drawing painting canvas, compared with rub resistance and modification.The strong adhesive force of coating, repeatedly friction coatings do not take off It falls.
(2) pigment and the adhesive force on painting canvas surface are also fine, if drawing very thick pigment on painting canvas surface, wait after having done Pigment is difficult to peel off, i.e., pigment will not fall off after people draw a picture, and has ensured that the quality drawn (uses propylene oil painting etc. for artist The performance test that pigment is drawn a picture shows).
(3) for this painting canvas to propylene, the effect of watercolor, gouache color is relatively good, painting canvas good water absorption, to dilute consistency of pigment It is not fastidious.These three pigment can be watered in various degree when drawing a picture.
(4) painting canvas stability itself is good, will not change colour and turn to be yellow for a long time after applying paint, 40 can be kept under sunlight It does not turn yellow (due to being Freehandhand-drawing painting canvas, works generally preserve indoors, so to the of less demanding of UV resistant).

Claims (3)

1. a kind of aqueous matt canvas of Freehandhand-drawing, it is characterised in that preparation method includes the following steps：
(1) gel resin layer material：By 1~3 part of trimethylolpropane trimethacrylate, 1~2 part of epoxy acrylate, absolute ethyl alcohol 2 ~3 parts of elder generations uniformly mix, then with 20~24 parts of acrylic ester adhesive, 20~22 parts of starch, 5~8 parts of alum, deionized water It is stirred evenly after 10~14 parts of mixing；
(2) base coating material：By 5~7 parts of silica, 30~32 parts of calcium carbonate, 10~15 parts of titanium dioxide, acrylate adhesion 20~23 parts of agent, 2~3 parts of brightener stir evenly after 20~25 parts of mixing of deionized water；
(3) topcoat material：By 10~12 parts of calcium carbonate, 20~23 parts of silica, 15~18 parts of deionized water, acrylate 10~13 parts of adhesive stirs evenly after 4~5 parts of mixing of surfactant；
(4) calendering processing first is carried out to fabric, then sprays gel resin layer, baking oven drying is carried out after painting；
(5) spraying bottom coating on gel resin layer is dried using baking oven after painting, then carries out heating calendering；
(6) finishing coat is sprayed on priming coat, is dried using baking oven after painting, and calendering processing is then carried out；
The number of each raw material is parts by weight；
The thickness of the gel resin layer is 50~80 μm；
The thickness of the priming coat is 100~180 μm；
The thickness of the finishing coat is 130~200 μm；
The heating temperature of step (5) the heating calendering is 110~120 DEG C, and calendering pressure is 40~45 tons；
The temperature of step (6) calendering is 70~80 DEG C, and calendering pressure is 40~45 tons.
2. the aqueous matt canvas of Freehandhand-drawing according to claim 1, it is characterised in that the fabric is using polyester-cotton blend or entirely Cotton material.
3. the aqueous matt canvas of Freehandhand-drawing according to claim 1, it is characterised in that three coatings carry out baking oven baking Dry temperature is 100~120 DEG C, and it is 5~6 ms/min that fabric, which passes through the speed of baking oven,.
CN201610757500.9A 2016-08-27 2016-08-27 A kind of aqueous matt canvas of Freehandhand-drawing and preparation method thereof Active CN106319984B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610757500.9A CN106319984B (en) 2016-08-27 2016-08-27 A kind of aqueous matt canvas of Freehandhand-drawing and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610757500.9A CN106319984B (en) 2016-08-27 2016-08-27 A kind of aqueous matt canvas of Freehandhand-drawing and preparation method thereof

Publications (2)

Publication Number Publication Date
CN106319984A CN106319984A (en) 2017-01-11
CN106319984B true CN106319984B (en) 2018-10-09

Family

ID=57789005

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610757500.9A Active CN106319984B (en) 2016-08-27 2016-08-27 A kind of aqueous matt canvas of Freehandhand-drawing and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106319984B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109403053B (en) * 2018-09-18 2021-08-17 上官星 Rapid high-oil-absorption canvas
CN109826017A (en) * 2019-02-14 2019-05-31 王景朋 A kind of preparation method of high-quality Freehandhand-drawing canvas
CN110743763A (en) * 2019-10-28 2020-02-04 浙江美欣达纺织印染科技有限公司 Washable high-fastness leather film coating treatment process for cotton fabric
US20220220665A1 (en) * 2021-01-11 2022-07-14 Taya Canvas (Shanghai) Company Ltd Textile structure
CN115247380A (en) * 2022-05-30 2022-10-28 江苏凤凰画材科技股份有限公司 Bronzing canvas and preparation method thereof
CN115125738B (en) * 2022-05-31 2023-07-25 江苏凤凰画材科技股份有限公司 Preparation method of Tang-Ka canvas

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4971651B2 (en) * 2006-03-01 2012-07-11 関西ペイント株式会社 Water-based colorful pattern paint and painting method
CN100368624C (en) * 2006-05-28 2008-02-13 宋健 Art canvas with non-filler polyvinyl built coating and its production process
CN102555655A (en) * 2011-12-21 2012-07-11 无锡凤凰画材有限公司 Method for processing colorful canvas
CN102555656A (en) * 2011-12-21 2012-07-11 无锡凤凰画材有限公司 Processing method of pearly-lustre canvas
CN102582351B (en) * 2011-12-26 2014-04-09 无锡凤凰画材有限公司 Crack canvas processing method
CN102587122A (en) * 2011-12-26 2012-07-18 无锡凤凰画材有限公司 Method for processing wash painting cloth
CN104862966B (en) * 2015-05-04 2016-08-17 江苏耐斯数码科技股份有限公司 A kind of wide cut flame retardant oil painting canvas and preparation method thereof
CN106120360A (en) * 2016-08-27 2016-11-16 无锡凤凰画材有限公司 A kind of Freehandhand-drawing oiliness semigloss oil painting canvas

Also Published As

Publication number Publication date
CN106319984A (en) 2017-01-11

Similar Documents

Publication Publication Date Title
CN106319984B (en) A kind of aqueous matt canvas of Freehandhand-drawing and preparation method thereof
CN106120360A (en) A kind of Freehandhand-drawing oiliness semigloss oil painting canvas
CN101157812B (en) Aqueous texture wallpaper paint and method for making same
CN104073112B (en) Heat-insulative light extinction aqueous coating composition and method for forming heat-insulative light extinction coating
CN105755800B (en) A kind of heat-reflective coating cloth
CN105219249B (en) A kind of smooth reflective heat-insulation paint
CN106478861B (en) A kind of modified aqueous acrylic acid resin and the method for preparing artificial color sand using it
CN103774434B (en) The three-dimensional painting canvas of ripple
TWI328601B (en)
CN109233508A (en) Water-water imitation marble paint and its preparation method and application
CN106747195A (en) High adsorption rate kieselguhr wall material and its preparation and construction method
CN109400012A (en) A kind of priming paint and the middle imitative clear-water concrete and preparation method thereof for applying unification
CN109370334A (en) A kind of insulating moulding coating and preparation method thereof for aqueous acrylamide acid type finishing coat
CN107964312A (en) A kind of art coatings of imitative cotton clothes' feel and preparation method thereof
CN104877571B (en) The cream-coloured stone coating of the imitative Germany of one kind and its construction technology
CN105131755B (en) A kind of preparation method of the self-crosslinking true mineral varnish of liquid sliver
CN104499286A (en) Leatherware repair agent
CN103981717A (en) Rope head provided with coating and preparation method of rope head
CN104213431B (en) A kind of preparation method of waterproof artificial leather
CN108505348A (en) A kind of gum waterproof air brushing canvas and its production method
CN108610771A (en) A kind of chalk slurry and its application process in wallpaper
CN107142737A (en) A kind of superfine fibre upper leather and preparation method thereof
CN110512812A (en) A kind of building decoration flexibility imitation stone patch and preparation method
CN109957271A (en) Fast light, water soluble acrylic acid esters resin coating that film forming is fast and preparation method thereof
CN108948908A (en) A kind of foaming jet drawing material and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CP01 Change in the name or title of a patent holder
CP01 Change in the name or title of a patent holder

Address after: 214131, Wuxi, Jiangsu province Binhu District, China Town, Suzhou Tin Road West Dragon Industrial Park

Patentee after: Jiangsu Fenghuang painting material technology Co., Ltd

Address before: 214131, Wuxi, Jiangsu province Binhu District, China Town, Suzhou Tin Road West Dragon Industrial Park

Patentee before: Wuxi Phoenix Drawing Materials Co.,Ltd

CP02 Change in the address of a patent holder
CP02 Change in the address of a patent holder

Address after: 214000 No.2 Huayuan Road, Binhu District, Wuxi City, Jiangsu Province

Patentee after: Jiangsu Fenghuang painting material technology Co., Ltd

Address before: 214131, Wuxi, Jiangsu province Binhu District, China Town, Suzhou Tin Road West Dragon Industrial Park

Patentee before: Jiangsu Fenghuang painting material technology Co., Ltd